TUTORIAL CHM524- CHAPTER 2-PART B

1. Define the Kohlrausch's L aw of the independent migration of ions.

2. Write the mean activity of Na2CO3, H2C2O4 , NH4Cl, K3PO4 in terms of ionic activity of
individual anions and cations. Assume complete dissociation
3. Calculate the value of m± in 5.0  10–4 molal solutions of (a) KCl, (b) Ca(NO3)2, and
(c) ZnSO4. Assume complete dissociation
4. Calculate γ±, and a± for a 0.0325 m solution of K4Fe(CN)6 at 298 K.
5. Calculate the Mean ionic molality of 0.025 M Barium hydroxide
6. Determine the ionic strength and mean activity coefficient of 0. 10 molal Na2SO4
solution.
7. Calculate the mean ionic activity of 0.035 m Na3PO4 with mean activity coefficient of
0.685
8. Calculate the molar solubility of BaSO4 in a) pure water, b) 0.01 M Na 2SO4 .
Comments the results.
9. Using the Debye-Hückel limiting law, calculate the of γ± in
5. 0 ×10–3 m of solutions of
a) KCl (Ans: 0.92)
c) ZnSO4 (Ans: 0.52)
Assume complete dissociation
10. The solubility of calcium sulphate is 0.67 g/L. Calculate the value of its Ksp
11. Calculate the mass( m) (in unit g) of KNO3 to add to 0.110mol/kg solution of KNO3( aq)
containing 5 00g of solvent i n order to raise its ionic strength to 1.00