Professional Documents
Culture Documents
05A,外文
05A,外文
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20042005
1 Multiple Choices ( 15 , 15 )
1 1 (0132)
Cl
NO2
(A)
,
:
+
NaHCO3
Cl
(B)
HO
NO2
Cl
OH
(C)
NO2
(D)
NO2
NO2
OH
OH
2 1 (9305)
OH
OH
A
CH3CH2OH
CH3OH
NO2
D
NO2
3 1 (7629)
NH2
(A)
NH3
(B)
Cl
(C)
NH2
NH2
(D)
4 1 (6791)
pKa
Cl
SO3H
SO3H
SO3H
NH2
SO3H
D
OH
Cl
NO2
5 1 (7729)
:
(A) ,
(B) ,
(C) ,
(D) ,
6 1 (0142)
90 C HNO3, H2SO4 ,:
(A) o-
(B) m-
(C) p-
(D)
71 (9307)
OH
A
CH3
OH
CH2
CH3
CH
OH
C
CH3
CHCH2OH
CH
CH3
CH
CH2
OH
CH
OH
8 1 (7767)
,
CH2
(A) CH3CH2C
(B) CH3CH2CNH2
CH
(C)
OH
9 1 (0602)
Ph3P :
(A)
(B)
(D)
OR
(C)
(D)
10 1 (4080)
, SN
(A ) C H 3 S N a
C H 3C l
(C H 3 )2 S
CH
(B ) C H 3 C H 2 O H
(C )
CH
CH
(D )
(C H 3 )2 C
B r2
C C l4
CH
H 2O
2 +
C H B r2C H B r2
OH
H 3C
+
N aCl
HCN
H 3C
C
2 CN
11 1 (0295)
(I), (II), (III), (IV):
(A) I>II>III>IV (B) II>III>I>IV (C) III>II>I>IV
(D) IV>I>III>II
12 13 1 (7480)
HO N
CH3
CH3 H2SO4
NH2
CH3
NH2
O
C
CH3
D
NH
CH3
14 1 (8051)
?
(A)
(B)
+
N
O
(D)
(C)
15 1 (0226)
(CH3)2C=CH2,?
(A) (CH3)2CHCH2OH
(B) (CH3)3COH
(C) CH3CH2CHCH3
(D) CH3CH2CH2CH2OH
OH
(CH3)2CHNH2
3. O2N
COOH
CH3
C C
CH3
COCH2CH3
COCH2CH3
4.
COOH
5.
HO
6. cyclohexanone oxime
OH
OH
7. 3,5-dimethoxybenzaldehyde
9. ethyl acetoacetate
8, N, N-dimethylformamide
10. aspirin
Br2
2.
CH2CH3
h
Cl2
3.
H
H3 C
N+(CH3)3
H
4.
CH3
O
HN
SO3H
5.
OH-
OH
Cl
Na2Cr2O7
H2SO4
6.
O
_
CHCH2CN
Ph3P+
7.
N
OH
H2SO4
CH3
8.
CH3
CH3C
CHCH3
HBr
CH2
9.
OH
10.
OH
H2SO4
CH3
HCOOOH
11
CH3
Hg(OAc)2 NaBD4
H2O
HO-
12.
CH3CH2C
CH
B 2H 6
THF
H2O2
HO-
13.
H
CO O Et
?
CO O Et
14.
CH2CHBrCH2CH3
15.
Et C
CH
KOH / ROH
(1 ) N a
(2 ) E tB r
(3 ) H 2 /L in d la r
?
5
HBr
ROOR
16.
CH2COCH3
NaOCH3
CH2COOCH3 CH3OH
17.
NaOH
PhCHO + CH3COPh
18.
O
COOCH3
NaOCH3
CH3CH2CH2Br
19.
Br2 , NaOH
CH3CH2CH2CH2CH2CONH2
20.
O
+
HN(C2H5)2
H2/Ni
21
Mg
2 CH3COCH3
H2O
1, Cl2, NaOH
+
2, H3O
PhH
22.
Cl
Cl2
FeCl3
Fe , HCl
CH3CH2COCl
NO2
23.
H3C
COOH
SOCl2
H2
Pd _BaSO4
24.
NBS
CCl4
1) HCHO
+
2) H3O
Mg
ether
25.
Cl
CH2(COOEt)2 NaOH
CHO
26.
CH3
+
CH3CH2N CH2CH2CH2CH3 OH
CH3
?
6
27.
CH2(COOC2H5)2 +
28.
N
H
NO2
CH3ONa / CH3OH
Cl
Cl
29.
O
NH
PhCH2Br
KOH(s)
1,H3O+
2,OH
30.
O
CO2Me
1.NaBH4
+
2.H / H2O
. Show how you would accomplish the following Synthesis in good yields5 20
NHCOCH3
1.
NO2
CH3
CH2
CHCH2
O CCH2CH2CH3
CH3
CH2CH3
3
CH2NH2
4
OH
H3C
5.
O
COOC2H5
COOC2H5
, CH2=CHCH2Br
The following road-map problem centers on the structure and properties of A, a key
intermediate in these reactions. Give structures for compounds A through J. (10 )
OH
H
NaBH4
H+
I
warm gently
(1) J
(2)H3O+
(1) CH3MgI
(2) H3O+
OH
CH2OH
PCC
(excess)
Zn(Hg)
HCl
A C8H12
BC8H18A CC8H14
DC8H14 A-D (5 )
.
AgNO3, H2O/CH3CH2OH
OH
CH2I
2.
CH2(COOEt)2
1, NaOEt
+
2, H3O
10