S GD T THI TH THPT QUC GIA LN 1 NM 2017

TNH PH YN Mn: KHOA HC T NHIN HA HC

THPT PHM VN NG Thi gian lm bi: 50 pht, khng k thi gian pht

( thi c 40 cu / 4 trang)
M : 132
Cho bit nguyn t khi ca cc nguyn t :
H =1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S =32; Cl = 35,5; K = 39; Ca = 40; Cr = 52;
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.

Cu 1: Trong s cc cht sau: xeluloz, saccaroz, frutoz, glucoz. S cht khi thy phn n cng
ch thu c glucoz l:
A. tinh bt xenluloz B. Tinh bt, xenluloz, saccaroz
C. xenluloz, fructoz, saccaroz D. Tinh bt, saccaroz
Cu 2: Pht biu no sau y ng ?
A. Polietilen v poli(vinyl clorua) l sn phm ca phn ng trng ngng.
B. T nilon-6,6 c iu ch t hexametyleniamin v axit axetic.
C. T visco, t xenluloz axetat thuc loi t tng hp.
D. Si bng , t tm l polime thin nhin.
Cu 3: Sobitol l sn phm ca phn ng ?
A. Oxi ha glucoz bng AgNO3 trong ammoniac.
B. Kh glucoz bng H2 ,xt Ni un nng.
C. Ln men ancol etylic.
D. Glucoz tc dng vi Cu(OH) 2.
Cu 4: Tn gi ca ca C2H5NH2 l:
A. etylamin B. imetylamin C. metylamin D. propylamin
Cu 5: tch Ag ra khi hn hp Ag, Cu, Fe m khi lng Ag khng thay i th dng cht no sau
y ?
A. HCl B. HNO3 C. Fe2(SO4)3 D. AgNO3
Cu 6: chng minh glucoz c tnh cht ca andehit, ta cho dung dch glucoz phn ng vi ?
A. Cu(OH)2 nhit thng to dung dch mu xanh lam.
B. Dung dch AgNO3 trong ammoniac.
C. Kim loi Na.
D. Dung dch HCl.
Cu 7: C 3 cht hu c: H2NCH2COOH, C2H5COOH v CH3(CH2)3NH2. nhn bit cc cht trn
dng thuc th l:
A. qu tm B. NaOH C. HCl D. H2SO4
Cu 8: Bit ion Pb2+ trong dung dich oxi ha c Sn. Hai thanh kim loi Pb v Sn c ni vi nhau
bng dy dn in v nhng vo dung dch HCl th cht b n mn in ha l:
A. HCl B. Pb C. Sn D. Pb v Sn
Cu 9: Ming chui xanh tip xc vi dung dch iot cho mu xanh tm v trong ming chui xanh c:
A. glucoz B. mantoz C. tinh bt D. saccaroz
Cu 10: Cng thc ha hc ca cht no l este ?
A. CH3CHO B. HCOOCH3 C. CH3COCH3 D. CH3COOH
Cu 11: to b nhn to (cht bo rn) t du thc vt (cht bo lng) ta cho du thc vt thc hin
phn ng ?
A. ehirro ho B. X phng ho C. Hiro ho D. Oxi ho
Cu 12: Cho hn hp hai axit bo gm axit oleic v axit stearic tc dng vi glixerol. S triglixerit ti
a to thnh l:

http://bloghoahoc.com Chuyn trang thi th Ha Trang 1/5 M thi 132

 A. 3 B. 5 C. 8 D. 6
Cu 13: Kim loi no sau y c cng ln nht trong tt c cc kim loi ?
A. Vonfam B. ng C. St D. Crom
Cu 14: Tnh cht ho hc c trng ca kim loi l:
A. tnh oxi ho B. tnh baz C. tnh kh D. tnh axit
Cu 15: Chn pht biu ng ?
A. Phn ng gia axit cacboxylic v ancol khi c mt ca axit sunfuric c l phn ng mt chiu.
B. Phn ng thu phn metyl axetat trong mi trng axit l phn ng thun nghch.
C. Khi thu phn cht bo lun thu c etilenglicol.
D. Tt c cc este phn ng vi dung dch kim lun thu c sn phm l mui v ancol.
Cu 16: Dy gm cc cht c sp xp theo th t tng dn lc baz t tri sang phi l:
A. phenylamin, etylamin, amoniac B. phenylamin, amoniac, etylamin
C. etylamin, amoniac, phenylamin D. etylamin, phenylamin, amoniac
Cu 17: Cht thuc loi isaccarit l:
A. fructoz B. glucoz C. xenluloz D. saccaroz
Cu 18: Hp cht no sau y thuc loi tripeptit ?
A. H2N-CH2-CO-NH-CH(CH3)-COOH B. H2N-CH2-CO-NH-CH2-CO-NH-CH2-COOH
C. H2N-CH2-CH2-CO-NH-CH2-COOH D. H2N-CH2-CH2-CO-NH-CH2-CH2-COOH
Cu 19: Hn hp X cha ba este mch h, trong phn t ch cha mt loi nhm chc v c to
bi t cc axit cacboxylic c mch khng phn nhnh. t chy ht 0,2 mol X cn dng 0,52 mol O2,
thu c 0,48 mol H2O. un nng 24,96 gam X cn dng 560 ml dung dch NaOH 0,75M thu c
hn hp Y cha cc ancol c tng khi lng l 13,38 gam v hn hp Z gm hai mui, trong c
a gam mui A v b gam mui B (MA < MB). T l gn nht a : b l:
A. 0,6 B. 1,2 C. 0,8 D. 1,4
Cu 20: un nng 0,1 mol hn hp E cha X, Y bng dung dch NaOH (va ). C cn dung dch
sau phn ng thu c m gam mui ca glyxin, alanin v valin. t chy hon ton lng mui ny
thu c 0,2 mol Na2CO3 v hn hp gm CO2, H2O, N2 trong tng khi lng ca CO 2 v H2O
l 65,6 gam. Mt khc t chy 1,51m gam hn hp E cn dng a mol O 2 thu c CO2, H2O v N2.
Gi tr ca a gn nht vi ?
A. 3,0 B. 2,5 C. 3,5 D. 1,5
Cu 21: C by ng nghim ng ring bit trong nm ng nghim (NH4)2SO4, FeCl2, Cr(NO3)3,
K2CO3, Al(NO3)3, K2Cr2O7 v (COONa)2. Cho Ba(OH)2 n d vo by ng nghim trn. Sau khi
cc phn ng kt thc s ng nghim thu c kt ta l:
A. 4 B. 5 C. 6 D. 7
Cu 22: Hp cht hu c n chc X phn t ch cha cc nguyn t C, H, O v khng c kh nng
trng bc. X tc dng va vi 96 gam dung dch KOH 11,66%. Sau phn ng c cn dung dch
thu c 23 gam cht rn Y v 86,6 gam nc. t chy hon ton Y thu c sn phm gm 15,68
lt CO2 (ktc); 7,2 gam nc v mt lng K 2CO3. Cng thc cu to ca X l:
A. CH3COOC6H5. B. HCOOC6H4CH3. C. HCOOC6H5. D. H3C6H4COOH.
Cu 23: t chy hon ton m gam mt cht bo X cn 1,106 mol O2, sinh ra 0,798 mol CO 2 v 0,7
mol H2O. Cho 24,64 gam cht bo X tc dng va vi dung dch cha a mol Br 2. Gi tr ca a l:
A. 0,10. B. 0,12. C. 0,14. D. 0,16.
Cu 24: Tin hnh cc th nghim sau:
(a) Cho Mg vo dung dch Fe 2(SO4)3 d (b) Sc kh Cl2 vo dung dch FeCl 2
(c) Dn kh H2 d qua bt CuO nung nng (d) Cho Na vo dung dch CuSO 4 d
(e) Nhit phn AgNO 3 (f) in phn nng chy Al 2O3
Sau khi kt thc cc phn ng, s th nghin thu c kim loi l:
A. 4 B. 2 C. 3 D. 5
Cu 25: Cho hn hp X gm hai cht hu c, no n chc, mch h (cha C, H, O) tc dng va
vi 20ml dung dch NaOH 2M thu c mt mui v mt ancol. un nng lng ancol thu c vi
axit H2SO4 c 170C thu c 0,015 mol anken (l cht kh iu kin thng). Nu t chy

