WEBSITE LUYN THI S 1 VIT NAM THI TH THPT QUC GIA LN 2

MOON.VN Mn: HA HC
Thi gian lm bi: 90 pht (50 cu trc nghim)

Cu 1. Phenol l hp cht hu c m
A. phn t c cha nhm -OH v vng benzen
B. phn t c cha nhm -OH lin kt trc tip vi nguyn t cacbon ca vng benzen
C. phn t c cha nhm -NH2 lin kt trc tip vi nguyn t cacbon ca vng benzen
D. phn t c cha nhm -OH lin kt trc tip vi nguyn t cacbon ngoi vng benzen
Cu 2. Trong mt chu k, theo chiu in tch ht nhn nguyn t tng dn:
A. Tnh kim loi ca cc nguyn t tng dn.
B. Tnh phi kim ca cc nguyn t gim dn.
C. Ho tr cao nht ca nguyn t i vi oxi tng dn.
D. Ho tr cao nht ca nguyn t phi kim i vi hiro l khng i.
Cu 3. Nhng vt bng nhm hng ngy tip xc vi H2O d nhit cao cng khng
phn ng vi H2O v b mt ca vt c lp mng:
A. Al2O3 rt mng bn chc khng cho H2O v kh thm qua.
B. Al(OH)3 khng tan trong nc ngn cn khng cho Al tip xc vi H2O v kh.
C. Hn hp Al2O3 v Al(OH)3 bo v Al.
D. Al tinh th b th ng vi kh v H2O.
Cu 4. Trong cc pht biu sau :
(1) Theo chiu tng dn in tch ht nhn, cc kim loi kim th (t Be n Ba) c nhit
nng chy gim dn.
(2) Kim loi Cs c dng ch to t bo quang in.
(3) Kim loi Mg c kiu mng tinh th lp phng tm din.
(4) Cc kim loi Na, Ba, Be u tc dng vi nc nhit thng.
(5) Kim loi Mg tc dng vi hi nc nhit cao.
S nhn xt ng l
A. 1 B. 3 C. 4 D. 2
Cu 5. Hp cht X tan trong nc to thnh dung dch khng mu. Dung dch ny to kt
ta vi dung dch BaCl2, khi phn ng vi NaOH to ra kh c mi khai, khi phn ng vi
dung dch HCl to ra kh lm c nc vi trong v lm mt mu dung dch thuc tm. Cht
X l
A. (NH4)2SO3. B. NH4HSO3. C. (NH4)2CO3. D. NH4HCO3.
Cu 6. Hn hp X gm cc cht hu c mch h, n chc c cng cng thc phn t l
C3H4O2. un nng nh 14,4 gam X vi dung dch KOH d n hon ton thu c dung
dch Y (gi s khng c sn phm no thot ra khi dung dch sau phn ng). Trung ha
baz cn d trong dung dch Y bng HNO3, thu c dung dch Z. Cho Z tc dng vi dung
dch AgNO3 d trong NH3 thu c 43,2 gam kt ta. Khi cho 14,4 gam X tc dng Na d
thu c ti a bao nhiu lt H2 ktc ?
A. 2,24 lt B. 1,12 lt C. 3,36 lt D. 4,48 lt
Cu 7. Khng nh no sau y l ng nht khi ni v lin kt ho hc trong phn t ca
cc hp cht hu c?
A. Lin kt ho hc trong phn t ca cc hp cht hu c l lin kt ion.
B. Lin kt ho hc trong phn t ca cc hp cht hu c l lin kt cho nhn.
C. Lin kt ho hc trong phn t ca cc hp cht hu c thng l lin kt cng ho tr.
D. Lin kt ho hc trong phn t ca cc hp cht hu c l lin kt cng ho tr phn cc.
Cu 8. Nhit phn hon ton hn hp gm Fe(NO3)3 v Cu(NO3)2 thu c hn hp kh X
v cht rn Y. Hp th ht X vo nc c dung dch Z, kh hon ton Y bng CO d
c cht rn T. T tan va ht trong dung dch Z ch gm 2 mui tan (to kh NO duy nht).
