Energy

ms= +1/2

Allowed transition

ms= -1/2
Bo

ms = 1

Electron spin number,S

Nuclei spin number,I

1/2
-

Energy splitting :

ms
1/2
- 1/2

Energy

mi= -1
ms= +1/2

mi= 0
ms = +1 , mi = 0
mi= +1

mi= -1
ms= -1/2

mi= 0
mi= +1

electron zeeman
interaction

nuclear zeeman
interaction

Bo

Electron spin number,S

Nuclei spin number,I

1/2
1

Energy splitting :

ms
1/2

- 1/2

mi
-1
0
1
-1
0
1

Electron spin number,S

Nuclei spin number,I

1/2
9/2

Energy splitting :

ms

1/2

mi
-9/2
-7/2
-5/2
-3/2
-1/2
1/2
3/2
5/2
7/2
9/2
Allowed transition:
ms = +1 , mi = 0

1/2

-9/2
-7/2
-5/2
-3/2
-1/2
1/2
3/2
5/2
7/2
9/2

Electron spin number,S

Nuclei spin number,I

1/2
1/2

Energy splitting :

ms

mi

-1/2
1/2
1/2

-1/2
- 1/2
1/2

Allowed transition:
ms = +1 , mi = 0

Electron spin1/2
number,S
Nuclei spin number,I
9/2

Energy splitting :

- 1/2

Energy splitting :

ms

1/2

- 1/2

mi
-9/2
-7/2
-5/2
-3/2
-1/2
9/2
7/2
5/2
3/2
1/2
-9/2
-7/2
-5/2
-3/2
-1/2
9/2
7/2
5/2
3/2
1/2