http://bloghoahoc.com Chuyn trang thi th Ha Trang 2/5 M thi 132

lng X nh trn ri cho sn phm qua bnh ng CaO d th khi lng bnh tng 7,75 gam. Bit
cc phn ng xy ra hon ton. Pht biu no sau y ng ?
A. Khi lng ca cht c phn t khi ln hn trong X l 2,55 gam.
B. Tng phn t khi ca hai cht trong X l 164.
C. Thnh phn phn trm khi lng cc cht trong X l 49,5% v 50,5%.
D. Mt cht trong X c 3 cng thc cu to ph hp vi iu kin bi ton.
Cu 26: Sc 13,44 lt CO2 (ktc) vo 200 ml dung dch X gm Ba(OH)2 1,5M v NaOH 1M. Sau
phn ng thu c dung dch Y. Cho dung dch Y tc dng vi 200 ml dung dch hn hp BaCl 2
1,2M v KOH 1,5M thu c m gam kt ta. Gi tr ca m l:
A. 66,98 B. 39,4 C. 47,28 D. 59,1
Cu 27: Nhn xt no sau y ng ?
A. a s cc polime d ha tan trong cc dung mi thng thng.
B. a s cc polime khng c nhit nng chy xc nh.
C. Cc polime u bn vng di tc ng ca axit, baz.
D. Cc polime d bay hi.
Cu 28: Trong cc cht di y, cht no l amin bc hai ?
A. H2N(CH2)6NH2 B. CH3NHCH3
C. C6H5NH2 D. CH3CH(CH3)NH2
Cu 29: Mt tripeptit X mch h c cu to t 3 amino axit l glyxin, alanin, valin. S cng thc
cu to ca X l:
A. 6 B. 3 C. 4 D. 8
Cu 30: Cacbohidrat no sau y c dng lm nguyn liu sn xut t visco ?
A. Saccaroz B. Tinh bt C. Glucoz D. Xenluloz
Cu 31: Cho 11 gam hn hp X gm hai este n chc, mch h tc dng ht vi 200 gam dung dch
KOH 5,6% un nng, chng ct dung dch sau phn ng thu c Y gm hai ancol ng ng k tip
c cn phn dung dch cn li c m gam cht rn khan. Cho Y vo bnh na d th khi lng bnh
tng 5,35 gam v c 1,68 lt kh thot ra (kc). Bit 16,5 gam X lm mt mu ti a dung dch cha a
gam Br2. Gi tr gn ng ca (m + a) l :
A. 40,7 B. 60,7 C. 56,7 D. 52,7
Cu 32: Cho cc pht biu sau v cacbohidrat :
(a) Glucoz v saccaroz u l cht rn c v ngt, d tan trong nc.
(b) Tinh bt v xenluloz u l polisaccarit.
(c) Trong dung dch glucoz v saccarozo u ha tan Cu(OH) 2 to phc mu xanh lam.
(d) Khi thy phn hon ton hn hp gm tinh bt v saccaroz trong mi trng axit ch thu
c mt loi monosaccarit duy nht.
(e) Khi un nng glucoz vi dung dch AgNO 3/NH3 thu c Ag.
(g) Glucoz v saccaroz u tc dng vi H 2 (xc tc Ni, un nng) to sorbitol.
S pht biu ng l:
A. 3 B. 4 C. 5 D. 6
Cu 33: Tin hnh in phn vi in cc tr v mng ngn xp mt dung dch cha m gam hn hp
CuSO4 v NaCl cho n khi nc bt u b in phn c hai in cc th dng li. anot thu
c 0,896 lt kh (kc). Dung dch sau khi in phn c th ha tan ti a 3,2 gam CuO. Gi tr ca
m l:
A. 11,94 B. 9,60 C. 5,97 . D. 6,40
Cu 34: Ha tan hon ton 25,3 gam hn hp X gm Mg, Al v Zn bng dung dch HNO 3. Sau khi
phn ng kt thc thu c dung dch Y v 4,48 lt (kc) kh Z (gm hai hp cht kh khng mu) c
khi lng 7,4 gam. C cn dung dch Y thu c 122,3 gam hn hp mui. S mol HNO 3 tham
gia phn ng gn nht vi gi tr no sau y ?
A. 1,81 mol B. 1,95 mol C. 1,8 mol. D. 1,91 mol

