4541

2009

SKEMA KIMIA PRAKTIS BESTARI

JUJ PAHANG

MARKING SCHEME
BAHAN PRAKTIS BESTARI
JUJ 2009

CHEMISTRY
SPM
PAPER 1
PAPER 2
PAPER 3

4541
2009

SKEMA KIMIA PRAKTIS BESTARI

JUJ PAHANG

MARKING SCHEME
BAHAN PRAKTIS BESTARI (JUJ) 2009
PAPER 1

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20

C
B
A
D
C
C
D
D
D
D
A
C
A
C
A
D
A
A
C
A

21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40

C
C
D
C
A
B
B
C
D
C
C
B
C
C
C
A
A
B
B
C

41
42
43
44
45
46
47
48
49
50

A
A
C
B
A
C
B
D
A
B

4541
2009

SKEMA KIMIA PRAKTIS BESTARI

JUJ PAHANG

MARKING SCHEME
BAHAN PRAKTIS BESTARI
JUJ 2009
PAPER 2
SECTION A
1

NO
(a)(i)
(ii)
(iii)
(iv)
(v)

MARKING CRITERIA
the number of proton in a nucleus

MARKS
1
1

13
6

T
T and U

T and U have same number of protons but different number of

neutron.

Carbon dating to estimate the age of fossils and artifacts

1

( b)

2 electrons in the first shell and 5 electrons in the second shell

1
Label of nucleus/ mark at the centre of the atom
1

(c )

V : 2.5 / 2,5

W : 2.6 / 2,6

TOTAL

NO

MARKING CRITERIA

MARKS

4541
2009

SKEMA KIMIA PRAKTIS BESTARI

JUJ PAHANG

Carbon dioxide

Limewater turns cloudy/ milky/chalky// white precipitate formed

(b)

Zinc oxide

(c)

ZnCO3 ZnO + CO2

1. correct formula for reactant
2. correct formula for products

1
1

(a)(i)
(ii)

(d)(i)

5
mol // 0.04 mol
125

(ii)

1.Correct ratio
1 mole of ZnCO3 : 1 mole of CO 2// 0.04 mole : 0.04 mole
2. Correct volume of gas with unit
0.04 x 24 dm3 // 0.96 dm3 // 960 cm3

(iii)

0.04 x 6.02 x 1023 molecules // 2.408 x 1022 molecules

TOTAL

NO
3

(a)
(i)

(ii)
(iii)

( b)
(c)

HCl + NaOH

MARKING CRITERIA
NaCl + H2O

MARKS

1.Correct formula of reactants

2. Correct Formula of products

1
1

The no. of mol of HCl = (22.00 x 0.2) /1000 // 0.0044

Mol of NaOH
= 0.0044

1
1

1. 1 mol HCl : 1 mol NaOH

2. Molarity of NaOH= 0.0044 x 1000/25.0

= 0.176 mol dm -3 //
3. Molarity for HCl = 2(0.1 x 22)
25
// 0.176 mol/dm3

Colourless to pink
1. Strong acid is the acid that completely disassociated in water
2. produce higher concentrated of hydrogen ions.
TOTAL

1
1
1
10

4541
2009

SKEMA KIMIA PRAKTIS BESTARI

NO
(a)(i)

(ii)

JUJ PAHANG

MARKING CRITERIA
Part X : Electrical to Chemical energy//
Electrical to Chemical
Part Y : Chemical energy to Electrical energy//
Chemical to Electrical

(b)(i)

MARKS
1

1
1

Blue colour becomes pale/paler // the intensity of the blue colour

decrease
(ii)
Because the concentration of the blue Cu2+ ions remains unchanged

Anode: 4 OH-

Cathode: 2H+

(c)(i)
O2 + 2 H2O + 4e-

(ii)
2e-

H2

(d)
Magnesium plate.

