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Waterbalance and Source of Wastewater in Sugar Mill & Refinery
Waterbalance and Source of Wastewater in Sugar Mill & Refinery
OBJECTIVES
To present the water balance of a typical raw sugar factory and refinery.
To discuss some considerations and recommendations for the efficient use of water in
a sugar factory and present various applicable technologies.
The over-all amount of water on earth has remained the same for about two billion
years since the earth was formed.
Of all the water on earth, only 2.5% is fresh water. Fresh water is either groundwater
(0.5%) or readily accessible water in lakes, streams, rivers, etc. (0.01%)
Less than 1% of the water supply on earth can be used as drinking water.
More than 2 billion people on earth do not have a safe supply of water.
It takes 7,000 liters (1,850 gal.) of water to refine one barrel of crude oil.
Conventionally, it takes 240-290 gal. (910-1,100 ltr.) of water to produce one Lkg of
raw sugar; but if managed well, it will take only 1-10 gallons.
WATER MANAGEMENT
*/
Nature's management of water is based on recycling and this principle should form the
basis of water management in the sugar industry.
Roughly 40% of the water entering in the cane is surplus. The more energy efficient a
factory is, the larger is the surplus water produced.
WATER MANAGEMENT
FACTS:
Sugarcane carries its own fuel and water to enable its processing.
The process of sugar manufacture has no step wherein any liquid effluent must be
generated and discharged.
Pollution control laws now demand treatment of the plants effluents to strictly
conform to the pollution tolerance limits before disposal.
User fee or levy for the use of water will soon be imposed and this will increase input
costs.
Extra/ undesirable/ unnecessary use of water in the process results in: loss of heat
energy; input of salts and impurities through raw water is partly responsible for scale
formation in heat exchangers and melassegenic effects in exhaustion; extra energy
input is required for pumping; loss of sugar by dissolution in water and generation of
effluent.
Work the plant on cane water, i.e. water brought in through sugarcane.
Minimize the use of ground/ surface water for the plant consumption.
WATER REQUIREMENT
A conventional Raw Sugar Factory will require about 2.1 to 2.8 cu.m/ ton cane
For a 5000 TCD factory this is about 440 cu.m. /hr. to 580 cu.m./hr.
A 5000 TCD factory can manage to work with only 20 cu.m. /hr. water being put into
its water system.
Table2EnergyUsage
Cane sugar refining
TABLE 1
(1)
(2)
Electricity
(a)
A typical refinery : 75 kWh/ton raw sugar
(b)
A modern refinery : 4 5 kWh/ton raw sugar
(3)
Wa t e r
(a) A typical refinery : 150% of raw sugar
(b) A modern refinery : 50% of raw sugar
Year
Fuel
kg / t
Water
mt / t
Power
kw hr / t
Steam
kg / t
1997
77
382
121.64
938
1998
67
366
83.84
720
1999
47
245
72.588
597
2000
44
252
58.43
680
2001
48
281
61.38
635
2002
48
188
51.38
638
2003
47
179
58.186
645
2004
37
154
48.4
604
Definition of Terms
External water: water entering the factory, other than water contained in the cane (i.e.
service or filtered water)
Service cooling system: vacuum, crystallizer and bearing cooling water circuits
Process water: any source of water produced by factory operations (i.e. excludes
external water and water from the service cooling systems).
SATURATED
BOILER GASES
EVAPORATION
AT MILLS
SERVICE
WATER
FACTORY
CANE
BAGASSE
BOILERS
WET ASH
& SMUTS
EVAPORATION
MOLASSES
DRIFT
LOSS
COOLING
TOWERS/
POND
FILTER
CAKE
BOILER
BLOWDOWN
SURPLUS
CONDENSATE
SYSTEM
OVERFLOW
Over-all Balance
Roughly 40% of the water entering the cane is surplus which will find its way out of the
mill in an effluent stream.
Water enters the mill as constituents of sugarcane and part of it goes out in the bagasse.
Water Losses
Water in the raw juice is lost through filter cake, pan and evaporator condensers, final
molasses, sugar and boiler blowdowns.
Other losses are in the cooling tower or spray pond overflow and drift loss (typically
5% of the water flow in the cooling system) and water in the boiler smuts.
Evaporation Losses
Evaporation occurs from certain process streams and during juice flashing.
Part of the water condensed in condensers will evaporate in the cooling towers or spray
ponds to provide the evaporative cooling required. As much as 85% of the vapor
condensed evaporates to provide the cooling.
SUGARFACTORYWATERBALANCE
Factory: Amatikulu
WATER IN
WATER OUT
Tons/hr.
