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Cathodic Protection

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Dfinition of Corrosion

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The chemical or electrochemical reaction between a material and its environments


that produces a deterioration of the material and its properties

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problem

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Degradation of technical qualities of the system

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Activation in neutron flux corrosion products

Choice of metal or alloys

metal insulation
Imposed current protection

PD

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Chemical (water purity, Ph)

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Reagent external environment adaptation

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Solutions

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Cathodic protection
Cathodic protection controls corrosion by making the whole metal surface a cathode of an electrochemical

By Sacrificial Anodes.

By Impressed Current.

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Cathodic protection can be achieved in two ways:

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cell

Sacrificial Anode

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In this method, Metallic structure is connected to more anodic metal.

PD

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The more active metal so employed is called sacrificial anode.

Galvanic series

Protection of buried pipelines.

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Pipeline

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Applications of sacrificial method

PD

Backfill

Sacrificial
anode

Pr
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Ev

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Water tanks

PD

Sacrificial Anode

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Marine structures

PD

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Ev

Sacrificiel anode

PD
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Ev

Pipe lines

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Choice of Galvanic Anode Material

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Metals like (Zn, Mg, Al) are used for making anode because they are more active low
electrochemical potential as compared to steel.
Zinc

high efficiency

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low current output

Ev

generally used for the protection of pipelines, where the effects of burial along
with the high duty coating tend to give low anode current densities.

PD

driving voltage diminishes with increasing temperature virtually ineffective at


temperatures of about 60o c.

Aluminium

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high capacities

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capable of operating at high temperatures upto


100o c.
alloy compositions relatively tolerant of trace
impurities

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offer an economic solution to sea water protection.

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Magnsium
dissolves vigorously in sea water use restricted only to soil applications or

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estuarine waters (high resistivity)

high current output

Ev

high rate of intergranular corrosion especially in low resistivity soils

PD

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low current output efficiency

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Recommended Electrolyte

Magnesium (Mg)

Soils & hot water

PD

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Aluminum (Al)

Soils & fresh / sea water

Ev

Zinc (Zn)

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Anode

Sea waters

Prepackaged Sacrificial Anode

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For soil applications: prepackaged Mg & Zn anodes

PD

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Mg

Backfill

Carbonaceous backfill

218-L

4518

Resistivity,
ohm-inch

0.02

0.01

Resistivity,
ohm-cm

0.05

0.03

99.0

99.9%

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Property

Carbon (L.O.I.
method)

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Moisture

0.10%

0.02%

Ash

0.35%

0.10%

VCM

0.30%

0/22%

Sulfur

3.75%

4.3%

46-50

62-66

+4M < 10%


+8M > 90%
-8M < 10%

4M 10%
+20M > 80%
-20M 10%

Bulk Density
(lbs/ft3)

PD

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Low resistivity to reduce anode to earth resistance.


High porosity to allow gases produced at the surface of the anode to escape.
Low density to provide high permeability with cost effectiveness.
In addition, the backfill should flow easily, and be of high purity.

General Sizing
+ 4 Mesh
+ 8 Mesh
- 8 Mesh

Magnsium

Potentiel CuSO4 Potentiel Ag/Agcl(v)


(V)
-1.50( standard)
-1.70(high
potentiel)
-1.1( Beralin )
-1.12(Becalin)
-1.00
-1.05

Consumption rate
(kgper/A/year)

PD

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Zinc

Current capacity (Ah/kg)

7.3
7.3

1100
1230

3.27( Beralin )
3.45 (Becalin)
11.5

2680( Beralin )
2550( Becalin)
760

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Aluminium

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sacrificial anode properties

Les formes de anode Aluminium et Zinc

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Slender ( stand-off )

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Application

Double crank flat bar


Straight flat bar

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Ev

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Flush mounted

PD

Application

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Bracelet

segmented Bracelet Anode

Ev

Half-Shell Bracelet Anode

PD

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Application

Ev

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Magnesium and Zinc Ribbon anodes

PD

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Application

PD
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Spherical

Type of anode

Value of Utilization Factor


0.9

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Long-slender tand off (L>4r)

0.85

Short -slender tand off (L<4r)

Bracelet half-shell

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Bracelet segmented

0.85
0.80

Ev

Long-flush-mounted (L>4r)
Short-flush mounted (L<4r)

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Anode utilization factor

0.80
0.75

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Impressed Current
ICCP systems use anodes connected to a DC source.

