Trng THPT chuyn TRN I NGHA THI TH I HC NM HC 2013 2014

( c 50 cu bt buc) MN HA HC. Thi gian lm bi: 90 pht.

M : 155
(Cho bit cc nguyn t khi: He=4, H=1, C=12, O=16, S=32, N=14, Cl=35,5; Br=80, Na=23, K=39,
Mg=24, Al=27, Ca=40, Cr= 52, Mn=55, Fe=56, Zn=65, Cu=64, Ag=108, Ba=137).

Cu 1. Cho 6,175 gam Zn tc dng va vi dung dch cha a mol HNO3. Sau phn ng thu c dung dch X v
0,448 lit hn hp kh Y gm NO, N2O. T khi hi ca Y so vi H2 l 18,5. C cn dung dch X thu c b gam
mui. Gi tr ca a v b ln lt l
A. 0,24 v 18,735. B. 0,14 v 17,955. C. 0,24 v 18,755. D. 0,14 v 18,755.
Cu 2. Nung nng hn hp gm bt Al v bt Fe3O4 trong mi trng khng c khng kh (xy ra phn ng
nhit nhm, hiu sut 100%). Cc cht sau phn ng cho tc dng vi dung dch NaOH (d), thu c 6,72 lt
kh H2 (ktc), cng lng cht ny nu tc dng vi dung dch H2SO4 long (d) thu c 26,88 lt kh H2
(ktc). Khi lng bt Al v Fe3O4 trong hn hp u ln lt l
A. 27 gam v 34,8 gam. B. 27 gam v 69,6 gam.
C. 54 gam v 69,6 gam. D. 54 gam v 34,8 gam.
Cu 3. t chy hon ton 0,11 gam mt este X thu c 0,22 gam CO2 v 0,09 gam H2O. S ng phn
este ca X l
A. 4. B. 3. C. 6. D. 2.
Cu 4. Xt ba nguyn t X, Y, Z c cu hnh electron ln lt l: X: 1s
2
2s
2
2p
6
3s
1
, Y: 1s
2
2s
2
2p
6
3s
2
,
Z: 1s
2
2s
2
2p
6
3s
2
3p
1
. Sp xp hiroxit ca X, Y, Z theo th t tng dn lc baz l
A. Y(OH)2 < Z(OH)3 < XOH. B. Z(OH)2 < Y(OH)3 < XOH.
C. Z(OH)3 < Y(OH)2 < XOH. D. XOH < Y(OH)2 < Z(OH)3.
Cu 5. lm sch mui n c ln tp cht CaCl2, MgCl2, BaCl2 cn dng 2 ho cht l
A. dung dch AgNO3, dung dch NaOH. B. dung dch Na2SO4, dung dch HCl.
C. dung dch NaOH, dung dch H2SO4. D. dung dch Na2CO3, dung dch HCl.
Cu 6. Cho cn bng: CH4(k) + H2O(k)

CO(k) + 3H2(k). Khi gim nhit th t khi ca hn hp kh so

vi H2 gim i. Pht biu ng khi ni v cn bng ny l
A. Phn ng thun to nhit, cn bng dch chuyn theo chiu thun khi tng nhit .
B. Phn ng nghch to nhit, cn bng dch chuyn theo chiu nghch khi tng nhit .
C. Phn ng thun thu nhit, cn bng dch chuyn theo chiu thun khi tng nhit .
D. Phn ng nghch thu nhit, cn bng dch chuyn theo chiu thun khi gim nhit .
Cu 7. Hp cht hu c thm X c cng thc CxHyO2 cha 6,45% H v khi lng. Khi cho cng mt s mol
X tc dng vi Na v NaOH th s mol hidro bay ra bng s mol NaOH phn ng. S ng phn X tha iu
kin trn l
A. 4. B. 3. C. 1. D. 2.
Cu 8. Cho 4,48 lit CO2 hp th ht vo 100 ml dung dch hn hp gm NaOH 0,6M v Ba(OH)2 1,2M sinh
ra kt ta v dung dch X. C cn dung dch X thu c m gam mui. Gi tr ca m l
A. 5,18. B. 5,04. C. 7,12. D. 10,22.
Cu 9. Mt oxit kim loi b kh hon ton cn 1,792 lit kh CO (ktc) thu c m gam kim loi R. Ha tan
ht m gam R bng dung dch HNO3 c nng thu c 4,032 lit kh NO2 duy nht (ktc). CTPT ca oxit l
A. Cr2O3. B. CrO. C. Fe3O4. D. FeO.
Cu 10. Cho cc phn ng: (1) O3 + dung dch KI, (2) F2 + H2O, (3) MnO2 + HCl (t
o
), (4) Cl2 + CH4, (5) Cl2 +
NH3 d, (6) CuO + NH3 (t
o
), (7) KMnO4 (t
o
), (8) H2S + SO2, (9) NH4Cl + NaNO2 (t
o
), (10) NH3 + O2 (Pt,
800
o
C). S phn ng c to ra n cht l
A. 6. B. 8. C. 7. D. 9.
Cu 11. Hn hp X gm 2 cht hu c n chc, u c cha C, H, O, u c %O = 53,33%.
-m gam hn hp X tc dng vi dung dch AgNO3/NH3 d, t
0
thu c ti a 12,96 gam Ag.
-m gam hn hp X tc dng va vi 336ml H2 ktc (Ni, t
0
).
T l khi lng ca hai cht hu c trong m gam hn hp X l
A. 1:1. B. 1:2. C. 1:3. D. 1: 4.
Cu 12. Cho cc cng thc phn t: C4H10O, C4H9Cl, C4H11N, C4H8. Cng thc phn t c s ng phn cu
to nhiu nht l
A. C4H10O. B. C4H11N. C. C4H9Cl. D. C4H8.
Cu 13. Pht biu no sau y ng ?
A. Lin kt peptit l lin kt -CO-NH- gia 2 n v amino axit.
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B. Trong mi trng kim, cc peptit u c phn ng mu biure (tao phc cht mu tm).
C. Tt c cc peptit u c kh nng tham gia phn ng thy phn.
D. Khi cho dung dch lng trng trng vo Cu(OH)2 thy xut hin phc cht mu xanh thm.
Cu 14. Tng s ht mang in trong anion
2
3
XY

bng 82. S ht proton trong ht nhn nguyn t X nhiu

hn s ht proton trong ht nhn nguyn t Y l 8 ht. S hiu nguyn t ca X, Y ln lt l
A. 16 v 8. B. 15 v 7. C. 14 v 8. D. 17 v 9.
Cu 15. Cho cc pht biu:
(1) Phn ng thy phn este trong mi trng axit l phn ng thun nghch.
(2) Cht bo l trieste ca etylen glicol vi cc axit bo.
(3) Tristearin, triolein c cng thc ln lt l: (C17H33COO)3C3H5, (C17H35COO)3C3H5.
(4) Cc cht bo thng khng tan trong nc v nh hn nc.
(5) Triolein c kh nng tham gia phn ng cng hiro khi un nng c xc tc Ni.
(6) Cht bo b thy phn khi un nng trong dung dch kim to axit bo v glixerol.
S pht biu ng l
A. 6. B. 3. C. 4. D. 5.
Cu 16. Oxi ha 0,16 mol mt ancol n chc, thu c hn hp X gm 1 axit cacboxylic, 1 andehit, ancol
d v H2O. Ngng t ton b X ri chia lm 2 phn bng nhau. Phn 1 cho tc dng ht vi Na d, thu c
1,008 lit kh H2 (ktc). Phn 2 cho phn ng trng bc hon ton thu c 19,44 gam Ag. Phn trm khi
lng ancol b oxi ha l
A. 31,25%. B. 62,5%. C. 40%. D. 15%.
Cu 17. Hn hp X gm axit glutamic v lysin. Bit:
- Cho m gam X phn ng va vi V lit dung dch HCl 1M.
- Cho m gam X phn ng va vi V/2 lit dung dch NaOH 2M.
Phn trm khi lng ca axit glutamic trong X l
A. 66,81%. B. 35,08%. C. 50,17%. D. 33,48%.
Cu 18. Cho cc cht sau: phenol, glixerol, glucoz, saccaroz, mantoz, fructoz, benzanehit, anhit
acrylic, axit axetic, propanal, axit fomic, xenluloz, etyl fomat, axetilen, vinylaxetilen. S cht tham gia phn
ng trng gng l
A. 8 cht. B. 9 cht. C. 7 cht. D. 6 cht.
Cu 19. Mt loi phn ure cha 95% (NH2)2CO, cn li l (NH4)2CO3. dinh dng ca loi phn ny l
A. 46,00%. B. 43,56%. C. 44,33%. D. 45,79%.
Cu 20. Cho este X c cng thc phn t l C4H6O2 phn ng vi dung dch NaOH, t
o
theo s sau:
X + NaOH mui Y + anehit Z. Cho bit phn t khi ca Y nh hn 70. X l
A. HCOOCH=CHCH3. B. CH3COOCH=CH2. C. HCOOCH2CH=CH2. D. CH2=CHCOOCH3.
Cu 21. Hn hp X gm tripeptit A v tetrapeptit B u c cu to bi glyxin v alanin. Thnh phn phn
trm khi lng nit trong A v B theo th t l 19,36% v 19,44%. Thy phn hon 0,1 mol hn hp X bng
mt lng dung dch NaOH va , thu c dung dch Y. C cn dung dch Y thu c 36,34 gam hn hp
mui. T l mol gia A v B trong hn hp X l
A. 2:3. B. 7:3. C. 3:2. D. 3:7.
Cu 22. Chia i V lt (ktc) hn hp kh gm axetilen v hidro. Phn 1 em t chy hon ton thu c 9
gam nc. Dn phn 2 qua ng s ng bt Ni un nng, thu c kh X. Dn X ln lt qua dung dch d
AgNO3 trong NH3 v dung dch d brom ng trong cc bnh A v B ni tip. bnh A thu c 12 gam kt
ta. t chy hon ton lng kh Y i ra t bnh B c 4,5 gam nc. Gi tr ca V v s mol brom phn
ng ti a trong B l
A. 11,2 lt v 0,2 mol. B. 22,4 lit v 0,1 mol. C. 22,4 lit v 0,2 mol. D. 11,2 lit v 1,01 mol.
Cu 23.
Cho cc pht biu di y:
(1) Cc halogen (F, Cl, Br, I) c s oxi ha t 1 n +7.
(2) Flo l cht ch c tnh oxi ha.
(3) F2 y c Cl2 ra khi dung dch mui NaCl.
(4) Tnh axit ca cc hp cht vi hiro ca cc halogen tng theo th t: HF < HCl < HBr < HI.
Cc pht biu lun ng l
A. (2), (3), (4). B. (2). C. (2), (4). D. (1), (2), (4).
Cu 24. Trong phn t hidroclorua c lin kt ha hc thuc loi
A. lin kt cng ha tr khng phn cc. B. lin kt cng ha tr phn cc.
C. lin kt hidro. D. lin kt ion.
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Cu 25. Khi ha tan cng mt lng kim loi R vo dung dch HNO3 c nng (d) hoc dung dch H2SO4
long (d) th th tch kh NO2 (sn phm kh duy nht) thu c gp 3 ln th tch kh H2 cng iu kin t
o

