HOMEWORK 2 CHE 111

1. The equation for the reaction, AgNO3(aq) + K2CrO4(aq) Ag2CrO4(s) + KNO3(aq), can be written as an ionic equation. In the ionic equation, the spectator ions are ___________ 2. Write the net ionic equation for the reaction which takes place when HBr(aq) is added to NH3(aq). 3. Write the net ionic equation for the reaction which takes place when HNO3(aq) is added to Mg(OH)2(s). 4. What is the molar concentration of a solution prepared by dissolving 0.100 moles of potassium nitrate in enough water to prepare 500 mL of the solution? 5. 6.67 mL of 18.0 molar sulfuric acid solution was dissolved in enough water to make 500 mL of solution. The molarity of the diluted solution is ____________________ 6. Sodium acetate, NaC2H3O2, has a formula weight of 82.034 g/mol. What is the molar concentration of a solution prepared by dissolving 2.05 g of sodium acetate in enough water to prepare 250 mL of the solution? 7. How many grams of NiSO47H2O would be required to prepare 200 mL of a solution that is 0.10 M in NiSO4? 8. A 100.0 mL sample of 0.0200 M AgNO3(aq) was allowed to react with an excess of NaCl(aq). The AgCl precipitate from the reaction was carefully dried and weighed. How many grams of precipitate should be obtained? 9. Write the equation for the ionization of nitric acid with water. _____________ 10. Each of the following solutions, 0.10 M Ba(NO3)2(aq) 0.10 M Mg(NO3)2(aq) 0.1 M K2CO3 0.10 M AgNO3(aq) 0.10 M Pb(NO3)2(aq) 0.10 M Zn(NO3)2(aq) 0.1 M NaCl was treated with some 0.10 M H2SO4(aq). Which of the solutions will show a reaction? 11-12. Balance the following reactions: AgNO3 + KBr Ca(NO3)2 + Na2CO3

13-14. Write the oxidation numbers of each atom in the following compounds: HClO4 , K2SO4, SF6, SnO2 15-16. Write the oxidation numbers of each atom in the following ions: NH4+, NO3-, ClO4-, HPO42-

17-19. Write and balance the following reactions: Mg + HCl Ag + HNO3 AgNO3 + NO2 + H2O Hg + HNO3 Hg(NO3)2 + NO + H2O 20. Balance the half reaction, NO3- + H+ NH4+ + H2O , taking place in acidic media. How many electrons are needed to balance the half reaction?