In Cane:
420
15.3
16.1
Tons cane/hr
Fibre % cane
Brix % cane
Softened water to boilers
Tons/hr
In bagasse to boilers:
288.1
71.1
Moist % bagasse
Brix % bagasse
51.8
1.4
9.5
In filter cake:
Cake % cane
Moisture % cake
Raw water into factory
3
75
0
3.5
In molasses:
3.8
78
Molasses % cane
DS % molasses
4.2
Boiler blowdown:
5.9
Steam % cane
HP Steam produced
Blowdown % steam
55.9
234.8
2.5
2.7
4.4
In boiler smuts
Smuts % cane
Moist % smuts
1.5
70
1.6
66
Evaporation
Pan evaporation
Jigger steam
Final effect evaporation
inj water tempsin
out
inj water flow to mill
inj water flow from mill
42.3
1.1
34.2
33
47.7
3125
3201
23.5
288.1
Total
Total
TOTAL SURPLUS
192.3
95.8
FACTORYWATERSYSTEM
Evaporation
Flash
MILLS
CLARIFICATION
FEED
WATER
STORAGE
PAN HOUSE
EVAPORATION
Filter
Wash Water
Imbibition
High Quality
Condensate
Condensate
Process
Water
Evaporation
LIME
PLANT
FLOCCULANT
MAKE-UP
CONDENSATE
FOR
PROCESS
USE
PROCESS
COOLING
TOWERS
Drift Less
Evaporation
Evaporation
Emergency
Make-up
Drift Less
BOILERS
Make-up
Blow Down
LOW QUALITY
SERVICE
WATER SYSTEM
SERVICE
COOLING
TOWERS
BOILERS
SCRUBBERS
External
Suppy
Over Flow
The quantity of condensate is much larger than the amount required in the boilers.
Within the factory, condensate is recycled as boiler feed water and as process water.
The best quality condensate is used for boiler feed water (usually the exhaust
condensate from the first effect evaporator and the second effect vapor condensate.
CONDENSATE
In evaporators and pans, the condensing steam is at higher pressure than the liquid
being boiled.
In juice heaters the pressure of the liquid in the tubes is higher than that on the steam
side. Heater condensate should generally not be used for boiler feed water.
STEAM CONDENSATE BALANCE SHEET 7,000 TCD MILLING RATE
STEAM
GENERATION
Boiler
Capacity
Mill
1
453.074
% Gen
80.00%
Steam
Gen
362.459
EXHAUST
AVAILABLE
No.
of
unit
1.00
Power
(Hp)
Steam
(lb/hr)
Water
Rate
500.00
12,982
25.96
EXHAUST
CONSUMER
Exhaust
(lb/hr)
12,333
Equipt
CONDENSATE
Exhaust
(lb/hr)
3rd Heater
28,545
For Boiler
Equipt
(lb/hr)
Equipt
1st Evap
215,137
3 Evap
nd
(lb/hr)
rd
105,645
th
1.00
800.00
25.96
20,772
19,733
Pans
53,295
2 Evap
133,574
4 Evap
105,645
Shredder
1.00
2,800.00
25.96
72,701
69,066
Evaporator
248,320
50% Pans
53,295
50% Pans
53,295
Mill Drive
5.00
650.00
25.96
84,385
80,165
Misc (5%)
16,508
1st Heater
27,929
nd
Power
House
5 MWTG
1.00
2.5 MWTG
2.00
4500*
26.49
159,819
2 Heater
28,268
3rd Heater
28,545
Total
349,326
151,828
STAND BY
Boiling
House
Make-up
for Exhaust
Total
11,801
362,459
333,125
Total
346,668
Total
402,006
*Power in
EXHAUST BALANCE
Exhaust available for process
333,125 lb/hr
BAGASSE BALANCE
Bagasse from cane
99.43 ton/hr
Blowdown 5%
346,668 lb/hr
13,544 lb/hr
6
ton/hr
4%
1,090
19,077 lb/hr
76.36
ton/hr
381,536 lb/hr
Excess Bagasse
23.07
ton/hr
402,006 lb/hr
20,470 lb/hr
lb/TC
20
15
30
10
>40
Nil
20
40
60
80
10
20
0.5
Not
Detectable
8.5-9.5
8.5-9.5
8.5-9.5
8.5-9.5
0.05
0.02
0.01
0.005
0.02
0.02
pH value
Oxygen (mg/l as O2 max.
Iron+ copper + nickel+ (mg/l)
Not applicable
Oil
Not detectable
Basis
for Estimation
3
Total Requirement
3
m /hr
1.
Mill
Turbines
and
reduction
gear oil
cooling
6.8% m /hr
for each
turbine (as
per rating)
28.00
2.
Cooling
of mill bearing
18.00
3.
Turbine and
reduction gear
cooling
18 m /hr
(as per makers
manual)
18.00
4.