v p sut. Khi lng mui sunfat thu c bng 62,81% khi lng mui nitrat to thnh. Kim loi R l
A. Zn B. Sn C. Cr D. Fe
Cu 26. Cho t t kim loi Ba ln lt vo 6 dung dch mt nhn l: NaCl, NH4Cl, FeCl3, AlCl3, (NH4)2CO3,
MgCl2. C th nhn bit c bao nhiu dung dch sau khi cc phn ng xy ra xong?
A. 4. B. 3. C. 5. D. 6.
Cu 27. Hn hp X cha K2O, NH4Cl, KHCO3 v BaCl2 c s mol bng nhau. Cho hn hp X vo nc (d),
un nng, dung dch thu c cha
A. KCl, KOH, BaCl2. B. KCl, KHCO3, BaCl2. C. KCl. D. KCl, KOH.
Cu 28. Chia m gam hn hp cc kim loi Al, Fe, Ba thnh 3 phn bng nhau.
Phn 1 tc dng vi nc d, thu c 0,896 lit H2 (ktc).
Phn 2 tc dng vi dung dch NaOH d thu c 1,568 lit H2 (ktc).
Phn 3 tc dng vi dung dch HCl d thu c 2,24 lit H2 (ktc).
Gi tr ca m l
A. 12,39. B. 24,78. C. 4,13. D. 8,26.
Cu 29. in phn dung dch cha m gam hn hp 2 mui CuSO4 v NaCl bng in cc tr, c mng ngn
n khi nc b in phn c 2 in cc th ngng in phn. Dung dch sau in phn ho tan va 1,16
gam Fe3O4 v anot ca bnh in phn c 448 ml kh bay ra (ktc). Khi lng dung dch gim sau khi in
phn l
A. 7,10. B. 1,03. C. 8,60. D. 2,95.
Cu 30. Triolein khng tc dng vi cht (hoc dung dch) no sau y ?
A. Cu(OH)2 ( iu kin thng). B. H2 (xc tc Ni, un nng).
C. H2O (xc tc H2SO4 long, un nng). D. Dung dch NaOH (un nng).
Cu 31. Khi ni v kim loi kim th, pht biu no sau y l sai ?
A. Phng php c bn iu ch kim loi kim th l in phn mui clorua nng chy ca chng.
B. T beri n bari kh nng phn ng vi H2O gim dn.
C. Khi t nng, cc kim loi kim th u bc chy trong khng kh.
D. Cc kim loi canxi v stronti c cng kiu mng tinh th lp phng tm din.
Cu 32. Ha tan hon ton hn hp gm 0,002 mol FeS2 v 0,003 mol FeS vo lng d dung dch H2SO4
c nng thu c Fe2(SO4)3, SO2 v H2O. Hp th ht lng SO2 trn bng 1 lng va dung dch
KMnO4 thu c dung dch X c pH = 2. Th tch ca dung dch X l
A. 2,00 lit. B. 1,50 lit. C. 1,14 lit. D. 2,28 lit.
Cu 33. Este n chc X c t khi hi so vi CH4 l 6,25. Cho 20 gam X tc dng 300 ml dung dch KOH
1M, t. C cn dung dch sau phn ng thu c 28 gam cht rn khan. Cng thc ca X l
A. CH3CH2COOCH=CH2. B. CH2=CHCH2COOCH3.
C. CH3COOCH=CHCH3. D. CH2=CHCOOCH2CH3.
Cu 34. Cho cng thc cu to ca cht X: HOOC-CH(CH3)-NH-CO-CH2-NH2 v cc pht biu sau:
(1). X l ipeptit to thnh t alanin v glyxin. (2). X c tn l alanylglyxin (Ala-Gly).
(3). X c phn ng mu biure. (4). X lm qu tm m ho .
(5). un nng X trong dung dch HCl d n phn ng hon ton c hn hp hai -aminoaxit.
S pht biu ng l
A. 2. B. 1. C. 4. D. 3.
Cu 35. Cho cc cht: Al2O3, Fe2O3, NaHCO3, Al, KHS, (NH4)2CO3, CH3COONa, Zn(OH)2. S cht trong
dy va phn ng c vi dung dch HCl, va phn ng c vi dung dch NaOH l
A. 4. B. 7. C. 5. D. 6.
Cu 36. S in phn dung dch CuCl2 (vi in cc tr) v s n mn in ho xy ra khi nhng hp kim
Zn - Cu vo dung dch HCl c c im chung l
A. cc dng u l s oxi ho Cl
-
. B. u sinh ra Cu cc m.
C. catot u xy ra s kh. D. u km theo s pht sinh dng in.
Cu 37. Hn hp X gm mt axit cacboxylic no, n chc A v mt ancol no n chc B (A v B u mch
h v c khi lng phn t bng nhau). t chy hon ton m gam hn hp X c 0,2 mol kh CO2. Cho m
gam hn hp X tc dng vi Na d thu c 0,84 lt H2 (ktc). T l khi lng ca hai cht A v B trong
hn hp X l
A. 1:1. B. 1:3. C. 1:4. D. 1:2.
Cu 38. Khi t chy mt polime sinh ra t phn ng ng trng hp isopren vi acrilonitrin bng lng oxi
va thu c hn hp kh gm CO2, hi H2O v N2 trong CO2 chim 58,33% v th tch. T l s mt
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xch isopren v acrilonitrin trong polime trn l
A. 3:2. B. 1:2. C. 2:1. D. 1:3.
Cu 39. C bao nhiu ng phn cu to, mch h c cng thc phn t C5H8 tc dng vi H2 d (xc tc
thch hp) thu c sn phm isopentan ?
A. 4. B. 6. C. 2. D. 3.
Cu 40. Trong kh thi cng nghip thng cha cc kh SO2, NO2, HF. Ngi ta dng cht no sau y l
tit kim nht loi b cc kh ?
A. NaOH. B. KOH C. Ca(OH)2. D. Ba(OH)2.
Cu 41. Chn pht biu ng
A. C5H12O c 8 ng phn thuc loi ancol.
B. Ancol l hp cht hu c trong phn t c nhm -OH.
C. Hp cht C6H5-CH2OH l phenol.
D. C4H10O c 2 ng phn ancol bc 2.
Cu 42. Cho 31,9 gam hn hp Al2O3, ZnO, FeO, CaO tc dng vi CO d, un nng thu c 28,7 gam hn hp X
(cc phn ng xy ra hon ton). Cho X tc dng vi dung dch HCl d thu c V lt kh H2 (ktc). V c gi tr l
A. 4,48 lt. B. 11,2 lt. C. 5,60 lt. D. 6,72 lt.
Cu 43. un nng 34,2 gam mantoz trong dung dch axit sunfuric long. Trung ha dung dch thu c sau
phn ng bng dung dch NaOH ri cho tc dng hon ton vi dung dch AgNO3/NH3 d, un nng thu c
37,8 gam Ag. Hiu sut phn ng thy phn mantoz l
A. 75,0%. B. 69,27%. C. 62,5%. D. 87,5%.
Cu 44. Hn hp X gm 3 ancol A, B, C u no, h, khi lng mol theo th t lp thnh 1 cp s cng vi
cng sai 30. t chy hon ton hn hp X thu c 13,44 lit CO2(ktc) v 16,2 gam H2O. S mol ancol C
bng 1/3 s mol hn hp X. Phn trm khi lng ancol C trong X l
A. 66,67%. B. 33,33%. C. 50,54%. D. 49,46%.
Cu 45. Cho tng cht C, Fe, BaCl2, Fe3O4, FeCO3, FeS, H2S, HI, AgNO3, HCl, Fe2O3, FeSO4 ln lt tc
dng vi H2SO4 c, nng. S phn ng thuc loi phn ng oxi ha - kh l
A. 6. B. 7. C. 9. D. 8.
Cu 46. Ha tan ht 0,15 mol P2O5 vo 200 gam dung dch H3PO4 9,8%, thu c dung dch X. Cho X tc
dng ht vi 750 ml dung dch NaOH 1M, thu c dung dch Y. Khi lng mui trong Y l
A. 14,2 gam Na2HPO4; 41,0 gam Na3PO4. B. 30,0 gam NaH2PO4; 35,5 gam Na2HPO4.
C. 45,0 gam NaH2PO4; 17,5 gam Na2HPO4. D. 30,0 gam Na2HPO4; 35,5 gam Na3PO4.
Cu 47. C 4 nhn xt sau
(1) Hn hp Na2O + Al2O3 (t l mol 1: 1) tan ht trong nc d.
(2) Hn hp Fe2O3 + Cu (t l mol 1: 1) tan ht trong dung dch HCl d.
(3) Hn hp KNO3 + Cu (t l mol 1: 1) tan ht trong dung dch H2SO4 long d.
(4) Hn hp FeS + CuS (t l mol 1:1) tan ht trong dung dch HCl d.
S nhn xt ng l
A. 4. B. 3. C. 2. D. 1.
Cu 48. Cho cc dung dch: HCl (X1); KNO3 (X2); HCl v Fe(NO3)2 (X3); Fe2(SO4)3 (X4). Dung dch c th
tc dng vi bt Cu l
A. X3, X4. B. X1, X3, X4. C. X1, X4. D. X4.
Cu 49. C cc kt lun sau:
(1) T glyxin, alanin v valin s to ra c 6 tripeptit cha ng thi glyxin, alanin v valin.
(2) C8H10O c 4 ancol thm khi b oxi ha to ra sn phm c kh nng tham gia phn ng trng gng.
(3) C4H8 c 4 ng phn lm mt mu dung dch brom.
(4) C4H11N c 4 ng phn khi tc dng vi HCl to ra mui dng RNH3Cl.
S kt lun ng l
A. 3. B. 1. C. 4. D. 2.
Cu 50. Cho cc cp cht sau: Cu v dung dch FeCl3, dung dch CuSO4 v H2S, dung dch FeCl2 v H2S,
dung dch FeCl3 v H2S, dung dch Fe(NO3)2 v HCl, dung dch BaCl2 v dung dch NaHCO3, dung dch
KHSO4 v dung dch Na2CO3. S cp cht xy ra phn ng khi trn ln vo nhau l
A. 7. B. 4. C. 5. D. 6.
----------------------------------------------------------------------------------------------------------
M : 155




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Trng THPT chuyn TRN I NGHA THI TH I HC NM HC 2013 2014
( c 50 cu bt buc) MN HA HC. Thi gian lm bi: 90 pht.
M : 189
(Cho bit cc nguyn t khi: He=4, H=1, C=12, O=16, S=32, N=14, Cl=35,5; Br=80, Na=23, K=39,
Mg=24, Al=27, Ca=40, Cr= 52, Mn=55, Fe=56, Zn=65, Cu=64, Ag=108, Ba=137).

