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    Point defects and line defects are two types of imperfections in crystals. Point defects include stoichiometric defects, impurity defects, and non-stoichiometric defects. In a solid solution of CdCl2 and AgCl, impurity defects are observed where some Ag+ sites are occupied by Cd2+, with each Cd2+ replacing two Ag+ sites and leaving another site vacant. When LiCl crystals are heated in Li vapor, the Li deposits on the crystal surface, Cl- ions diffuse and combine with Li to form more LiCl, releasing electrons that become trapped at anion sites called F centers, coloring and paramagnetically changing the crystal. Schottky and Frenkel defects are two common types that

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    Point defects and line defects are two types of imperfections in crystals. Point defects include stoichiometric defects, impurity defects, and non-stoichiometric defects. In a solid solution of CdCl2 and AgCl, impurity defects are observed where some Ag+ sites are occupied by Cd2+, with each Cd2+ replacing two Ag+ sites and leaving another site vacant. When LiCl crystals are heated in Li vapor, the Li deposits on the crystal surface, Cl- ions diffuse and combine with Li to form more LiCl, releasing electrons that become trapped at anion sites called F centers, coloring and paramagnetically changing the crystal. Schottky and Frenkel defects are two common types that

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    21 views2 pages

    Material Downloaded From and Portal For CBSE Notes, Test Papers, Sample Papers, Tips and Tricks

    Uploaded by

    Ashish Bajpai
    Point defects and line defects are two types of imperfections in crystals. Point defects include stoichiometric defects, impurity defects, and non-stoichiometric defects. In a solid solution of CdCl2 and AgCl, impurity defects are observed where some Ag+ sites are occupied by Cd2+, with each Cd2+ replacing two Ag+ sites and leaving another site vacant. When LiCl crystals are heated in Li vapor, the Li deposits on the crystal surface, Cl- ions diffuse and combine with Li to form more LiCl, releasing electrons that become trapped at anion sites called F centers, coloring and paramagnetically changing the crystal. Schottky and Frenkel defects are two common types that

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    CBSE TEST PAPER-04

    CLASS - XII CHEMISTRY (The Solid State)


    [ANSWERS]
    Topic imperfections in crystals

    Ans 01:

    The defects are irregularities in the arrangement of constituent particles in a


    crystal.

    Ans 02:

    Defects are of two types


    Point defects: - Irregularities or deviations from ideal arrangement around a
    point or on atom in a crystal.
    Line defect: - Irregularities or deviation from ideal arrangement in entire row of
    lattice points.

    Ans 03:

    point defects are of three types stoichiometric defect, impurity defect & non
    stoichiometric defect.

    Ans 04:

    (a) Schottky defect.


    (b) It decreases the density of crystal.
    (c) NaCl, KCl
    (d) The crystal remains electrically neutral.

    Ans 05:

    In a solid solution of CdCl2 and AgCl, impurity defect is observed. In the crystal of
    AgCl, some of the sites of Ag+ are occupied by Cd2+, each Cd2+ replacing two Ag+. It
    replaces the site of one ion and other site remains vacant.

    Material downloaded from http://myCBSEguide.com and http://onlineteachers.co.in


    Portal for CBSE Notes, Test Papers, Sample Papers, Tips and Tricks

    Ans 06:

    When crystals of LiCl are heated in an atmosphere of Li vapour the Lithium


    atoms are deposited on the surface of crystal. The Cl- ions diffuse to the surface of
    crystal & combine with Li atoms to from LiCl which happens by loss of electrons
    by Li atoms to form Li+ ions. These released elements diffuse into the crystal &
    electrons get excited after absorbing light from visible region & emit pink colour.

    Ans 07:

    F centre is the position of an anion in an ionic crystal which is occupied by a


    trapped electron

    Ans 08:

    The crystal becomes paramagnetic and coloured due to presence of f centre

    Ans 09:

    AgBr.

    Ans 10:

    (a) Schottky defect ionic substances in which the cation and anion are of almost
    similar sizes eg. NaCl, KCl, CrCl.
    (b) Feenkel Defect Ionic substances in which there is large difference in size of
    ions eg. ZnS, AgCl, AgBr.

    Material downloaded from http://myCBSEguide.com and http://onlineteachers.co.in


    Portal for CBSE Notes, Test Papers, Sample Papers, Tips and Tricks

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