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8 Absorber Design
8 Absorber Design
CHAPTER No.8
DESIGN OF ABSORBER
8.1 ABSORPTION
The removal of one or more component from the mixture of gases by using a
suitable solvent is second major operation of Chemical Engineering that based on mass
transfer.
In gas absorption a soluble vapors are more or less absorbed in the solvent from its
mixture with inert gas. The purpose of such gas scrubbing operations may be any of the
following;
a) For Separation of component having the economic value.
b) As a stage in the preparation of some compound.
c) For removing of undesired component (pollution).
Physical absorption,
2)
Chemical Absorption.
Physical Absorption:
In physical absorption mass transfer take place purely by diffusion and physical
absorption is governed by the physical equilibria.
Chemical Absorption:
In this type of absorption as soon as a particular component comes in contact with
the absorbing liquid a chemical reaction take place. Then by reducing the concentration
of component in the liquid phase, which enhances the rate of diffusion.
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Production of Acrylonitrile
DESIGN OF ABSORBER
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Production of Acrylonitrile
DESIGN OF ABSORBER
3)
4)
5)
The packed column provides continuous contact between vapor and liquid phases
while the plate column brings the two phases into contact on stage wise basis.
SCALE: For column diameter of less than approximately 6 ft. It is more usual to
employ packed towers because of high fabrication cost of small trays. But if the
column is very large then the liquid distribution is problem and large volume of
packing and its weight is problem.
PRESSURE DROP: Pressure drop in packed column is less than the plate column.
In plate column there is additional friction generated as the vapor passes through
the liquid on each tray. If there are large No. of Plates in the tower, this pressure
drop may be quite high and the use of packed column could effect considerable
saving.
LIQUID HOLD UP: Because of the liquid on each plate there may be a Urge
quantity of the liquid in plate column, whereas in a packed tower the liquid flows
as a thin film over the packing.
SIZE AND COST: For diameters of less than 6 ft, packed tower require lower
fabrication and material costs than plate tower with regard to height, a packed
column is usually shorter than the equivalent plate column.
From the above consideration packed column is selected as the absorber, because
in our case the diameter of the column is less than 6 ft. As the solubility is infinity so the
liquid will absorb as much gases as it remain in contact with gases so packed tower
provide more contact. It is easy to operate.
Packing:
The packing is the most important component of the system. The packing provides
sufficient area for intimate contact between phases. The efficiency of the packing with
respect to both HTU and flow capacity determines to a significance extent the overall size
of the tower. The economics of the installation is therefore tied up with packing choice.
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Production of Acrylonitrile
DESIGN OF ABSORBER
The packings are divided into those types which are dumped at random into the
tower and these which must be stacked by hand. Dumped packing consists of unit 1/4 lo
3 inches in major dimension and are used roost in the smaller columns. The units in
stacked packing are 2 to about 8 inches in size, they are used only in the larger towers.
The Principal Requirement of a Tower packing are:
1)
It must be chemically inert to the fluids in the tower.
2)
It must be strong without excessive weight.
3)
It must contain adequate passages for both streams without excessive liquid
hold up or pressure drop.
4)
It must provide good contact between liquid and gas.
5)
It must be reasonable in cost.
Thus most packing is made of cheap, inert, fairly light materials such as clay,
porcelain, or graphite. Thin-walled metal rings of steel or aluminum are some limes used.
Common Packings are:
a) Berl Saddle.
b) Intalox Saddle.
c) Rasching rings.
d) Lessing rings.
e) Cross-partition rings.
f) Single spiral ring.
g) Double - Spiral ring.
h) Triple - Spiral ring.
Production of Acrylonitrile
DESIGN OF ABSORBER
Determining the height of the column
Calculating the operating velocity
Calculating the flooding velocity
Determining the pressure drop.
Select and design the column internal features: packing support, liquid
distributer and redistributer.
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Production of Acrylonitrile
DESIGN OF ABSORBER
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Production of Acrylonitrile
DESIGN OF ABSORBER
Production of Acrylonitrile
DESIGN OF ABSORBER
X=0.661(Y-0.0002) (1)
Y=1.513X +0.0002 (2)
Equations (1) and (2) are the operating line equations.