Magnesium is more electropositive/ situated at the higher position in

the electrochemical series

(e) (i)

1
Positive Terminal: Cu2+ + 2e-

Cu

(ii)
Negative Terminal: Mg

Mg 2+ + 2e-

TOTAL

10

4541
2009

SKEMA KIMIA PRAKTIS BESTARI

NO
5
(a)(i)
(ii)

ANSWERS
C4H8
Platinum / Nickel

MARKS
1
1

(b)(i)

(ii)

JUJ PAHANG

1
1

ethyl butanoate // etil butanoat

(c )
C4H8 + [o]

C3H7COOH //

[o]

C4H8 C3H7COOH
1. correct formula for reactant + oxygen /[O]
2. Correct formula for product

1
1

1. Functional diagram
2. Labelled diagram

1
1

1. Butene is an unsaturated hydrocarbon // has double bond

2. Butane is a saturated hydrocarbon // has single bond
TOTAL

1
1
11

(d)

(e)

4541
2009

SKEMA KIMIA PRAKTIS BESTARI

NO
(a)

JUJ PAHANG

MARKING CRITERIA
Cu2+ , SO42- // copper (II) ions, sulphate ions
accept: Cu2+ , SO42-, H+, OH-

MARKS
1

(b)

Copper (II) sulphate// copper sulphate

(c )(i)

Double decomposition // precipitation reaction

(ii)

1- solution X is heated until 1/3 of the volume / until saturated

2- cooled to room temperature
3- filter the crystal/salt // dry the crystal/salt by using filter paper.

1
1
1

Pb2+ + SO42- PbSO4

- correct formula for reactants
- correct formula for product

1
1

(d)

(e)(i)
(ii)

Sodium hydroxide solution // ammonia aqueous // ammonium

hydroxide solution
1- Add sodium hydroxide solution (until excess)
2- Blue precipitate formed //
If ammonia aqueous/ammonium hydroxide solution :
1- add ammonia aqueous/ammonium hydroxide solution (until
excess)
2- Blue precipitate soluble in excess
TOTAL

1
1
1

11

4541
2009

SKEMA KIMIA PRAKTIS BESTARI

JUJ PAHANG

SECTION B
7

NO
(a)
(b)( i)
(ii)

MARKING CRITERIA
1. Heat change when one mole of water is formed
2. reaction between an acid and an alkali.
HCl + NaOH

NaCl + H2O
1.Correct formula for reactants
2. Corret formula for products
Heat released = mc
= (25 + 25) (4.2)(13.6) / 2856 J
Heat of neutralization = 2856 / 57 kJ mol-1
0.05

MARKS
1
1
1
1
1
1

Energy
HCl

(iii)

NaOH

H2O + NaCl

1. Mark and label two level of energy

2. Formula/name of reactants and product for an exothermic
reaction
1. Ethanoic acid is a weak acid
2. Some of the heat given out is used for the
dissociation of molecules
Apparatus : Plastic cup/Polystyrene cup,
thermometer, measuring cylinder
Materials : [25 100] cm 3 of [0.5 - 2.0] mol dm-3
hydrochloric acid,
[25 100] cm 3 of [0.5 - 2.0] mol dm-3
sodium hydroxide ,
[25 100] cm 3 of [0.5 - 2.0] mol dm-3
sulphuric acid

(iv)
(c)

1.
2.

1. [25-100] cm3 of [0.5 -2.0] mol dm-3 hydrochloric acid

is measured andpour into a plastic cup.
2. [25-100] cm3 of [0.5 - 2.0] mol dm-3 sodium hydroxide
is measured and poured into another plastic cup.
3. Measure and record the initial temperature for both
solutions.
4. Mix / add the two solutions.
5. Stir the mixture thoroughly.
6. Measure and record the highest temperature.
7. Steps 1 to 6 is repeated using [25-50] cm3 of [0.5-2.0] mol dm-3
sulphuric acid and sodium hydroxide to replace
hydrochloric acid and sodium hydroxide.
8. Precaution steps :
the plastic cup must be covered / the solutions must be added
quickly / the temperature reading must be taken immediately
after the addition of solutions.
TOTAL