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For larger structures, galvanic anodes cant economically deliver


enough current to provide complete protection.

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The negative terminal of DC is connected to pipeline to be protected.


The anode is kept in back fill to increase the electrical contact with the
surrounding soil.

PD

This current is given to insoluble anode like graphite, stainless steel or


scrap iron buried in soil.

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consumables( produits ferreux, acier,fonte)

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The anodes are classified into 2 large families

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No consommables (graphite imprgn , ferro-silicuim ,magntite ,


Mixed Metal oxide (MMO),High-silicium cost iron (HSCI ), titane platin
,niobium platin)

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consumables( ferreux ,acier)

Ev

Tubular
Consumption rate

Current density

Density

Water, soil

9kg/A.year

No limit

7.8g/cm3

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Place

Are the most common impressed current anodes

Are used in soil, water or sea water

Come in two grades; FeSi and FeSiCr for sea water applications

Cable connection to anode shall be handled with great care.

PD

No consumable

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Anode Type

Ev

1.Mixed metal oxide coated titanium.


2. Platinised titanium/niobium.
3. Lead-silver-antimony.
4. Silicon iron with chrome.
5. Magnetite.

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For seawater applications

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For buried applications


1.Mixed metal oxide coated titanium.
2. Scrap iron
3. Lead-silver-antimony.
4. Silicon iron with chrome.
5. Graphite

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Mixed Metal oxide (MMO)

Ribbon ,
Mesh et tubular
, wire ,rod

27kg

Weight

PD

Forme

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Is corrosion proof anode coat Ir and Ta on titanium substrate pevided ,Ribbon,Mesh and tubular
By its form used to prevent corrosion for storage tank bottom,pipe and offshore structures

Application

Avantages et dsavantages

pile, tank
bottom,

Tend to use MMO anode


Light weight
High durability , variaty form

PD

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Types MMO anodes

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Ribbon

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MMO-Ribbon Anode

Out put current

Current density

Design life

0.5-4 mg/A/year

0.45mA/m

3A/m

50 years

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Consumption rate

PD

Tableau de Dimensions

PD
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Ev

Application

Consumption rate

Out put current

Current density

Design life

3.5mA/m

110A/m

100 years

Pr
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MMO-Mesh Anode

PD

Tableau de Dimensions

PD
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Ev

Application

Carbounacious

Size anode
Diameter(m Length(mm)
m)
500

Pr
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Environement

Ev

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Anode MMO-Tubular

Out put current Current


Design life
density(A/m)
(A/m)
4

50

20

1000

500

100

20

25

1000

100

20

Brackich water

25

1000

100-600

20

Sea water

25

500

25

600

20

1000

50

Brakfill

25

PD

Fresh water

25

Calcined
petrolum coke

PD
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Application

PD
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MMO-wire Anode

Application

PD

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TANKS above ground


Underground Storage Tanks
TANKS WATER
Shallow horizontal
NATURAL WATER

Length (inch)

Brakfill

39.37

0.25

0.25
0.50
0.75
0.125

Fresh water

39.37

39.37

PD
Sea water

0.0006 to 0.006

0.210
0.044

0.167

39.37

0.270
0.123

0.25

0.245

0.50

0.490

0.75
0.125

20 years

100

20 years

100

20 years

100-300

20 years

600

20 years

0.140

0.50

50

0.069

0.088

0.75
0.125

Brackich water

0.210
0.035

0.25

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Design life

0.140

Ev

0.75
0.125

0.035

Current density
(A/m)

0.069

0.50

Calcined petrolum coke

Out put current (A/inch)

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Dimeter(inch )
0.125

Carbounacious

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MMO-ROD Anode

39.37

0.740
0.123

0.25

0.245

0.50

0.490

0.75

0.740

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Application

PD

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Ev

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PUMPS
CONDENSERS and water boxes
Water intakes

PD

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Tubular Anode

Ev

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high-silicon cost iron (HSCI)

Rod sitck Anode

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Tubular Anode

Consumption rate : 0.45kg/A/year, utilization factor : 0.65

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Rod sitck Anode

Consumption rate : 0.25kg/A/year, utilization factor : 0.85


Environement

10-30

Sea water

10-50

Fresh water

10-30

PD

soil

Current density(A/m)

Application

Most universal matriel

Strong fragility

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Avantages & dsavantages

PD

Bad construct ability

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underground piping
underground tank
the tank bottom
inside of the water tank

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Flexible anode
PROTECT MULTIPLE PIPELINES IN A CORRIDOR
EASY TO INSTALL ALONG WITH PIPE IN THE SAME TRENCH.

