SIKKIM UNIVERSITY

Department of Chemical Sciences

Organic Chemistry II: CHE-PG-C202
Unit 1: March, 2016
Dr. B. G. Roy
Total Marks: 25

Time: 1 h
Answer any Five (5 x 5 = 25)

1. Write products of following reactions with correct stereochemistry. Explain the

stereochemistry with proper reasoning.
5

2. Give mechanisms for the following reactions, classifying any pericyclic reactions
involved.
4

c) Write product(s) for following reaction.

1

3. Write product(s) for following reactions.

5
a)

b)
4. Suggest plausible mechanism of following multistep reactions and in each case
state what type of pericyclic reactions has taken place.
5

a)

b)

c) Write correct product with proper stereochemistry.

2

5. Write products of following reactions with correct stereochemistry. Give

mechanism in each case. Which type of pericyclic reactions are these?
4

a)

b)

c) Write correct product for following reactions.

1

6. Write products with correct stereochemistry and give mechanism in each case.
3

a)

b)

c) Write mechanism for following transformation? Mention the class of reaction they
belongs to.
2

7. a) Explain the following reactions with mechanism and comment on the

difference between them. 3

c) Write mechanism for following transformations? Mention the class of reaction

they belongs to.
2