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( thi c 6 trang)
H v tn: S bo danh:
Cho bit khi lng nguyn t (theo vC) ca cc nguyn t :
H = 1; He=4; Li = 7; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; P = 31; S = 32; Cl = 35,5; K = 39; Ca = 40; Fe = 56;
Cu = 64; Zn = 65; As = 75 ; Br = 80; Rb = 85,5; Sr=88; Ag = 108;Sn = 119; Ba = 137.
P N S 2
I. PHN CHUNG CHO TT C CC TH SINH:
Cu 1:Chn pht biu ng nht
A. Trong kh than kh, hm lng CO nhiu hn kh than t
B. Trong phng thi nghim, CO c iu ch bng cch thi CO
2
qua C nung nng trn ngn la n
cn
C. CO c thu bng cch y khng kh (p ngc bnh)
D. CO c dng lm nhin liu kh
Cu 2: Oxi ha 38 gam hn hp propanal, ancol A no n chc bc 1 v este B (to bi mt axit ng ng
ca axit acrylic v ancol A) c hn hp X gm axit v este. Mt khc, cho lng X phn ng vi 0,5 lt
dung dch NaOH 1,5M th sau phn ng trung ha ht NaOH d cn 0,15 mol HCl c dung dch D. C cn
D c hi cht hu c E, cn li 62,775 gam hn hp mui. Cho E tch nc 140
o
C (
2 4
H SO c xc tc)
c F c t khi vi E l 1,61. A v B ln lt l:
A.
2 5
C H OH v
2 3 5 5
C H COOC H C.
3
CH OH v
4 7 3
C H COOCH
B.
3
CH OH
v
3 5 3
C H COOCH
D.
2 5
C H OH
v
4 7 2 5
C H COOC H

