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Stator Water System
Stator Water System
diagnosing,
monitoring &
addressing leakage
and pluggage
in water - cooled
generator stator
windings
A.K.Sahay, CC-OS
B.Manjul, Kahalgaon
V.K.Garg, Badarpur
Crevice corrosion :
Due to spongy nature of braze, water makes its way
to small voids at braze surface and stagnates
If the void size is large enough, sizable amount of
water comes in and start attacking the phosphorous
rich phase of braze alloy.
As the material starts , void size goes on increasing
and water chemistry changes to phosphoric acid.
This process continues till the crevice reaches
critical volume, thereby precipitating out Phosphate
salt( Cu3P)on the surface of the braze which stops
further corrosion.
Importance
Frequency of monitoring
Most important
Continuous
Useful
Continuous
promising technology Continuous
Critical parameter
Continuous
Critical parameter
Continuous
Important information Continuous
Important parameter Continuous
Important parameter
Daily
indicative information
Daily
Laboratory Analysis:
Copper Concentration Limited usefulness
Once in two week
Copper in ion exchange Good indicative
At each resin change
or filter
information
Conductivity
Conductivity is temperature dependent.
e.g. Conductivity of pure DM water at 25 Deg C= 0.054
us/cm, while that at 60 deg C= 0.25 us/cm
Dissolved Oxygen
Measurement of DO in stator water affords valuable
information about hydrogen leakage through stator
Tiny H2 leakage- non-detectable through H2 gas trap or
consumption pattern- leads to lowering of DO content
of Stator water
Unit A
Date
29.01.08
15.02.08
DO ppm
3.8 ppm
0.4 ppm
Remark
Conductor leakage confirmed
27.12.09
22.01.10
5.8 ppm
0.5 ppm
Unit B
Size of leakage :
-
22.05.09
1.3 ( after stopping make up for 5 hrs)
17.05.09
4.2 ppm
14.04.09
3.8
QuantificationFrom gas trap in a 200mw set with PSW operating at 300 mm vacuum in the expansion tank.
Suppose the make up water has 8 ppm of dissolved oxygen(D.O.) and PSW temperature is 40 0
C
Henrys law , P = X . H
Where P = Partial pressure of O2 in ata
X = Amount of dissolved oxygen in ppm
H = Henrys law constant for O2 at 40 0 C (3.01 x 0.01 )
P = 8 x 3.01.0.01 = 0.24 ata
E.g. let
In this case total volume of H2 gas leaking through PSW system per day
= 0.11 x 0.027 x 24 = 0.0324 M 3
( Flow of PSW of a 200 MW set is 27 M3/hr)
of H2 gas /day
<223 mv
>266 mv
>315 mv
<305 mv
For test of 16 days, stator water was alkalized with NaOH to pH=8.7
ECP drops from 252 mv to 69 mv, then it drifted slowly upward.
Towards the end ECP trends upward despite constant pH
Cleaning by EDTA
Before Cleaning
After cleaning
Preventing Pluggage :
(a)
( b)
(c)
(d)
Conclusion :
-