http://bloghoahoc.com Chuyn trang thi th Ha Trang 3/5 M thi 132

Cu 35: Cho 5,2 gam hn hp gm Al, Mg v Zn tc dng va vi dung dch H 2SO4 10% thu
c dung dch Y v 3,36 lt kh H2 (kc). Khi lng ca dung dch Y l:
A. 152 gam B. 146,7 gam C. 175,2 gam . D. 151,9 gam
Cu 36: Hn hp X cha cht A (C5H16O3N2) v cht B (C4H12O4N2) tc dng vi dung dch NaOH va
, un nng cho n khi phn ng xy ra hon ton ri c cn thu c m gam hn hp Y gm 2 mui
D v E (MD < ME) v 4,48 lt (ktc) hn hp Z gm 2 amin no, n chc, ng ng k tip c t khi so
vi H2 bng 18,3. Khi lng ca mui E trong hn hp Y l:
A. 4,24 B. 3,18 C. 5,36 D. 8,04
Cu 37: Hn hp gm 1,3 mol Mg v x mol Zn vo dung dch cha 2 mol Cu 2+ v 2 mol Ag+ sau phn
ng hon ton, lc b phn dung dch thu c cht rn gm 2 kim loi. Gi tr ca x c th l:
A. 1,8 B. 2 C. 2,2 D. 1,5
Cu 38: in phn 200 ml dung dch CuSO4 0,75M bng in cc tr vi cng dng in khng i
I = 5A, n khi khi lng dung dch gim 13,35 gam th dng in phn. Thi gian in phn l ?
A. 9650 giy B. 7720 giy C. 6755 giy D. 8685 giy
Cu 39: Nh t t n d dung dch Ba(OH) 2 ln lt vo cc dung dch sau: NaHCO 3, AlCl3,
NaHSO4, (NH4)2CO3, FeCl3, Na2SO4 v KNO3. S trng hp thu c kt ta l:
A. 4 B. 6 C. 7 D. 5
Cu 40: X l -amino axit trong phn t cha 1 nhm NH2 v 1 nhm -COOH. Ly 0,01 mol X tc
dng va vi dung dch HCl 0,1M thu c dung dch Y. Cho 400 ml dung dch KOH 0,1M vo
Y, c cn dung dch sau phn ng, thu c 2,995 gam rn khan. Cng thc cu to ca X l.
A. H2N-CH2-CH2-COOH B. (CH3)2-CH-CH(NH2)-COOH
C. H2N-CH2-COOH D. CH3-CH(NH2)2-COOH

----------HT----------

http://bloghoahoc.com Chuyn trang thi th Ha Trang 4/5 M thi 132

 PHN TCH HNG DN GII
THI TH THPT PHM VN NG PH YN LN 1
Cu 1: Chn A.
Cc cacbohirat khi thy phn n cng ch thu c glucoz l: Tinh bt, xenluloz v mantoz.
H 2O
- Thy phn mantoz: C12H22O11 2C6H12O6 (glucoz)
H
H
- Thy phn tinh bt, xenluloz: (C6 H10O5 ) n nH 2O nC6 H12O 6
Cu 2: Chn D.
A. Sai, Polietilen v poli(vinyl clorua) l sn phm ca phn ng trng hp.
B. Sai, T nilon-6,6 c iu ch t hexametyleniamin v axit aipic.
C. Sai, T visco v t xenluloz axetat thuc loi t bn tng hp (hay t nhn to).
D. ng, Si bng v t tm l polime thin nhin.
Cu 3: Chn B.
Ni,t o
- Phn ng kh glucoz: CH2OH[CHOH]4CHO + H2 CH2OH[CHOH]4CH2OH (sobitol)
Cu 4: Chn A.
Tn gi Etylamin imetylamin Metylamin Propylamin
Cng thc cu to C2H5NH2 CH3NHCH3 CH3NH2 CH3CH2CH2NH2
Cu 5: Chn C.
- tch Ag ra khi hn hp gm Ag, Fe v Cu ta dng dung dch Fe2(SO4)3.
Fe2(SO4)3 + Fe 3FeSO4 Cu + Fe2(SO4)3 CuSO4 + 2FeSO4
- Ag khng tan trong dung dch Fe2(SO4)3 nn ta tch ly phn khng tan ra l Ag.
Cu 6: Chn B.
- Phn ng chng minh glucoz c tnh cht ca andehit l phn ng gia glucoz vi dung dch
AgNO3 trong NH3, un nng (thuc th Tollens) cho phn ng trng bc:
to
CH2OH[CHOH]4CHO + 2[Ag(NH3)2]OH CH2OH[CHOH]4COONH4 + 2Ag + 3NH3 + H2O
Cu 7: Chn A.
Cht
H2N-CH2-COOH C2H5COOH CH3(CH2)3NH2
Thuc th
Qu tm Khng i mu Ha . Ha xanh.
Cu 8: Chn C.
- Trong n mn in ha ca cp kim loi Sn-Pb, Sn l kim loi c tnh kh mnh hn ng vai tr l
anot (cc m) v b n mn cn Pb c tnh kh mnh hn ng vai tr l catot (cc dng) v c
bo v; khi Sn b n mn ht th lc Pb s b n mn.
Cu 9: Chn C.
- Trong ming chui xanh c cha tinh bt, khi cho tip xc vi dung dch iot th c mu xanh tm.
Ngc li, i vi ming chui chn th lc tinh bt b thy phn ht khi cho tip xc vi dung
dch iot th khng c hin tng xy ra.
Cu 10: Chn B.
Cng thc cu to CH3CHO HCOOCH3 CH3COCH3 CH3COOH
Thuc loi Anehit Este Xeton Axit cacboxylic
Cu 11: Chn C.
- Trong thnh phn cht bo rn c cha cc gc axit bo no do vy chuyn ha thnh cc cht bo
lng c cha cc gc axit bo khng no th ngi ta dng phn ng ehiro ha. Ngc li, chuyn
ha cht bo lng thnh cht bo rn ngi ta dng phn ng hiro ha.
Cu 12: Chn D.
- Gi A v B ln lt l cc gc ca axit bo: C 17H33COO- v C17H35COO- . C 6 triglixerit ti a
to thnh tng ng vi cc gc axit bo l : AAA ; ABA ; AAB ; BBB ; BAB ; BBA.