Cu 3: Cho 9,6 gam kim loi R tc dng vi 500ml dung dch
3
HNO c mol/lt va , thu c 2,24 lt kh A
(l kh duy nht, ktc) v dung dch B. C cn dung dch B thu c 59,2 gam mui khan. A khng th l kh
no sau y?
A.
2
N O B.
2
N C. NO D.
2
NO
Cu 5: in phn 500ml dung dch ( )
3
3
Fe NO a(M) vi in cc tr cho n kh c bt kh xut hin c 2 in cc
th ngng in phn. yn h thng in phn cho n khi khi lng catot khng i th thy thot ra 3,36 (l) kh
(ktc) khng mu ho nu trong khng kh. Gi tr ca a l:
A. 0,3M B. 0,4M C. 0,2M D. 0,15M
Cu 6 : Chiu gim dn nhit si ca cc cht : etanol (1), glyxin(2), acid etanoic (3), phenol (4), acid metanoic (5)
l :
A. 2 5 3 4 1 > > > > B. 5 3 2 4 1 > > > > C. 5 3 4 2 1 > > > > D . 3 2 5 4 1 > > > >
Cu 7 : Trong s cc cht sau : anilin, phenol, nitrobenzen, metyl phenyl ete, phenyl bromua, toluen, benzandehit, acid
benzoic, phenyl axetat. S cht khi tc dng vi
2 3
/ Cl FeCl (t l 1 :1) ch cho mt sn phm duy nht l :
A. 2 B. 3 C. 4 D. 5
Cu 8 : Thc hin phn ng nhit nhm gm
3 4
Fe O v Al. Sau phn ng xy ra hon ton, nghin hn hp sau phn
ng thnh bt mn ri chia thnh 2 phn :
Phn 1 : Cho tc dng vi NaOH d thu c 6,72 (l) kh (ktc) v cht rn cn li c khi lng bng
13
6
khi lng
M THI ZKB 2012
DIN N BOXMATH.VN THI TH I HC NM 2012
BoxMath MN: HO HC
S II Thi gian lm bi: 90 pht
M thi ZKB 2012
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phn 1.
Phn 2 : cho tc dng vi
3
HNO d thu c 10,08 (l) hn hp kh gm
2
N Ov NO c t khi so vi H
2
l
3
59
. Khi
lng ca hn hp ban u l :
A. 93,17g B. 86,72g C. 90,23g D. Kt qu khc.
Cu 9: Dung dch X gm HF C(M) v NaF 3C (M). in li ca HF trong dung dch X 25
o
C l 3,2%. in
ly tng 5 ln th cn phi pha long dung dch i bao nhiu ln:
A. 5 B. 6 C.7 D. 8
Cu 10: t chy hon ton 21,6g hn hp A gm
2
FeS v CuS thu c cht rn B v 6,72 (l) kh mi hc X. Dn CO
(d) qua B nung nng thu c C, ho tan C trong
3
HNO c, t
o
, d thu c kh Y. Trn ton b X v Y li vi nhau
thu c Z. Dn Z qua 11 (l) dung dch
2 2
H O 0,17% (d=1,2g/ml) thu c dung dch D. Cho mt lng d
Kalidicromat vo D thu c V (l) kh T. ( Cc kh u o ktc v th tch dung dch khng i). pH ca dung dch D
v V c gi tr l:
A. 2 v 2,464 (l) B. 1 v 1,232 (l) C. 1 v 2,464 (l) D. 2 v 1,232 (l)
Cu 12: Cho cc nhn xt sau:
1. Nc gia-ven c dng ph bin hn Clorua vi.
2. iu ch nc gia-ven trong cng nghip bng cch p dung dch NaCl khng c mng ngn.
3. Ozon c nhiu ng dng: ty trng, du n, cha su rng, st trng nc,
4. Acid sunfuric c dng nhiu nht trong tt c cc acid v c.
5. Thuc u que dim c cha Kaliclorat.
6. Dung dch ho tan kh hidro sunfua va c tnh oxi ho, va c tnh kh.
7. Trong pentan-1,2-dien c 5 nguyn t ccbon trng thi lai ho
2
sp .
S nhn nh khng chnh xc l:
A. 1 B. 2 C. 3 D. 4
Cu 13: Cho cc nhn xt sau.
1.
2
SiO l oxit axit, d tan trong kim nng chy v khng tan trong axit.
2. Vi hoc g tm thu tinh lng (Hn hp Kalisilicat v Natrisilicat) s kh b chy.
3. C 4 cht hu c mch h c cng thc
2 2 n
C H O tc dng vi ( ) ( )
3
2
[ ] OH Ag NH sinh ra kt ta.
4. iu ch etanol t butan cn ti thiu 2 phn ng.
5.
2 3 2 3
, , ZnO Al O Cr O l cc cht lng tnh nn u d tan trong dung dch kim long.
6. Trong mng tinh th kim loi ch c cc nguyn t kim loi cc nt mng tinh th.
7. C 3 cng thc cu to ca hp cht l ng phn ca Toluen tham gia phn ng vi ( ) ( )
3
2
[ ] OH Ag NH .
S nhn xt ng l:
A. 4 B. 2 C. 3 D. 5