1
1
1
1
1
1
1
1
1
1
1
1
1
1

20

4541
2009
NO
8

SKEMA KIMIA PRAKTIS BESTARI

(a)(i)

JUJ PAHANG

MARKING CRITERIA
1. Electrolyte is a substance that can conduct electricity
when they are in molten or aqueous state
2. undergo chemical changes

MARKS
1
1

(a)(ii)

(b) (i)
(b) (ii)

(b) (iii)

(b)(iv)

sodium chloride solution/hydrochloric acid solution/molten

lead(II) iodide/ molten lead(II) bromide
[ any 2 answers of ionic compound in molten or aqueous]

Lead(II) ions and bromide ions/ Pb2+ and Br -

anode: brown gas released

cathode : shining grey substance is seen/grey solid is

formed/mass of the cathode increase

Electrode W: Bromine gas

Electrode X : lead is formed

Electrode W : 2Br-

Br2 + 2e

(c)
Materials :
Iron spoon, silver plate, silver nitrate solution

Apparatus :
Battery/power supply, connecting wires, beaker

Procedure :
1. Fill/add/pour the silver nitrate solution into a beaker
2. Dip iron spoon as cathode and silver plate as anode
3. Connect to power supply (battery) / Complete the circuit

1
1
1

Silver plate

spoon
Silver nitrate
solution

Functional
apparatus
-1
Labelled
diagram
-1

4541
2009
NO

SKEMA KIMIA PRAKTIS BESTARI

JUJ PAHANG

MARKING CRITERIA
Half equation at anode : Ag
Ag+ + e
+
Half equation at cathode : Ag + e Ag
Observations :
Anode : The silver plate becomes thinner.
Cathode : The spoon was coated with a layer of silver.
Ways to achieve a good electroplating:
1. The iron spoon was rotated slowly when the experiment
was conducted.
2. The iron spoon must be cleaned and free of grease
3. The concentration of Siver ions in the electrolyte or the
current used must be low
TOTAL

MARKS
1
1
1
1
1
1
1
Total=14m
Max 10m
20

4541
2009

SKEMA KIMIA PRAKTIS BESTARI

JUJ PAHANG

SECTION C
9

NO
(a)
(i)
(ii)

(b)

MARKING CRITERIA
Alloy is a mixture of two or more elements with a certain fixed
composition.
Bronze - copper and tin /
Brass - copper and zinc /
Steel - iron and carbon
[correct alloy and correct component] - 2 m
Statues/monuments / medals /artistic materials /
Making of musical instruments/kitchenware /
Building of body of aeroplanes/cars / surgical instruments
[Any 2 correct uses] 2m

MARKS
1

(c )

(i) 1.Arrangement of atoms for metal A and metal B

2.Different sizes of atom for metal A and metal B
(ii) 1. Atom of the impurity fills the disrupt the arrangement of atoms
2. reduces the layer of atoms from sliding
3. Alloy is stronger/harder than its pure metal

1
1
1
1
1

1.
2.

functioning
Diagram is labeled

- 1m
- 1m

3. Apparatus : brass / bronze /copper block,

Weight[0.5-2.0kg], steel ball, ruler,retort

10

1
1
1

4541
2009

SKEMA KIMIA PRAKTIS BESTARI

NO

MARKING CRITERIA

JUJ PAHANG
MARKS

Prosedure:
1. A steel ball is attached on the surface of the metal block.
2. [0.5-2]kg weight is held [50-1000]m from the surface of the
copper block, using thread.
3. the weight is released
4. the diameter of dent formed is measured.
5. Step 4 is repeated 3/5 times
6. Steps 1 to 5 are repeated with brass / bronze block.
7. the results obtained are recorded.
TOTAL

