Islamic University of Gaza

Faculty of Science / Chemistry

Org final 2000.doc

Organic Exam
Time 2 hours
11.1.2000

60

Name .St. No.

1)
(
(
(
(
(
(
(
(

Indicate if the following statements are true ( ) or false ( X)

)
)
)
)
)
)
)
)

12345678-

phenoles are stronger acids than alcohols.

SN2 mechanism is a one-step process.
SN2 reactions proceed with inversion plus racemization.
The rate of SN1 reactions depend on the concentration of the nucleophile.
Tertiary alcohols react slowly with alkyl halides.
Grignard reagent is best prepared in ethanol as a solvent.
The carbonyl carbon has a tetrahedral geometry.
Electron withdrawing groups enhance acidity of carboxylic acids.

2)

20

Name the following compounds

OH

CH3
H3C

OMe

O
CH3

CH3-C-O-CH2-CH3

CH3-N-C-H
CH3

Br
CH3-NH-CH2-CH2-OH

CH3-CH-CH-CO2H
O

3)

Complete the following equations

CH3

1) H3C

heat

OH

major product
Br

2)

10

H+

CH2CH3

Mg / ether

CH2-CH2-CH-CH3

D2 O

Ph

3)

CH3CH2OCH(CH3)2

4)

CH3CH2CH2OH

HI

heat

CrO3 / H+

1) CH3MgBr

5)

O
2) H2O
Acetyl chloride
CH3

6) H3C

CH2CH3
NH2

7)

Aceton

CH = CH - CH-CH2O

NaBH4

Ph
O
H

8)

9) CH2O

+ NH2OH.HCl
O
CH3 - C - CH3

NaOH

base

CH2CH2CH3
10)

KMnO4
Heat