CHUYN PHN NG OXI HO KH

A.nh ngha- s oxi ho-quy tc xc nh s oxi ho-iu kin phn ng oxi ho

kh xy ra
I.nh ngha:
L phn ng ho hc trong c s dch chuyn electron gia cc cht phn ng, hay
phn ng oxi ho kh l phn ng ho hc trong c s thay i s oxi ho ca mt s
nguyn t.
VD:
2Na + CL2 ->2NaCL
Na -> Na+ + 1e (qu trnh oxi ho)
(cht kh)
CL2+ 2e -> 2CL- (qu trnh kh)
(cht oxi ho)
II.S oxi ho: ( Mc oxi ho )
in tch ca nguyn t nguyn t trong phn t, nu gi nh lin kt gia cc nguyn t
l lin kt ion.
III.Xc nh s oxi ho:
1.Trong hp cht v c:
Bn quy tc c bn
2.Trong hp cht hu c:
Tng t hp cht v c
-Xc nh theo cng thc phn t nh trong cc hp cht v c, xc nh c s oxi ho
trung bnh ca C hoc s oxi ho ca C.
-Xc nh s oxi ho ca tng nguyn t cc C da vo cng thc cu to
VD:
C20 H 41O22

C-3H3C+3O-OH S oxi ho ca C = 0 ( S oxi ho ca C = 0 )

IV. iu kin phn ng oxi ho kh xy ra v th t cc qu trnh oxi ho kh
-Da vo dy in ho
Li+K+Ba2+Ca2+Na+Mg2+AL3+Mn2+Zn2+Cr3+Fe2+Ni2+Sn2+Pb2+2H+Cu2+Fe3+Hg2+Ag+Au3+
Li K Ba Ca Na Mg AL Mn Zn Cr Fe Ni Sn Pb H2 Cu Fe2+ Hg Ag Au
-Quy tc
B. Lp phng trnh phn ng oxi ho kh theo phng php thng bng electron
I. Cc bc tin hnh: 4 bc c bn
II.Mt s dng phn ng oxi ho kh
1.Dng n gin: (Trong phn ng c mt cht oxi ho, mt cht kh r rng)
Cu + H2SO4 c,to CuSO4 + SO2 + H2O
Al + HNO3 AL(NO3)3 + N2O + H2O
Na2SO3 + KMnO4 +H2O Na2SO4 + MnO2 + KOH
FeSO4 + K2Cr2O7 + H2SO4 Fe2(SO4)3 + K2SO4 + Cr2(SO4)3 + H2O
Fe3O4 + HNO3 Fe(NO3)3 + NO + H2O
2.Phn ng oxi ho kh ni phn t: ( phn ng ch xy ra trong mt phn t )
KClO3 to KCL + O2