11

1
1
1
1
1
1
1
20

4541
2009
NO
10

SKEMA KIMIA PRAKTIS BESTARI

JUJ PAHANG

MARKING CRITERIA
(a) The rate of reaction in this reaction refers to the mass of sulphur formed
per unit time, that is the time taken for the cross on a filter paper placed
under the conical flask to disappear
(b) Na2S2O3 + H2SO4 Na2 SO4 + S + SO2 + H2O
1. Correct formula for reactants
2. Correct formula for products

(c)

1. Number of moles of H2SO4 acid = 2(5) // 0.01 mol

1000
2. 1 mole of acid produced 1 mol of sulphur
3. mole for sulphur = 0.01 mol
4. Mass of sulphur formed = 0.01 x 32 // 0.32g

(d) 1. Uniform scale

2. Labelled of axes with units
3. All points are transferred correctly
4. Smooth curve
(e) When the concentration of sodium thiosulphate solution is increase the
rate of reaction also increase
(f) Concentration(mol dm-3)

MARKS
2

1
1

1
1
1
1
1
1
1
1
1

1/time(s-1)

1. Labelled axes with units & directly proportional

(g) 1. The rate of reaction for experiment 1 is greater /

higher than experiment 4
2. the concentration of sodium thiosulphate solution Na2S2O3
in experiment 1 is higher than experiment 4.
3. When the concentration of the solution of is increase/higher, the
number of reactant particles also increase/higher
4. The frequency of collision between thiosulphate ions and hydrogen
ions increases
5. The frequency of effective collision also increases
6. The rate of reaction also increases
TOTAL

12

1
1
1
1
1
1
20

4541
2009

SKEMA KIMIA PRAKTIS BESTARI

JUJ PAHANG

SKEMA PAPER 3 KIMIA JUJ 2009

Question No.
1(a)

RUBRIC
Able to record all readings accurately to one decimal
point

SCORE
3

Sample answer :
Set 1 - 13.2
Set II - 13.4
Set III - 13.6
Able to record all readings correctly without decimal
point/
or
Able to record 2 reading correctly

Able to record 1 readings correctly

No response or wrong response

13

4541
2009
Question No.
1(b)

SKEMA KIMIA PRAKTIS BESTARI

RUBRIC
Able to construct a table that contains the following
information.
1. Correct title : Experiment, pH value
(Accept : Set , pH reading)
2. Transfer all pH readings from (a) correctly
3. Complete list of experiments : Set I, Set II, Set III

JUJ PAHANG
SCORE

sample answer :
3
Experiment

pH value

Set I
Set II
Set III
or

13.2
13.4
13.6

Experiment/set

pH value

I
13.2
II
13.4
III
13.6
or
Experiment Set I
Set II
Set III
pH Value
Able to construct a table that contains the following
information.
1. Correct titles : Experiment, pH value
(Accept : Set , pH reading)
2. Incomplete list of experiments
any two correct answer
Experiment/Set

pH value

Set I
Set II

13.2
13.4

Able to construct a less accurate table that contains the

following information
1. At least one title
2. Incomplete list of experiment
Sample answer :
Experiment

pH Value

Set I

No response or wrong response or empty table

14

4541
2009
Question No.
1 (c ) (i)

SKEMA KIMIA PRAKTIS BESTARI

RUBRIC
Able to state the observation correctly
Sample answer :
Set
I

II

SCORE

Alkali solution//pH value 13.38 //

Yellow flame //Move rapidly and
randomly on the water surface //
hiss sound.
Alkali solution//pH value 13.56 //
lilac flame// move very rapidly and
randomly on the water surface //
hiss and pop sound.