Cooling
3.5
5.
Sulphitation Station
(i) 4 Nos. sulfur furnace of
continuous type (2 working)
(ii) Two electrically driven
water cooler air com3
pressor of 500 m /hr
3
and 250 m /hr respectively
(a) Water
cooling jacket
(b) Scrubber for
cooling
-
2.0 m per
jacket
3
0.35 m per
house (estimated)
(as per makers
manual)
4.0
7.0
3.5
6.
7.
for cooling
C massecuites
0.8 m of cold
water per ton
of massecuite
10.80
8.
Centrifugals: 15 Nos.
Centrifugals of Robert's
design of 450 kg/ charge
capacity
For cooling of
brake drum
32.20
9.
For gland
cooling, etc.
Estimated
3.15
TOTAL
129.50
b.
10.80
TABLE 2
Purpose
Basis
of estimation
Water Temp.
preferred
1.
Imbibition
23% on cane
Hot 73 C
2.
Make up water
for boiler
5% of total
generation
Hot
3.30
3.
Milk of lime
(by volume)
1.2% cane
Hot
1.50
4.
Hot
10.80
5.
At pans
5% on cane
Hot
6.50
Qty. of require3
ment in m /hr
23.60
6.
Make up water
for condensing
system
3% loss on
evaporation and 2%
windage loss i.e. 5%
of total spray capacity
of 9 lakh gph
Cold
202.50*
7.
Cleaning and
washing
Estimated
9.00
Cold
3.85
at 20 gallons
per head
by actual measurement
19.80
-
9.00
Total
87.25
Boilers. Taking the total steam requirement as 450 kg/t.c. and expressing the capacity of the factory in tch as
A. Water for the boiler must be assumed as 10-15 %, normally 10%. We have then
0.05A
0.060 x 1.5
0.09A
0.040 x 1.5
0.06A
0.02A
0.30A
Water at centrifugals
0.01A
0.20A
0.30A
0.04A
0.20A
1.27A
Guidelines/ Suitable Designs of a Closed Water Circuit System (Mangal Singh, 1994)
Evaporator station with multiple bleeding of vapors for vacuum pan use, juice heating by
VLIH and by vapors bled from the evaporator bodies.
Boiler feed water requirements being met by condensates from the pre-evaporator and 1st and
2nd bodies of the evaporators with arrangements of surplus storage and pumping back.
Classification, collection and recycling of condensates for various process requirements and
steam generation.
Centralized collection of all hot condensates other than those for boiler use in an overhead
collection tank providing for draw down lines incorporating preferential distribution system
to various consumption points, e.g. lime slaking, cake washing, centrifugals and magmas,
pans and maceration, etc.
Provision in the central collection tank of raw water make-up to meet deficiencies if any, and
its automated working with tank level control and resultant removal of parallel cold water
lines from the process house or no provision thereof in case of new installations.
Closed circuit of hot water for heating of massecuites in crystallizers and pugmills with
provision of heating the water in circulation with thermostatic temperature control.
Arrangements for collection of all cooling waters in a suitably sized masonry or steel tank
which could also be designed to effect cooling as well as receiving the make-up water from
the raw water source, as well as arrangement for collection of boiler and feed water tank
overflows with provisions of pumping back when required and collection of surplus hot
water from the overflow of the overhead hot water tank and its being pumped for maceration
and/or back to the overhead tank for make-ups when required.
Designing/lay-out of the boiling/ centrifugal house floor and drains to enable collection of
spillages, leaks and washings for pumping back to the process.
Reclaiming continuously the condensates from the VLIH whether in operation or not and
diverting it to maceration.
Arrangement to divert the lime house and grit washings into the condenser water channel to
reclaim both the water and residual lime which helps to make up the condenser water pH.
All mills will have a surplus of water to dispose of. Disposal methods:
1. Fert-irrigation effluent diluted with irrigation water
2. Ponding system surplus water is contained during the crushing season and
treated during the off-season.
In all other cases, the surplus has to be treated before it can either be re-used or
returned to the watercourse. Attempts should be made to reduce the quantity and the
concentration of dissolved substances in the effluent.
Treatment Methods
Aerobic treatment
Anaerobic treatment
Recovery of leaks/ spillages
Cleaning
Distillery slops concentration and incineration
Disposal of Slops
The sludge from Fermentation could be fed into the boiler, by mixing with slops or mixing
with the supplementary fuel.
The ash from the boiler is a source of potash and could be a field nutrient.
The condensate from the Slops Evaporation plant and spent lees treated in a RO plant and
the permeate used for molasses dilution or for Cooling tower make up. RO Reject taken to
slops concentration plant.
The blow down from cooling tower and boiler (harmless effluents) are cooled and taken to
sugar plant's effluent treatment plant.