PD

38

Length (m)

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Diameter (mm)

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MULTIPLE LINEAR ANODES CAN BE DEPLOYED TO ENSURE

500-1000

Out put current


(mA/m)

Backfill weight

weight

52-1000

1.15kg/m

1.5kg/m

Application

PD

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Parallel Anode Pipeline CP


Underground Cable Ducts CP
New Construction Tank Bottom CP
Replacement Tank Bottom CP

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Graphite anode

Avantages

Dsavantages

PD

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Readily available in a variety of sizes


relatively inexpensive
A good conductor of electricity
high ratio of surface area to weight
improve low current density current
discharge and low resistance
electrolyte
chemically resistant
Do not form a high resistance layer
corrosion products
Easy to machine

Operating at low current density


lower mechanical strength, very fragile

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Consumption rate& current density

PD

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Dimensions

PD

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Characteristic of Magntite anode

Ev

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Magntite Anode

operates at high current densities with


extremely low dissolution
not susceptible to ripple in DC supply
no limit on DC voltage output
light weight and easy to install, removable for
inspection and reinstallment
centre cable-to-anode connection for uniform
current distribution and consumption of anode
surface

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Type of magntite anode

Place: neutral soil and water without chlorine and sulphate content

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Ev

Applications:shallow groundbeds, deep groundbeds

PD

Place :chlorine and/or sulphate containing soil or stagnant water


Applications :shallow groundbeds, deep groundbeds

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CANISTER FOR TYPE: MA-U + TYPE: MA-CS

PD

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Coke brackfill

PD
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Ev

Application

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Place : flowing seawater or brackish water


Applications: platforms, jetties, harbours

PD

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Place :chlorine containing soil or stagnant water


Applications: deep groundbeds open hole, deep groundbeds closed
hole, water tanks

Place : chlorine containing soil or stagnant water


Applications: deep groundbeds open hole, deep groundbeds closed
hole, water tanks

Passive film formation, high cost, high


breakdown potential, fair conductivity.

Titanium (Ti)

Passive film formation, low cost, low


breakdown potential, poor conductivity

Ev

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Niobium (Nb)

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Platinised Titanium/Niobium

PD

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Pt/Ti-Nb- Rod anodes

Screw-in type Pt/Ti-Nb rod anodes with pressure


resistant head structure are widely used for internal
protection of condensers and other process equipment

Ev

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Pt/Ti-NbMesh anodes

PD

Pt/Ti-Nb Wire anodes

Pr
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Pt/Ti-Nb mesh anodes are used for the protection


of reinforced concrete structures.

Pt/Ti-Nb wire anodes are used for the internal protection of water
tanks and pipelines.

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Electrochemical characteristics of impressed current anodes

Consumption
Rate (g/Ay)

Maximum current
(A/m)

Maximum
voltage(V)

MMO-SeawaterMMO-buried-

0.0006 to 0.006
0.006to 0.008

400to 1000
80to100

Platinised
titaniumseawater-

0.004to 0.012

Platinised
Niobiumseawater-

0.004to0.012

Lead silverseawater-

15to75

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Anode Materiels

500to1000

50

150to250

24

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Ev

500to 1000

100to300

10to30

50

Magnetite-buried

2to 3

80to100

50

Graphite buried-

200to500

5to15

50

PD

Silicon iron
chrome-buried-

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Transformer rectifier

Pr
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Ev

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The rectifier transformers are used for current cathodic protection systems imposed from underground
structures or submerged.