Thnh phn % v khi lng Fe(NO3)3 trong hn hp u l
A. 39,16% B. 56,28% C. 72,02% D. 63,19%
Cu 9. Cho 13,92 gam hn hp X gm FeO, Fe3O4, Fe2O3 (trong s s mol FeO bng s
mol Fe2O3) tc dng va dung dch H2SO4 long c dung dch X. Sc kh Clo vo
dung dch X n khi phn ng xong c dung dch Y, C cn dung dch Y c m gam
mui khan. Gi tr ca m l
A. 32,15 B. 33,33 C. 35,25 D. 38,66
Cu 10. Cho 13 gam ht km Zn vo mt cc ng dung dch H2SO4 1,5 M (dng d)
nhit thng. Nu gi nguyn cc iu kin khc th khi bin i iu kin no sau y s
khng lm tng tc phn ng?
A. Thay 13 gam ht km bng 13 gam bt km.
B. Thc hin nhit cao hn (khong 50oC).
C. Dng th tch dung dch H2SO4 1,5M gp i ban u.
D. Thay dung dch H2SO4 1,5M bng dung dch H2SO4 3M.
Cu 11. Cho phn ng: NaX(rn) + H2SO4(c) NaHSO4(rn) + HX(kh)
o
t

Cc cht c th iu ch theo phn ng trn l

A. HCl, HBr v HI. B. HF, HCl v HNO3.
C. HF, HCl v HBr. D. HBr, HI v H3PO4.
Cu 12. Cho 0,01 mol mt hp cht ca st (X) tc dng ht vi H2SO4 c nng (d), ch
thot ra 0,112 lt (ktc) kh SO2 (l sn phm kh v kh duy nht). Trong cc cht: Fe3O4,
FeCO3, FeS, Fe(NO3)2, s cht tho mn X l
A. 1 B. 2 C. 3 D. 4
Cu 13. Hn hp kh X gm propen v vinylaxetilen. Cho a mol X tc dng vi lng d
dung dch AgNO3 trong NH3, thu c 15,9 gam kt ta. Mt khc a mol X phn ng ti a
vi 0,35 mol Br2. Gi tr ca a l
A. 0,10 B. 0,15 C. 0,20 D. 0,25
Cu 14. Cho aminoaxit no, mch h, c cng thc CnHmO2N. Mi quan h gia n vi m l
A. m = 2n B. m = 2n + 1 C. m = 2n + 2 D. m = 2n + 3
Cu 15. Thy phn hon ton 7,46 gam pentapeptit mch h X (c to nn t cc -
amino axit c cng thc dng H2NCxHyCOOH) bng dung dch NaOH d, thu c 11,10
gam mui. Mt khc thy phn hon ton 7,46 gam X bng dung dch HCl d, thu c m
gam mui. Gi tr ca m l
A. 8,90 B. 10,75 C. 11,11 D. 12,55
Cu 16. Dung dch X cha 0,1 mol Ba ; 0,2 mol Ca ; 0,3 mol Na+ v a mol HCO3 . un
2+ 2+

dung dch X n cn thu c hn hp mui khan Y. Nung Y n khi lng khng i thu
c m gam cht rn Z. Gi tr ca m l
 A. 35,8. B. 55,6. C. 42,4. D. 83,5.
Cu 17. t chy hon ton 10,33 gam hn hp X gm axit acrylic, axit aipic, axit
propanoic v ancol etylic (trong s mol axit acrylic bng s mol axit propanoic) thu c
hn hp kh v hi Y. Dn Y vo 3,5 lt dung dch Ca(OH)2 0,1M thu c 27 gam kt ta
v nc lc Z. un nng nc lc Z li thu c kt ta. Nu cho 10,33 gam hn hp X
trn tc dng vi 100ml dung dch KOH 1,2M, sau phn ng c cn dung dch th thu c
khi lng cht rn l
A. 10,12 gam B. 12,21 gam C. 12,77 gam D. 13,76 gam
Cu 18. Thy phn hon ton cht X bng dung dch NaOH long un nng, thu c hai
cht hu c Y v Z u c phn ng trng bc. Cht X khng th l
A. Cl - CH = CH - COO - CH =CH2 B. HCOO - CH2CHO
C. HCOO - CH2Cl D. Cl2CH - COO - CH =CH2
Cu 19. tch ring Ag t hn hp kim loi Cu, Fe, Ag m khng lm thay i khi lng
Ag ta c th dng lng d dung dch no sau y ?