http://bloghoahoc.com Chuyn trang thi th Ha Trang 5/5 M thi 132

Cu 13: Chn D.
Cu 14: Chn C.
Cu 15: Chn B.
A. Sai, Phn ng gia axit cacboxylic v ancol khi c mt ca axit sunfuric c l phn ng thun
nghch.
B. ng, Phn ng thu phn metyl axetat trong mi trng axit l phn ng thun nghch.
C. Sai, Khi thu phn cht bo lun thu c glixerol.
D. Sai, Ly v d: HCOOC6H5 + 2NaOH HCOONa + C6H5ONa + H2O
Cu 16: Chn B.
- Dy sp xp tnh baz tng dn l: phenylamin (C 6H5NH2) < amoniac (NH3) < etylamin (C2H5NH2)
Cu 17: Chn D.
Cu 18: Chn B.
Cu 19: Chn D.
- Quy i hn hp X thnh gc hidrocacbon C xHy v nhm COO (CO2). V vy khi t X th s mol
O2 tham gia phn ng chnh bng s mol O 2 t gc C xHy.
- Khi t 0,2 mol X (gi nh t nhm C xHy) th :
BT:O
n CO2 (khi t C x H y ) n O2 0,5n H 2O 0,28 m C x H y 12n CO2 2n H 2O 4,32 (g)
- Cho 24,96 gam X tc dng vi NaOH th
6, 48
n X(trong 24,96g) 0,2. 0,3mol
4,32
n COO n NaOH 0, 42 m C x H y 24,96 44n COO 6, 48
n COO(trong 0,2 mol X) 0, 42 0,28 mol

1,5
+ Ta nhn thy rng nC(trong gc CxHy ) nC(trong nhm -COO) 0,28 , v th s nguyn t C trong gc
CxHy bng s nhm COO trong cc phn t este.
n 0, 42
+ Mc khc : n COO NaOH 1, 4 . T 2 d kin trn ta suy ra c cc este trong X l
nX 0,3
HCOOCH3,(COOCH3 )2 v HCOOCH2CH2OOCH . Khi :
BTKL
68n HCOONa 134n (COONa)2 m X 40n NaOH m ancol 28,38 n HCOONa 0,24 mol



BT:Na
n HCOONa 2n (COONa) 2
n NaOH 0, 42 n (COONa)2 0,09 mol
m 0,24.68
HCOONa 1,353
m (COONa)2 0,09.134
Cu 20: Chn B.
- Qui i 0,1 mol E thnh C2H3ON, -CH2 v H2O.
+ Vi n C 2H3ON 2n Na 2CO3 0,4 mol v n H2O n E 0,1mol
- Cho 0,1 mol E tc dng vi dung dch NaOH thu c hn hp mui ( quy i) gm C2H4O2NNa
(0,4 mol) v CH2. Khi t hon ton lng mui trn th theo d kin bi, ta c :
44nCO2 18n H2O mbnh tng 44(1,5n C2H3ON n CH2 ) 18(2nC2H4O2Na n CH2 ) 65,6(g) n CH2 0,4mol
Suy ra nO2 (tham gia phn ng chy) 2,25n C2H3ON 1,5n CH2 1,5mol
Vy n O2 (khi t 1,51mgam E) =1,51.1,5 = 2,265mol
Cu 21: Chn B.
(1) Ba(OH)2 + (NH4)2SO4
BaSO4 + 2NH3 + 2H2O
(2) Ba(OH)2 + FeCl2
Fe(OH)2 + BaCl2
(3) 4Ba(OH)2(d) + 2Cr(NO3)3
Ba(CrO2)2 + 3Ba(NO3)2 + 4H2O
(4) Ba(OH)2 + K2CO3
BaCO3 + 2KOH

