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TUTORIAL THERMOCHEMISTRY

SKU1023
1) a. State Hess's Law
b. Use Hess's Law to calculate the enthalpy change for the reaction
WO3(s) + 3H2(g) W(s) + 3H2O(g)
from the following data
2W(s) + 3O2(g) 2WO3(s) H = 1685.4 kJ
2H2(g) + O2(g) 2H2O(g)
H = 477.84 kJ
2) 2.53 g of solid NaOH is dissolved in 100.00 g of water in a coffee cup calorimeter, all the
reagents initially being at 20.0C. Calculate the final temperature (in oC) of the solution
obtained, given the following information:
NaOH(s) NaOH(aq)
H = 43.0 kJ/mol
Heat capacity of NaOH solution = 4.18 J/(gK)
3) The complete combustion of liquid benzene is represented by the equation:
C6H6(l) + 7 1 2 O2(g) 6CO2(g) + 3H2O(l)
Using the data below, calculate, for this reaction, at 25C.
a. H
b. S
c. G
Substance:
H f (kJ/mol):
S(J/mol.K):

C6H6(l)
49
173

O2(g)
0
205

CO2(g)
394
214

H2O(l)
286
70

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