KMnO4 to K2MnO4 + MnO2 + O2

Cu(NO3)2 to CuO + NO2 + O2
(NH4)2Cr2O7 to N2 + Cr2O3 +H2O
3.Phn ng t oxi ho kh: (cc nguyn t ca cng mt nguyn t t cng mt s
oxi ho bin thnh nhiu s oxi ho khc nhau )
Cl2 + KOH to KCL + KCLO3 + H2O
K2MnO4 + H2O KMnO4 + MnO2 + KOH
NaCLO NaCL + NaCLO3
I2 + NaOH NaI + NaIO + H2O
S + NaOH Na2SO4 + Na2S + H2O
4.Phn ng oxi ho kh phc tp:
a. Phn ng c ch:
Cu 1
Fe + HNO3 Fe(NO3)3 + NxOy + H2O
Fe3O4 + HNO3 Fe(NO3)3 + NxOy + H2O
FexOy + HNO3 Fe(NO3)3 + NO + H2O
MxOy + HNO3 M(NO3)n + NO + H2O
FexOy + CO FenOm + CO2
Cu 2
1. R + HNO3 R(NO3)n
+ NO
+ H2O
2. R + HNO3 R(NO3)m
+ NH4NO3 + H2O
3. M + HNO3 M(NO3)n + N2O + H2O
4. R + H2SO4 R2(SO4)m
+ SO2
+ H2 O
5. M + H2SO4 M2(SO4)m + H2S
+ H2 O
6. R + HNO3 R(NO3)3
+ NxOy + H2O
7. M + HNO3 M(NO3)n
+ NxOy + H2O
8. Fe3O4 + HNO3 Fe(NO3)3 + NxOy
+ H2O
9. FeO + HNO3 Fe(NO3)3 + NxOy + H2O
M(NO3)n + NO
10. MxOy
+ HNO3
+ H2O
to
11. FexOy
+ H2SO4 c Fe2(SO4)3 + SO2 + H2O
M(NO3)m + NO
12. M2(CO3)n + HNO3
+ CO2 + H2O
Fe(NO3)3 + NxOy + H2O
13. Fe3O4
+ HNO3
Fe(NO3)3 + NnOm + H2O
14. FexOy
+ HNO3
b.Phn ng c s thay i s oxi ho ca nhiu hn hai nguyn t
FeS2 + HNO3 Fe(NO3)3 + H2SO4 + NO + H2O
Cu2S + HNO3 Cu(NO3)2 + H2SO4 + NO + H2O
As2S3 + KClO3 H3AsO4 + H2SO4 + KCL
CuFeS2 + Fe2(SO4)3 + O2 + H2O CuSO4 + FeSO4 + H2SO4
c.Phn ng oxi ho kh c hp cht hu c
C2H2 + KMnO4 + H2O H2C2O4 + MnO2 + KOH
CH3OH + KMnO4 + H2SO4 HCOOH + MnSO4 + K2SO4 + H2O
CH3-C CH + KMnO4 + KOH CH3COOK + K2CO3 + MnO2 + H2O
CH3-CH=CH2 + KMnO4 + H2O CH3-CHOH-CH2OH + MnO2 + KOH
CnH2n+1OH + K2Cr2O7 + H2SO4 CH3COOH + Cr2(SO4)3 + K2SO4 + CO2 + H2O
CxHyO + KMnO4 + HCl CH3CHO + MnCl2 + CO2 + KCl + H2O

d.Phn ng c cha cc ion( ch in tch 2 v )

Cu + NO3- + H+ Cu2+ + NO + H2O
Cr3+ + OH- + Br2 CrO42- + Br- + H2O
H2S + MnO4- + H+ Mn2+ + S + H2O
SO32- + MnO4- + OH- MnO42- + SO42- + H2O
C. Mt s cht oxi ho thng gp
KMnO4 , K2MnO4 , MnO2

Mi trng axit

Mn2+

Mi trng trung tnh

MnO2
KMnO4
K2MnO4
Mi trng OH

Mi trng axit
Mui (III) (Cr3+)

K2Cr2O7 , K2CrO4

Cr2O72- + H2O

CrO42- + 2H+ nn

Mi trng OHCr2O72-

CrO4

2-

CrO42Mi trng trung tnh

Cr(OH)3

Mi trng axit
HNO3

NH4NO3
N2
N2O
NO
NO2

Mi trng axit
-

NO3 ( Mui nitrat)

H2SO4

NO
H2S
S
SO2

D. Lp phng trnh phn ng theo phng php cn bng ion-electron

p dng ch yu cho trng hp cc phn ng xy ra trong dung dch
Thit lp cc phng trnh phn ng cho dng ion
I. Cc bc tin hnh:
- Vit cc na phn ng ( oxi ho v kh )
- Cn bng cc na phn ng:
+ Cn bng s nguyn t mi nguyn t hai v ca cc na phn ng:
Mi trng Axit : V no tha oxi thm H+ to H2O, hay v no thiu oxi th thm H2O to
ra H+
Mi trng Baz : V no tha oxi th thm H 2O to OH- hay v no thiu oxi th thm
OH- to H2O
H2O cn bng s nguyn t H
Cn bng s nguyn t O
+ Cn bng in tch
- Cn bng electron : Tng s electron cho = Tng s electron nhn
- Cng cc na phn ng v hon thnh
II. Mt s dng bi :
1. Cn bng cc phng trnh phn ng sau theo phng php cn bng ion- electron:
KMnO4 + KNO2 + H2SO4 MnSO4 + KNO3 + K2SO4 + H2O
NaCrO2 + Br2 + NaOH Na2CrO4 + NaBr + H2O
KMnO4 K2SO3 + H2O MnO2 + K2SO4 + KOH
2. Hon thnh cc phng trnh phn ng oxi ho kh sau:
MnO4- + SO32- Mn2+ + SO42MnO4- + SO32- MnO2 + SO42As2S3 + NO3- AsO43- + SO42- + NO2
H2S + MnO4- Mn2+ S
SO32- + MnO4- MnO42- + SO42E. Bi tp p dng p dng phn ng oxi ho kh:
I. Yu cu chung :
-Cc bi ton lin quan ti phn ng ox ho kh
-S dng phng trnh hoc cc bn phn ng
-p dng nh lut bo ton electron, kt hp vi mt s bo ton khc
-iu kin v th t cc phn ng oxi ho kh
II. Mt s dng bi tp:
1. Kim loi hoc hn hp kim loi tc dng vi axit hoc hn hp axit HCl, H 2SO4
long
VD1:
Cho 3,68 gam hn hp Al v Zn tc dng vi mt lng va dung dch H 2SO4 10% thu
c 2,24 lt kh H2 ( ktc). Tnh khi lng dung dch thu c sau phn ng.
VD2:
Ho tan 14,6 gam hn hp X gm AL v Sn bng dung dch HCL(d), thu c5,6 lit kh
H2 ( ktc). Tnh th tch kh oxi( ktc) cn dng phn ng hon ton vi hn hp X.
VD3:
Cho H2SO4 long d td vi 6,66g hn hp 2 kim loi X v Y u ha tr II , ngi ta thu
c 0,1 mol kh, ng thi khi lng hh gim 6,5g . Ha tan phn cn li bng H 2SO4
c nng ngi ta thy thot ra 0,16g kh SO2 . X v Y l nhng kim loi no ?
VD4:

Cho 7,22 gam hn hp X gm Fe v kim loi M c ho tr khng i. Chia hn hp thnh

hai phn bng nhau:
Ho tan ht phn mt trong dung dch HCL c 2,128 lt H2.
Ho tan ht phn hai trong dung dch HNO3 c 1,792 lt kh NO duy nht (ktc)
Xc nh M v % khi lng mi kim loi.
2.Kim loi hoc hn hp kim loi tc dng vi axit hoc hn hp axit HNO 3 long
hoc c, H2O4 c
VD1:
Cho 6,72 gam Fe vo 400ml dung dch HNO 3 1M ,n khi phn ng xy ra hon ton thu
c kh NO ( sn phm kh duy nht) v dung dch X. Tnh s gam Cu ti a b ho tan
trong dung dch X
VD2:
Cho 1,35 gam hn hp Cu , Mg , Al tc dng vi HNO3 d c 896 ml ( ktc) hn hp gm
NO v NO2 c M 42 . Tnh tng khi lng mui nitrat sinh ra (kh ktc).
VD3:
Ha tan hon ton 12,42 gam Al bng dung dch HNO 3 long (d), thu c dung dch X
v 1,344 lt ( ktc) hn hp kh Y gm hai kh l N 2O v N2. T khi ca hn hp Y so
vi kh H2 l 18. C cn dung dch X, thu c m gam cht rn khan. Gi tr ca m?
VD4:
em ha tan hon ton 5,6 gam Fe trong dung dch HNO 3 long, sau khi kt thc phn
ng, thy cn li 1,12 gam cht rn khng tan. Lc ly dung dch cho vo lng d dung
dch AgNO3, sau khi kt thc phn ng, thy xut hin m gam cht rn khng tan. Tr s
ca m l?
VD5:
Ho tan cng mt lng kim loi R vo dung dch HNO3 c nng v vo dung dch
H2SO4 long th th tch NO2 thu c bng 3 ln th tch H2 cng iu kin, khi lng
mui sunfat bng 62,81% khi lng mui nitrat to thnh.
Tnh khi lng nguyn t R
Mt khc khi nung cng mt lng kim loi R nh trn th cn th tch O 2 bng 22,22%
th tch NO2 trn cng iu kin v thu c cht rn A l oxit ca kim loi R. Ho tan
20,88 gam A vo dung dch HNO 3( ly d 25% so vi lng cn thit) thu c 0,672 lit
kh B(ktc) l mt oxit ca nit NxOy. Tnh khi lng HNO3 nguyn cht cn thit ho
tan A v lng HNO3 ban u.
3.Kim loi tc dng vi nc, kim loi tc dng vi dung dch kim
VD1:
Thc hin hai th nghim sau:
Th nghim 1: Cho m gam hn hp Ba v Al vo nc d, thu c 0,896 lit kh(ktc)
Th nghim 2: Cng cho m gam hn hp trn vo dung dch NaOH d thu c 2,24 lit
kh(ktc). Cc phn ng xy ra hon ton. Tnh khi lng m
VD2:
Ho tan 7,3 gam hn hp X gm kim loi Na v kim loi M(ho tr khng i) trong nc
thu c dung dch Y v 5,6 lit kh H 2(ktc). trung ho dung dch Y cn dng 100 ml
dung dch HCL 1M. Tnh phn trm v khi lng ca kim loi M trong hn hp.
4.Oxit kim loi hoc hn hp oxit kim loi tc dng vi axit hoc hn hp axit HNO 3,
H2SO4
VD1:

Ho tan 2,16 gam FeO trong HNO3 c, sau mt thi gian thy thot ra 0,224 lit kh X
(ktc) l sn phm kh duy nht. Xc nh X.
VD2:
Trn 0,54 gam bt nhm vi hn hp bt Fe 2O3 v CuO ri tin hnh phn ng nhit
nhm trong iu kin khng c khng kh mt thi gian, thu c hn hp cht rn X.
Ho tan hon ton cht rn X trong HNO 3 c nng d th thu c Vlt kh NO duy
nht(ktc). Tnh V
VD3:
Ho tan 20,88 gam mt oxits st bng dung dch H2SO4 c nng, thu c dung dch X
v 3,248 lt SO2(sn phm kh duy nht ktc) c cn dung dch X c m gam mui
sunpht khan. Tnh m.
5.Kim loi tc dng vi dung dch mui:
VD1:
Dung dch X gm AgNO3 v Cu(NO3)2 c cng nng . Ly mt lng gm 0,03 mol
AL v 0,05 mol Fe cho vo 100ml dung dch X cho ti khi phn ng kt thc thu c
cht rn Y gm ba kim loi. Cho Y vo ung dch HCL d thu c 0,007 gam H2.
Tnh nng hai mui ban u.
VD2:
Cho 0,84 gam bt Mg vo 100 ml dung dch hn hp Cu(NO 3)2 0,15M v Fe(NO3)3 0,2M
cho n khi phn ng hon ton thu c m gam cht rn.
VD3:
Cho 0,8 mol bt Mg vo dung dch cha 0,6 mol FeCl3 v 0,2 mol CuCl2. Sau khi phn
ng kt thc thu c cht rn A v dung dch B. C cn dung dch B thu c bao nhiu
gam cht rn khan?
VD4 :
1,368 gam hn hp X gm FeO, Fe2O3, Fe3O4 tc dng va ht vi dung dch HCl (cc
phn ng xy ra hon ton) thu c dung dch Y, c cn dung dch Y thu c hn hp 2
mui, trong khi lng mui FeCl2 l 1,143 gam. Dung dch Y c th ha tan ti a bao
nhiu gam Cu?
VD5:. Ha tan ht m gam Cu vo 400 ml dung dch Fe(NO3)3 12,1% thu c dung dch A
c nng Cu(NO3)2 3,71%. Nng % theo khi lng Fe(NO3)3 trong dung dch A l?
VD6: Cho hai thanh kim loi X u c ho tri II v c khi lng bng nhau. Thanh 1
nhng vo dung dch Cu(NO3)2. Thanh 2 nhng vo dung dch Pb(NO 3)2. Sau mt thi
gian thanh mt gim 0,2%. Thanh 2 tng 28,4%. S mol ca hai dung dch ban u u
gim mt lng nh nhau. Tm X
6. Mui NO3- trong mi trng axit
Bi 1. Cho 19,2 gam Cu vo 500ml dd NaNO3 1M, sau thm 500ml dd HCl 2M
a. Cu c tan ht hay khng? Tnh th tch NO bay ra ktc.
b. Tnh CM cc ion trong dd A thu c sau P.
c. PhI thm bao nhiu lt dd NaOH 0,2M kt ta ht Cu2+ cha trong dd A?
Bi 2.Cho 1,92 gam ng vo 100 ml dung dch cha ng thi KNO3 0,16M v H2SO4
0,4M, thy sinh ra mt cht kh c t khi hi i vi H2 l 15 v thu dung dch A.
a. Vit phng trnh ion thu gn ca phn ng xy ra v tnh th tch kh sinh ra ( iu
kin tiu chun).

