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    Conductometric analysis measures the electrolytic conductivity of solutions to determine purity, content, and endpoints in titrations. It works by measuring how well a solution conducts an electric current, which depends on ion concentration and type. Conductivity increases linearly with concentration for some ranges and allows direct measurement of salt and acid solutions. It is commonly used to check purity of water and detect endpoints in volumetric analysis due to its inexpensive equipment requirements.

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    Conductometric analysis measures the electrolytic conductivity of solutions to determine purity, content, and endpoints in titrations. It works by measuring how well a solution conducts an electric current, which depends on ion concentration and type. Conductivity increases linearly with concentration for some ranges and allows direct measurement of salt and acid solutions. It is commonly used to check purity of water and detect endpoints in volumetric analysis due to its inexpensive equipment requirements.

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    9 views2 pages

    CLAS TS 018 1e

    Uploaded by

    ملاك المجره
    Conductometric analysis measures the electrolytic conductivity of solutions to determine purity, content, and endpoints in titrations. It works by measuring how well a solution conducts an electric current, which depends on ion concentration and type. Conductivity increases linearly with concentration for some ranges and allows direct measurement of salt and acid solutions. It is commonly used to check purity of water and detect endpoints in volumetric analysis due to its inexpensive equipment requirements.

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    Clariant Analytical Services

    Clariant Produkte (Deutschland) GmbH CLAS Rhein-Main

    TECHNICAL SHEET 018

    Conductometric analysis
    Applications Purity control of solutions (demineralized water in power stations, water for chromatography, high-purity water for chemical and pharmaceutical synthesis) Sensor/detector for titrations Quantification of contents of solutions (acid baths, salt solutions) Sensor in chemical plants for reaction control Ion chromatography detector

    Principle Determination of the electrolytic conductivity, generally called conductometric analysis, has been used for approx. 130 years. Conductometric analysis is the measurement of the alternating current conductivity of solutions. It is a nonspecific method. For qualitative results other techniques are required (e.g. ion chromatography - retention time of pure standards). The electrolytic conductivity is a sum parameter, resulting from the individual conductivities of the ions in the solution. The conductivity is a function of the concentration, which is linear within certain concentration ranges. The ion mobility, which determines the alternating current conductivity, depends on type of ion (size and hydration), the polarity of the solvent, the temperature and the viscosity. Direct conductometric concentration measurements can be made using inexpensive equipment in salt solutions or pure acids and bases. The main application of the conductometric analysis is the determination of an end point in volumetric analysis. The method is also widely used to check the total electrolyte content of water.

    contact: Di Patricia Teuscher CLAS Rhein-Main Industriepark Griesheim Lab 4301 Phone +049 (0) 69 3800 2992 patricia.teuscher@clariant.com

    +049 (0) 69 305 55055 CLAS@clariant.com

    www.clas.clariant.com

    Clariant Analytical Services

    TECHNICAL SHEET 018

    Conductometric analysis

    Principle and measurement setup of conductometric analysis

    Examples
    Conductometric titration of an NaOH/NH3 mixture with HCl

    Precipitation titrations with determination of equivalence point by conductometry

    +049 (0) 69 305 55055 CLAS@clariant.com

    www.clas.clariant.com

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