Cu 1. Hn hp X gm 2 cht hu c n chc, u c cha C, H, O, u c %O = 53,33%.
-m gam hn hp X tc dng vi dung dch AgNO3/NH3 d, t
0
thu c ti a 12,96 gam Ag.
-m gam hn hp X tc dng va vi 336ml H2 ktc (Ni, t
0
).
T l khi lng ca hai cht hu c trong m gam hn hp X l
A. 1:1. B. 1:2. C. 1: 4. D. 1:3.
Cu 2. Cho cc pht biu:
(1) Phn ng thy phn este trong mi trng axit l phn ng thun nghch.
(2) Cht bo l trieste ca etylen glicol vi cc axit bo.
(3) Tristearin, triolein c cng thc ln lt l: (C17H33COO)3C3H5, (C17H35COO)3C3H5.
(4) Cc cht bo thng khng tan trong nc v nh hn nc.
(5) Triolein c kh nng tham gia phn ng cng hiro khi un nng c xc tc Ni.
(6) Cht bo b thy phn khi un nng trong dung dch kim to axit bo v glixerol.
S pht biu ng l
A. 5. B. 4. C. 3. D. 6.
Cu 3. Hn hp X gm tripeptit A v tetrapeptit B u c cu to bi glyxin v alanin. Thnh phn phn
trm khi lng nit trong A v B theo th t l 19,36% v 19,44%. Thy phn hon 0,1 mol hn hp X bng
mt lng dung dch NaOH va , thu c dung dch Y. C cn dung dch Y thu c 36,34 gam hn hp
mui. T l mol gia A v B trong hn hp X l
A. 2:3. B. 7:3. C. 3:2. D. 3:7.
Cu 4. Cho tng cht C, Fe, BaCl2, Fe3O4, FeCO3, FeS, H2S, HI, AgNO3, HCl, Fe2O3, FeSO4 ln lt tc
dng vi H2SO4 c, nng. S phn ng thuc loi phn ng oxi ha - kh l
A. 6. B. 9. C. 7. D. 8.
Cu 5. Tng s ht mang in trong anion
2
3
XY

bng 82. S ht proton trong ht nhn nguyn t X nhiu

hn s ht proton trong ht nhn nguyn t Y l 8 ht. S hiu nguyn t ca X, Y ln lt l
A. 17 v 9. B. 16 v 8. C. 14 v 8. D. 15 v 7.
Cu 6. in phn dung dch cha m gam hn hp 2 mui CuSO4 v NaCl bng in cc tr, c mng ngn
n khi nc b in phn c 2 in cc th ngng in phn. Dung dch sau in phn ho tan va 1,16
gam Fe3O4 v anot ca bnh in phn c 448 ml kh bay ra (ktc). Khi lng dung dch gim sau khi in
phn l
A. 7,10. B. 1,03. C. 8,60. D. 2,95.
Cu 7. Este n chc X c t khi hi so vi CH4 l 6,25. Cho 20 gam X tc dng 300 ml dung dch KOH
1M(t). C cn dung dch sau phn ng thu c 28 gam cht rn khan. Cng thc ca X l
A. CH2=CHCH2COOCH3. B. CH3CH2COOCH=CH2.
C. CH3COOCH=CHCH3. D. CH2=CHCOOCH2CH3.
Cu 8. Pht biu no sau y ng ?
A. Trong mi trng kim, cc peptit u c phn ng mu biure (tao phc cht mu tm).
B. Tt c cc peptit u c kh nng tham gia phn ng thy phn.
C. Lin kt peptit l lin kt -CO-NH- gia 2 n v amino axit.
D. Khi cho dung dch lng trng trng vo Cu(OH)2 thy xut hin phc cht mu xanh thm.
Cu 9. Cho cn bng: CH4(k) + H2O(k) CO(k) + 3H2(k). Khi gim nhit th t khi ca hn hp kh so
vi H2 gim i. Pht biu ng khi ni v cn bng ny l
A. Phn ng thun to nhit, cn bng dch chuyn theo chiu thun khi tng nhit .
B. Phn ng thun thu nhit, cn bng dch chuyn theo chiu thun khi tng nhit .
C. Phn ng nghch thu nhit, cn bng dch chuyn theo chiu thun khi gim nhit .
D. Phn ng nghch to nhit, cn bng dch chuyn theo chiu nghch khi tng nhit .
Cu 10. Hn hp X gm axit glutamic v lysin. Bit:
- Cho m gam X phn ng va vi V lit dung dch HCl 1M.
- Cho m gam X phn ng va vi V/2 lit dung dch NaOH 2M.
Phn trm khi lng ca axit glutamic trong X l
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A. 35,08%. B. 66,81%. C. 50,17%. D. 33,48%.
Cu 11. Khi t chy mt polime sinh ra t phn ng ng trng hp isopren vi acrilonitrin bng lng oxi
va thu c hn hp kh gm CO2, hi H2O v N2 trong CO2 chim 58,33% v th tch. T l s mt
xch isopren v acrilonitrin trong polime trn l
A. 2:1. B. 1:3. C. 1:2. D. 3:2.
Cu 12. Cho cc cht: Al2O3, Fe2O3, NaHCO3, Al, KHS, (NH4)2CO3, CH3COONa, Zn(OH)2. S cht trong
dy va phn ng c vi dung dch HCl, va phn ng c vi dung dch NaOH l
A. 7. B. 5. C. 6. D. 4.
Cu 13. C bao nhiu ng phn cu to, mch h c cng thc phn t C5H8 tc dng vi H2 d (xc tc
thch hp) thu c sn phm isopentan ?
A. 2. B. 6. C. 3. D. 4.
Cu 14. Khi ha tan cng mt lng kim loi R vo dung dch HNO3 c nng (d) hoc dung dch H2SO4
long (d) th th tch kh NO2 (sn phm kh duy nht) thu c gp 3 ln th tch kh H2 cng iu kin t
o