b. Tnh th tch dung dch NaOH 0,5M ti thiu cn dng kt ta ton b Cu 2+ trong
dung dch A.
Bi 3 Tnh VNO (ktc) thot ra trong 2 trng hp:
a. Cho 6,4 gam Cu tc dng vi 120 ml dd HNO3 1M( long).
b. Cho 6,4 gam Cu tc dng vi 120 ml dd hn hp HNO3 1M + H2SO4 0,5M.
7. Phn ng oxi ha kh qua nhiu giai on
Cu 1: Nung 8.4 gam Fe trong khng kh, sau phn ng thu c m gam X gm Fe,
FeO, Fe2O3 v Fe3O4 . Ha tan m gam hh X bng HNO3 d, thu c 2.24 lt kh NO2
(ktc) l sn phm kh duy nht. Tnh gi tr m
Cu 6 Cho 11,36 gam hn hp gm Fe, FeO, Fe2O3 v Fe3O4 phn ng ht vi dung
dch HNO3 long (d), thu c 1,344 lt kh NO (sn phm kh duy nht, ktc) v
dung dch X. C cn dung dch X thu c m gam mui khan. Tnh gi tr ca m.
Cu 2 Cho kh H2 i qua ng s cha m gam Fe2O3 un nng, sau mt thi gian thu c
20,88 gam hn hp 4 cht rn. Ho tan ht lng cht rn trn trong dd HNO 3 d thy
thot ra 0,39 mol NO2 duy nht. Tnh khi lng HNO3 tham gia phn ng?
Cu 3 Cho 2,352 lit CO (ktc) i qua m gam hn hp A gm FeO, Fe 3O4, Fe2O3 c s mol
bng nhau nung nng thu c hn hp cht rn B. Cho B tan ht trong dd HNO 3 d thy
thot ra 2,24 lit NO duy nht (ktc). Cc phn ng xy ra hon ton. Tnh m?
Cu 4 Cho kh CO qua ng s cha m gam Fe 2O3 nung nng, sau mt thi gian thu c
13,92 gam hn hp X gm Fe, FeO, Fe 3O4, Fe2O3. Ho tan ht X bng dd HNO 3 c nng
d thu c 5,824 lit NO2 duy nht (ktc). Tnh m?

Bi tp tham kho
1. M + HNO3 --> M(NO3)n + NO2 + H2O

2. M + HNO3 --> M(NO3)n + NO + H2O

3. M + HNO3 --> M(NO3)n + N2O + H2O
4. M + HNO3 --> M(NO3)n + N2 + H2O
5. M + HNO3 --> M(NO3)n + NH4NO3 + H2O
6. M + HNO3 --> M(NO3)n + NxOy + H2O
7. M + H2SO4 --> M2(SO4)n + SO2 + H2O
8. M + H2SO4 --> M2(SO4)n + S + H2O
9. M + H2SO4 --> M2(SO4)n + H2S + H2O
10.M2Ox + HNO3 --> M(NO3)3 + NO + H2O
11.FeO + HNO3 --> Fe(NO3)3 + NO2 + H2O
12.FeO + HNO3 --> Fe(NO3)3 + NO + H2O
13.Fe3O4 + HNO3 --> Fe(NO3)3 + NO2 + H2O
14.Fe3O4 + HNO3 --> Fe(NO3)3 + NO + H2O
15.Fe + O2 + H2O --> Fe(OH)3
16.KNO2 + HClO3 --> KNO3 + HCl
17.H2SO3 + H2O2 --> H2SO4 + H2O
18.H2SO3 + H2S --> S + H2O
19.O3 + KI + H2O --> O2 + I2 + KOH
20.KNO2 + HClO3 --> KNO3 + HCl
21.H2SO3 + H2O2 --> H2SO4 + H2O
22.Cl2 + KOH --> KCl + KClO3 + H2O
23.M + HNO3 --> M(NO3)n + NxOy + H2O
24.S + KOH --> K2S + K2SO3 + H2O
25.H2SO3 + H2S --> S + H2O
26.Cl2 + KOH --> KClO + KCl + H2O
27.Cl2 + KOH --> KClO3 + KCl + H2O
28.S + KOH --> K2S + K2SO3 + H2O
29.Fe + KNO3 --> Fe2O3 + N2 + K2O
30.Fe(OH)2 O2 + H2O --> Fe(OH)3
31.KI + H2O + O3 --> KOH + I2 + O2
32.CxHyOz + O2 --> CO2 + H2O
33.KOH + Cl2 --> KClO + KCl + H2O
34.KClO3 --> KCl + KClO4
35.NO2 + H2O --> HNO3 + NO
36.Al + FexOy --> Al2O3 + Fe
37.CxHyOz + O2 --> CO2 + H2O
38.HNO2 --> HNO3 + NO + H2O
39.Fe + KNO3 --> Fe2O3 + N2 + K2O
40.Al + Fe3O4 --> Al2O3 + Fe
41.S + NaOH --> Na2SO4 + Na2S + H2O
42.Br2 + NaOH --> NaBr + NaBrO3 + H2O
43.Fe2S + O2 --> SO2 + Fe2O3
44.FexOy + H2SO4 --> Fe2(SO4)3 + SO2 + H2O
45.FexOy + HNO3 --> Fe(NO3)3 + NO + H2O
46.FeCu2S2 + O2 --> Fe2SO3 + CuO + SO2
47.Ca3(PO4)2 + Cl2 + C --> POCl + CO + CaCl2
48.Ca3(PO4)2 + SiO2 + C --> P4 + CaSiO3 + CO