PD

Transformer rectifier intrieur

Transformer rectifier extrieur

Pr
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Ev

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Types of transformers rectifier

PD

Transformers rectifier Air cooled

Transformers rectifier oil cooled

PD

Pr
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Ev

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Air cooled standard Line

PD

Pr
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Ev

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Air Cooled UT & SW Series

PD

Pr
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Ev

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Air Cooled Gas Station Series

PD

Pr
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Ev

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Oil Cooled & Explosion Proof

PD

Pr
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Ev

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Oil Cooled & Explosion Proof

ORD Oil Cooled & Explosion Proof

PD

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Ev

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Rugged smaller rectifiers for lower output


applications under severe conditions
Maximum 200 watts & 20 amps single phase

Pr
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Ev

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Air Cooled ES Line

PD

Low output, low cost, lightweight cathodic protection


rectifiers for underground
storage tanks and other low DC power cathodic
protection applications maximum 200 wattts & 10
amps

PD

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Example of transforms rectifier forms

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At each regular cycle operator confirm type potential


value and manually adjust voltage and current in order
to maintain target potential value.

Automatic Rectifier

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For maintaining initially set type potential value such


value is feed back by rectifier automatically thus
voltage and current is controlled accordingly.

PD

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Manual Rectifier

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Rectifier

Tension entre

Tension sortie

Courant sortie

Type de
redresseur

Frquence

12,16,24,48,75,
100V DC

5,10,15,25,50,1
00,150,200,250,
300,400,500,60
0A DC

Silicium diode
Thyristor

50Hz/60Hz

PD

230v AC/400v
AC

Pr
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Characteristic of transformers rectifier

Ev

Transformer

Pr
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Ev

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Anode jonction box

Specifically construted for CP system installations


Sufficient number of terminals ( five terminals minimum) with associated hardware for number and size

of cables

PD

Equipped with variable resistors of adequate electrical rating for each anode
Equipped with combination bracket for pole or wall mounting

PD
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Ev

PD

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Ev

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Example of junction Box order form

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Test stations

Specifically constructed for CP system installations

PD

wire specified

Post is 7 foot long -3inch-diameter polyvinyl chloride (PVC) with a1/2 inch-diameter, solid PVC cross bar unless other

Sufficient number of terminal ( five terminal minimum)with associated hardware for the number and size of cable

Vent Pipe

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Nominal 1-inch inside diameter


at surface
Pipe below surface can be larger

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than 1 inch in diameter and sized


as needed for depth of well and
per CP specification section

within the coke backfill column and


non slotted outside the limits of

PD

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the coke backfill column

Ev

The vent pipe should be slotted

PD

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Ev

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Remote Monitoring Test Box

PD

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Remote Monitoring Test Box

Definition of Ground bed

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System of buried or submerged anodes connected to positive terminal.


.

Types of ground beds


Deep-well GB

Horizontal shallow GB

Vertical shallow GB

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PD

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cathodic protection system installation

PD

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Deep-well GB
One or more anodes installed vertically at a nominal depth of 50 m or more below the
earth's surface.

Attach the first anode to centralizer

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Anode and vent pipe installation

The vent pipe should be installed with the first anode by attaching it to one of

PD

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the centralizer straps with a stainless clamp as shown in

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No anodes should be buried until the Earth has inspected the placement of anodes
and given permission to backfill

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coke backfill materiel should be introduced into the bottom of the drill hole using a pipe
is the length of the anode hole and a pumping action to fill the drill hole

PD

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Ev

five feet of sand backfill placed on top of the coke backfill

PD
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Ev

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Shallow vertical groundbed ( depth 3m-5m)

PD

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Ev

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The individual or multiple anode groundbed resistances can be determined using Dwight
formula or can be determined graphically

Shallow horizontal groundbed( depth 3m-5m)

PD

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Sometimes due to unfavorable soil conditions shallow horizontal groundbeds are preferred.
Again earth resistances can be determined by calculation.

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Avantages & disavantages groundbed

Avantages

Disavantages

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Shallow ground bed resistance is higher in areas of high


resistivity surface soils.
Shallow ground beds are more affected by seasonal variations
than deep ground beds
It may not be possible to install a shallow ground bed in
congested areas and areas of interference.
Shallow ground bed may results in higher anodic potential
gradients to other structures than a deep ground bed.

