THI TH I HC, CAO NG NM 2011- LN 1 Tr.

THPT PHAN CHU TRINH Mn: HA HC_ Khi A, B Thi gian lm bi: 90 pht, khng k thi gian pht thi ny gm c 04 trang M : 132 ------------------------------------------------------------------------------------------------------------------------Hc sinh dng bt ch t kn vo vng trn c ch ci tng ng vi la chn ng trong giy lm bi
Cu 1: Mi mi tn l mt phn ng v ch xt sn phm chnh, dy chuyn ha no sau y c phn ng khng th thc hin c?
H O , H ,t A. C6H5CH=CH2 2 Y1 CuO Y2 Ag. B. Heptan toluen axit benzoic T benzen.
o

S GD-T TP. NNG

CuO, t O2 , xt, t Br2 NaOH, t C. C3H6 X1 X2 X3 axit cacboxilic hai chc. 1:1
o o o

D. Lipit natri oleat axit oleic Z tristearin. Cu 2: Nhn nh no sau y lun ng ? A. Ion NH l ion c tnh axit nn tt c dung dch mui NH u c tnh axit. 4 4 B. Tt c cc mui hirophotphat u tan trong nc.
C. Tt c mui NO3 v NH u b nhit phn v u l cht in li mnh. 4 D. Ion NO3 l ion trung tnh nn tt c dung dch mui nitrat u c tnh trung tnh.

Cu 3: Th nghim no sau y khng to ra KClO3? A. Sc kh Cl2 qua dung dch KOH c nng. B. Sc kh O3 vo dung dch KCl nng. C. in phn khng mng ngn dung dch KCl c nng. D. Cho Ca(ClO3)2 tc dng vi KCl v lm lnh. Cu 4: Cc cht trong cc hn hp sau c cng s mol: Na v Al; K v Zn; Na v Al 2O3; Na v BaO. S hn hp tan ht trong nc d l A. 4. B. 1. C. 3. D. 2. Cu 5: Cho 14,8 gam hn hp X gm 2 ancol n chc A v B (MA < MB) tc dng Na (d), thu c 3,36 lt hiro (ktc). Oxi ha cng lng hn hp X c hn hp anehit Y. Cho ton b lng Y phn ng ht vi lng d AgNO3 trong NH3 thu c 86,4 gam Ag. B c s ng phn ancol l A. 5 B. 3 C. 4 D. 2 Cu 6: Cho phn ng: FeSO4 + K2Cr2O7 + KHSO4 Cr2(SO4)3 + ... Tng h s cc cht trong PTHH sau khi cn bng l A. 33 B. 32 C. 46 D. 40 Cu 7: Cho cc cp cht sau: CH3COOH v K2S; FeS v HCl; Na2S v HCl; CuS v H2SO4 long. C bao nhiu cp cht nu xy ra phn ng th c phng trnh ion thu gn l: 2H+ + S2 H2S? A. 2 B. 3 C. 4 D. 1 Cu 8: Hin tng no sau y khng ng? A. Cho dung dch AlCl3 vo dung dch Na[Al(OH)4] c kt ta xut hin. B. Hn hp AgCl v AgBr tan ht trong dung dch NH3 long d. C. Cho tinh du thng vo nc brom lc k th nc brom mt mu. D. Cho anilin vo hn hp NH4NO2 v CH3COOH th c kh bay ra. Cu 9: Phn ng no sau y khng ng?
t A. CH2=CH-CH2Cl + H2O CH2=CH-CH2OH + HCl B. 3CH2=CH-CH2OH + 2KMnO4 + 4H2O 3CH2OH-CHOH-CH2OH + 2KOH + 2MnO2 C. CH3CH=CHCHO + Br2 + H2O CH3CH=CHCOOH + 2HBr
o