v p sut. Khi lng mui sunfat thu c bng 62,81% khi lng mui nitrat to thnh. Kim loi R l
A. Zn B. Cr C. Sn D. Fe
Cu 15. Cho 31,9 gam hn hp Al2O3, ZnO, FeO, CaO tc dng vi CO d, un nng thu c 28,7 gam hn hp X
(cho cc phn ng xy ra hon ton). Cho X tc dng vi dung dch HCl d thu c V lt kh H2 (ktc). V c gi tr
l
A. 11,2 lt. B. 6,72 lt. C. 5,60 lt. D. 4,48 lt.
Cu 16. Triolein khng tc dng vi cht (hoc dung dch) no sau y ?
A. Cu(OH)2 ( iu kin thng). B. H2O (xc tc H2SO4 long, un nng).
C. H2 (xc tc Ni, un nng). D. Dung dch NaOH (un nng).
Cu 17. Cho cc cht sau: phenol, glixerol, glucoz, saccaroz, mantoz, fructoz, benzanehit, anhit
acrylic, axit axetic, propanal, axit fomic, xenluloz, etyl fomat, axetilen, vinylaxetilen. S cht tham gia phn
ng trng gng l
A. 7 cht. B. 9 cht. C. 6 cht. D. 8 cht.
Cu 18. un nng 34,2 gam mantoz trong dung dch axit sunfuric long. Trung ha dung dch thu c sau
phn ng bng dung dch NaOH ri cho tc dng hon ton vi dung dch AgNO3/NH3 d, un nng thu c
37,8 gam Ag. Hiu sut phn ng thy phn mantoz l
A. 62,5%. B. 87,5%. C. 75,0%. D. 69,27%.
Cu 19. Cho este X c cng thc phn t l C4H6O2 phn ng vi dung dch NaOH, t
o
theo s sau:
X + NaOH mui Y + anehit Z. Cho bit phn t khi ca Y nh hn 70. X l
A. CH2=CHCOOCH3. B. HCOOCH=CHCH3. C. HCOOCH2CH=CH2. D. CH3COOCH=CH2.
Cu 20. C 4 nhn xt sau
(1) Hn hp Na2O + Al2O3 (t l mol 1: 1) tan ht trong nc d.
(2) Hn hp Fe2O3 + Cu (t l mol 1: 1) tan ht trong dung dch HCl d.
(3) Hn hp KNO3 + Cu (t l mol 1: 1) tan ht trong dung dch H2SO4 long d.
(4) Hn hp FeS + CuS (t l mol 1:1) tan ht trong dung dch HCl d.
S nhn xt ng l
A. 2. B. 4. C. 1. D. 3.
Cu 21. Chia i V lt (ktc) hn hp kh gm axetilen v hidro. Phn 1 em t chy hon ton thu c 9
gam nc. Dn phn 2 qua ng s ng bt Ni un nng, thu c kh X. Dn X ln lt qua dung dch d
AgNO3 trong NH3 v dung dch d brom ng trong cc bnh A v B ni tip. bnh A thu c 12 gam kt
ta. t chy hon ton lng kh Y i ra t bnh B c 4,5 gam nc. Gi tr ca V v s mol brom phn
ng ti a trong B l
A. 11,2 lt v 0,2 mol. B. 22,4 lit v 0,1 mol. C. 11,2 lit v 1,01 mol. D. 22,4 lit v 0,2 mol.
Cu 22. Chn pht biu ng
A. Hp cht C6H5-CH2OH l phenol.
B. C5H12O c 8 ng phn thuc loi ancol.
C. Ancol l hp cht hu c trong phn t c nhm -OH.
D. C4H10O c 2 ng phn ancol bc 2.
Cu 23. Ha tan hon ton hn hp gm 0,002 mol FeS2 v 0,003 mol FeS vo lng d dung dch H2SO4
c nng thu c Fe2(SO4)3, SO2 v H2O. Hp th ht lng SO2 trn bng 1 lng va dung dch
KMnO4 thu c dung dch X c pH = 2. Th tch ca dung dch X l
A. 1,50 lit. B. 1,14 lit. C. 2,00 lit. D. 2,28 lit.
Cu 24. C cc kt lun sau:
(1) T glyxin, alanin v valin s to ra c 6 tripeptit cha ng thi glyxin, alanin v valin.
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(2) C8H10O c 4 ancol thm khi b oxi ha to ra sn phm c kh nng tham gia phn ng trng gng.
(3) C4H8 c 4 ng phn lm mt mu dung dch brom.
(4) C4H11N c 4 ng phn khi tc dng vi HCl to ra mui dng RNH3Cl.
S kt lun ng l
A. 4. B. 1. C. 3. D. 2.
Cu 25. t chy hon ton 0,11 gam mt este X thu c 0,22 gam CO2 v 0,09 gam H2O. S ng phn
este ca X l
A. 6. B. 2. C. 3. D. 4.
Cu 26. Xt ba nguyn t X, Y, Z c cu hnh electron ln lt l: X: 1s
2
2s
2
2p
6
3s
1
, Y: 1s
2
2s
2
2p
6
3s
2
,
Z: 1s
2
2s
2
2p
6
3s
2
3p
1
. Sp xp hiroxit ca X, Y, Z theo th t tng dn lc baz l
A. Y(OH)2 < Z(OH)3 < XOH. B. Z(OH)2 < Y(OH)3 < XOH.
C. XOH < Y(OH)2 < Z(OH)3. D. Z(OH)3 < Y(OH)2 < XOH.
Cu 27. Cho cc cng thc phn t: C4H10O, C4H9Cl, C4H11N, C4H8. Cng thc phn t c s ng phn cu
to nhiu nht l
A. C4H10O. B. C4H9Cl. C. C4H11N. D. C4H8.
Cu 28. Nung nng hn hp gm bt Al v bt Fe3O4 trong mi trng khng c khng kh (xy ra phn ng
nhit nhm, hiu sut 100%). Cc cht sau phn ng cho tc dng vi dung dch NaOH (d), thu c 6,72 lt
kh H2 (ktc), cng lng cht ny nu tc dng vi dung dch H2SO4 long (d) thu c 26,88 lt kh H2
(ktc). Khi lng bt Al v Fe3O4 trong hn hp u ln lt l
A. 54 gam v 69,6 gam. B. 27 gam v 34,8 gam.
C. 54 gam v 34,8 gam. D. 27 gam v 69,6 gam.
Cu 29. Oxi ha 0,16 mol mt ancol n chc, thu c hn hp X gm 1 axit cacboxylic, 1 andehit, ancol
d v H2O. Ngng t ton b X ri chia lm 2 phn bng nhau. Phn 1 cho tc dng ht vi Na d, thu c
1,008 lit kh H2 (ktc). Phn 2 cho phn ng trng bc hon ton thu c 19,44 gam Ag. Phn trm khi
lng ancol b oxi ha l
A. 40%. B. 31,25%. C. 62,5%. D. 15%.
Cu 30. Cho t t kim loi Ba ln lt vo 6 dung dch mt nhn l: NaCl, NH4Cl, FeCl3, AlCl3, (NH4)2CO3,
MgCl2. C th nhn bit c bao nhiu dung dch sau khi cc phn ng xy ra xong?
A. 5. B. 3. C. 6. D. 4.
Cu 31. Trong kh thi cng nghip thng cha cc kh SO2, NO2, HF. Ngi ta dng cht no sau y l
tit kim nht loi b cc kh ?
A. NaOH. B. Ba(OH)2. C. Ca(OH)2. D. KOH
Cu 32. Cho cc phn ng: (1) O3 + dung dch KI, (2) F2 + H2O, (3) MnO2 + HCl (t
o
), (4) Cl2 + CH4, (5) Cl2 +
NH3 d, (6) CuO + NH3 (t
o
), (7) KMnO4 (t
o
), (8) H2S + SO2, (9) NH4Cl + NaNO2 (t
o
), (10) NH3 + O2 (Pt,
800
o
C). S phn ng c to ra n cht l
A. 6. B. 9. C. 8. D. 7.
Cu 33. Hn hp X cha K2O, NH4Cl, KHCO3 v BaCl2 c s mol bng nhau. Cho hn hp X vo nc (d),
un nng, dung dch thu c cha
A. KCl, KHCO3, BaCl2. B. KCl. C. KCl, KOH, BaCl2. D. KCl, KOH.
Cu 34. S in phn dung dch CuCl2 (vi in cc tr) v s n mn in ho xy ra khi nhng hp kim
Zn - Cu vo dung dch HCl c c im chung l
A. catot u xy ra s kh. B. u sinh ra Cu cc m.
C. cc dng u l s oxi ho Cl
-
. D. u km theo s pht sinh dng in.
Cu 35. lm sch mui n c ln tp cht CaCl2, MgCl2, BaCl2 cn dng 2 ho cht l
A. dung dch NaOH, dung dch H2SO4. B. dung dch AgNO3, dung dch NaOH.
C. dung dch Na2CO3, dung dch HCl. D. dung dch Na2SO4, dung dch HCl.
Cu 36. Chia m gam hn hp cc kim loi Al, Fe, Ba thnh 3 phn bng nhau.
Phn 1 tc dng vi nc d, thu c 0,896 lit H2 (ktc).
Phn 2 tc dng vi dung dch NaOH d thu c 1,568 lit H2 (ktc).
Phn 3 tc dng vi dung dch HCl d thu c 2,24 lit H2 (ktc).
Gi tr ca m l
A. 24,78. B. 12,39. C. 8,26. D. 4,13.
Cu 37. Cho cng thc cu to ca cht X: HOOC-CH(CH3)-NH-CO-CH2-NH2 v cc pht biu sau:
(1). X l ipeptit to thnh t alanin v glyxin. (2). X c tn l alanylglyxin (Ala-Gly).
(3). X c phn ng mu biure. (4). X lm qu tm m ho .
(5). un nng X trong dung dch HCl d n phn ng hon ton c hn hp hai -aminoaxit.
S pht biu ng l
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A. 4. B. 3. C. 2. D. 1.
Cu 38. Hn hp X gm mt axit cacboxylic no, n chc A v mt ancol no n chc B (A v B u mch
h v c khi lng phn t bng nhau). t chy hon ton m gam hn hp X c 0,2 mol kh CO2. Cho m
gam hn hp X tc dng vi Na d thu c 0,84 lt H2 (ktc). T l khi lng ca hai cht A v B trong
hn hp X l
A. 1:2. B. 1:1. C. 1:3. D. 1:4.
Cu 39. Mt oxit kim loi b kh hon ton cn 1,792 lit kh CO (ktc) thu c m gam kim loi R. Ha tan
ht m gam R bng dung dch HNO3 c nng thu c 4,032 lit kh NO2 duy nht (ktc). CTPT ca oxit l
A. FeO. B. Fe3O4. C. CrO. D. Cr2O3.
Cu 40. Ha tan ht 0,15 mol P2O5 vo 200 gam dung dch H3PO4 9,8%, thu c dung dch X. Cho X tc
dng ht vi 750 ml dung dch NaOH 1M, thu c dung dch Y. Khi lng mui trong Y l
A. 14,2 gam Na2HPO4; 41,0 gam Na3PO4. B. 30,0 gam Na2HPO4; 35,5 gam Na3PO4.
C. 45,0 gam NaH2PO4; 17,5 gam Na2HPO4. D. 30,0 gam NaH2PO4; 35,5 gam Na2HPO4.
Cu 41. Cho 4,48 lit CO2 hp th ht vo 100 ml dung dch hn hp gm NaOH 0,6M v Ba(OH)2 1,2M sinh
ra kt ta v dung dch X. C cn dung dch X thu c m gam mui. Gi tr ca m l
A. 7,12. B. 5,04. C. 10,22. D. 5,18.
Cu 42. Cho cc dung dch: HCl (X1); KNO3 (X2); HCl v Fe(NO3)2 (X3); Fe2(SO4)3 (X4). Dung dch c th
tc dng vi bt Cu l
A. X4. B. X1, X4. C. X3, X4. D. X1, X3, X4.
Cu 43. Hn hp X gm 3 ancol A, B, C u no, h, khi lng mol theo th t lp thnh 1 cp s cng vi
cng sai 30. t chy hon ton hn hp X thu c 13,44 lit CO2(ktc) v 16,2 gam H2O. S mol ancol C
bng 1/3 s mol hn hp X. Phn trm khi lng ancol C trong X l
A. 50,54%. B. 33,33%. C. 66,67%. D. 49,46%.
Cu 44. Trong phn t hidroclorua c lin kt ha hc thuc loi
A. lin kt cng ha tr khng phn cc. B. lin kt hidro.
C. lin kt cng ha tr phn cc. D. lin kt ion.
Cu 45. Hp cht hu c thm X c cng thc CxHyO2 cha 6,45% H v khi lng. Khi cho cng mt s
mol X tc dng vi Na v NaOH th s mol hidro bay ra bng s mol NaOH phn ng. S ng phn X tha
iu kin trn l
A. 3. B. 2. C. 4. D. 1.
Cu 46.
Cho cc pht biu di y:
(1) Cc halogen (F, Cl, Br, I) c s oxi ha t 1 n +7.
(2) Flo l cht ch c tnh oxi ha.
(3) F2 y c Cl2 ra khi dung dch mui NaCl.
(4) Tnh axit ca cc hp cht vi hiro ca cc halogen tng theo th t: HF < HCl < HBr < HI.
Cc pht biu lun ng l
A. (2), (3), (4). B. (2). C. (1), (2), (4). D. (2), (4).
Cu 47. Mt loi phn ure cha 95% (NH2)2CO, cn li l (NH4)2CO3. dinh dng ca loi phn ny l
A. 45,79%. B. 44,33%. C. 43,56%. D. 46,00%.
Cu 48. Cho 6,175 gam Zn tc dng va vi dung dch cha a mol HNO3. Sau phn ng thu c dung dch X
v 0,448 lit hn hp kh Y gm NO, N2O. T khi hi ca Y so vi H2 l 18,5. C cn dung dch X thu c b gam
mui. Gi tr ca a v b ln lt l
A. 0,24 v 18,735. B. 0,24 v 18,755. C. 0,14 v 18,755. D. 0,14 v 17,955.
Cu 49. Cho cc cp cht sau: Cu v dung dch FeCl3, dung dch CuSO4 v H2S, dung dch FeCl2 v H2S,
dung dch FeCl3 v H2S, dung dch Fe(NO3)2 v HCl, dung dch BaCl2 v dung dch NaHCO3, dung dch
KHSO4 v dung dch Na2CO3. S cp cht xy ra phn ng khi trn ln vo nhau l
A. 5. B. 4. C. 6. D. 7.
Cu 50. Khi ni v kim loi kim th, pht biu no sau y l sai ?
A. T beri n bari kh nng phn ng vi H2O gim dn.
B. Khi t nng, cc kim loi kim th u bc chy trong khng kh.
C. Phng php c bn iu ch kim loi kim th l in phn mui clorua nng chy ca chng.
D. Cc kim loi canxi v stronti c cng kiu mng tinh th lp phng tm din.
------------------------------------------------------------------------------------------------------ M : 189

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Trng THPT chuyn TRN I NGHA THI TH I HC NM HC 2013 2014
( c 50 cu bt buc) MN HA HC. Thi gian lm bi: 90 pht.
M : 223
(Cho bit cc nguyn t khi: He=4, H=1, C=12, O=16, S=32, N=14, Cl=35,5; Br=80, Na=23, K=39,
Mg=24, Al=27, Ca=40, Cr= 52, Mn=55, Fe=56, Zn=65, Cu=64, Ag=108, Ba=137).

