UNIVERSITI

TUNKUABDULRAHMAN

Faculty

F ES

Unit Code

UEMX4963

Course

BEng.(Hons)CivilEngineering

Unit Title

Engineering
Applicationin
Environment

Lecturer

Dr. LeeKhiaMin

Year/
Semester
Session

Tutorial:Metallon Complexation

Q1.

Solid waste from mining operations(mine tailings)frequently contain various FeS(st

minerals.In the presentof bacteria,water will feachthroughthe tailingsto form a very
acidicliquid stream containingFe3*and SOat-.The liquid stream is calledacid mine
drainage.
Determinethe speciation
of ferriciron and sulfurin acidminedrainageif the water is at
pH 2 with Fet*,= 5 x 1O-3M and Sr = 10-2M.

Q2.

Determinewhich metalforms a strongercomplexwith cyanideion : Fe3*or Ni2*.Forthis

purpose,sameamountof total Fe3*and Ni2*are addedto a solutioncontainingsome
total cyanideand,then cafculating
the concentrations
of the complexesformed.
At pH 2,Fe1=Nir = 1x 1O-s
M and CN1= 1x 10-3M, determinewhichcyanidecomplexis
formedat the highestconcentration.

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