D. Cl

CH=CH-CH2Cl + NaOH long

Cl

CH=CH-CH2OH + NaCl

Trang 1/4 - M thi 132

Cu 10: Khng c un nng hay c cn, ch c dng thm mt thuc th phn bit cc dung dch: HCl, KI, ZnBr2, Mg(NO3)2? Trong cc thuc th sau: dung dch AgNO3, dung dch NaOH, qu tm, dung dch NH3, c bao nhiu thuc th khng dng c? A. 2 B. 3 C. 1 D. 4 Cu 11: in phn (bng in cc tr, c mng ngn) dung dch cha 0,02 mol FeSO4 v 0,06 mol HCl vi dng in 1,34A trong 2 gi. Gi s hiu sut in phn l 100%, khi lng kim loi v tng th tch kh ( ktc) sinh ra ti cc in cc l A. 11,2 gam v 0,896 lt. B. 5,6 gam v 4,48 lt. C. 0,56 gam v 0,448 lt. D. 1,12 gam v 1,568 lt. Cu 12: X, Y, Z l 3 nguyn t cng chu k, bit rng: - Oxit ca X tan trong nc to ra dung dch c pH > 7 - Oxit ca Y tan trong nc to ra dung dch c pH < 7 - Oxit ca Z va tc dng vi dung dch HCl, va tc dng vi dung dch NaOH. Th t tng in tch ht nhn ca chng l: A. X < Z < Y B. X < Y < Z C. Y < X < Z D. Y < Z < X Cu 13: Tinh bt, xenluloz, saccaroz, mantoz u c kh nng tham gia A. phn ng vi [Cu(NH3)4](OH)2. B. phn ng thy phn. C. phn ng vi Cu(OH)2 nhit thng. D. phn ng kh vi Cu(OH)2 khi un nng. Cu 14: un nng 20 gam mt loi cht bo trung tnh vi dung dch cha 0,24 mol NaOH. Khi phn ng x phng ha xy ra hon ton, phi dng 0,18 mol HCl trung ha NaOH d. Vy khi lng NaOH cn x phng ha 1 tn cht bo trn, khi lng glixerol v khi lng x phng cha 72 % (theo khi lng) mui natri ca axit bo sinh ra t mt tn cht bo ln lt l: A. 120kg ; 92kg ; 1028kg B. 120kg ; 92kg ; 1427,77kg. C. 140kg ; 100kg ; 1040kg. D. 300kg ; 230kg ; 1070kg. Cu 15: Trong cc phn t sau: SiF4 , K2O2, Fe2O3 ,Na2O c bao nhiu phn t m tt c cc lin kt ho hc trong mi phn t u l lin kt ion? A. 1 B. 3 C. 4 D. 2 Cu 16: ng dng no sau y khng phi ca nc Gia-ven? A. Dng lm cht git ra. B. Tit trng. C. Ty mi hi. D. Ty trng vi si. Cu 17: Trn 5,13 gam bt Al vi 10 gam hn hp CuO, Fe2O3 ri tin hnh phn ng nhit nhm n khi phn ng hon ton. Hn hp sau phn ng c ho tan trong dung dch HNO3 long d thu c hn hp kh NO, N2O theo t l mol l 1: 2. Th tch ca hn hp kh ny ( ktc) l A. 1,344 lt. B. 1,792 lt. C. 2,016 lt. D. 0,672 lt. Cu 18: t chy hon ton 0,15 mol hn hp 2 ankan thu c 9,45g H2O. Cho sn phm chy vo dung dch Ca(OH)2 d th khi lng kt ta thu c l A. 37,5g. B. 52,5g. C. 15g. D. 42,5g. 2+ Cu 19: Nhng 1 l Mn vo dung dch Zn thy mt lp km ph ngoi l Mn. Mt khc, ion Co2+ c th oxi ha Zn thnh Zn2+ v ion H+ c th oxi ha Co thnh Co2+. Da vo kt qu thc nghim trn ngi ta xp cc cp oxi ha kh theo chiu tng th in cc chun nh sau: A. 2H+/H2 ; Co2+/Co ; Mn2+/Mn ; Zn2+/Zn B. 2H+/H2 ; Co2+/Co ; Zn2+/Zn ; Mn2+/ Mn C. Zn2+/Zn ; Co2+/Co ; Mn2+/Mn; 2H+/H2 D. Mn2+/Mn ; Zn2+/Zn ; Co2+/Co ; 2H+/H2 Cu 20: Hp cht C4H8O2 c s ng phn n chc, mch h l A. 7. B. 6. C. 4. D. 8. Cu 21: Cho 1,76 gam hn hp Z gm 2 cht hu c X, Y c cng cng thc phn t C 4H8O2 v c cng s mol tc dng ht vi dung dch NaOH to ra 2,06 gam hn hp mui. X, Y l A. CH3COOC2H5 v C2H5COOCH3. B. HCOOC3H7 v C2H5COOCH3. C. C3H7COOH v C2H5COOCH3. D. C3H7COOH v CH3COOC2H5. Cu 22: Cho aminoaxit X phn ng vi ancol metylic CH3OH thu c este Y c t khi hi so vi khng kh bng 3,07. X l A. axit 2-aminopropanonic B. axit aminoaxetic C. axit 2-aminopropanioic D. axit -aminopropionic