Equation For Equilibrium Curve:
LET
Production of Acrylonitrile
DESIGN OF ABSORBER
Pressure of entering gases=P= 1.7 atm
Average molecular weight of entering gases=28.4 Kg(HYSYS)
Density of gas mixture= g = PM /RTg
= (1.728.4) /(0.08205317)
=1.86Kg/m3
Density of liquid solvent at 5oC= L=1022Kg/m3(HYSYS)
Viscosity of liquid solvent at 5oC = L =1.4 cp(From Appendix-9 MCcab & Smith 5thEd)
Viscosity of Gaseous mixture at 44 oC = g = 0.103 cp
Now
Abscissa of fig 11.44
L
G
g
L
= 0.04
Production of Acrylonitrile
DESIGN OF ABSORBER
As
Area =A= G / G* =2.35 m2
Diameter of column=D= 4[A]
[3.14]
So
Where
aw
1 exp 1.45 c
a
0.75
Lw
0.1
0.05
Lw 2 a
2g
L
Lw
a
L L
2
0.2
aw
61
1 exp 1.45
92
70
0.75
10.66
3
92 1.4 10
0.1
10.66 2 92
2
1022 9.8
0.05
10.66 2
3
1022 70 10 92
= 53.5 m2/m3
aw
K L
L g
1
3
Lw
0.0051
aw L
Production of Acrylonitrile
2
3
L DL
1
2
ad
0 .4
107
0.2
DESIGN OF ABSORBER
KL = liquid film coefficient m/s
dp = packing size =50 x 10-3 m (From table 11.4 Coulson & Richardson)
DL = diffusivity of liquid = 1.7 x 10-9 m2/sec (From Coulson & Richardson)
Then, by substituting the values,
KL = 7.87 x 10-4 m/s
Calculation Of Gas Film Mass Transfer Coefficient:
K G RTg
aD g
Vw
K5
a
g
0.7
D
g
g
1
3
ad
G
m
H
G K a P
G w
Where,
And
L
m
L K a C
L w t
H = Liquid-film transfer unit height
H
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Production of Acrylonitrile
DESIGN OF ABSORBER
Lm= 10.66/18 = 0.59 Kmol/m2.sec
Ct = Concentration of solvent = 1022/18 = 56.7 Kmol/m3
Then,
HL = 0.59/(6.94 10-4 53.5 56.7)
= 0.28 m
Calculation Of Height Of Transfer Units:
As,
H oG H G
mGm
HL
Lm
HG = 0.40 m
HL =
0.28 m
So,
Height of transfer units=HOG = 0.4 + 0.75 0.28
HOG = 0.61 m (From Coulson & Richardson, range is 0.6
to 1m, topic 11.14.3)
L g
Production of Acrylonitrile
G L
109
DESIGN OF ABSORBER
= 0.04
Operating velocity of gas
g
L
G
g
L
= 0.04
G = 4.6 m/sec
Operating velocity as
= (2.76/4.6) 100
% of flooding velocity
= 60% (Operating velocity must be 50-90% of flooding
velocity,MCcab & Smith)
Calculation of wetting rate:
If very low liquid rates have to be used the packing wetting rate should be checked to
make it sure it is above the minimum recommended by packing manufacturer Wetting
rate is defined by following relation.
Wetting rate = Liquid volumetric flow rate per unit cross-sectional area
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Production of Acrylonitrile
DESIGN OF ABSORBER
Specific area of packing per unit volume
Liquid volumetric flow rate/Unit cross-sectional area = 90195/(360010222.35)
=1.0410 -2 m3/m2-sec
Specific area of packing = 92 m2/m3
Wetting rate =1.1310-4 m3sec-1/m2
.
Calculation Of Pressure Drop At Flooding:
From McCabe & smith 5th edition,Eq.22.1,
Pressure drop at flooding is given by relation.
Pflooding =0.115Fp 0.7
Where
Pflooding =pressure drop at flooding.
Fp =packing factor for 3-inch ceramic intalox saddles = 22
Pflooding =0.115(22)0.7
= 1 in.H2O/ft of packing (For 3-in packing size,it should be 0.7 to
1.5 in.H2O/ft of packing, MCcab & Smith)
Pflooding=0.8kPa/m of packing
Calculation Of Total Pressure Drop:
From figure 22.6, MCcab & Smith(5th Ed.)
Gx
Gy
Here,
y
x y
Gx = L
(lb/sec.ft2)
Gy = G
(lb/sec.ft2)
= 0.04
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Production of Acrylonitrile
DESIGN OF ABSORBER
x L
=
(lb/ft3)
(lb/ft3)
Also,
G2 FpL0.1 / g (L - g)gc = 0.069
Then,
P = 0.6 in.H2O/ft of packing
P =1.9 in.H2O/m of packing
P = 47.5 mmH2O/m of packing (Recommended pressure drop for
absorber is 15 to 50 mmH2O/m of packing, topic 11.14.4, Coulson &
Richardson)
Total Pressure Drop = 47.5 x 9= 427.5 mmH2O/m of packing
Total Pressure Drop = 4 kPa/m of packing
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Production of Acrylonitrile
DESIGN OF ABSORBER
Item No:
A-104
No. required:
01
Exit gas
Liquid
Liquid leaving
Kg/hr
Kg/hr
entering
Kg/hr
79465
Kg/hr
90195
104765
94035
Design Data:
No. of transfer units = 15
Height of transfer units = 0.61 m
Height of packing section = 9 m
Total height of column
= 11 m
Diameter = 1.73 m
Pressure drop = 4kPa/m of packing
Internals:
Size and type = 66 mm
Material of packing:
Packing arrangement:
Type of packing support:
Intalox saddles
Ceramic
Dumped
Simple grid & perforated support
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Production of Acrylonitrile