A. Fe(NO3)3. B. Cu(NO3)2. C. AgNO3. D. Fe(NO3)2.
Cu 20. Hn hp X gm cc cht c cng s mol Fe3O4, Al2O3, CuO v MgO. Nung nng X
ri dn lung kh H2 d qua thu c hn hp rn Y. Cho Y vo dung dch HCl d thu c
m gam mui v 3,36 lt H2 (ktc). Bit cc phn ng xy ra hon ton. Gi tr ca m l
A. 40,70. B. 42,475. C. 37,15. D. 43,90.
Cu 21. Cht X l mt loi thuc cm c cng thc phn t C9H8O4. Cho 1 mol X phn ng
ht vi dung dch NaOH thu c 1 mol cht Y, 1 mol cht Z v 2 mol H2O. Nung Y vi hn
hp CaO/NaOH thu c parafin n gin nht. Cht Z phn ng vi dung dch H2SO4 long
d thu c hp cht hu c tp chc T khng c kh nng trng gng. C cc pht biu
sau:
(a) Cht X phn ng vi NaOH (t) theo t l mol 1 : 2.
(b) Cht Y c tnh axit mnh hn H2CO3.
(c) Cht Z c cng thc phn t C7H4O4Na2.
(d) Cht T khng tc dng vi CH3COOH nhng c phn ng vi CH3OH (H2SO4 c, to).
S pht biu ng l
A. 1 B. 2 C. 3 D. 4
Cu 22. Nung nng hn hp bt gm a mol Fe v b mol S trong kh tr, hiu sut phn ng
bng 75%, thu c hn hp rn Y. Cho Y vo dung dch HCl d, sau khi cc phn ng xy
ra hon ton, thu c hn hp kh Z c t khi so vi H2 l 5,0. T l a : b l
A. 3 : 1. B. 2 : 1. C. 1 : 2. D. 1 : 3.
Cu 23. Cho Fe vo dung dch hn hp gm AgNO3 v Cu(NO3)2, khi cc phn ng xy ra
hon ton thu c dung dch X (gm hai mui) v cht rn Y (gm hai kim loi). Hai mui
trong X l
A. Fe(NO3)3 v Cu(NO3)2 B. Fe(NO3)2 v AgNO3
C. Fe(NO3)2 v Cu(NO3)2 D. Fe(NO3)3 v AgNO3
Cu 24. Cho Zn ti d vo dung dch gm HCl; 0,05 mol NaNO3 v 0,1 mol KNO3. Sau khi
kt thc cc phn ng thu c dung dch X cha m gam mui; 0,125 mol hn hp kh Y
gm hai kh khng mu, trong c mt kh ha nu trong khng kh. T khi ca Y so vi
H2 l 12,2. Gi tr ca m l
A. 64,05. B. 61,375. C. 57,975. D. 49,775.
 Cu 25. Cho mui X tc dng vi dung dch NaOH va , thu c dung dch cha hai
cht tan. Mt khc cho a gam dung dch mui X tc dng vi a gam dung dch cha
Ca(OH)2, thu c cha n 2a gam dung dch Y. Cng thc ca X l
A. NaHCO3. B. NaHS. C. KHCO3. D. KHS.
Cu 26. Thy phn hon ton 0,1 mol este X bng NaOH, thu c mt mui ca axit
cacboxylic Y v 7,6 gam ancol Z. Cht Y khng c phn ng trng bc, Z ha tan c
Cu(OH)2 to dung dch mu xanh lam. Cng thc cu to ca X l
A. HCOOCH2CH(CH3)OOCH. B. CH3COOCH2CH2CH2OOCCH3.
C. HCOOCH2CH2CH2OOCH. D. CH3COOCH2CH(CH3)OOCCH3.
Cu 27. Axit no sau y khng phi l axit bo ?