Cu 1. Triolein khng tc dng vi cht (hoc dung dch) no sau y ?
A. Cu(OH)2 ( iu kin thng). B. H2 (xc tc Ni, un nng).
C. H2O (xc tc H2SO4 long, un nng). D. Dung dch NaOH (un nng).
Cu 2. Cho 4,48 lit CO2 hp th ht vo 100 ml dung dch hn hp gm NaOH 0,6M v Ba(OH)2 1,2M sinh
ra kt ta v dung dch X. C cn dung dch X thu c m gam mui. Gi tr ca m l
A. 10,22. B. 5,04. C. 7,12. D. 5,18.
Cu 3. Xt ba nguyn t X, Y, Z c cu hnh electron ln lt l: X: 1s
2
2s
2
2p
6
3s
1
, Y: 1s
2
2s
2
2p
6
3s
2
,
Z: 1s
2
2s
2
2p
6
3s
2
3p
1
. Sp xp hiroxit ca X, Y, Z theo th t tng dn lc baz l
A. Z(OH)2 < Y(OH)3 < XOH. B. Y(OH)2 < Z(OH)3 < XOH.
C. XOH < Y(OH)2 < Z(OH)3. D. Z(OH)3 < Y(OH)2 < XOH.
Cu 4. Cho 6,175 gam Zn tc dng va vi dung dch cha a mol HNO3. Sau phn ng thu c dung dch X v
0,448 lit hn hp kh Y gm NO, N2O. T khi hi ca Y so vi H2 l 18,5. C cn dung dch X thu c b gam
mui. Gi tr ca a v b ln lt l
A. 0,14 v 18,755. B. 0,14 v 17,955. C. 0,24 v 18,735. D. 0,24 v 18,755.
Cu 5. Mt loi phn ure cha 95% (NH2)2CO, cn li l (NH4)2CO3. dinh dng ca loi phn ny l
A. 43,56%. B. 44,33%. C. 45,79%. D. 46,00%.
Cu 6. Mt oxit kim loi b kh hon ton cn 1,792 lit kh CO (ktc) thu c m gam kim loi R. Ha tan
ht m gam R bng dung dch HNO3 c nng thu c 4,032 lit kh NO2 duy nht (ktc). CTPT ca oxit l
A. FeO. B. Fe3O4. C. Cr2O3. D. CrO.
Cu 7. t chy hon ton 0,11 gam mt este X thu c 0,22 gam CO2 v 0,09 gam H2O. S ng phn
este ca X l
A. 4. B. 2. C. 6. D. 3.
Cu 8. lm sch mui n c ln tp cht CaCl2, MgCl2, BaCl2 cn dng 2 ho cht l
A. dung dch Na2SO4, dung dch HCl. B. dung dch AgNO3, dung dch NaOH.
C. dung dch Na2CO3, dung dch HCl. D. dung dch NaOH, dung dch H2SO4.
Cu 9. Khi t chy mt polime sinh ra t phn ng ng trng hp isopren vi acrilonitrin bng lng oxi
va thu c hn hp kh gm CO2, hi H2O v N2 trong CO2 chim 58,33% v th tch. T l s mt
xch isopren v acrilonitrin trong polime trn l
A. 2:1. B. 1:2. C. 3:2. D. 1:3.
Cu 10. Hn hp X cha K2O, NH4Cl, KHCO3 v BaCl2 c s mol bng nhau. Cho hn hp X vo nc (d),
un nng, dung dch thu c cha
A. KCl, KOH, BaCl2. B. KCl, KHCO3, BaCl2. C. KCl. D. KCl, KOH.
Cu 11. C 4 nhn xt sau
(1) Hn hp Na2O + Al2O3 (t l mol 1: 1) tan ht trong nc d.
(2) Hn hp Fe2O3 + Cu (t l mol 1: 1) tan ht trong dung dch HCl d.
(3) Hn hp KNO3 + Cu (t l mol 1: 1) tan ht trong dung dch H2SO4 long d.
(4) Hn hp FeS + CuS (t l mol 1:1) tan ht trong dung dch HCl d.
S nhn xt ng l
A. 2. B. 4. C. 3. D. 1.
Cu 12. Khi ha tan cng mt lng kim loi R vo dung dch HNO3 c nng (d) hoc dung dch H2SO4
long (d) th th tch kh NO2 (sn phm kh duy nht) thu c gp 3 ln th tch kh H2 cng iu kin t
o

v p sut. Khi lng mui sunfat thu c bng 62,81% khi lng mui nitrat to thnh. Kim loi R l
A. Sn B. Zn C. Fe D. Cr
Cu 13. Cho este X c cng thc phn t l C4H6O2 phn ng vi dung dch NaOH, t
o
theo s sau:
X + NaOH mui Y + anehit Z. Cho bit phn t khi ca Y nh hn 70. X l
A. CH2=CHCOOCH3. B. HCOOCH2CH=CH2. C. HCOOCH=CHCH3. D. CH3COOCH=CH2.
Cu 14. Chn pht biu ng
A. Hp cht C6H5-CH2OH l phenol.
B. C4H10O c 2 ng phn ancol bc 2.
C. Ancol l hp cht hu c trong phn t c nhm -OH.
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D. C5H12O c 8 ng phn thuc loi ancol.
Cu 15. S in phn dung dch CuCl2 (vi in cc tr) v s n mn in ho xy ra khi nhng hp kim
Zn - Cu vo dung dch HCl c c im chung l
A. u sinh ra Cu cc m. B. cc dng u l s oxi ho Cl
-
.
C. catot u xy ra s kh. D. u km theo s pht sinh dng in.
Cu 16. Nung nng hn hp gm bt Al v bt Fe3O4 trong mi trng khng c khng kh (xy ra phn ng
nhit nhm, hiu sut 100%). Cc cht sau phn ng cho tc dng vi dung dch NaOH (d), thu c 6,72 lt
kh H2 (ktc), cng lng cht ny nu tc dng vi dung dch H2SO4 long (d) thu c 26,88 lt kh H2
(ktc). Khi lng bt Al v Fe3O4 trong hn hp u ln lt l
A. 27 gam v 69,6 gam. B. 27 gam v 34,8 gam.
C. 54 gam v 34,8 gam. D. 54 gam v 69,6 gam.
Cu 17. Ha tan ht 0,15 mol P2O5 vo 200 gam dung dch H3PO4 9,8%, thu c dung dch X. Cho X tc
dng ht vi 750 ml dung dch NaOH 1M, thu c dung dch Y. Khi lng mui trong Y l
A. 30,0 gam Na2HPO4; 35,5 gam Na3PO4. B. 45,0 gam NaH2PO4; 17,5 gam Na2HPO4.
C. 30,0 gam NaH2PO4; 35,5 gam Na2HPO4. D. 14,2 gam Na2HPO4; 41,0 gam Na3PO4.
Cu 18. Tng s ht mang in trong anion
2
3
XY

