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Natural gas is used as the raw material for the ammonia plant. Process
feed and fuel gas (natural gas) arrives at plant site through a 14 line
from Mari Gas field located 55km away.
The field has to deliver 180 million standard cubic feet (sfc) of natural
gas. But 170 million scf is delivered to the FFC, Goth Machhi plants, 75
million scf of which, is delivered to Plant-II.
The design composition of natural gas is:
CH4
C2H 6
C3H 8
CO2
N2
S
73.8%
0.2%
8.0%
18.0%
5ppm
AREA-42
Area-42 is comprised of the following main units:
Desulphurizer (R-4101)
Primary Reformer (F-4201)
Secondary Reformer (R-4202)
Medium pressure shift converter (R-4203)
Low pressure shift converter (R-4204)
DESULPHURIZATION:
The natural gas that feeds the plant contains up to 5ppm of sulphur
compounds which have to be removed in order not to poison the
reforming catalyst in the Primary Reformer (F-4201) and the Shift
catalysts in CO converters R-4203 and R-4204.
The Desulphurizer R-4201 contains two 10.5m 3 beds of ZnO catalyst
(HTZ-3). The normal operating temperature in the desulphurization
section will be 300-400oC. At low temperatures, the catalyst will react
with hydrogen sulphide (H2S). This inorganic sulphide is removed from
the process gas in the Desulphurizer. The following reaction occurs:
H2S
ZnO
ZnS
H2O
At normal operating temperature, the catalyst will also react with the
carbonyl sulphide (COS).
ZnO
COS
ZnS
CO2
To some extent it will also remove organic sulphur compounds;
however, these should be pre-hydrogenated in a hydrogenation unit.
The purpose of mixing of recycle gas in the process gas is that it
H2
H2S
H2
H 2S
+
+
CO
R-H
H2O
H2
CO
Almost all of the sulphur is removed by passing through the first bed.
The second bed acts as standby so that in any case if the first bed gets
exhausted, the second bed comes in service.
The sulphur contained in the natural gas leaving the Desulphurizer is,
therefore, reduced to a very low level, i.e. below 0.05ppm by weight.
REFORMING:
The reforming unit consists of a tubular catalytic Primary Reformer F4201, an auto thermal catalytic Secondary Reformer R-4202 and a
waste heat (convection) section.
The steam reforming of the hydrocarbons can be described by the
following reactions:
CnHm + 2H2O
H2O
heat
C n-1Hm-2
CO2
CH4
-
2H2O
CO 2
H 2O
H 2O
heat
(Shift Conversion)
CO2
H2
CO
heat
60.49%
N2
7.57%
CO
10.46%
CO2
9.95%
Ar
0.01%
CH4
11.52%
O2
2H2
O2
CO2
H 2O
heat
heat
2H2O
and, in the super heater, the saturated steam coming from the steam
drum V-4201, and waste heat boiler E-4501 are partially superheated
before final superheating takes place in the flue gas section. The
process gas is then cooled to 220 oC in the BFW preheaters E-4212A/B
before it is sent to the 1st shift convertor (R-4203).
The reformed gas contains:
H2
54.61%
N2
22.15%
CO
13.5%
CO2
7.71%
Ar
0.2%
CH4
1.83%
CO 2
(soot)
This occurs when the gas is cooled. This reaction can only take place
below 800oC and because of equilibrium conditions and above 650 oC
because of low reaction rate. This temperature range should be passed
quickly.
SHIFT CONVERSION:
The CO conversion (shift reaction) takes place in two reactors R-4203
and R-4204.
CO
H 2O
CO 2
H2
heat
This reaction will proceed in contact with a catalyst. The reaction is
favored by low temperature and more steam, whereas, higher
temperatures result in lower reaction rates. As the reaction results,
there is a rise of outlet temperatures and the heat must be removed
before the completion of conversion.