Cu 14: t cht hon ton hn hp X gm amoniac, metylamin, imetylamin, etylmetylamin bng mt lng khng
kh va sau dn ton b sn phm qua bnh ng
2 5
PO d th thy khi lng bnh tng 11,52g v thot ra 75,264
(l) kh (ktc). Nu ly ton b X trn tc dng vi
2 4
H SO d th khi lng mui to ra l:
A. 50g. B. 60g C. 16,16g D. 24g
Cu 15: Nhit phn hon ton a mol
3
BaCO v b mol
3
CaCO . Cho cht rn thu c vo c mol HCl thu c dung
dch A. Cho kh
2
CO thu c t vic nung hp th hon ton vo dung dch A thu c m(g) kt
ta. Ly ton b kt ta em nung hon ton trong khng kh th thu c V (l) kh (ktc). Biu thc lin h ng l:
A. ( ) V 22, 4 2a 2b c = + B. ( ) V 11, 2 2a 2b c = +
Cu 11: in phn 200ml
4
uS C O 0,5M v
2 4
Na SO 0,1M vi in cc tr, H=100%, cng 10A trong 35 pht 23
giy. Dung dch sau phn ng c kh nng ho tan ti a m(g)
3 4
Fe O . Gi tr ln nht ca m l:
A. 5,8g B. 6,38g C. 6,96g D. 6,496g
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C. ( ) V 22, 4 a b c = + D. ( ) V 11, 2 2a 2b c = +
Cu 16: t chy hon ton 0,15 mol triglixerit A thu c 376,2g
2
CO v 135g
2
H O. Tnh ch s iot ca X. (Ch s
iot ca mt cht bo l s gam iot phn ng vi tt c nt i c trong 100g A).
A. 86,59 B. 12,99 C. 10,83 D. Kt qu khc.
Cu 17: Cho cc phn ng sau:
1.
2 2
SO H S + 2.
2 2 3 2 4
Na S O H SO + 3.
3
FeCl HI +
4.
2 2
Cl H S + 5.
2 2 2
H O KNO + 6.
3
O Ag +
7.
2
Mg CO + 8.
3
KClO HCl + 9.
3
NH Cu +
10. ( ) ( )
3 3
2
[ ] HCOOCH Ag NH OH + 11.
2 3
2 5
450
o
Al O
C
C H OH
12.
2 2
F H O + 13.
3
KNO C S + + 14. ( )
3 4 2
2
Ca PO SiO C + +
15.
2 3
FeCl AgNO +
S trng hp to ra n cht l:
A.11 B. 13 C. 15 D. 14
Cu 18: t chy hon ton 0,336 (l) mt ankadien lin hp X sau tip tc dn sn phm chy qua 400ml dung dch
( )
2
Ba OH 0,15M thu c 8,865g kt ta. Cng thc ca X l:
A.
3 4
C H B.
4 6
C H C.
5 8
C H D.
3 4
C H v
5 8
C H
Cu 19: Cho cc cht: Bc axetilua, metan, 1,2-dicloetan, Canxi cacbua, propan, etyl clorua, metanol, etanol, nhm
cacbua. S cht u iu ch ra etanal bng 2 phn ng ho hc l:
A.5 B. 6 C. 7 D. 8
Cu 20: Ho tan hon ton hn hp 9,75g Zn, 2,7g Al vo 200ml dung dch cha ng thi
3
HNO 1,5M, HCl 1M v
2 4
H SO 1,25M thu c sn phm kh duy nht l NO. Khi lng cht rn sau khi c cn l:
A. 46,4g B. 36,45g C. 42,75g D. Kt qu khc.
Cu 21: Hn hp X gm 2 este n chc. Cho 0,5 mol X vo dung dch ( ) ( )
3
2
[ ] Ag NH OH d thu c 43,2g Ag.
Cho 14,08g X tc dng vi KOH va thu c hn hp 2 mui ca 2 acid ng ng lin tip v 8,256g hn hp 2
ancol n chc, ng ng lin tip. S lng X thoa mn yu cu bi ton l:
A. 2 B. 3 C. 5 D. 4
Cu 22: X c cng thc phn t
4 8 2
C H O , mch thng v tho mn cc tnh cht sau:
- X lm mt mu dung dch brom.
- 4,4g X+ Na d sinh ra 0,56 (l)
2
H
- Oxi ho X bng CuO,
o
t to ra Y a chc.
CTCT ca X l:
A.
3 2
CH CH COCHO B. ( )
2
CH CH CH OH CHO =
C. ( )
2
3
HO CH CHO D. ( )
2 3
HO CH CH CH CHO
Cu 23: A l hn hp gm 2 este n chc ( )
1 2 1 2
, , X X X X < l ng ng ca nhau c t l mol tng ng l 1:2.
Hn hp 24,4g A c s mol cc i. (C
1 2
, X X u lm mt mu nc brom). Nu ly mt cht
3
X l ng phn ca
1
X ( c khi lng bng khi lng ca
1
X trong A) em tc dng vi ( )
3 2
[ ( ) ] Ag NH OH th lng kt ta ln nht
c th to ra l:
A. 43,2g B. 21,6g C. 36,856g D. 64,8g
Cu 24: pH ca dung dch acid HA 0,226% trong nc l 2,536. Pha long dung dch trn 2 ln th pH ca dung dch l
2,692. Hng s acid
A
K ca HA l:
A.
5
2, 6.10