A. Axit stearic. B. Axit oleic. C. Axit aipic. D. Axit panmitic.
Cu 28. Cho cc phn ng ha hc:
(a) FeS + 2HCl FeCl2 + H2S.
(b) NaHS + HCl NaCl + H2S.
(c) BaS + H2SO4 BaSO4 + H2S.
(d) K2S + 2HCl 2KCl + H2S.
S phn ng c cng phng trnh ion thu gn vi phn ng: Na2S + H2SO4 Na2SO4 +
H2S l
A. 4 B. 3 C. 2 D. 1
Cu 29. S no di y khng c dng iu ch trong cng nghip hin nay ?
O2 ,t
o
A. P P2O5
H 2O
H3PO4.
O2 ,t
o
O2 (V2O5 ,t )
o
H 2O
B. FeS2 SO2 SO3 H2SO4
H 2 SO4 Ca PO
C. Ca3(PO4)2 H3PO4
3 4 2
Ca(H2PO4)2.
O O2 , H 2O
O2 ( Pt ,t )
NO 2 NO2 HNO3.
o
D. NH3
Cu 30. Cht no di y khng c ngun gc t xenluloz ?
A. Amiloz. B. T visco. C. Si bng. D. T axetat.
Cu 31. Cho hnh v m t th nghim to khi trng t hai dung dch X v Y:

Bit mi dung dch ch cha mt cht tan duy nht. X, Y khng phi cp cht no di y ?
A. NH3 v HCl. B. CH3NH2 v HCl. C. (CH3)3N v HCl. D. Benzen v Cl2.
Cu 32. Amino axit X trong phn t ch cha hai loi nhm chc. Cho 0,1 mol X tc dng
va vi 0,2 mol HCl, thu c 19,1 gam mui. S nguyn t hiro trong phn t X l
 A. 14 B. 12 C. 10 D. 8
Cu 33. Hp cht hu c X c cng thc cu to: OHC-COOH. X th hin tnh oxi ha
trong phn ng vi cht no sau y ?
A. H2 (Ni, to). B. Nc brom. C. AgNO3/NH3, to. D. Cu(OH)2.
Cu 34. Trong cng nghip: X dng iu ch anehit axetic; Y dng iu ch axit axetic
theo phng php hin i; Z dng iu ch phenol. Vy X, Y, Z khng phi l cht no
di y ?
A. metanol B. etilen. C. etanol. D. cumen.
Cu 35. t chy hon ton m gam hn hp gm hai este X, Y l ng phn ca nhau cn
dng 22,4 gam O2, thu c 13,44 lt CO2 (ktc) v 10,8 gam H2O. Mt khc nu cho m
gam hn hp trn tc dng vi dung dch cha 8,42 gam NaOH ri c cn dung dch thu
c sau phn ng th cn li 14,72 gam cht rn khan. Bit gc axit ca Y c s nguyn t
cacbon nhiu hn gc axit ca X. T l mol nX : nY l
A. 3 : 1. B. 3 : 2. C. 2 : 3. D. 1 : 3.
Cu 36. Hn hp X gm 0,2 mol mantoz v 0,3 mol saccaroz. un nng X vi dung dch
HCl mt thi gian thu c dung dch Y. Cho Y phn ng hon ton vi lng d dung dch
AgNO3 trong NH3, thu c 181,44 gam Ag. Mt khc, dung dch Y lm mt mu ti a V
ml dung dch Br2 2M. Gi tr ca V l (bit cc phn ng thu phn mantoz v saccaroz
c cng hiu sut)
A. 588. B. 420. C. 294. D. 300.
Cu 37. Cho cc cht: Al, AlCl3, Al2O3, Al(OH)3, NaAlO2, (NH4)2SO4.Al2(SO4)3.24H2O. S
cht va phn ng vi dung dch NaOH long, va phn ng vi dung dch HCl l
A. 2. B. 3. C. 4. D. 5.
Cu 38. in phn dung dch X cha m gam hn hp CuSO4 v NaCl bng in cc tr,
mng ngn xp. Khi thy c hai in cc u xut hin bt kh th ngng in phn, thu
c dung dch Y v 0,336 lt kh thot ra ti anot. Dung dch Y c th ha tan ti a 1,16
gam Fe3O4. Bit hiu sut in phn 100%, cc kh sinh ra khng tan trong dung dch. Gi
tr ca m l
A. 4,155. B. 4,370. C. 4,585. D. 2,985.
Cu 39. C cc tnh cht sau:
(a) Khng lm i mu qu tm.
