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Constants and Equations for Thermodynamics and

Electrochemical Cells
R = 0.08206 L atm/(K mol) = 8.314 J/(K mol)
Faraday Constant = 96485 C/mol e- = 96485 J/(Vmol)
Avagadros Number = 6.022 x 1023

Suniverse = Ssystem + Ssurroundings


G = H TS
At Equilibrium (or reversible), T = H/S
Grxn = (Gf(products)) (Gf(reactants))
Srxn = (S(products)) (S(reactants))
G = RT Ln{Q/K}
G = G + RT Ln{Q}
G = RT Ln{K}
G = nFE
Ecell = Ecathode Eanode = Eoxidation + Ereduction
E = E (RT/(nF)) Ln{Q}
E = E (0.0592/n) Log{Q}

(at 298K)

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