B.
4
1, 83.10

C.
5
4,88.10

D.
4
6, 41.10

Cu 25: Tng h s nguyn nh nht ca cc phn t v ion trong phn ng sau l:
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( )
2 2 2
3 4 2
4
[ ] Hg SCN IO Cl H ICl SO Hg H O HCN
+ +
+ + + + + + +
A. 30 B. 38 C. 34 D. 40
Cu 26: St tn ti di dng ( )
3
2
Fe HCO trong ngun cung cp cho cc nh my nc, cch tin hnh thu c
nhiu Fe nht (kinh t nht) l :
A. dng NaOH B. Sc khng kh (
2
O )
C. Nc vi D. Dng kh Clo
Cu 27: Cho m(g) hn hp gm M, MO, Al vo nc d, sau phn ng thu c 3,024 (l) kh (ktc); 0,54g cht rn
khng tan v dung dch A. Rt 110ml dung dch HCl 1M vo A thu c 5,46g kt ta. Nu cho m(g) hn hp trn
vo
3
, HNO c, nng, d th s mol
3
HNO phn ng l:
A. 0,71 mol. B. 0,72 mol. C. 0,5 mol. D. 0,68 mol.
Cu 28: Hn hp X gm trimetyl amin v 2 hidrocacbon ng ng lin tip. t chy hon ton 100ml X bng oxi
va thu c 550ml hn hp Y gm kh v hi nc. Dn Y qua
2 5
PO d thy cn li 200ml kh thot ra (o cng
iu kin). Cng thc ca hai hidrocacbon l:
A.
4 2 6
& CH C H B.
2 4 3 6
& C H C H C.
2 6 3 8
& C H C H D.
3 6 4 8
& C H C H

Cu 29: in phn
( )
3
2, 5 m NaCl 1,1367% c d= 1,17g/ml (in cc tr) nhit thp, khuy u cc sn phm
phn ng vi nhau trong qu trnh in phn. Sau mt thi gian ngng in phn. Ly ra mt mu 100 ml dung dch,
thm vo lng d KI v dung dch
2 4
H SO long. Lng
2
I thot ra phn ng ht vi 40 ml dung dch
2 2 3
Na S O
0,5M. Khi lng mui to thnh trong dung dch sau in phn l:
A. 34,052kg B. 35,520kg C. 36,25kg D. 37,250kg
Cu 30: Thy phn hon ton 68,4 gam saccarozo trong mi trng axit, thu c dung dch X. Cho ton b dung dch
X phn ng ht vi lng d dung dch ( ) ( )
3
2
[ ] Ag NH OH , un nng, thu c m gam Ag. Gi tr ca m l:
A. 86,3 g B. 86,4 g C. 86,5 g D. 86, 6 g.
Cu 31: Lng ho cht ti thiu dng nhn bit cc dung dch sau l bao nhiu:
3 2 3 2 2 3 3
, , , , , , , , AgNO MgCl FeCl FeCl KOH CuCl NaNO AlCl HBr
A. 1 B. 2 C.3 D. Khng cn dng thm
Cu 32: C 6 dung dch ng trong cc l mt nhn v c nh s t 1 n 6 (khng theo th t).
( ) ( ) ( )
4 4 2 3 3 2 3
2 2 2
, , , , , NaOH NH SO Na CO Ba NO CaCl Pb NO . Thc hin cc th nghim v nhn thy rng:
- Dung dch 2 to kt ta vi 1, 3, 4.
- Dung dch 5 to kt ta vi 1, 3, 4.
- Dung dch 2 khng to kt ta vi 5
- Dung dch 1 khng to kt ta vi 3, 4.
- Dung dch 6 khng phn ng vi 5.
- Cho dung dch 3 vo 6 thy xut hin kt ta. Lc th kt ta tan.
Ly 100g dung dch 5 c nng 21,2% ri sc 1 lng kh
2
CO vo thu c dng dch A. Cho t t 0,25mol HCl
vo dung dch A thy thot ra 2,24 (l) kh (ktc). Xc nh th tch kh hp th:
A. 2,24 (l) B. 1,12 (l) C. 3,36(l) D. 4,48(l)
Cu 33: Thc hin cc th nghim vi mt cht X nh sau:
- t chy hon ton X thu c
2
CO v
2
H O c t l khi lng tng ng l 132:63
- X phn ng vi NaOH v HCl iu kin thng u vi t l mol 1:1
- X phn ng vi NaOH d thu c cht lng hu c Y. Nung Y cng vi acid sunfuric c nng ch thu c mt
sn phm hu c duy nht.
T X ngi ta iu ch mt cht Z c M=74. Bit Z phn ng c vi ( ) ( )
3
2
, ,[ ] Na NaOH Ag NH OH .
S phn ng ti thiu m t X iu ch c Z l:
A. 2 B. 3 C. 4 D. 5
Cu 34: Cho cc nhn nh sau:
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a. Phn ng cng HBr vo
2
OO CH CH C H = sn phm chnh l
3
OO CH CHBr C H .
b. Oxi ho etylen bng oxi vi xc tc l Ag thu c sn phm c th trng hp to ra polime.
c. nhit cao, phn ng gia buta-1,3-ien vi HCl u tin cng 1-4
d. Cc nguyn t cacbon trong benzen, buta-1,3-ien, cyclopentan u cng nm trn mt mt phng.
e. Menton, mentol l nhng dn xut ca tecpen c th dng cha bnh.
f. nhit thp, phn ng gia but-2-in v Brom (d) to ra dn xut tetrabrom.
g. Glicogen v nha rezit u c cu trc mng khng gian.
h. Sn phm thu phn poly (vinyl clorua) dng lm keo dn.
i. C glyxin v sn phm ca n khi phn ng vi ( )
2 4
NaNO NaHSO + u c th trng ngng to ra polime.
S nhn nh khng chnh xc l:
A. 2 B. 3 C. 4 D. 5
Cu 35 : Hin tng no di y khng chnh xc.
A. Cho NaOH vo dung dch
3
CrBr n d thu c dung dch mu xanh lam v nu thi kh oxi d vo th thy dung
dch chuyn sang mu vng.
B. Dn kh CO qua bt s ng anhirit cromit nung nng th thy cht rn chuyn t mu sang lc.
C. Cho Zn vo dung dch HCl d thu c lng kh nhiu hn khi cho lng Zn nh trn (c thm mt t Cu) vo
dung dch HCl d. (H=100%)
D. Ag trong khng kh lu ngy thy cht rn chuyn sang mu en.
Cu 36 : Thc hin s phn ng sau :