Therefore, the reaction takes place in two steps using copper based
catalyst in both reactors. In spite of low steam/gas ratio, this system
ensures a low CO slippage and a low formation of by-products.
(4.4m3 LK-811)
(48.8m3 LK-811)
(8.4m3 LK-821)
Chlorine, silica and sulphur are the serious poisons for the catalyst,
which must be avoided. The chlorine and silica will be fixed in the
upper protection layer and it is made sure that no sulphur should be
present in the feed.
At startup combined charge needs to be activated. It takes place by
the reduction of the catalyst with hydrogen in a carrier gas. The
reduction temperature is between 150-200 oC depending upon the
space velocity.
The catalyst can be operated at a 200 oC. The temperatures should be
kept above the dew point of steam. The reduced catalyst is prophoric
and must not be exposed to air.
The main part of the reaction takes place in the 1 st CO converters with
a conversion of 90% of the CO fed. The contents of the reactor, after
this much reaction, are needed to be cooled somewhat before feeding
to the 2nd shift converter.
After the reforming, normally about 13.9% and 7.71% by volume of CO
and CO2 respectively are present in the gas. In the first CO converter,
the CO content is reduced to 0.35%.
The major part of the reaction takes place here, causing a temperature
rise of 90-120oC. The outlet temperature of 340oC is acceptable for this
catalyst but not for the higher activity catalyst of 2nd shift converter.
AREA-43
Area-43 is comprised of:
CO2 removal section
Methanation
H 2O
2R2NH
CO2
+
R3NH+
CO 2
+
R 2NH2+
HCO3+
R2NCOO
The first reaction is for MDEA and the second is for piperazine.
The CO2 absorption takes place in the absorber (C-4302). Absorption
takes place in two steps: First in the lower part with the semi lean
(flashed) solution, where the major absorption takes place. This part of
the column is filled with 2 CS rings. Second is in the upper part where
the lean (stripped) solution is used for scrubbing. Lean absorber is
provided with 1 CS rings. These rings are used for high interfacial
areas between gas and liquid.
The gas leaving the absorber contains less than 500 ppm of CO 2. To
prevent the losses by entrainment of the lean solution in the gas
leaving the absorber, the top of the column is provided with three
bubble cap trays which are fed with BFW, which traps the solution
allowing only purified gas to pass through it.
The rich solution leaving the bottom of the absorber is depressurized in
the hydraulic turbine (XP-4301) which is used as a driver for the
flashed solution pump (P-4301A), thereby reducing total electric power
consumption of the process. The pressure of the rich solution is
reduced from 27kg/cm2g to 5.5kg/cm2g.
Regeneration of Solution:
The regeneration of the solution is done in two steps:
Flashing
Stripping
First the flash regeneration of the rich solution is done. It is further
done in two stages. In HP flash drum (V-4302), the main parts of the
dissolved inert components are liberated at 5.5kg/cm 2g. The flashed
solution is cooled to 40oC in the recycle gas cooler (E-4307). The
condensate is separated in recycle gas separator (V-4305). The flashed
gas is compressed in the MDEA recycle compressor (K-4301). It is a PD
compressor that brings the gas to the pressure of the absorber and
feed it to the absorber inlet.
The remaining CO2 is removed in the LP flash drum (V-4301) at
pressure 0.3kg/cm2g. Both flash drum are provided with packing of 2
SS and CS rings and two bubble cap trays to prevent solution loss due
to entrainment. The condensate from recycle gas separator (V-4305)
and CO2 separator (V-4303) is fed on the bubble cap trays.
The flashing is done in two stages due to the presence of absorbed
inert gas along with CO2 in the solution. Since the partial pressure of
CO2 is greater than 5.5kg/cm2g, some part of it remains in the solution
while other inerts totally flash out of the solution due to lower partial
pressures. Then in the second stage, the pressure is reduced below
5.5kgkg/cm2g to flash out remaining CO2 from the solution.
