Data Sheet for Chemistry A

(version 2.2)

GCE Advanced Level and Advanced Subsidiary

Chemistry A (H034, H434)
Chemistry A units F321F326
The information in this sheet is for the use of candidates following Chemistry A (H034 and H434). Copies
of this sheet may be used for teaching.

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Do not send this Data Sheet for marking; it should be retained in the centre or destroyed.

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up to the Invigilator at the end of the examination.

OCR 2014
GCE Chemistry A

DC (NH/SW) 90286

1H

NMR chemical shifts relative to TMS

H

HN

NH2

CH

*
OH

N
O

C
OH

12

HC

13C

HC

H
C

H
11

10

6
/ppm

HC

Cl

HC

Br

HC

CH

NMR chemical shifts relative to TMS

O

C
O
C

C
C

220

200

C
C

180

160

C
H

140

O
C

C
120

100

80

60

Cl

Br
40

20

/ppm

Chemical shifts are typical values and can vary slightly depending on the solvent, concentration and substituents.
*OH and NH chemical shifts are very variable (sometimes outside these limits) and are often broad. Signals are not usually seen as split peaks.
OCR 2014
GCE Chemistry A

The Periodic Table of the Elements

1

4.0

1.0

He

hydrogen

Key

helium

9.0

relative atomic mass

10.8

12.0

14.0

16.0

19.0

20.2

lithium

beryllium

name

boron

carbon

nitrogen

oxygen

fluorine

neon

23.0

24.3

27.0

28.1

31.0

32.1

35.5

39.9

sodium

magnesium

aluminium

silicon

phosphorus

sulfur

chlorine

argon

39.1

40.1

45.0

47.9

50.9

52.0

54.9

55.8

58.9

58.7

63.5

65.4

69.7

72.6

74.9

79.0

79.9

83.8

potassium

calcium

scandium

titanium

vanadium

chromium

manganese

25

iron

26

cobalt

nickel

copper

zinc

gallium

germanium

arsenic

selenium

bromine

krypton

85.5

87.6

88.9

91.2

92.9

95.9

[98]

101.1

102.9

106.4

107.9

112.4

114.8

118.7

121.8

127.6

126.9

131.3

6.9

Li
3

Na
11

19

Rb

Be

atomic symbol

atomic (proton) number

Mg

Al

12

Ca
20

Sr

13

Sc
21

Ti

22

Zr

23

Nb

Cr
24

Mo

Mn

Tc

Fe

Ru

Co
27

Rh

Ni
28

Pd

rubidium

strontium

yttrium

zirconium

niobium

molybdenum

technetium

ruthenium

rhodium

palladium

132.9

137.3

138.9

178.5

180.9

183.8

186.2

190.2

192.2

caesium

barium

lanthanum

hafnium

tantalum

tungsten

rhenium

osmium

[223]

[226]

[227]

[261]

[262]

[266]

[264]

francium

radium

actinium

rutherfordium

dubnium

seaborgium

140.1

140.9

cerium

37

Cs
55

Fr
87

38

Ba
56

Ra
88

39

La*
57

Ac*
89

Cu
29

Ag

Zn
30

Cd

Ga
31

In

silver

cadmium

indium

195.1

197.0

iridium

platinum

gold

[277]

[268]

[271]

bohrium

hassium

meitnerium

144.2

144.9

150.4

praseodymium

neodymium

promethium

232.0

[231]

238.1

thorium

protactinium

uranium

40

Hf
72

Rf

104

Ce
58

Th
90

41

Ta
73

Db

105

Pr
59

Pa
91

42

W
74

Sg

106

Nd
60

92

43

Re
75

Bh

107

44

Os
76

Hs

Ir

77

Mt

Pt
78

Ds

47

Au
79

Si
14

Ge
32

Sn

15

As
33

Sb

O
8

16

Se
34

Te

F
9

Cl
17

Br
35

50

200.6

204.4

207.2

209.0

[209]

[210]

[222]

mercury

thallium

lead

bismuth

polonium

astatine

radon

Hg
80

Tl
81

Pb
82

51

Bi
83

52

Po
84

53

At
85

Rg

168.9

173.0

175.0

samarium

europium

gadolinium

terbium

dysprosium

holmium

erbium

thulium

ytterbium

lutetium

[237]

[242]

[243]

[247]

[245]

[251]

[254]

[253]

[256]

[254]

[257]

neptunium

plutonium

americium

curium

berkelium

californium

einsteinium

fermium

mendelevium

nobelium

lawrencium

93

Pu
94

Am
95

Cm
96

54

Rn
86

Elements with atomic numbers 112116 have been reported but not
fully authenticated

167.3

Np

Xe

49

48

164.9

64

36

xenon

162.5

63

Kr

iodine

158.9

62

18

tellurium

157.2

61

Ar

[272]

darmstadtium roentgenium

Gd

10

antimony

152.0

Eu

Ne

tin

111

Sm

109

46

110

Pm

108

45

Tb
65

Bk
97

Dy
66

Cf
98

Ho
67

Es
99

Er
68

Fm
100

Tm
69

Md
101

Yb
70

No

102

Lu
71

Lr

103

OCR 2014
GCE Chemistry A

General Information

1 mol of gas molecules occupies 24.0 dm3 at room temperature and pressure, RTP.

Avogadro constant, NA = 6.02 1023 mol1.

Ionic product of water, Kw = 1.00 1014 mol2 dm6.

Characteristic infrared absorptions in organic molecules

bond

location

wavenumber/cm1

alcohols, esters, carboxylic acids

10001300

aldehydes, ketones, carboxylic acids, esters, amides

16401750

organic compound with a C

28503100

carboxylic acids

25003300 (very broad)

amines, amides

32003500

alcohols, phenols

H bond

32003550 (broad)

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OCR 2014
GCE Chemistry A