A
1 1 1
A
B C B
+


2 2
B C
Bit
2
C l mui ca Ag vi nguyn t nhm VII, tan c trong nc.
Trong
2
B , nguyn t trung tm c s oxi ho l:
A. 0 B.
1
2
+ B. 2 + C.
3
2
+
Cu 37: Hn hp A gm 0,03mol hn hp 2 cht ( ) ( )
2
OO
x y
H N R C H ( x 3y = v gc R c 2 v + s ) v este no
n chc mch h. t chy hon ton A thu c 0,05mol
2
CO v 0,07 mol
2
H O. Cho ton b A trn phn ng vi
2
HNO d thu c V (l) kh. Gi tr ln nht ca V l:
A. 5,376 (l) B. 6,72 (l) C. 5,6 (l) D. 6,272 (l)
Cu 38: Nhit phn 50,56g
4
KMnO sau mt thi gian thu c 46,72g cht rn. Cho ton b kh sinh ra phn ng ht
vi hn hp X gm Mg, Fe thu c hn hp Y nng 13,04g. Ho tan hon ton Y trong
2 4
H SO c, nng d, thu
c 1,344 (l) kh (ktc). Phn trm khi lng ca Mg trong X l:
A. 52,17 % B. 39,13% C. 28,15% D. 46,15%
Cu 39: Mt ancol no a chc X c s nhm OH bng s nguyn t C. Trong X hidro chim xp x 10%. un X vi
xc tc thch hp loi nc thu c Y m 18
Y X
M M = . Nhn nh chnh xc nht l:
A. T khi ca Y so vi X l 0,8 B. X l glyxerol
C. Y l andehit acrylic D. Y l etanal.
II. PHN RING (Th sinh ch c chn mt trong hai phn).
1. Theo chng trnh chun (T cu 41 n cu 50).
Cu 41: A l mt amino acid thin nhin v l mt trong cc amino acid cu to nn protein ca chng ta. Bit A phn
ng vi NaOH v HCl u theo t l mol 1: 1. t chy hon ton 4,45g A thu c 3,36 (l) kh
2
CO . Tn bn h thng
ca A l:
A. Acid 2-aminopropanoic B. Acid - -aminopropionic.
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C. Alanin D. Acid 3 aminopropanoic