III

Question No.
1 (c)(ii)

Observation
Alkali solution//pH value 13.21
//hiss sound// move on the surface
of the water

JUJ PAHANG

Able to state two observation correctly

Or
Able to state the observation incorrectly

Able to state one observation correctly

No response or wrong response

RUBRIC
Able to give any prediction correctly
Sample answer:
-

SCORE

Move more vigorous/ more reactive than

potassium//can explode

Able to give any prediction correctly without comparison

-

Move more vigorous/ more reactive

Able to give an idea of prediction

2
1

No response or wrong response

15

4541
2009
Question No.
1 (c) (iii)

Question No.
1( c ) (iv)

SKEMA KIMIA PRAKTIS BESTARI

Rubric
Able to state the relationship correctly

JUJ PAHANG
Score

Sample answer:
Going down the group 1, the reactivity towards water
increases // vise versa
- Able to state less accurate relationship
Sample answer:
Going down the group 1, the reactivity increases // vise
versa

Able to state an idea

Sample answer:
The reactivity of group 1 elements increases /decreases
No response or wrong response

Rubric
Able to state the three variables correctly

0
Score

Sample answer:
Manipulated variables :
Responding variables :
Constant variables

Question No.
1 (d)

Type of group 1 elements / metal

Reactivity of group 1 element
towards water
water//size of metal

Able to state any two variable correctly

Able to state any one variable correctly

2
1

No response or wrong response

Rubric
Able to give explanation correctly

Score

Sample answer :
hydrogen ion /H+ from acid/hydrochloric acid react
with hydroxide ion /OH- from sodium hydroxide
completely.

Able to give explanation without completely

Sample answer:
Hydrogen ion /H+ from acid react with hydroxide ion/
OH- from alkali

Able to give an idea of explanation

1
Sample answer:
Acid react with alkali// react with acid//react with alkali
No response or wrong response
0

16

4541
2009
Question No.
1 (e)

SKEMA KIMIA PRAKTIS BESTARI

Rubric
Able to arrange all the elements in descending order
correctly

JUJ PAHANG
Score
3

Sample answer:
Potassium, Sodium, Lithium
2
Able to arrange at least two elements in descending order
Sample answer :
Sodium, potassium, lithium
1
Able to arrange the elements in ascending order
Smple answer :
Lithium, sodium, potassium
0
No response or wrong response
Question No.
2(a)

Rubric
Able to state the relationship correctly between the
manipulative variable and the responding variable with
direction.

Score
3

-Manipulated variable
Number of carbon atom per molecule
- Direction of the responding variable
Higher/increase
-Responding variable
Heat of combustion
Sample answer
When the number of carbon atom per molecule
increases, the (value of) heat of combustion increases //
The higher the number of carbon atom per molecule, the
higher the heat of combustion
* if reverse score 2
Able to state relationship between the manipulated
variable and responding variable

Sample answer
The number of carbon atom per molecule affect the heat
of combustion
Able to state the idea of hypothesis

Sample answer
Number of carbon atom affect the heat of
combustion//number of carbon and heat of combustion
No response or wrong answer

17

4541
2009
Question No.
2(b)

SKEMA KIMIA PRAKTIS BESTARI

Rubric
Able to state the operational definition for heat of
combustion correctly

JUJ PAHANG

Score
3

Sample answer
The heat released/produced when 1 mole of alcohol is
completely burnt in excess oxygen
Able to state the meaning for heat of combustion
incorrectly

Sample answer
The heat released when 1 mole of alcohol is burnt.// the
heat released when alcohol is burnt in excess oxygen.

Question No.
2(c)

Able to state the idea of heat of combustion

Sample answer:
The heat released//alcohol is burnt//oxygen is used in
burning of alcohol
No response or wrong response

Rubric
Able to state the inference from the graph correctly
Sample answer
The number of carbon atom per alcohol molecule
increase/becomes higher ,the heat of combustion
increase/becomes higher
Able to state the inference less accurate

Score
3

Sample answer
The heat of combustion increase/becomes higher the
number of carbon atom per alcohol molecule
increase/becomes higher
Able to state the idea of inference
The relationship is directly propotional//the number of
carbon atom and heat of combustion
No response or wrong response