http://bloghoahoc.com Chuyn trang thi th Ha Trang 6/5 M thi 132

 (5) 4Ba(OH)2(d) + 2Al(NO3)3
Ba(AlO2)2 + 3Ba(NO3)2 + 4H2O
(6) 2Ba(OH)2 + K2Cr2O7
2BaCrO4 + 2KOH + H2O
(7) Ba(OH)2 + (COONa)2 Ba(COO)2 + 2NaOH
Vy c 5 ng nghim thu c kt ta l (1), (2), (4), (6) v (7).
Cu 22: Chn A.
86,8 84,8
- Ta c n KOH 0,2 mol v n H 2O(trong dd KOH) 84,8(g) n H 2O(sp p vi KOH) 0,1 mol
18
BTKL
- m X m mui 18n H 2O(sp p vi KOH) 56n KOH 13,6(g)
n C(trong X) n CO2 n K 2CO3 0,8 mol

- Khi t chy hn hp Y th :
n H(trong X) 2n H 2O(t Y) 2n H 2O(sp p vi KOH) n KOH 0,8 mol

m 12n C n H
n O(trong X) X 0,2 mol
16
n
Ta c C :H :O n C :n H :n O 8 : 8 : 2(C 8H8O2 ) mc khc OH 2 X l este c to thnh t
nX
phenol hoc ng ng.
- Theo d kin bi th X khng tham gia phn ng trng bc, vy X l CH 3COOC 6 H 5
Cu 23: Chn C.
- Khi t chy m gam X ta c h phng trnh sau :

BTKL
m X 44n CO 2 18n H 2O 32n O 2 12,32 (g)
n n H 2O
BT:O 2n CO 2 n H 2O 2n O 2 k X CO 2 1 8 3 CO 5 CC
n O(trong X) 0, 014 mol n X
6
- Khi cho 24,64 gam X (tc l 0,028 mol X) tc dng vi dung dch Br 2 th : n Br2 5n X 0,14 mol
Cu 24: Chn C.
- Phng trnh xy ra:
(a) Mg + Fe2(SO4)3 MgSO4 + 2FeSO4 (1) Mg + FeSO4 MgSO4 + Fe (2)
+ Nu cho Mg tc dng vi Fe 3+ d th ch dng li phn ng (1) khi sn phm s khng c kim
loi.
+ Nu cho Mg d tc dng vi Fe 3+ th xy ra c 2 phn ng (1) v (2) khi sn phm thu c c
cha kim loi.
o
t
(b) Cl2 + 2FeCl2
2FeCl3 (c) H2 + CuO Cu + H2O
2NaOH + H2 ; 2NaOH + CuSO 4
(d) 2Na + 2H2O Cu(OH)2 + Na2SO4
to pnc
(e) 2AgNO3 2Ag + 2NO2 + O2 (f) 2Al 2O3
4Al 3O2
Vy c 3 th nghim thu c kim loi l (c), (e), (f).
Cu 25: Chn C.
- Khi t chy X c n CO2 n H2O 44nCO2 18n H2O mbnh tng 44a 18a 7,75 a 0,125mol
- Xt qu trnh X tc dng vi NaOH :
+ Nhn thy rng, n NaOH nanken , trong trong X cha 1 este v 1 axit. Khi dehirat ha ancol th :
n este(A) n anken 0,015mol n axit(B) n X n este 0,025mol
- Gi CA v CB ln lt l s nguyn t C ca este A v axit B (vi C A 3, CB 1)

n A .C A n B .C B n CO2 0,015C A 0,025C B 0,125 C A 5 v C B 2(tha)