PD

Pr
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Ev

Shallow ground beds are less expensive to install than the deep
ground beds.
Current requirement tests that accurately simulate actual
installation are easy to conduct.
Shallow ground beds may be installed with anodes either in
vertical or in horizontal position. Vertical anode ground bed has
slight edge over the horizontal ground bed in terms of resistance
and current spread. However, field condition lead to the
selection.
Compaction of backfill material around the anode in a shallow
ground bed is easy to achieve.
Anodes may be added in a shallow ground bed after installation
if required, provided there is capacity in the power supply and
the cable.
Inspection, replacement or repair of ground bed components is
easy.
Determination of shallow ground bed performance is easy and
fairly accurate.

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Cable Connections

Cable to - cable connection

Cable to - pipe connection

PD

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Ev

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Cable to - cable connection

Ev

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straight joint

Application

PD

Pr
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Low Voltage 1kV (1000v), Telecommunication


and Signalisation
- Underground, above ground, under water

Ev

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Jointing resin

Pr
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Very high resistance against UV, chemicals and earth alkaline & sea water
High impact resistance

Low curing temperature

PD

No toxic emission

Good adhesion to all cable materials (PVC, PE, PP and XLPE)

PD
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Application

For cable-to-pipe connection :

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Cable to - pipe connection

Ev

1- Thermite ( Cad / Exothermic ) Welding


2- Pin Brazing

PD

Pr
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3- Mechanical connection ( for gas pipelines )

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Thermite welding

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Crucible

Disks

PD

Pr
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Ev

Cartridge

Cartridge

PD

Pr
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Ev

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Thermite Plastic Weld Cap

No Liquid Primer Needed


Easy Field-Applied Corrosion Protection
Ideal for Keyhole Applications
Elastomeric Compound Encases Weld
Profile
Serrations Conform to Small Diameter

Application

PD

Pr
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Ev

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Thermite Welding

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Protecting the Thermite Weldment

PD

Self-adhesive
Handy-cap

Pr
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Ev

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Pin Brazing

Pins & Ferrules

Pin Brazing Unit

PD

Ev
Pr
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Grinder

Pistol / Gun

Lug

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Application

Ev

1 Clean the surface

2 Load gun with pin &

Pr
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ferrule

PD

4 Test connection

3 pin braze

connection of gas

PD

Pr
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Ev

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Mechanical Connection : recommended for drain point


pipelines

Electrical Isolation(Insulation)

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AC Fault Currents
Mitigation of induced AC Voltages
Lightning

PD

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Isolation joint Flange kit

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Isolation joint Flange kit

PD

Pr
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Type E Gaskets extend to the


outside diameter of the flange.
They feature precision located
bolt holes, to automatically center
the gasket, and offer maximum
protection against foreign
material shorting-out the flange

Ev

Type E Gaskets

Type F Gaskets

Type "F" gaskets are made without


bolt holes, to fit tightly inside the
overall bolt hold circle of the flange
faces. The outside diameter of the
gasket fits tightly in place, assuring a
well centered position.

PD

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Polarization cell

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Ev

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Monoblock joints

PD

Resistance in air: greater than 5 M


Testing voltage: 3 000 V - 50 Hz
Hydraulic test pressure: 1.5 x PN
Temperature: up to 70 C

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Surge Protection

Specification
Type

EC-Type Examination Certificate


DC Spark-Over Voltage
AC Spark-Over Voltage (50Hz)

Pr
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Impulse Spark-Over Voltage at 5kV/


-for 99% of measured values (Wave 1.2/50, 6kV)

Max. Impulse Discharge Current (wave 8/20)


Nominal Impulse Discharge Current (wave 8/20)
Max. Lightening Impulse Current Iipm (10/350)
Charge
Specific Energy
Insulation Resistance at 100VDC
Capacitance at 1MHz
Weight

PD

Casing

Degree of Protection
Operating and Storage Temperature
Ordering Code

HGS 100 EX
400 . 750 kV
> 500 Vrms
< 1500 V
150 kA
75 kA
100 kA
50 As
2500 kJ/
>1G
5 pF
535 g
Korundum/ binary resin with an external
Steel Coat, resistant to climatic effects
IP66
-40.+90oC
100 04

Ev

al
ua

tio
n

Application

PD

Pr
o

Spark Gap Fitted

PD

Pr
o

Ev

al
ua

tio
n

Carrier pipeline insulators

PD
Pr
o

tio
n

al
ua

Ev

Application

tio
n

Anode connection

PD

Pr
o

Ev

al
ua

Anodes cables are connected to anode / positive junction box


Each anode can be connected via a variable resistance to control the
current output
A header cable connects the AJB to e +Ve terminal of T/R