Cu 42: Cho cc cht sau:
3 2
, , , KNO HCl MnO Zn. S cht kh ti a c th to ra t cc cht trn l:
A. 5 B. 7 C. 9 D. Kt qu khc.
Cu 43: Cho hn hp X gm cc kim loi , , , , Zn Cr Fe Cu Ag . Nung A trong kh quyn oxi thu c hn hp A. Ho
tan A trong HBr d thu c dung dch B v cht rn C. Ly C nung trong khng kh thu c D. Cho KOH d vo B
sau sc kh
2
O d vo thu c dung dch E, kt ta F. Nung F trong khng kh thu c cht rn G. em c cn
cn thn dung dch E thu c cht rn khan H. Tng s lng ln nht cc cht c trong D, G v H l:
A. 8 B 9 C. 6 D. Kt qu khc.
Cu 44: Cho cc cht sau: metyl phenyl ete, anilin, metanal, glyxerol, sacarozo, matozo, glyxylalanylglyxin.
Nu ch cho php dng mt thuc th duy nht th s cht ti a c th nhn bit c l:
A. 7 B. 6 C. 5 D. 4
Cu 45: Crackinh mt lng pentan thu c hn hp X gm
5 12 5 10 5 8 5 6 2
, , , , C H C H C H C H H . T khi ca X so vi
hidro l 14,4. Nu cho 0,6 mol X qua dung dch brom d th s mol
2
Br phn ng l:
A. 0,36 mol B. 0,45 mol. C. 0,6 mol. D. 0,8 mol.
Cu 46: Ho tan hon ton 1,62 gam nhm vo 280 ml dung dch
3
HNO 1M thu c dung dch A v kh NO (sn
phm kh duy nht). Mt khc, cho 7,35 gam hai kim loi kim thuc hai chu k lin tip vo 500 ml dung dch HCl,
thu c dung dch B v 2,8 (l) kh
2
H (ktc). Khi trn dung dch A vo dung dch B thy to thnh 1,56 gam kt ta.
Tnh nng mol/l ca dung dch HCl dng:
A. 0,3M B. 0, 4M C. 0, 5M D. 0,6M
Cu 47: Cho axit cacboxylic no, mch h cha n nguyn t C v a nhm COOH (A). trung ho 5,2
gam axit A trn cn dng 16ml dung dch NaOH 20% (d = 1,25g/ml). Tm biu thc lin h gia a v n:
A. 4a 7n 1 = + B. a 7n 11 = + C. 7a 11n 1 = + D. 11a 7n 1 = +
Cu 48: Ho tan 2,56 g Cu vo 25,2 g dung dch
3
HNO 60% thu c dung dch A v hn hp kh mu nu ( nu
em ra ngoi khng khi th thy mu nu m hn), thm 210ml dung dch NaOH 1M vo dung dch A. Sau khi phn
ng kt thc em c cn dung dch thu c cht rn X. Nung X trong khng kh n khi lng khng i thu c
17,4 g cht rn. Tnh C% cc cht trong dung dch A.
A. 28,65% v 28,81% B. 31,26% v 25,72%
C. 32,19% v 22,81% D. Kt qu khc.
Cu 49: Ho tan hon ton 30,4g hn hp X gm
2
, uS, , Cu C Cu S S vo dung dch
3
HNO d thu c 20,16 (l) kh
NO duy nht (ktc) v dung dch Y. Thm ( )
2
Ba OH d thu c khi lng kt ta l:
A. 110,95g B. 109,95g C. 122,2g D. 113,2g
Cu 50: Mt hn hp 2 cht hu c n chc A v B. C 2 u tc dng vi NaOH . t chy A hay B th th tch
2
CO v hi nc u bng nhau (cng iu kin). Ly 16,2g hn hp trn tc dng va vi 100 ml dung dch NaOH
2M, sau c cn dung dch thu c 19,2 g cht rn. (Bit A v B c s nguyn t cacbon hn km nhau mt n v.
Xc nh A v B:
A.
2 4 2 3 6 2
& C H O C H O B.
4 8 2 3 6 2
& C H O C H O C.
4 8 2 5 10 2
& C H O C H O D. Kt qu khc.

