1.

Kurva kalibrasi (soal AAS)

The absorbances of unknown samples were 0.217, 0.215 and 0.212. Calculate the concentration of Cd in river
sediment
Jawaban :

kons
0
2
4
6
8
10
sampel

absorbans
0
0,127
0,25
0,382
0,513
0,698
0,217

0
0,124
0,251
0,379
0,515
0,7
0,215

0
0,13
0,253
0,384
0,52
0,701
0,212

Rata-rata
0
0,127
0,251333
0,381667
0,516
0,699667
0,214667

Konsentrasi sampel = (0,21467+0,013)/0,068 = 3,348 ppm

2. Standar adisi (AAS) :
An AAS method for the quantitative determination of the concentration of Ca2+ in blood yields an Ssamp of
0.22 for a 1.00-mL sample of blood that has been diluted to 5.00 mL. A second 1.00-mL sample is spiked
with 1.00 L of a 2500-ppb Ca2+ standard and diluted to 5.00 mL, yielding an Sspike of 0.419. Determine the
concentration of Ca2+ in the original sample of blood.
Jawaban :

A sampel = K [(C sampel awal x V sampel) /V total]

0,22 = K [ (C sampel awal x 1)5
K =( 0,22 x 5 ) / 1 x Csampel awal
K = 1,1 / C sampel awal........................1)
Masukkan persamaan 1} ke nilai K untuk persamaan A spiking :
A spiking = K [(C sampel awal x V sampel) /V total] + K [(C standar awal x V standar) /V total]
0,419 = 1,1 / C sampel awal [( C sampel awal x 1) +(2500 x 1 X 10-3) / 5]
0,419 = 0,22 + 0,55 / C sampel
0,199 = 0,55/C sampel
C sampel = 2,89 ppb
3. Standard adisi multiple point (AAS)

Calculate the Cu concentration in the sample solution

Jawaban :

vol
sampel
10
10
10
10
10

[standar]
Absorbans
vol standar diencerkan spike
0
0
0,201
10
2,44
0,292
20
4,88
0,378
30
7,32
0,467
40
9,76
0,554

A spiking = K [(C sampel awal x V sampel) /V total] + K [(C standar awal x V standar) /V total]
Persamaan garis : Y = 0,036 X + 0,202

X intersept = 0,202/0,036 = 5,611

5,611 = (Csampel x V Sampel)/ Vtotal
5,611 = (Csampel x 10) / 50
C sampel = 28,055 ppm
4. A standard sample was prepared containing 10.0 ppm of an analyte and 15.0 ppm of an internal standard.
Analysis of the sample gave signals for the analyte and internal standard of 0.155 and 0.233 (arbitrary
units), respectively. Sufficient internal standard was added to a sample to make it 15.0 ppm in the internal
standard. Analysis of the sample yielded signals for the analyte and internal standard of 0.274 and 0.198,
respectively. Report the concentration of analyte in the sample.
Jawaban :
I standard/I IS = K Cstandard / C IS
0,155/0,233 = K (10/15)
K = 0,993
I sampel/I IS = K Csampel / C IS
0,274/0,198 = 0,993 x C sampel / 15
C sampel = 20,904 ppm
5. Gluodenis describes the use of ICP to analyze samples containing Ni in brass. The analysis for Ni uses an
internal standard. Results for a typical calibration are shown in the following table. What is the %w/w Ni in
a sample for which the ratio of emission intensity is 1.10 x 103?

Jawaban :

% w/w Ni dalam sampel :

1,1 x 10-3 = 0,923 X 0,005
% w/w Ni dalam sampel = 0,0066
6. Suatu sampel yang mengandung tembaga ditentukan kadarnya menggunakan ICP dengan metode internal
standar dengan logam Au. Hasil pengukuran beberapa konsentrasi larutan tembaga memberikan hasil
sebagai berikut :
Konsentrasi
Cu (ppm)

Konsentrasi
Au (ppm)

Intensitas
emisi Cu

Intensitas
emisi Au

0,322

0,222

10

0,672

0,234

15

0,933

0,233

20

1,345

0,233

Hitung kadar logam tembaga dalam sampel tersebut jika sampel menghasilkan intensitas emisi 0,545 dan
intensitas emisi internal standar 5ppm adalah 0,245
Jawaban :

I sampel / I IS = 0,545 /0,245

= 2,224
Y = 0,286 X + 0,00008
2,24 = 0,286 X + 0,00008
Kadar logam tembaga = (2,24-0,00008)/0,286
= 7,77 ppm
Jika dibuat kurva terhadap rasio I IS/Istandar maka sebagai sumbu X adalah 1/ C standar
7. The concentration of As(III) in water can be determined by differential pulse polarography in 1 M HCl. The
initial potential is set to 0.1 V versus the SCE, and is scanned toward more negative potentials at a rate of
5 mV/s. Reduction of As(III) to As(0) occurs at a potential of approximately -0.44 V versus the SCE. The peak
currents, corrected for the residual current, for a set of standard solutions are shown in the following table.
[As(III)] (M) ip(mA)
1.00 106 0.298
3.00 106 0.947
6.00 106 1.83
9.00 106 2.72
What is the concentration of As(III) in a sample of water if the peak current under the same conditions is
1.37 mA?
Jawaban :

Konsentrasi arsen dalam sampel air :

Arus puncak = 1,37 mA
1,37 = 30129 X + 0,017
X = (1,37 0,017)/30129
-5
= 0,0000449 M = 4,49 X 10 M
8. The concentration of copper in a sample of sea water is determined by anodic stripping voltammetry using
the method of standard additions. When a 50.0-mL sample is analyzed, the peak current is 0.886 mA. A
5.00-mL spike of 10.0-ppm Cu2+ is added, giving a peak current of 2.52 mA. Calculate the parts per million
of copper in the sample of sea water.
Jawaban :
Ip = arus puncak
Ip sampel = K C sampel
0,886 = K x C sampel
K = 0,886/C sampel.............1)
Masukkan K dari persamaan 1) ke persamaan di bawah ini (Ip spiking) :
Ip spiking = K [(C sampel awal x V sampel) /V total] + K [(C standar awal x V standar) /V total]
2,52 = 0,886 / C sampel [(Csampel X 50)/5+50] + 0.886/C sampel [(10 x 5)/5+50]
2,52 = 0,805 + 0,733/Csampel
2,52-0,805 = 0,733/C sampel
C sampel = 0,427 ppm
9. A 25.0-mL sample of Ni2+ gave a wave height of 2.36 A (corrected for residual current) in a polarographic
analysis. When 0.500 mL of solution containing 28.7 mM Ni2+ was added, the wave height increased to 3.79
A. Find the concentration of Ni2+ in the unknown.
Jawaban :
Ip sampel = K C sampel
2.36 = K x C sampel
K = 2.36 /C sampel.............1)
Masukkan K dari persamaan 1) ke persamaan di bawah ini (Ip spiking)
Ip spiking = K [(C sampel awal x V sampel) /V total] + K [(C standar awal x V standar) /V total]
3,79 = 2.36 / C sampel [(Csampel X 25)/25+0,5] + 2.36 /C sampel [(28,7 x 0,5)/0,5+25]
3,79 = 2,31 + 1,328 / C sampel
1,48 = 1,328 /C sampel
Konsentrasi Ni dalam sampel = 1,328/1,48 = 0,897 nM