PD

Main Cable to +ve


Terminal of T/R
Direct connection to +ve bus bar

Positive Junction Box

Anode Cables from


GB

Pr
o

Ev

al
ua

tio
n

Anode connection

al
ua
Pr
o

Ev

Main Cable to +ve


Terminal of T/R

Connection via variable


resistance

PD

Anode Cables from GB

tio
n

Anode connection

Positive Junction Box

PD

Pr
o

Ev

al
ua

tio
n

Impressed current anodes are some


times packaged with the
Carbonaceous backfill.

tio
n

Safety and Testing

Do not test electrical equipment when it is raining


Approach a rectifier carefully

Ev

Check for grounding using an AC voltmeter

al
ua

Safety

All work performed on the rectifier should take place with the power off at both the rectifier and an external

PD

Pr
o

circuit breaker

tio
n

Testing

1-Structure electrical continuity

Voltage difference between the cable

Ev

3- Static anode to electrolyte potentials

al
ua

2-Test station integrity

At anode location for impressed current system

PD

Pr
o

At each test station enclosure for galvanic anodes

metalwork
At each individual test station location

tio
n

4-Static structure to soil potentials of the buried and submerged

al
ua

Portable reference electrode placed as close to buried metalwork


as possible

Ev

Current output of each individual anode in junction box

Pr
o

Variable resistor setting for each anode and structure


5- Cable connection to rectifier

PD

terminal

Structure cable must be connected to the Negative DC output

Anode cable must be connected to the positive DC output


terminal

al
ua

Time between testing cycles is 30 to 60 days

tio
n

6-Second and Subsequent Testing Cycles

Cathodic protection system not adjusted between

Ev

testing cycles

PD

Pr
o

All testing during the first testing cycle repeated

tio
n

Mesurement potentiel

Copper / Copper Sulfate

Silver / Silver Chloride

Soil

Sea Water

PD

Pr
o

Ev

al
ua

Structure/Electrolyte Potential is measure by means of a reference


electrode :

Copper sulfate

Silver chloride

PD

Pr
o

Ev

al
ua

tio
n

Copper / Copper Sulfate

Typical Arrangement for


Pipe to Soil
Measurement

al
ua

CopperRod
Copper

CuSO4 Saturated
Solution
HIGH SO42- IONS
CONTENT

tio
n

Copper / Copper Sulfate

AVO meter

Cu

SO42-

Ev

Cu2+

SO42-

Pr
o

Porous Disc

Sulfate ions migrate

PD

from CSE to soil

H2O (Soil) HIGH WATER CONTENT


Water molecules

migrate into CSE

Pipe

PD
Pr
o

tio
n

al
ua

Ev

PD
Pr
o

tio
n

al
ua

Ev

Pr
o

Ev

al
ua

tio
n

corrosion Potentiels in soil and seawater

PD

The value 850 mV is the CP criterion for protecting steel in


aggressive soils
The value 800 mV is the CP criterion for protecting steel in
aggressive seawater

Soil resistivity

al
ua

tio
n

Soil represents the electrolyte


Soils with low resistivity have high conductivity; i.e. corrosive

Corrosivity

up to 1,000

Severely corrosive

1,000-5,000
5,000-10,000

Ev

Soil resistivity (ohm.cm)

Corrosive

Moderately corrosive
Slightly corrosive

20,000 and above

Non-corrosive

Pr
o

10,000-20,000

PD

Ev

al
ua

tio
n

For Measurement of Soil Resistivity

Pr
o

Power Unit

Kit

PD

Stainless Steel Pins

Cables

PD

Pr
o

Ev

al
ua

tio
n

Test Posts for CP Monitoring

tio
n

Application

PD

Pr
o

Ev

al
ua

Copper / Copper Sulfate

PD

Pr
o

Ev

al
ua

tio
n

Silver / Silver Chloride

PD

Pr
o

Ev

al
ua

tio
n

Avantages of sacrificial and Impressed current

PD

Pr
o

Ev

al
ua

tio
n

Disavantages of sacrificial and Impressed current

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