Vy (A) l C 5H10O2 v (B) l C 2H 4O2

http://bloghoahoc.com Chuyn trang thi th Ha Trang 7/5 M thi 132

A. Sai, chnh lch khi lng gia A v B l: m 102n A 60n B 0,03(g)
B. Sai, Tng khi lng phn t khi ca A v B l 162.
102n A
C. ng, %m A .100% 50,5 %m B 49,5
102n A 60n B
D. Sai, Este A c 7 ng phn tng ng l: CH 3COO-C3H7 (2 ng phn) ; HCOO-C4H9 (4 ng
phn) ; C2H5COOC2H5 (1 ng phn) v axit B ch c 1 ng phn l CH 3COOH.
Cu 26: Chn D.
- Khi cho 0,6 mol CO2 tc dng vi dung dch X gm 0,3 mol Ba(OH)2 v 0,2 mol NaOH:
n BT: C
V OH n CO2 n OH n CO32 n OH n CO2 0,2 mol n HCO3 n CO2 n CO32 0, 4 mol
2
- Khi cho dung dch Y tc dng vi dung dch cha 0,24 mol BaCl 2 v 0,3 mol KOH th:
HCO3 OH Ba 2
BaCO3 H 2O
0,4 mol 0,3mol 0,54 mol 0,3mol

mBaCO3 0,3.197 59,1(g)

Cu 27: Chn B.
A. Sai, a s cc polime khng tan trong cc dung mi thng thng.
B. ng, Hu ht cc polime khng c nhit nng chy xc nh, nng chy nhit kh rng.
C. Sai, Ly v d nh:

D. Sai, Cc polime khng bay hi.

Cu 28: Chn B.
- Bc ca amin c tnh bng s nguyn t H trong phn t aminoac b thay th bi gc
hidrocacbon do vy ch c CH 3NHCH3 l amin bc 2.
Cu 29: Chn A.
- C 6 cng thc cu to l:
GlyAlaVal, GlyValAla, AlaGlyVal, AlaValGly, ValGlyAla, ValAlaGly.
Cu 30: Chn D.
- T visco c to thnh t phn ng gia xenluloz vi CS 2 v NaOH to thnh mt dung dch
nht gi l visco. Bm dung dch ny qua nhng l rt nh ri ngm trong dung dch H 2SO4 to
thnh t visco.
Cu 31: Chn D.
- Xt hn hp ancol Y :
+ Cho Y tc dng vi Na th : n Y n X 2n H2 0,15mol
mY

BTKL
m Y m bnh tng 2n H 2 5,5(g) M Y 36,66 . Vy trong Y gm CH3OH v C2H5OH
nY
n CH3OH n C 2 H 5OH 2n H 2 n CH 3OH 0,1mol
Vi
32n CH3OH 46n C 2 H 5OH 5,5 n C 2 H 5OH 0,05mol
- Khi cho 11 gam X tc dng vi 0,2 mol KOH th :

http://bloghoahoc.com Chuyn trang thi th Ha Trang 8/5 M thi 132


BTKL
m rn khan m X 56n KOH m Y 16,7(g)
m
- Xt hn hp X ta c : M X X 73,33 . Vy trong X c cha HCOOCH3,
nX
m 60n HCOOCH 3 11 60.0,1
+ Gi B l este cn li c: M B X 100(C 2 H 3COOC 2 H 5 ) .
nB 0,05
Vy hn hp X gm HCOOCH3 (0,1 mol) v C2H3COOC2H5 (0,05 mol)
- Khi cho 16,5 gam X (tc 0,15 mol HCOOCH3 v 0,075 mol C2H3COOC2H5) tc dng vi Br2 th :
n Br2 n HCOOCH3 n C 2 H3COOC 2 H5 0,225mol m Br2 36(g)
Vy m rn khan m Br2 52,7(g)
Cu 32: Chn B.
- C 4 nhn nh ng l (a), (b), (c) (e).
(d) Sai, Khi thy phn tinh bt ch thu c glucoz cn khi thy phn saccaroz th thu c c
glucoz v fructoz.
(g) Sai, Ch c glucoz phn ng vi H2 (Ni. t0) thu c sorbitol, saccaroz th khng tham gia
phn ng hiro ha.
Cu 33: Chn A.
- V dung dch ha tan c CuO nn dung dch sau in phn c cha H + (tc l ti anot nc
in phn). Ta c : n H 2n CuO 0,08mol
Ti catot Ti anot
Cu2+ + 2e Cu 2Cl- Cl2 + 2e
x mol 2x mol x mol 2y mol y mol 2y mol
+
H2O 4H + O2 + 4e
0,08 mol 0,02 mol 0,08 mol