bng 82. S ht proton trong ht nhn nguyn t X nhiu

hn s ht proton trong ht nhn nguyn t Y l 8 ht. S hiu nguyn t ca X, Y ln lt l
A. 17 v 9. B. 14 v 8. C. 16 v 8. D. 15 v 7.
Cu 19. in phn dung dch cha m gam hn hp 2 mui CuSO4 v NaCl bng in cc tr, c mng ngn
n khi nc b in phn c 2 in cc th ngng in phn. Dung dch sau in phn ho tan va 1,16
gam Fe3O4 v anot ca bnh in phn c 448 ml kh bay ra (ktc). Khi lng dung dch gim sau khi in
phn l
A. 2,95. B. 7,10. C. 8,60. D. 1,03.
Cu 20. Este n chc X c t khi hi so vi CH4 l 6,25. Cho 20 gam X tc dng 300 ml dung dch KOH
1M(t). C cn dung dch sau phn ng thu c 28 gam cht rn khan. Cng thc ca X l
A. CH2=CHCH2COOCH3. B. CH3COOCH=CHCH3.
C. CH2=CHCOOCH2CH3. D. CH3CH2COOCH=CH2.
Cu 21. Hn hp X gm tripeptit A v tetrapeptit B u c cu to bi glyxin v alanin. Thnh phn phn
trm khi lng nit trong A v B theo th t l 19,36% v 19,44%. Thy phn hon 0,1 mol hn hp X bng
mt lng dung dch NaOH va , thu c dung dch Y. C cn dung dch Y thu c 36,34 gam hn hp
mui. T l mol gia A v B trong hn hp X l
A. 7:3. B. 3:2. C. 3:7. D. 2:3.
Cu 22. Oxi ha 0,16 mol mt ancol n chc, thu c hn hp X gm 1 axit cacboxylic, 1 andehit, ancol
d v H2O. Ngng t ton b X ri chia lm 2 phn bng nhau. Phn 1 cho tc dng ht vi Na d, thu c
1,008 lit kh H2 (ktc). Phn 2 cho phn ng trng bc hon ton thu c 19,44 gam Ag. Phn trm khi
lng ancol b oxi ha l
A. 31,25%. B. 40%. C. 62,5%. D. 15%.
Cu 23.
Cho cc pht biu di y:
(1) Cc halogen (F, Cl, Br, I) c s oxi ha t 1 n +7.
(2) Flo l cht ch c tnh oxi ha.
(3) F2 y c Cl2 ra khi dung dch mui NaCl.
(4) Tnh axit ca cc hp cht vi hiro ca cc halogen tng theo th t: HF < HCl < HBr < HI.
Cc pht biu lun ng l
A. (2), (4). B. (2), (3), (4). C. (2). D. (1), (2), (4).
Cu 24. Cho cc dung dch: HCl (X1); KNO3 (X2); HCl v Fe(NO3)2 (X3); Fe2(SO4)3 (X4). Dung dch c th
tc dng vi bt Cu l
A. X4. B. X3, X4. C. X1, X4. D. X1, X3, X4.
Cu 25. Cho tng cht C, Fe, BaCl2, Fe3O4, FeCO3, FeS, H2S, HI, AgNO3, HCl, Fe2O3, FeSO4 ln lt tc
dng vi H2SO4 c, nng. S phn ng thuc loi phn ng oxi ha - kh l
A. 6. B. 7. C. 8. D. 9.
Cu 26. Trong phn t hidroclorua c lin kt ha hc thuc loi
A. lin kt cng ha tr phn cc. B. lin kt hidro.
C. lin kt cng ha tr khng phn cc. D. lin kt ion.
Cu 27. Cho cc cht sau: phenol, glixerol, glucoz, saccaroz, mantoz, fructoz, benzanehit, anhit
acrylic, axit axetic, propanal, axit fomic, xenluloz, etyl fomat, axetilen, vinylaxetilen. S cht tham gia phn
ng trng gng l
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A. 9 cht. B. 7 cht. C. 6 cht. D. 8 cht.
Cu 28. Cho 31,9 gam hn hp Al2O3, ZnO, FeO, CaO tc dng vi CO d, un nng thu c 28,7 gam hn hp X
(cc phn ng xy ra hon ton). Cho X tc dng vi dung dch HCl d thu c V lt kh H2 (ktc). V c gi tr l
A. 4,48 lt. B. 6,72 lt. C. 11,2 lt. D. 5,60 lt.
Cu 29. Hn hp X gm axit glutamic v lysin. Bit:
- Cho m gam X phn ng va vi V lit dung dch HCl 1M.
- Cho m gam X phn ng va vi V/2 lit dung dch NaOH 2M.
Phn trm khi lng ca axit glutamic trong X l
A. 50,17%. B. 66,81%. C. 33,48%. D. 35,08%.
Cu 30. Cho cng thc cu to ca cht X: HOOC-CH(CH3)-NH-CO-CH2-NH2 v cc pht biu sau:
(1). X l ipeptit to thnh t alanin v glyxin. (2). X c tn l alanylglyxin (Ala-Gly).
(3). X c phn ng mu biure. (4). X lm qu tm m ho .
(5). un nng X trong dung dch HCl d n phn ng hon ton c hn hp hai -aminoaxit.
S pht biu ng l
A. 2. B. 3. C. 1. D. 4.
Cu 31. Cho cc cp cht sau: Cu v dung dch FeCl3, dung dch CuSO4 v H2S, dung dch FeCl2 v H2S,
dung dch FeCl3 v H2S, dung dch Fe(NO3)2 v HCl, dung dch BaCl2 v dung dch NaHCO3, dung dch
KHSO4 v dung dch Na2CO3. S cp cht xy ra phn ng khi trn ln vo nhau l
A. 6. B. 7. C. 5. D. 4.
Cu 32. Hn hp X gm mt axit cacboxylic no, n chc A v mt ancol no n chc B (A v B u mch
h v c khi lng phn t bng nhau). t chy hon ton m gam hn hp X c 0,2 mol kh CO2. Cho m
gam hn hp X tc dng vi Na d thu c 0,84 lt H2 (ktc). T l khi lng ca hai cht A v B trong
hn hp X l
A. 1:1. B. 1:3. C. 1:2. D. 1:4.
Cu 33. Pht biu no sau y ng ?
A. Tt c cc peptit u c kh nng tham gia phn ng thy phn.
B. Trong mi trng kim, cc peptit u c phn ng mu biure (tao phc cht mu tm).
C. Khi cho dung dch lng trng trng vo Cu(OH)2 thy xut hin phc cht mu xanh thm.
D. Lin kt peptit l lin kt -CO-NH- gia 2 n v amino axit.
Cu 34. Khi ni v kim loi kim th, pht biu no sau y l sai ?
A. T beri n bari kh nng phn ng vi H2O gim dn.
B. Cc kim loi canxi v stronti c cng kiu mng tinh th lp phng tm din.
C. Khi t nng, cc kim loi kim th u bc chy trong khng kh.
D. Phng php c bn iu ch kim loi kim th l in phn mui clorua nng chy ca chng.
Cu 35. Ha tan hon ton hn hp gm 0,002 mol FeS2 v 0,003 mol FeS vo lng d dung dch H2SO4
c nng thu c Fe2(SO4)3, SO2 v H2O. Hp th ht lng SO2 trn bng 1 lng va dung dch
KMnO4 thu c dung dch X c pH = 2. Th tch ca dung dch X l
A. 2,28 lit. B. 2,00 lit. C. 1,14 lit. D. 1,50 lit.
Cu 36. Cho cc phn ng: (1) O3 + dung dch KI, (2) F2 + H2O, (3) MnO2 + HCl (t
o
), (4) Cl2 + CH4, (5) Cl2 +
NH3 d, (6) CuO + NH3 (t
o
), (7) KMnO4 (t
o
), (8) H2S + SO2, (9) NH4Cl + NaNO2 (t
o
), (10) NH3 + O2 (Pt,
800
o
C). S phn ng c to ra n cht l
A. 7. B. 9. C. 6. D. 8.
Cu 37. Hp cht hu c thm X c cng thc CxHyO2 cha 6,45% H v khi lng. Khi cho cng mt s
mol X tc dng vi Na v NaOH th s mol hidro bay ra bng s mol NaOH phn ng. S ng phn X tha
iu kin trn l
A. 2. B. 4. C. 1. D. 3.
Cu 38. Chia m gam hn hp cc kim loi Al, Fe, Ba thnh 3 phn bng nhau.
Phn 1 tc dng vi nc d, thu c 0,896 lit H2 (ktc).
Phn 2 tc dng vi dung dch NaOH d thu c 1,568 lit H2 (ktc).
Phn 3 tc dng vi dung dch HCl d thu c 2,24 lit H2 (ktc).
Gi tr ca m l
A. 24,78. B. 8,26. C. 12,39. D. 4,13.
Cu 39. C bao nhiu ng phn cu to, mch h c cng thc phn t C5H8 tc dng vi H2 d (xc tc
thch hp) thu c sn phm isopentan ?
A. 4. B. 6. C. 2. D. 3.
Cu 40. Cho cc cht: Al2O3, Fe2O3, NaHCO3, Al, KHS, (NH4)2CO3, CH3COONa, Zn(OH)2. S cht trong
dy va phn ng c vi dung dch HCl, va phn ng c vi dung dch NaOH l
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A. 5. B. 6. C. 7. D. 4.
Cu 41. Cho cc pht biu:
(1) Phn ng thy phn este trong mi trng axit l phn ng thun nghch.
(2) Cht bo l trieste ca etylen glicol vi cc axit bo.
(3) Tristearin, triolein c cng thc ln lt l: (C17H33COO)3C3H5, (C17H35COO)3C3H5.
(4) Cc cht bo thng khng tan trong nc v nh hn nc.
(5) Triolein c kh nng tham gia phn ng cng hiro khi un nng c xc tc Ni.
(6) Cht bo b thy phn khi un nng trong dung dch kim to axit bo v glixerol.
S pht biu ng l
A. 3. B. 6. C. 4. D. 5.
Cu 42. Trong kh thi cng nghip thng cha cc kh SO2, NO2, HF. Ngi ta dng cht no sau y l
tit kim nht loi b cc kh ?
A. Ca(OH)2. B. KOH C. Ba(OH)2. D. NaOH.
Cu 43. Hn hp X gm 2 cht hu c n chc, u c cha C, H, O, u c %O = 53,33%.
-m gam hn hp X tc dng vi dung dch AgNO3/NH3 d, t
0
thu c ti a 12,96 gam Ag.
-m gam hn hp X tc dng va vi 336ml H2 ktc (Ni, t
0
).
T l khi lng ca hai cht hu c trong m gam hn hp X l
A. 1: 4. B. 1:2. C. 1:3. D. 1:1.
Cu 44. Cho cn bng: CH4(k) + H2O(k) CO(k) + 3H2(k). Khi gim nhit th t khi ca hn hp kh
so vi H2 gim i. Pht biu ng khi ni v cn bng ny l
A. Phn ng thun to nhit, cn bng dch chuyn theo chiu thun khi tng nhit .
B. Phn ng thun thu nhit, cn bng dch chuyn theo chiu thun khi tng nhit .
C. Phn ng nghch thu nhit, cn bng dch chuyn theo chiu thun khi gim nhit .
D. Phn ng nghch to nhit, cn bng dch chuyn theo chiu nghch khi tng nhit .
Cu 45. Cho t t kim loi Ba ln lt vo 6 dung dch mt nhn l: NaCl, NH4Cl, FeCl3, AlCl3, (NH4)2CO3,
MgCl2. C th nhn bit c bao nhiu dung dch sau khi cc phn ng xy ra xong?
A. 4. B. 5. C. 3. D. 6.
Cu 46. Chia i V lt (ktc) hn hp kh gm axetilen v hidro. Phn 1 em t chy hon ton thu c 9
gam nc. Dn phn 2 qua ng s ng bt Ni un nng, thu c kh X. Dn X ln lt qua dung dch d
AgNO3 trong NH3 v dung dch d brom ng trong cc bnh A v B ni tip. bnh A thu c 12 gam kt
ta. t chy hon ton lng kh Y i ra t bnh B c 4,5 gam nc. Gi tr ca V v s mol brom phn
ng ti a trong B l
A. 22,4 lit v 0,2 mol. B. 11,2 lit v 1,01 mol. C. 11,2 lt v 0,2 mol. D. 22,4 lit v 0,1 mol.
Cu 47. un nng 34,2 gam mantoz trong dung dch axit sunfuric long. Trung ha dung dch thu c sau
phn ng bng dung dch NaOH ri cho tc dng hon ton vi dung dch AgNO3/NH3 d, un nng thu c
37,8 gam Ag. Hiu sut phn ng thy phn mantoz l
A. 75,0%. B. 69,27%. C. 87,5%. D. 62,5%.
Cu 48. C cc kt lun sau:
(1) T glyxin, alanin v valin s to ra c 6 tripeptit cha ng thi glyxin, alanin v valin.
(2) C8H10O c 4 ancol thm khi b oxi ha to ra sn phm c kh nng tham gia phn ng trng gng.
(3) C4H8 c 4 ng phn lm mt mu dung dch brom.
(4) C4H11N c 4 ng phn khi tc dng vi HCl to ra mui dng RNH3Cl.
S kt lun ng l
A. 4. B. 1. C. 3. D. 2.
Cu 49. Hn hp X gm 3 ancol A, B, C u no, h, khi lng mol theo th t lp thnh 1 cp s cng vi
cng sai 30. t chy hon ton hn hp X thu c 13,44 lit CO2(ktc) v 16,2 gam H2O. S mol ancol C
bng 1/3 s mol hn hp X. Phn trm khi lng ancol C trong X l
A. 66,67%. B. 33,33%. C. 49,46%. D. 50,54%.
Cu 50. Cho cc cng thc phn t: C4H10O, C4H9Cl, C4H11N, C4H8. Cng thc phn t c s ng phn cu
to nhiu nht l
A. C4H10O. B. C4H11N. C. C4H9Cl. D. C4H8.
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M : 223

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Trng THPT chuyn TRN I NGHA THI TH I HC NM HC 2013 2014
( c 50 cu bt buc) MN HA HC. Thi gian lm bi: 90 pht.
M : 257
(Cho bit cc nguyn t khi: He=4, H=1, C=12, O=16, S=32, N=14, Cl=35,5; Br=80, Na=23, K=39,
Mg=24, Al=27, Ca=40, Cr= 52, Mn=55, Fe=56, Zn=65, Cu=64, Ag=108, Ba=137).