The CO2 released from the flash vessels is saturated with water at
75oC, which is cooled in the LP flash gas cooler (E-4304) to 40 oC. The
condensate is separated in the CO2 separator and the 99.8% pure CO2
is sent to urea-II. The condensate is returned in the regeneration
system.
The solution leaving the flash vessels is divided into two streams. The
major portion is sent to the Flashed solution main pump (P-4301A/B)
which pumps the solution to absorber pressure and feed in the
absorber as semi lean solution. The remaining part is sent to the
flashed solution split stream pump (P-4302A/B). Before entering the
top of the CO2 stripping column (C-4301), solution is preheated in
solution heat exchanger (E-4301) by the lean solution at the
downstream of the stripper. The solution is heated by the steam at 97113oC produced by the MDEA reboiler (E-4215) which boils the MDEA
solution by exchanging heat from the process gas. The CO 2 leaving the
stripper is saturated with water at 97 oC. The vapors are passed through
the LP flash vessel. By condensation of water, the temperature of the
LP flash vessel is increased, resulting in its better performance.
The lean solution from the bottom of the stripper is cooled in solution
heat exchanger (E-4301), DMW preheater (E-4306), lean solution
cooler (E-4303). It is then pumped by the lean solution pump (P4303A/B) to the top of the absorber.
METHANATION:
After the removal of the CO2 from the process gas, the traces of CO 2
and CO must be removed, since these compounds are poison for the
ammonia catalyst.
It is done in the methanator (R-4311), where the reverse of the
reforming reaction takes place and following exothermic chemical
reactions occur:
CO
3H 2
CH 4
H 2O
heat
CO2
+
heat
4H 2
CH 4
2H 2O
AREA-44
Area-44 is comprised of:
First three of these are steam turbine driven whereas the last ones are
motor driven.
1st Stage:
Air enters the suction of the first stage at a pressure of around
-0.01kg/cm2g. After passing through the first stage, the air is
compressed to a pressure of 1.71kg/cm 2g. Due to this compression, the
temperature of the air is raised to 199oC, which is dropped to 40oC by
passing through a heat exchanger E-4421. The moisture of the air is
removed into the knockout vessel V-4421. The air enters the second
stage.
2nd Stage:
Air enters the suction of the second stage at a pressure of around
1.71kg/cm2g. After passing through the second stage, the air is
compressed to a pressure of 7.12kg/cm 2g. Due to this compression, the
temperature of the air is raised to 203oC, which is dropped to 40oC by
passing through a heat exchanger E-4422. The residual moisture of the
air is removed into the knockout vessel V-4422.
The discharge of the 2nd stage is equipped with an inter-stage vent
valve. During startup, the compressor cant be run on max speed; the
speed is brought gradually to the desired value. The excess of gas on
the upstream of the compressor is vent after the second stage. This is
done by the vent valve until the compressor gains its normal working
speed.
3rd Stage:
Air enters the suction of the third stage at a pressure of around
7.12kg/cm2g. After passing through the third stage, the air is
compressed to a pressure of 15.1kg/cm 2g. Due to this compression, the
temperature of the air is raised to 144oC, which is dropped to 88oC by
passing through a heat exchanger E-4423.
After the 3rd stage, a part of the air is extracted and cooled in the heat
exchanger E-4424 and after removing the residual moisture from the
air in the knock out vessel V-4425, it is sent to the air storage tank V5001A. From here, the air is supplied to the instrument air generation
section, inert gas generation section and as the passivation air.
The remaining air is sent to the suction of the 4th stage.
4th Stage:
Air enters the
15.11kg/cm2g.
compressed to
temperature of
WATER TREATMENT
There are two water sources for the Fauji Fertilizer Company:
Canal Water
Well Water
Canal water supply comes from the way of Rahim Yar Khan. This supply
from canal is not continuous and there comes a need of another source
when the canal water supply is cut off.