2. Theo chng trnh nng cao (T cu 51 n cu 60).
Cu 51: Cho cn bng sau : ( ) ( )
3 2 6
2AlCl k Al Cl k thi im m nng ca
2 6
Al Cl tng 25 ln th nng
ca
3
AlCl thay i nh th no:
A. Gim 25 ln B. Gim 5 ln C. Tng 25 ln D. Tng 5 ln.
Cu 52: Cho 2 s phn ng sau:
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Trang 7

3 2
2
,
1 2 4 2 1 1 1
,ete
2 2 4 2 2 2 2
:
:
o
H O t H O HCN
CO Mg HCl
X C H Br A B C
X C H Br A B C
+



Cho 37,6g mi cht
1 2
, X X thc hin 2 s trn. Sau ly ton b
1
C tc dng vi Na d thu cj V (l) kh.
2
C
tc dng vi etan-1,2-imin d (H=100%) th thu c m (g) polime. Gi tr ca V v m l:
A. V=4,48 (l) v m=28,4g. B. V=2,24 (l) v m=42,6g.
C. V=1,12 (l) v m=28,4g. D. V=4,48 (l) v m=42,6g.
Cu 53: Khng th oxi ho Au thnh
3
Au
+
bng cch:
A. Tc dng vi kh Flo.
B. Ho tan trong nc cng toan.
C. Cho vo dung dch HCN c ho tan kh oxi.
D. Ho tan trong nc clo sc thm kh oxi.
Cu 54: Hn hp kh A cha mt ankan v mt cycloankan. T khi ca A so vi hidro l 25,8. t chy hon ton
2,58(g) A ri hp th ht sn phm chy vo dung dch ( )
2
Ba OH d thu c 35,46 g kt ta. Cng thc phn t ca
cc cht trong A l:
A.
4 10 3 6
& C H C H B.
2 6 4 8
& C H C H C.
4 8 3 8
& C H C H D.
2 6 3 6
& C H C H .
Cu 55: t chy hon ton 4g mt hidrocacbon A th kh cn 8,96 (l)
2
O (ktc). A l:
A. anken hoc ankin B. ankan C. ankin D. ankin hoc cycloaken
Cu 56: Cho hp cht hu c X c mch cacbon khng phn nhnh cha C, H, O. un X vi 200 ml dung dch KOH
1M thu c dung dch Y. trung ho KOH d trong dung dch Y cn 80 ml dung dch HCl 0,5M thu c dung
dch Z. C cn dun dch Z thu c 2 ancol n chc v 18,34 g hn hp 2 mui. CTCT ca X l:
A.
3 2 2 2 2
OO CH CH CH C CH CH CH = . B.
3 2 2 5
OCO OO CH CH CHCH C C H = .
C.
3 2 2 3
OCOCH OO CH CH CHCH C CH = . D.
3 2 2 3
OCO OO CH CH CHC CH CH CH = .
Cu 57: Cho 28,8g mt oxit kim loi A vo dung dch
3
HNO d thu thu c 1,82(l) hn hp kh
2
N O v NO c t
khi so vi hidro l
230
13
. A l:
A. FeO B. MnO C.
3 4
Fe O D. Kt qu khc.
Cu 58: Cho 6,85 g Bari kim loi vo 150 ml dung dch
4
CrSO 0,3M trong khng kh n phn ng hon ton th khi
lng kt ta thu c l:
A. 14,09g B. 10,485g C. 3,87g D. 14,355g
Cu 59: Mt phn ng quan trng to nn m gy nhim mi trng l:
( ) ( ) ( ) ( )
34
3 2 2
, 6.10
C
O k NO k O k NO k K + + =
Nu nng ban u l: | | ( ) | | ( ) | | | | ( )
6 5 4 3
3 2 2
10 ; 10 ; 2, 5.10 ; 8, 2.10 O M NO M NO O M

= = = = th phn ng
c xu hng:
A. Cn bng ng B. Chuyn dch theo chiu thun
C. Cn bng tnh. D. Chuyn dch theo chiu nghch.
Cu 60: Th t tng dn tnh acid ca cc ion sau: ( ) ( ) ( ) ( )
3 4 3 3 6 5 3
1 , 2 , 3 , 4 HCO NH CH NH C H NH
+ + +
l:
A. 1 3 2 4 < < < B. 3 2 4 1 < < < C. 1 3 4 2 < < < D. 4 2 3 1 < < <

The end ^ ^
(Th sinh khng c s dng bng h thng tun hon.
Gim th coi thi khng gii thch g thm.)


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thi c cht sai st, c sa li, mong cc bn thng cm.
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Phm Duy Hin.