18

1
0

4541
2009
Question No.
3(a)

SKEMA KIMIA PRAKTIS BESTARI

Rubric
Able to state the aim of the experiment correctly

JUJ PAHANG
Score
3

Sample answer
To compare/investigate/study the effect of total surface
area on the rate of reaction//
To compare/investigate/study size of the reactant/particles
on the rate of reaction
Able to state the aim of the experiment less accurately

Sample answer
To investigate /study /compare the effect of total surface
area/size //
rate of reaction depends on size/total surface area
Able to give an idea of the aim of the experiment

Sample answer
To investigate/compare/study the rate of reactions
/surface area/size
No response or wrong response
Question No.
3(b)

Rubric
Able to state the three variables correctly

0
Score
3

Sample answer
Manipulated variables:
Total surface area of marble chips//size of marble chips
Responding variable:
Rate of reaction//volume of hydrogen gas
Constant variable
Mass of marble chips//volume and concentration of
hydrochloric acid//temperature
Able to state any two variables correctly
Able to state any one variable correctly
No response or wrong response

19

2
1
0

4541
2009
Question No.
3(c)

SKEMA KIMIA PRAKTIS BESTARI

Rubric
Able to state the relationship correctly between the
manipulated variable and the responding variable
Sample answer
When the total surface area of reactants (marble chips)
increase /decrease,the rate of reaction
increase/decrease//
When the size of reactants(marble chips)increase/
decrease, the rate of reaction decrease/increase
Able to state the relationship between the manipulated
variable and the responding variable with direction
Sample answer
The rate of reaction of reactants/(marble chips) increase/
decrease/fast when the total surface area increase
/decrease/low//
the rate of reaction increase/decrease when the size
decrease/increase
Able to state the idea of hypothesis

JUJ PAHANG
Score
3

Sample answer
Size of marble chips/reactants effect the rate of reaction
No response or wrong response
Question No.
3(d)

Rubric
Able to give complete list of substances and apparatus

0
Score
3

Sample answer
Substances:
Water, large marble chips, small marble chips , [name of]
acid
Apparatus:
Water trough/basin/pail/tray/tank, burette, delivery tube,
retort stand, conical flask, stopwatch, stopper, measuring
cylinder, electronic balance
Able to list the substances and the apparatus below :

Sample answer
Substances:
Water, marble chips, [name of] acid
Apparatus:
Water trough/basin/pail/tray/tank, burette, delivery tube,
conical flask, stopwatch, stopper, electronic balance
Able to list the substances and the apparatus below :

Sample answer
Substances:
marble chips, acid
Apparatus:
Water trough/basin/pail/tray/tank (or any container),
burette (measuring cylinder), conical flask, stopwatch
No response or wrong response

20

4541
2009
Question No.
3(e)

SKEMA KIMIA PRAKTIS BESTARI

Rubric
Able to list all the steps correctly

JUJ PAHANG
Score
3

Sample answer
1. Fill the water basin/ trough with water
2. Fill a burette with water and invert in a water
basin/trough
3. clamp the burette with a retort stand
4. Record the initial reading
5. Pour (50cm3) acid into the conical flask
6. Put large marble chips / small marble chips into the
conical flask. Close the conical flask immediately
with a stopper and start the stopwatch.
7. Record the burette reading at intervals of 30
seconds until the reaction stops.
8. Repeat the experiment/(steps 1-7 )/using
small/large marble chip
Able to list down steps 2, 5, 6,7
Able to list down steps 5, 6
No response or wrong response

Question No.
3(f)

Rubric
Able to tabulate the data with the following aspects

2
1
0

Score
2

1. correct titles with correct unit

Sample answer
Time/min //
time/s
Burette
reading (cm3)
Volume of gas
(cm3)
Able to tabulate the data with correct title without unit //
at least two correct title with unit
No response or wrong response

21

1
0