To overcome the need of water, the second source is the well water.
The wells that provide water to FFC are located in Ahmedpur Lamma,
40 km away from the plant site.
The water from these two sources is stored on the plant site at S-912
basin. It consists of three sections:
Fire pit
Suction pit
Main Reservoir
4000m3
7000m3
30000m3
Fire pit and main reservoir are filled with well water, whereas suction
pit is filled with canal water. These sections are interconnected by
gates, which can be set to open or close according to the situation of
the supply.
The fire water is for any emergency or incident of fire on the plant site
or the township. Four fire water pumps are used to pressurize the
water for fire hydrants. Pumps (P-972A/B) have a capacity of 50m 3/h
and always pressurize the header at 7kg/cm 2g. In intense situations
when this capacity is not enough or when the pressure drops below
Ca(HCO3)2
2CaCO 3
2H2O
This converts soluble bi-carbonates into insoluble carbonates, which
can easily be separated in the separation zone.
To remove the turbidity, aluminium sulphate is added in the water. This
causes the following reaction:
Al2(SO4)3
Ca(HCO3)2
Al(OH) 3 + CaSO4 +
CO2 + H2O
The Al(OH)3 attaches the clay, organic matter and dirt particles with it
and settles down in the settling zone of the clarifier. Since it takes
more time to settle due to slight density difference, a polyelectrolyte is
added in the water as a flocculent. It makes flocks of those settling
masses and increases their density. This lowers the settling time.
The concentration of the sulphates and aluminium in the water is kept
below 10ppm and 20ppb respectively.
The sludge is periodically removed from the bottom of the clarifier. The
water flow pattern is made in such a way that after the mixing zone
and removal of hardness, the water goes below the sludge bed and
passes through it. The bed of insoluble matter acts as a filtering
medium. Thats why whole of the sludge is not removed from the
bottom. A specific height of sludge is always maintained in the clarifier.
Then the water is raised in the settling zone where grooved channels
are made where the clarified water overflows in is sent in the Clarified
water basin (S-902). The major part of the clarified water i.e. around
80% is sent to the cooling towers as their makeup water through
pumps (P-904A/B/C).
Sand Filters:
The remaining water is further processed for making able to be used in
the boilers for the generation of steam. Pumps (P-905A/B/C) deliver the
clarified water in the Sand filters (V-901A/B/C/D/E). Gravels are used as
the filtering media, which removes the residual turbidity including clay,
sand, mud and other organic impurities from the water. The turbidity
level after the clarifier becomes in ppbs. The sand filters are back
washed after every 16 hours of service.
Backwashing is initiated by air scoring. Air scoring is an operation of
blowing the air from the bottom of the vessel. This loosens the gravel
bed that is blocked by the impurities. Then, previously filtered water
from the sand filters is used to backwash the filters. Backwashing is
done for 20 minutes. This is repeated after every 16 hours of sand filter
in service.
The filtered water is sent to the storage into the tank T-902 having a
capacity of 750m3. The filtered water is sent to a series of ion
exchangers. Pumps (MP-907A/B/C/D/E) are used to deliver this water to
the Strong cation exchanger (V-905). The water leaving the tank T-902
is having a pH around 10.2 due to the dissolved mineral salts.
Degasifier:
Degasifier consists of a bed of rashig rings. The water is sprayed from
the top and the air is blown from the bottom. This air decomposes the
weak acids as:
H2CO3
air
H2O
CO2
Carbon Filters:
The process condensate from urea and ammonia is led to the carbon
filters (V-914). It contains a bed of activated carbon that stops any
urea, ammonia, dissolved gases, oil or organic matter or their traces on
its surface. The water leaving the carbon filters is now completely free
from all the insoluble impurities.
The water from carbon filters (V-914) and from the strong anion
exchanger (V-908) is now taken to the mix bed polisher by means of
pumps MP-915A/B/C.