49.MnO2 + HCl --> MnCl2 + Cl2 + H2O

50.FeCu2S2 + O2 --> Fe2O3 + CuO + SO2
51.KClO3 + NH3 --> KNO3 + KCl + Cl2 + H2O
52.K2Cr2O7 + HCl --> CrCl3 + KCl + Cl2 + H2O
53.NO2 + NaOH --> NaNO3 + NaNO2 + H2O
54.K2MnO4 + H2O --> MnO2 + KMnO4 + KOH
55.FeCl2 + H2O2 + HCl FeCl3 + H2O
56.I2 + Na2S2O3 Na2S4O6 + NaI
57.R2On + NH3 R + N2 + H2O (R l Pb,Cu,Ag)
58.KI + HNO3 I2 + KNO3 + NO + H2O
59.H2S + HNO3 H2SO4 + NO + H2O
60.MnO2 + O2 + KOH K2MnO4 + H2O
61.K2MnO4 + H2O --> KMnO4 + MnO2 + KOH
62.KMnO4 + HCl --> MnCl2 + KCl + Cl2 + H2O
63.KMnO4 + HCl --> KCl + MnCl2 + Cl2 + H2O
64.KClO3 + NH3 --> KNO3 + KCl + Cl2 + H2O
65.Ca3(PO4)2 + Cl2 + C --> POCl3 + CO + CaCl2
66.As2S3 + HNO3 + H2O --> H3AsO4 + H2SO4 + NO
67.Al + NaNO3 + NaOH --> Na3AlO3 NH3 + H2O
68.K2MnO4 + H2O --> MnO2 + KMnO4 + KOH
69.Mn(OH)2 + Cl2 + KOH MnO2 + KCl + H2O
70.As2S3 + HNO3 + H2O --> H3AsO4 + H2SO4 + NO
71.NaBr + NaBrO3 + H2SO4 --> Br2 + Na2SO4 + H2O
72.Cr2O3 + KNO3 + KOH K2CrO4 + KNO2 + H2O.
73.CrI3 + Cl2 + KOH --> K2CrO4 + KIO4 + KCl + H2O
74.NaBr + NaBrO3 + H2SO4 --> Br2 + Na2SO4 + H2O
75.KMnO4 + K2SO3 + H2O --> MnO2+ K2SO4 + KOH
76.KMnO4 + KNO2 + H2O --> MnO2+ KNO3 + KOH
77.KMnO4 + SO2 + H2SO4 -->MnSO4 + K2SO4 + H2O
78.FeS2 + HNO3 + HCl FeCl3 + H2SO4 + NO + H2O
79.FeS + HNO3 --> Fe(NO3)3 + Fe2(SO4)3 + NO + H2O
80.FeS2 + HNO3 --> Fe(NO3)3 + H2SO4 + N2Ox + H2O
81.Zn + HNO3 --> Zn(NO3)2 + NO + NH4NO3 + H2O
82.FeS2 + HNO3 --> Fe(NO3)3 + NO + H2SO4 + H2O
83.CrI3 + Cl2 + KOH --> K2CrO4 + KIO4 + KCl + H2O
84.CrCl3 + Na2O2 + NaOH --> Na2CrO4 + NaCl + H2O
85.CrCl3 + Na2O2 + NaOH --> Na2CrO4 + NaCl + H2O
86.FeS2 + HNO3 + HCl --> FeCl3 + H2SO4 + NO + H2O
87.FeS + HNO3 --> Fe3(NO3)3 + Fe2(SO4)3 + NO + H2O
88.MnO2 + KBr + H2SO4 Br2 + MnSO4 + K2SO4 + H2O