Trang 2/4 - M thi 132

Cu 23: t 11,2 gam bt Fe bng O2 thu c 13,6 gam cht rn X. Cho cht rn X tan hon ton trong dung dch HNO3 long, d thu c V lt kh NO (sn phm kh duy nht o ktc). V c gi tr l A. 1,12. B. 3,36. C. 2,24. D. 1,56. Cu 24: Cho hn hp gm FeO, CuO, Fe3O4 c cng s mol tc dng ht vi dung dch HNO3 thu c hn hp kh gm 0,09 mol NO2 v 0,05 mol NO. S mol HNO3 phn ng l A. 3,82 mol. B. 0,98 mol. C. 1,82 mol. D. 1,58 mol. Cu 25: Cho m gam hn hp X gm hai ancol n chc, k tip nhau trong dy ng ng tc dng vi CuO d, nung nng thu c mt hn hp rn Z v mt hn hp hi Y (c t khi hi so vi H 2 l 13,75). Cho ton b Y phn ng vi mt lng d AgNO3 trong dung dch NH3 un nng, sinh ra 64,8 gam Ag. Gi tr ca m l A. 6,76. B. 8,8. C. 7,8. D. 7,4. Cu 26: Trong cc cht sau: Fe2(SO4)3, Cu(NO3)2, CuSO3, Cu2O, Cu2S, c bao nhiu cht c th to ra CuSO4 bng mt phn ng? A. 3 B. 2 C. 4 D. 5 Cu 27: Cho 2,7g Al vo 400 ml dung dch FeCl3 1M, sau khi phn ng hon ton thu c dung dch X. Cho dung dch NaOH long d vo dung dch X thu c kt ta Y (khng cho tip xc khng kh). Khi lng Y l A. 21,4g. B. 37,7g. C. 32,1g. D. 45,5g. Cu 28: Xt cc cht hu c sau : (1) propanal; (2) propan-2-on; (3) propenal; (4) prop-2-in-1-ol. S cht khi tc dng vi H2 d (xc tc Ni, to) u cho sn phm ging nhau l A. 2 B. 3 . C. 4 D. 1 Cu 29: Cho 1,344 lt kh NH3 (ktc) qua ng cha 8g CuO nung nng. Sau phn ng thu c cht rn X. Cho X tc dng vi dung dch HNO3 1M th c kh NO (sn phm kh duy nht ktc). Cc phn ng xy ra hon ton. Th tch dung dch axit cn dng ho tan X l A. 80ml. B. 240ml. C. 60ml. D. 260ml. Cu 30: t chy hon ton 1 mol este X thu c 3 mol kh CO2. Mt khc khi x phng ha 0,1 mol este trn thu c 8,2 gam mui cha natri. S ng phn mch h, n chc ng vi CTPT ca X l A. 2 B. 4 C. 5 D. 3 Cu 31: t chy hon ton 0,4 mol hn hp A gm 2 anken lin tip , c m gam nc v (m + 39) gam CO2. CTPT ca 2 anken ny l A. C5H10 v C6H12 B. C3H6 v C4H8 C. C2H4 v C3H6. D. C4H8 v C5H10. Cu 32: Pht biu no sau y ng? A. ng phn l cc cht c cng cng thc phn t, nhng do cng thc cu to khc nhau nn tnh cht khc nhau. B. Cc cht khc nhau c cng thc chung l CnH2n (n 2) u cng dy ng ng C. Dy ng ng l tp hp cc cht c cng thc phn t hn km nhau mt hay nhiu nhm metylen. D. Tt c cc cht c cng thc phn t khc nhau nhng c cng thc chung l CnH2n+2 u cng dy ng ng. Cu 33: Cho m1 gam hn hp K2O, Al2O3 tan ht trong nc thu c 100 ml dung dch X ch cha mt cht tan c nng 1M. Sc CO2 d vo dung dch X thu c m2 gam kt ta. Gi tr ca m1 v m2 ln lt l A. 4,9 v 7,8. B. 4,9 v 3,9. C. 9,8 v 7,8. D. 14,7 v 11,7. Cu 34: Cho 183 gam mt loi cao su buna-S phn ng va ht vi dung dch cha 0,5 mol Br2 trong CCl4. T l kt hp ca butaien v stiren trong cao su buna-S ny l A. 1 : 3. B. 1 : 2. C. 2 : 3. D. 3 : 5. Cu 35: kh hon ton mt lng anehit n chc mch h X cn 4a mol H2. Sn phm thu c cho tc dng ht vi Na thu c a mol H2. Dy ng ng ca X c cng thc chung l A. CnH2n-1CHO ( n 2.) B. CnH2n-3CHO (n 4). C. CnH2n-7CHO (n 6). D. CnH2n-2CHO ( n 3). Cu 36: Thy phn 34,2 gam hn hp saccaroz v mantoz c cng s mol vi hiu sut 50% thu c dung dch X. Khi lng Ag sinh ra khi cho ton b dung dch tc dng vi lng d dung dch AgNO3 trong NH3 l A. 27 gam B. 32,4 gam C. 21,6 gam D. 43,2 gam Cu 37: Cho 1,62 gam nhm vo 100 ml dung dch cha CuSO4 0,6M v Fe2(SO4)3 xM. Kt thc phn ng thu c 4,96 gam cht rn gm 2 kim loi. Gi tr ca X l A. 0,15. B. 0,1. C. 0,2. D. 0,25. Trang 3/4 - M thi 132