As defined is one where all surplus water leaving the factory meets the general discharge
standards, without requiring conventional downstream effluent treatment. It does not mean
that the factory has no exit water stream, as the water balance of any cane sugar factory
results in a water excess due to the high water content in cane.
Imbibition Tank
Imbibition Tank
Process C. Towers
Process C. Towers
Service C. Towers
Service C. Towers
Flocculant & Lime
Service
Water
Effluent
Overflows & Leaks
Surplus
Water
Service
Water
Evaporators
Evaporators
General Cleaning
General Cleaning
Fire System
Fire System
Stormwater Drains
2A
R
e
c
y
c
l
e
Stormwater Drains
2B
Eliminate water usage where possible. (e.g. water- cooler air compressors were replaced
with air-cooled compressors.
Substitute external water with a process water stream of the minimum required quality.
Substitute condensate with lower quality process water where appropriate. (This increases
the amount of condensate available for users which require high quality water.)
Monitor the use and availability of process water throughout the factory to ensure that
factory users have an adequate supply of water at all times. Flowmeters are used to monitor
water usage; and level transmitters, on storage tanks/sumps, are used to monitor water
availability. Sufficient storage capacity or some form of make-up facility is provided for
each source of process water, such that unsteady operating conditions are catered for.
APPLIED TECHNOLOGIES
ADVANTAGE
Reduction of steam consumption by 2-5%.
Centralized System of condensate r emoval without
pumps.
No level and control valves required.
Exhaust condensate heat recovery without any
contamination.
Light weight Stainless Steel Design.
Reduces Final condensate temperature to
DC
SC
MULTI-JET CONDENSER
MULTI-JET with
CONTROL VALVES
MIXED JUICE
FROM MILL
MIXED JUICE TO
HEATER STATION
SEALING
WATER
VACUUM LINE
JUICE
HEATER
LAST CELL
EVAPORATOR
VAPOR
CONDENSATE
SEPARATOR
CONDENSATE TO
SEALING TANK
BAROMETRIC
CONDENSER
RANGE
260-280
32-38
50-55
60-63
4.8-9.9
AVE.
270
35
52
62
6.1
Feed
Temperatu
re
Gauge
Feed
Pressu
re
Gauge
TYPICAL RO SYSTEM
Pump
Low
Suction Suction
Pressu Pressu
re
re
Gauge Switch
Chemic
al
Addition
5 - 10
Filter
Feed
Pressure
Control Valve
High
Pressure
Pump
Reverse Osmosis
Membrane
Elements
Pressure
Vessel
Permeate
Flow
Concentra
Flo te
Pressurew
Gauge
RO
PuF
meped
Discharge
Feedwater
Sampling
Point
Flow
Indicator
Concentrate
Sampling
Point
Combined
Permeate
Sampling Point
Brin
e
Flow
Indicator
Concentrat
e Sampling
Valve
Permeate
Flow
Permeate to Drain
Flow
to Point of
Use
WATER USAGE
Take 100 kg of 65 brix sugar liquor:
(a) Water needed is 35 kg per 65 kg of raw sugar
(b) Water to be recovered by surface condenser is 21.7 kg
(c) Total water needed % raw sugar:
= (35-21.7) x 100/65 = 20.5%
Climate change caused by both natural events (like volcanic eruptions) and human
activities (Greenhouse gas emissions)
1.0
0.8
0.6
Smooth Curve
0.4
Annual values
0.2
0.0
-0.2
-0.4
1860
1880
1900
1920
1940
Year
Sea ice
1960
1980
2000
SUN
ATMOSPHERE
Some of the
infrared radiation
is absorbed and
re-emitted by the
greenhouse
gases. The effect
of this is to warm
the surface and
the lower
atmosphere.
Solar
radiation
passes
through the
clear
atmosphere.
Most radiation is
absorbed by the
Earths surface
and warms it.
EARTH
Transportation
Energy Generation
Industrial Processes
Land Use:
Agriculture & Forestry
Infrared radiation
is emitted from the
Earths surface.
Coastal Areas:
Erosion and flooding
Inundation
Change in wetlands
Water Resources:
Changes in water supply
and water quality
Competition/Trans-border
Issues
Forests: Change in
Ecologies, Geographic range
of species, and
Health and productivity
Human Health:
Weather related
mortality
Infectious disease Air
quality - respiratory
illness
Industry and
Energy: Changes
in Energy demand
Product demand &
Supply
Global-Mean Temperatures
1.0
0.8
0.6
Smooth Curve
0.4
Annual values
0.2
0.0
-0.2
-0.4
1860
1880
1900
1920
1940
1960
1980
2000
Year
SAVE WATER
THE WORLD
IS IN
YOUR HANDS