3 1

2015-2014
2m BAC:

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( 7 )
(E210) C6H5-COOH (E211) C6H5-COONa
. light
m0 V0
S0 C0 pH pH=3,1
-1 )1(.
-2 C0 V0 xq )1( .
-3 C6H5COOH/ C6H5COO-
-3-1 pKA C6H5COOH/ C6H5COO- )1( .KA
-3-2 C6H5COO-C6H5COOH
)1( .S0
+
-3-3 C0 ] [H3O KA )1(.C6H5COOH/ C6H5COO
-4-3 S0 )1( . C0=10-2mol/L :
-7-3 )1( .2-3
6( 1 )
E=10V R=410 D R=100
L . r

-1 1( .)
-2 ) i(t 1
-2-1 r 1( .)
-2-2 r 1( .)
-3 ) (t=0 k ) i(t 2
-3-1 )1( . i(t )

i(t ) A.e 1( . A )

-2-3 ) i(t
-3-3 L 1( . )
6( 2 )
L=0,1H
R C .E
t=0 .2 ( )1 ( )2 u C
.R

-1 1( . )
-2 E 1( . )
-2 :1
-1-2 1( . )
-2-2 T 1( . )
-2-3 T T0 . 1( . C )
-4 R=0 .2 u C
1( . )

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 2015-2014
2m BAC:

3 1
:

( 7 )
-1 .
C6H5COOH+ H2O C6H5COO-+ H3O+
-2 C0 V0 xq .

C6H5COOH + H2O C6H5COO- + H3O+

0
C0V0

0
0

xq
C0V0- xq

xq
xq
-3-1 pKA C6H5COOH/ C6H5COO- pKA=4,2 : KA=10-pKA=6,3.10-5
-3-2 pH<pKA C6H5COO-
-3-3 KA .C6H5COOH/ C6H5COO-
2
+
[H3 O ]q = [C6H5COOO ]q
.[H3 O+ ] q
[C6H5COO ]q .[H3 O+ ]q
{ K A = C [H O+] :

K
=
A
[C6H5COOH]q
[C6H5COOH]q = C0 [H3 O+ ]q
0
3
q
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-4-3 S0 + [H3 O+ ]q :
-7-3 = 0,08 :

] [H3 O+
C0

.[H3 O+ ] q
KA

= C0 C0=10 mol/L
-2

= .1-3

6( 1 )
-1 .

)(
-2-1 : r :i(t)=Imax=cte UL=L +r.i(t)=r.Imax
)Imax=E/(R+r
10
E
r=I r=24.103 410 = 6,67
-2-2 r R .
max

-3 ) (t=0 )i(0)= Imax=E/(R+r

-3-1 ) . i(t :
)(
)(
UL(t)+UR(t)=0 ) UL=L +r.i(t ) UR=R.i(t +.i(t)=0
+

i(t ) A.e

-2-3
t
A t
) i (t
A t

.e :
. .e + A.e =0 + = +

dt

0
: A t=0 )i (0) A.e =A=E/(R+r
-3-3 =4ms L=.(R+r)=4.10-3.(100+6,67)=0,43H
6( 2 )
* 2
* -1 :1
-2 E UC(0)=E=6V
-2 :1
-1-2
-2-2 T T=4ms:
-2-3 T T .
T=2.. = 0,42

(0,004)2
4.2 .0,1

= C=4.02 .

-4 R=0 .2 u C