Cu 38: Hin nay sn xut nha P.V.C ngi ta s dng nguyn liu u tin l A. vi v than B. cacbua canxi C. cn cng nghip D. etilen Cu 39: Hn hp X gm Na, Ba v Al tan ht trong nc to ra dung dch X v thot ra 0,12 mol hiro. Th tch dung dch HCl 2M ti thiu cn dng tc dng vi dung dch X to ra dung dch trong sut l A. 60 ml. B. 120 ml. C. 240 ml. D. 1,20 lt. Cu 40: Dy no di y ch gm cc cht c th lm nht mu dung dch nc Br2? A. Axit axetic, propilen, axetilen. B. Etilen, axit acrilic, saccaroz. C. Metylxiclopropan, glucoz, axit fomic. D. Buta-1,3-ien, metylaxetilen, cumen. Cu 41: Cho a mol Mg v b mol Zn dng bt vo dung dch cha c mol Cu(NO3)2 v d mol AgNO3 thu c dung dch cha 3 mui. (Bit a < c + 0,5d). Quan h gia a, b, c, d l: A. b < c - a +

1 d 2

B. b < a + c -

1 d 2

C. b > c - a +d

D. a > c + d -

b 2

Cu 42: C 3 dung dch: (NH4)2CO3, Na[Al(OH)4], C6H5ONa v 3 cht lng: C6H5CH3, C6H6, C6H5NH2 ng trong cc l ring bit mt nhn. Khng c un nng hay c cn, nu ch dng dung dch HCl th phn bit bao nhiu cht? A. 3 B. 6 C. 5 D. 4 Cu 43: Nhng 1 thanh kim loi M vo 1 lt dung dch CuSO4 xM, kt thc phn ng thy thanh kim loi M tng 20 gam. Nu cng nhng thanh kim loi trn vo 1 lt dung dch FeSO4 xM, kt thc phn ng th thy thanh M tng 16 gam. Vy M l A. Mg. B. Ni. C. Mn. D. Zn. Cu 44: Cho cht hu c X c cng thc phn t l C7H8 tc dng vi AgNO3 d trong dung dch NH3 thu c cht Y. Phn t khi ca Y ln hn phn t khi ca X l 214. S ng phn cu to ca X l A. 5. B. 4. C. 3. D. 2. Cu 45: Cho s phn ng: C2H2 X Y CH3COOH. Trong cc cht sau: CH2=CH-OOCCH3,C2H4, CO2, C2H5OH, CH3CHO, s cht ph hp vi X l A. 3. B. 2. C. 4. D. 1. Cu 46: Thanh st c ph mt lp bo v nhng lp bo v b sy st su n lp st bn trong. Trng hp no sau y thanh st b n mn nhanh nht? A. Lp bo v l ng. B. Lp bo v l crom. C. Lp bo v l km D. Lp bo v l nha. Cu 47: Nhn nh no di y ng? A. Cc nguyn t c s in tch ht nhn bng 19, 24, 29 u c s electron ha tr l 4s1. B. Nguyn t c cc electron ha tr l 4d25s2 thuc chu k 5, nhm IIA. C. Nguyn t chu k 5, nhm VIIA c cc electron ha tr l 5s25p5. D. Nguyn t chu k 4, nhm VIB c cc electron ha tr l 3d44s2 Cu 48: Mi mi tn l mt phn ng, dy chuyn ha no sau y khng th thc hin c? A. Cl2 Ca(ClO)2 Cl2 I2 AlI3
HCN 2 2 2, B. CH2=CH2 B D Ag C. Glucoz X CH3COOH Y CH3CHO Z CH4. D. H2SO4 X FeS Y SO2 MgS Cu 49: Ho tan a gam oleum H2SO4.3SO3 vo 131gam dung dch H2SO4 40% thu c mt oleum cha 10% SO3 v khi lng. Gi tr ca a l A. 594,0 B. 570,8 C. 630,0 D. 651,4 Cu 50: Cho hn hp kh: O2, CO2, N2, H2S v hi H2O. C bao nhiu cht trong cc cht sau: CaCl2 (khan), P2O5 (khan), H2SO4 c, CuSO4 (khan) c th lm kh hn hp kh trn? A. 4 B. 2 C. 3 D. 1 ----------------------------------------------------- HT ---------Th sinh c s dng bng tun hon cc nguyn t ha hc v my tnh cm tay
O , PdCl , CuCl , t o

Trang 4/4 - M thi 132