BT:e
2n 2n Cl 2 4n O 2 2x 2y 0,08 x 0,06 mol
Xt hn hp kh ta c: Cu 2
n Cl 2 n kh n O 2 y 0,02 y 0,02 mol
m 160n CuSO4 58,5n NaCl 11,94(g)
Cu 34: Chn D.
n NO n N 2O 0,2 n NO 0,1mol
- Xt hn hp kh Z ta c :
30n NO 44n N 2O 7, 4 n N 2O 0,1mol
n NO3 (trong mui) 3n NO 8n N2O 9n NH 4 1,1 9x
- Ta c: m mui m kim loi 18n NH4 62n NO3 122,3 25,3 18x 62(1,1 9x) x 0,05mol
n HNO3 10n NH4 4n NO 10n N2O 1,9 mol
Cu 35: Chn D.
98n H2SO4 .100
- Ta c: n H2SO4 n H2 0,15mol m dd H2SO4 147(g)
C%
BTKL
m Y m kim loi m dd H 2SO 4 2n H 2 151,9(g)
Cu 36: Chn D.
- Khi cho hn hp X tc dng vi NaOH va th :
t0
(C 2 H 5 NH 3 ) 2 CO3 (A) 2NaOH Na 2CO3 (D) 2C 2H 5 NH 2 2H 2O
t0
(COONH 3CH 3 ) 2 (B) 2NaOH (COONa) 2 (E) CH 3 NH 2 2H 2O
- Xt hn hp kh Z ta c :

http://bloghoahoc.com Chuyn trang thi th Ha Trang 9/5 M thi 132

n C2H5 NH 2 n CH3NH 2 0, 2 n C2H5NH 2 0, 08mol n E 0,5n CH3NH 2 0, 06 mol

45n C2H5 NH 2 31n CH3NH 2 0, 2.18,3.2 n CH3NH 2 0,12 mol m E 0, 06.134 8, 04(g)

Cu 37: Chn D.
- Hn hp kim loi gm Ag v Cu, gi s hn hp gm Mg v Zn tc dng va vi dung dch cha 2
2n Cu2 n Ag 2n Mg
mol Cu2+ v 2 mol Ag+ th : n Zn 1,7 mol (Khng c p n).
2
- Chng t dung dch sau phn ng cha Mg2+, Zn2+ v Cu2+. V vy n Zn 1,7mol
Cu 38: Chn D.
- Qu trnh in phn xy ra nh sau :
Ti catot Ti anot
Cu 2 2e
Cu 4H 4e O2
2H 2 O
H 2 O 2e H 2 2OH
- Theo bi ta c h sau :

BT:e
2n H2 2n Cu2 4n O2 4n O2 2n H2 0,3 n O2 0,1125mol

64n Cu2 2n H2 32n O2 m dd gim
32n O2 2n H2 3,75 n H2 0,075mol
96500n e
- Vy n e 4n O2 0, 45mol t 8685 (s)
I
Hng t duy 2 :
m 80n CuO 13,35 80.0,15
- Ta c n H2O dd gim 0,075mol
18 18
96500n e
- Vy n e 2n CuO 2n H 2O 0, 45mol t 8685(s)
I
Cu 39: Chn D.
- Phng trnh phn ng :
Ba(OH)2 + 2NaHCO3 BaCO3 + Na2CO3 + H2O
4Ba(OH)2 + 2AlCl3
Ba(AlO2)2 + 3BaCl2 + 4H2O
Ba(OH)2 + 2NaHSO4 BaSO4 + Na2SO4 + H2O
Ba(OH)2 + (NH4)2CO3 BaCO3 + 2NH3 + H2O
3Ba(OH)2 + 2FeCl3 3BaCl2 + 2Fe(OH)3
Ba(OH)2 + Na2SO4 BaSO4 + 2NaOH
Ba(OH)2 + KNO3 : khng phn ng
Vy c 5 trng hp thu c kt ta l: NaHCO3, NaHSO4, (NH4)2CO3, FeCl3 v Na2SO4.
Cu 40: Chn C.
- Rn khan gm KOH (d), KCl, NH2RCOOK, vi n KCl n X 0,01mol v n NH2 RCOOK n X 0,01mol

BT:K
n KOH(d) n KOH n KCl n NH 2 RCOOK 0,02 mol
m mui 74,5n KCl 56n KOH(d)
m NH2 RCOOK 113 R l -CH 2 X l NH 2 CH 2 COOH (glyxin)
n NH2 RCOOK

http://bloghoahoc.com Chuyn trang thi th Ha Trang 10/5 M thi 132