Cu 1. Chn pht biu ng
A. Hp cht C6H5-CH2OH l phenol.
B. C5H12O c 8 ng phn thuc loi ancol.
C. Ancol l hp cht hu c trong phn t c nhm -OH.
D. C4H10O c 2 ng phn ancol bc 2.
Cu 2. Cho cc pht biu:
(1) Phn ng thy phn este trong mi trng axit l phn ng thun nghch.
(2) Cht bo l trieste ca etylen glicol vi cc axit bo.
(3) Tristearin, triolein c cng thc ln lt l: (C17H33COO)3C3H5, (C17H35COO)3C3H5.
(4) Cc cht bo thng khng tan trong nc v nh hn nc.
(5) Triolein c kh nng tham gia phn ng cng hiro khi un nng c xc tc Ni.
(6) Cht bo b thy phn khi un nng trong dung dch kim to axit bo v glixerol.
S pht biu ng l
A. 6. B. 5. C. 3. D. 4.
Cu 3. Hn hp X gm axit glutamic v lysin. Bit:
- Cho m gam X phn ng va vi V lit dung dch HCl 1M.
- Cho m gam X phn ng va vi V/2 lit dung dch NaOH 2M.
Phn trm khi lng ca axit glutamic trong X l
A. 35,08%. B. 50,17%. C. 33,48%. D. 66,81%.
Cu 4. Hn hp X gm 2 cht hu c n chc, u c cha C, H, O, u c %O = 53,33%.
-m gam hn hp X tc dng vi dung dch AgNO3/NH3 d, t
0
thu c ti a 12,96 gam Ag.
-m gam hn hp X tc dng va vi 336ml H2 ktc (Ni, t
0
).
T l khi lng ca hai cht hu c trong m gam hn hp X l
A. 1:3. B. 1:1. C. 1:2. D. 1: 4.
Cu 5. lm sch mui n c ln tp cht CaCl2, MgCl2, BaCl2 cn dng 2 ho cht l
A. dung dch AgNO3, dung dch NaOH. B. dung dch Na2CO3, dung dch HCl.
C. dung dch NaOH, dung dch H2SO4. D. dung dch Na2SO4, dung dch HCl.
Cu 6. Este n chc X c t khi hi so vi CH4 l 6,25. Cho 20 gam X tc dng 300 ml dung dch KOH
1M(t). C cn dung dch sau phn ng thu c 28 gam cht rn khan. Cng thc ca X l
A. CH3COOCH=CHCH3. B. CH2=CHCOOCH2CH3.
C. CH2=CHCH2COOCH3. D. CH3CH2COOCH=CH2.
Cu 7. Chia i V lt (ktc) hn hp kh gm axetilen v hidro. Phn 1 em t chy hon ton thu c 9
gam nc. Dn phn 2 qua ng s ng bt Ni un nng, thu c kh X. Dn X ln lt qua dung dch d
AgNO3 trong NH3 v dung dch d brom ng trong cc bnh A v B ni tip. bnh A thu c 12 gam kt
ta. t chy hon ton lng kh Y i ra t bnh B c 4,5 gam nc. Gi tr ca V v s mol brom phn
ng ti a trong B l
A. 22,4 lit v 0,2 mol. B. 11,2 lt v 0,2 mol. C. 11,2 lit v 1,01 mol. D. 22,4 lit v 0,1 mol.
Cu 8. Ha tan ht 0,15 mol P2O5 vo 200 gam dung dch H3PO4 9,8%, thu c dung dch X. Cho X tc
dng ht vi 750 ml dung dch NaOH 1M, thu c dung dch Y. Khi lng mui trong Y l
A. 30,0 gam Na2HPO4; 35,5 gam Na3PO4. B. 14,2 gam Na2HPO4; 41,0 gam Na3PO4.
C. 45,0 gam NaH2PO4; 17,5 gam Na2HPO4. D. 30,0 gam NaH2PO4; 35,5 gam Na2HPO4.
Cu 9.
Cho cc pht biu di y:
(1) Cc halogen (F, Cl, Br, I) c s oxi ha t 1 n +7.
(2) Flo l cht ch c tnh oxi ha.
(3) F2 y c Cl2 ra khi dung dch mui NaCl.
(4) Tnh axit ca cc hp cht vi hiro ca cc halogen tng theo th t: HF < HCl < HBr < HI.
Cc pht biu lun ng l
A. (2). B. (1), (2), (4). C. (2), (3), (4). D. (2), (4).
Cu 10. Nung nng hn hp gm bt Al v bt Fe3O4 trong mi trng khng c khng kh (xy ra phn ng
nhit nhm, hiu sut 100%). Cc cht sau phn ng cho tc dng vi dung dch NaOH (d), thu c 6,72 lt
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kh H2 (ktc), cng lng cht ny nu tc dng vi dung dch H2SO4 long (d) thu c 26,88 lt kh H2
(ktc). Khi lng bt Al v Fe3O4 trong hn hp u ln lt l
A. 54 gam v 34,8 gam. B. 54 gam v 69,6 gam.
C. 27 gam v 69,6 gam. D. 27 gam v 34,8 gam.
Cu 11. Xt ba nguyn t X, Y, Z c cu hnh electron ln lt l: X: 1s
2
2s
2
2p
6
3s
1
, Y: 1s
2
2s
2
2p
6
3s
2
,
Z: 1s
2
2s
2
2p
6
3s
2
3p
1
. Sp xp hiroxit ca X, Y, Z theo th t tng dn lc baz l
A. XOH < Y(OH)2 < Z(OH)3. B. Z(OH)3 < Y(OH)2 < XOH.
C. Z(OH)2 < Y(OH)3 < XOH. D. Y(OH)2 < Z(OH)3 < XOH.
Cu 12. Tng s ht mang in trong anion
2
3
XY

bng 82. S ht proton trong ht nhn nguyn t X nhiu

hn s ht proton trong ht nhn nguyn t Y l 8 ht. S hiu nguyn t ca X, Y ln lt l
A. 15 v 7. B. 17 v 9. C. 14 v 8. D. 16 v 8.
Cu 13. Cho este X c cng thc phn t l C4H6O2 phn ng vi dung dch NaOH, t
o
theo s sau:
X + NaOH mui Y + anehit Z. Cho bit phn t khi ca Y nh hn 70. X l
A. HCOOCH=CHCH3. B. CH2=CHCOOCH3. C. CH3COOCH=CH2. D. HCOOCH2CH=CH2.
Cu 14. un nng 34,2 gam mantoz trong dung dch axit sunfuric long. Trung ha dung dch thu c sau
phn ng bng dung dch NaOH ri cho tc dng hon ton vi dung dch AgNO3/NH3 d, un nng thu c
37,8 gam Ag. Hiu sut phn ng thy phn mantoz l
A. 87,5%. B. 62,5%. C. 69,27%. D. 75,0%.
Cu 15. Cho cc cht sau: phenol, glixerol, glucoz, saccaroz, mantoz, fructoz, benzanehit, anhit
acrylic, axit axetic, propanal, axit fomic, xenluloz, etyl fomat, axetilen, vinylaxetilen. S cht tham gia phn
ng trng gng l
A. 6 cht. B. 9 cht. C. 8 cht. D. 7 cht.
Cu 16. Pht biu no sau y ng ?
A. Khi cho dung dch lng trng trng vo Cu(OH)2 thy xut hin phc cht mu xanh thm.
B. Trong mi trng kim, cc peptit u c phn ng mu biure (tao phc cht mu tm).
C. Lin kt peptit l lin kt -CO-NH- gia 2 n v amino axit.
D. Tt c cc peptit u c kh nng tham gia phn ng thy phn.
Cu 17. Cho 31,9 gam hn hp Al2O3, ZnO, FeO, CaO tc dng vi CO d, un nng thu c 28,7 gam hn hp X
(cc phn ng xy ra hon ton). Cho X tc dng vi dung dch HCl d thu c V lt kh H2 (ktc). V c gi tr l
A. 5,60 lt. B. 6,72 lt. C. 11,2 lt. D. 4,48 lt.
Cu 18. S in phn dung dch CuCl2 (vi in cc tr) v s n mn in ho xy ra khi nhng hp kim
Zn - Cu vo dung dch HCl c c im chung l
A. cc dng u l s oxi ho Cl
-
. B. u km theo s pht sinh dng in.
C. catot u xy ra s kh. D. u sinh ra Cu cc m.
Cu 19. Cho cc cht: Al2O3, Fe2O3, NaHCO3, Al, KHS, (NH4)2CO3, CH3COONa, Zn(OH)2. S cht trong
dy va phn ng c vi dung dch HCl, va phn ng c vi dung dch NaOH l
A. 6. B. 5. C. 4. D. 7.
Cu 20. t chy hon ton 0,11 gam mt este X thu c 0,22 gam CO2 v 0,09 gam H2O. S ng phn
este ca X l
A. 6. B. 2. C. 4. D. 3.
Cu 21. Khi t chy mt polime sinh ra t phn ng ng trng hp isopren vi acrilonitrin bng lng oxi
va thu c hn hp kh gm CO2, hi H2O v N2 trong CO2 chim 58,33% v th tch. T l s mt
xch isopren v acrilonitrin trong polime trn l
A. 1:3. B. 1:2. C. 3:2. D. 2:1.
Cu 22. Khi ni v kim loi kim th, pht biu no sau y l sai ?
A. Khi t nng, cc kim loi kim th u bc chy trong khng kh.
B. Cc kim loi canxi v stronti c cng kiu mng tinh th lp phng tm din.
C. T beri n bari kh nng phn ng vi H2O gim dn.
D. Phng php c bn iu ch kim loi kim th l in phn mui clorua nng chy ca chng.
Cu 23. in phn dung dch cha m gam hn hp 2 mui CuSO4 v NaCl bng in cc tr, c mng ngn
n khi nc b in phn c 2 in cc th ngng in phn. Dung dch sau in phn ho tan va 1,16
gam Fe3O4 v anot ca bnh in phn c 448 ml kh bay ra (ktc). Khi lng dung dch gim sau khi in
phn l
A. 2,95. B. 7,10. C. 1,03. D. 8,60.
Cu 24. Mt loi phn ure cha 95% (NH2)2CO, cn li l (NH4)2CO3. dinh dng ca loi phn ny l
A. 45,79%. B. 46,00%. C. 43,56%. D. 44,33%.
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Cu 25. C 4 nhn xt sau
(1) Hn hp Na2O + Al2O3 (t l mol 1: 1) tan ht trong nc d.
(2) Hn hp Fe2O3 + Cu (t l mol 1: 1) tan ht trong dung dch HCl d.
(3) Hn hp KNO3 + Cu (t l mol 1: 1) tan ht trong dung dch H2SO4 long d.
(4) Hn hp FeS + CuS (t l mol 1:1) tan ht trong dung dch HCl d.
S nhn xt ng l
A. 2. B. 3. C. 4. D. 1.
Cu 26. Hn hp X gm 3 ancol A, B, C u no, h, khi lng mol theo th t lp thnh 1 cp s cng vi
cng sai 30. t chy hon ton hn hp X thu c 13,44 lit CO2(ktc) v 16,2 gam H2O. S mol ancol C
bng 1/3 s mol hn hp X. Phn trm khi lng ancol C trong X l
A. 66,67%. B. 50,54%. C. 33,33%. D. 49,46%.
Cu 27. Oxi ha 0,16 mol mt ancol n chc, thu c hn hp X gm 1 axit cacboxylic, 1 andehit, ancol
d v H2O. Ngng t ton b X ri chia lm 2 phn bng nhau. Phn 1 cho tc dng ht vi Na d, thu c
1,008 lit kh H2 (ktc). Phn 2 cho phn ng trng bc hon ton thu c 19,44 gam Ag. Phn trm khi
lng ancol b oxi ha l
A. 15%. B. 40%. C. 62,5%. D. 31,25%.
Cu 28. C cc kt lun sau:
(1) T glyxin, alanin v valin s to ra c 6 tripeptit cha ng thi glyxin, alanin v valin.
(2) C8H10O c 4 ancol thm khi b oxi ha to ra sn phm c kh nng tham gia phn ng trng gng.
(3) C4H8 c 4 ng phn lm mt mu dung dch brom.
(4) C4H11N c 4 ng phn khi tc dng vi HCl to ra mui dng RNH3Cl.
S kt lun ng l
A. 4. B. 2. C. 3. D. 1.
Cu 29. Cho 6,175 gam Zn tc dng va vi dung dch cha a mol HNO3. Sau phn ng thu c dung dch X
v 0,448 lit hn hp kh Y gm NO, N2O. T khi hi ca Y so vi H2 l 18,5. C cn dung dch X thu c b gam
mui. Gi tr ca a v b ln lt l
A. 0,14 v 18,755. B. 0,24 v 18,755. C. 0,14 v 17,955. D. 0,24 v 18,735.
Cu 30. Hp cht hu c thm X c cng thc CxHyO2 cha 6,45% H v khi lng. Khi cho cng mt s
mol X tc dng vi Na v NaOH th s mol hidro bay ra bng s mol NaOH phn ng. S ng phn X tha
iu kin trn l
A. 1. B. 4. C. 2. D. 3.
Cu 31. Cho tng cht C, Fe, BaCl2, Fe3O4, FeCO3, FeS, H2S, HI, AgNO3, HCl, Fe2O3, FeSO4 ln lt tc
dng vi H2SO4 c, nng. S phn ng thuc loi phn ng oxi ha - kh l
A. 7. B. 9. C. 8. D. 6.
Cu 32. Chia m gam hn hp cc kim loi Al, Fe, Ba thnh 3 phn bng nhau.
Phn 1 tc dng vi nc d, thu c 0,896 lit H2 (ktc).
Phn 2 tc dng vi dung dch NaOH d thu c 1,568 lit H2 (ktc).
Phn 3 tc dng vi dung dch HCl d thu c 2,24 lit H2 (ktc).
Gi tr ca m l
A. 8,26. B. 4,13. C. 12,39. D. 24,78.
Cu 33. Hn hp X gm mt axit cacboxylic no, n chc A v mt ancol no n chc B (A v B u mch
h v c khi lng phn t bng nhau). t chy hon ton m gam hn hp X c 0,2 mol kh CO2. Cho m
gam hn hp X tc dng vi Na d thu c 0,84 lt H2 (ktc). T l khi lng ca hai cht A v B trong
hn hp X l
A. 1:4. B. 1:1. C. 1:2. D. 1:3.
Cu 34. Trong phn t hidroclorua c lin kt ha hc thuc loi
A. lin kt cng ha tr phn cc. B. lin kt hidro.
C. lin kt ion. D. lin kt cng ha tr khng phn cc.
Cu 35. Cho cc dung dch: HCl (X1); KNO3 (X2); HCl v Fe(NO3)2 (X3); Fe2(SO4)3 (X4). Dung dch c th
tc dng vi bt Cu l
A. X1, X3, X4. B. X4. C. X1, X4. D. X3, X4.
Cu 36. Hn hp X cha K2O, NH4Cl, KHCO3 v BaCl2 c s mol bng nhau. Cho hn hp X vo nc (d),
un nng, dung dch thu c cha
A. KCl, KOH, BaCl2. B. KCl, KOH. C. KCl, KHCO3, BaCl2. D. KCl.
Cu 37. Khi ha tan cng mt lng kim loi R vo dung dch HNO3 c nng (d) hoc dung dch H2SO4
long (d) th th tch kh NO2 (sn phm kh duy nht) thu c gp 3 ln th tch kh H2 cng iu kin t
o

v p sut. Khi lng mui sunfat thu c bng 62,81% khi lng mui nitrat to thnh. Kim loi R l
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A. Fe B. Sn C. Cr D. Zn
Cu 38. Cho cc cng thc phn t: C4H10O, C4H9Cl, C4H11N, C4H8. Cng thc phn t c s ng phn cu
to nhiu nht l
A. C4H10O. B. C4H8. C. C4H11N. D. C4H9Cl.
Cu 39. Cho cn bng: CH4(k) + H2O(k) CO(k) + 3H2(k). Khi gim nhit th t khi ca hn hp kh
so vi H2 gim i. Pht biu ng khi ni v cn bng ny l
A. Phn ng thun thu nhit, cn bng dch chuyn theo chiu thun khi tng nhit .
B. Phn ng thun to nhit, cn bng dch chuyn theo chiu thun khi tng nhit .
C. Phn ng nghch to nhit, cn bng dch chuyn theo chiu nghch khi tng nhit .
D. Phn ng nghch thu nhit, cn bng dch chuyn theo chiu thun khi gim nhit .
Cu 40. Cho cng thc cu to ca cht X: HOOC-CH(CH3)-NH-CO-CH2-NH2 v cc pht biu sau:
(1). X l ipeptit to thnh t alanin v glyxin. (2). X c tn l alanylglyxin (Ala-Gly).
(3). X c phn ng mu biure. (4). X lm qu tm m ho .
(5). un nng X trong dung dch HCl d n phn ng hon ton c hn hp hai -aminoaxit.
S pht biu ng l
A. 4. B. 2. C. 1. D. 3.
Cu 41. Ha tan hon ton hn hp gm 0,002 mol FeS2 v 0,003 mol FeS vo lng d dung dch H2SO4
c nng thu c Fe2(SO4)3, SO2 v H2O. Hp th ht lng SO2 trn bng 1 lng va dung dch
KMnO4 thu c dung dch X c pH = 2. Th tch ca dung dch X l
A. 2,00 lit. B. 1,50 lit. C. 1,14 lit. D. 2,28 lit.
Cu 42. Cho cc phn ng: (1) O3 + dung dch KI, (2) F2 + H2O, (3) MnO2 + HCl (t
o
), (4) Cl2 + CH4, (5) Cl2 +
NH3 d, (6) CuO + NH3 (t
o
), (7) KMnO4 (t
o
), (8) H2S + SO2, (9) NH4Cl + NaNO2 (t
o
), (10) NH3 + O2 (Pt,
800
o
C). S phn ng c to ra n cht l
A. 7. B. 8. C. 6. D. 9.
Cu 43. Trong kh thi cng nghip thng cha cc kh SO2, NO2, HF. Ngi ta dng cht no sau y l
tit kim nht loi b cc kh ?
A. NaOH. B. Ba(OH)2. C. Ca(OH)2. D. KOH
Cu 44. Triolein khng tc dng vi cht (hoc dung dch) no sau y ?
A. Cu(OH)2 ( iu kin thng). B. Dung dch NaOH (un nng).
C. H2O (xc tc H2SO4 long, un nng). D. H2 (xc tc Ni, un nng).
Cu 45. Cho 4,48 lit CO2 hp th ht vo 100 ml dung dch hn hp gm NaOH 0,6M v Ba(OH)2 1,2M sinh
ra kt ta v dung dch X. C cn dung dch X thu c m gam mui. Gi tr ca m l
A. 7,12. B. 5,18. C. 5,04. D. 10,22.
Cu 46. C bao nhiu ng phn cu to, mch h c cng thc phn t C5H8 tc dng vi H2 d (xc tc
thch hp) thu c sn phm isopentan ?
A. 4. B. 3. C. 6. D. 2.
Cu 47. Cho t t kim loi Ba ln lt vo 6 dung dch mt nhn l: NaCl, NH4Cl, FeCl3, AlCl3, (NH4)2CO3,
MgCl2. C th nhn bit c bao nhiu dung dch sau khi cc phn ng xy ra xong?
A. 3. B. 4. C. 5. D. 6.
Cu 48. Cho cc cp cht sau: Cu v dung dch FeCl3, dung dch CuSO4 v H2S, dung dch FeCl2 v H2S,
dung dch FeCl3 v H2S, dung dch Fe(NO3)2 v HCl, dung dch BaCl2 v dung dch NaHCO3, dung dch
KHSO4 v dung dch Na2CO3. S cp cht xy ra phn ng khi trn ln vo nhau l
A. 7. B. 4. C. 5. D. 6.
Cu 49. Hn hp X gm tripeptit A v tetrapeptit B u c cu to bi glyxin v alanin. Thnh phn phn
trm khi lng nit trong A v B theo th t l 19,36% v 19,44%. Thy phn hon 0,1 mol hn hp X bng
mt lng dung dch NaOH va , thu c dung dch Y. C cn dung dch Y thu c 36,34 gam hn hp
mui. T l mol gia A v B trong hn hp X l
A. 2:3. B. 3:2. C. 3:7. D. 7:3.
Cu 50. Mt oxit kim loi b kh hon ton cn 1,792 lit kh CO (ktc) thu c m gam kim loi R. Ha tan
ht m gam R bng dung dch HNO3 c nng thu c 4,032 lit kh NO2 duy nht (ktc). CTPT ca oxit l
A. CrO. B. Cr2O3. C. FeO. D. Fe3O4.
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M : 257

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Trng THPT chuyn TRN I NGHA THI TH I HC NM HC 2013 2014
( c 50 cu bt buc) MN HA HC. Thi gian lm bi: 90 pht.

p n m : 155

01. C 14. A 27. C 40. C

02. B 15. B 28. A 41. A

03. A 16. B 29. D 42. A

04. C 17. C 30. A 43. A

05. D 18. A 31. B 44. D

06. D 19. D 32. D 45. D

07. B 20. A 33. A 46. B

08. C 21. C 34. B 47. B

09. C 22. B 35. D 48. A

10. B 23. C 36. C 49. A

11. D 24. B 37. D 50. C

12. B 25. D 38. D

13. C 26. D 39. D

p n m : 189

01. C 14. D 27. C 40. D

02. C 15. D 28. D 41. A

03. C 16. A 29. C 42. C

04. D 17. D 30. C 43. D

05. B 18. C 31. C 44. C

06. D 19. B 32. C 45. A

07. B 20. D 33. B 46. D

08. B 21. B 34. A 47. A

09. C 22. B 35. C 48. B

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10. C 23. D 36. B 49. A

11. B 24.C 37. D 50. A

12. C 25. D 38. A

13. C 26. D 39. B

p n m : 223

01. A 14. D 27. D 40. B

02. C 15. C 28. A 41. A

03. D 16. A 29. A 42. A

04. D 17. C 30. C 43. A

05. C 18. C 31. C 44. C

06. B 19. A 32. C 45. D

07. A 20. D 33. A 46. D

08. C 21. B 34. A 47. A

09. D 22. C 35. A 48. C

10. C 23. A 36. C 49. C

11. C 24. B 37. D 50. B

12. C 25. C 38. C

13. C 26. A 39. D

p n m : 257

01. B 14. D 27. C 40. C

02. C 15. C 28. C 41. D

03. B 16. D 29. B 42. C

04. D 17. D 30. D 43. C

05. B 18. C 31. C 44. A

06. D 19. A 32. C 45. A

07. D 20. C 33. C 46. B
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08. D 21. A 34. A 47. D

09. D 22. C 35. D 48. C

10. C 23. A 36. D 49. B

11. B 24. A 37. A 50. D

12. D 25. B 38. C

13. A 26. D 39. D



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