(b) lu trong khng kh b ho en.
(c) Tc dng vi nc brom to kt ta.
(d) t tan trong nc lnh nhng tan nhiu trong nc nng.
S tnh cht ng cho c phenol (C6H5OH) v anilin (C6H5NH2) l:
A. 4. B. 3. C. 2. D. 1.
Cu 40. Chia hn hp X gm 2 axit hu c n chc, mch h, l ng ng k tip thnh 3
phn bng nhau.
Phn 1: Tc dng vi dung dch NaHCO3 d, thu c 2,24 lt kh CO2 (ktc).
Phn 2: t chy hon ton thu c 6,272 lt CO2 (ktc).
Phn 3: Tc dng va vi etylen glicol thu c m gam hn hp 3 este khng cha nhm
chc khc.
Gi tr ca m l
A. 9,32. B. 8,47. C. 9,82. D. 8,42.
 Cu 41. Cho m gam bt Fe vo 50 ml dung dch Cu(NO3)2 1M, sau phn ng thu c dung
dch X v 4,88 gam cht rn Y. Cho 4,55 gam bt Zn vo dung dch X, kt thc phn ng
thu c 4,1 gam cht rn Z v dung dch cha mt mui duy nht. Gi tr ca m l
A. 4,48. B. 2,80. C. 5,60. D. 8,40.
Cu 42. Cho hp cht hu c X tc dng vi dung dch AgNO3/NH3 (d) thu c sn
phm Y. Cho Y tc dng vi dung dch HCl hoc dung dch NaOH u sinh ra cht kh v
c. X l
A. CH3CHO. B. (NH4)2CO3. C. C2H2. D. HCOONH4.
Cu 43. Cho hn hp X gm Cu v Fe3O4 vo lng d dung dch H2SO4 long. Kt thc
cc phn ng thu c dung dch Y v cht rn Z. Dy ch gm cc cht m khi cho chng
tc dng ln lt vi dung dch Y th u c phn ng oxi ha - kh xy ra l
A. KMnO4, NaNO3, Fe, Cl2. B. Fe2O3, K2MnO4, K2Cr2O7, HNO3.
C. BaCl2, Mg, SO2, KMnO4. D. NH4NO3, Mg(NO3)2, KCl, Cu.
Cu 44. Cho 1,74 gam hn hp X gm kim loi M (nhm IIA) v Al tc dng ht vi dung
dch HNO3 c nng, d thu c 0,1 mol NO2. Mt khc, cho 2,1 gam M phn ng ht vi
lng d dung dch HCl th th tch kh H2 thu c vt qu 1,12 lt (ktc). Kim loi M l
A. Mg. B. Ba. C. Ca. D. Be.
Cu 45. Cht X l mt baz mnh, c s dng rng ri trong nhiu ngnh cng nghip
nh sn xut clorua vi, vt liu xy dng. Cng thc ca X l
A. KOH. B. NaOH. C. Ca(OH)2. D. Ba(OH)2.
Cu 46. Trong cc cp cht cho di y, cp cht no c th cng tn ti trong mt dung
dch ?
A. Fe(NO3)3 v AgNO3. B. NH3 v AgNO3.
C. Na2ZnO2 v HCl. D. NaHSO4 v NaHCO3.
Cu 47. Trong s cc loi t sau: t tm; t visco; t nilon-6,6; t axetat; t capron; t
enang. Nhng loi t thuc loi t nhn to l
A. T nilon 6,6 v t capron. B. T tm v t enang.
C. T visco v t nilon-6,6. D. T visco v t axetat.
Cu 48. iu kin thng, cht no sau y khng c kh nng phn ng vi dung dch
H2SO4 long ?
A. FeCl3. B. Fe2O3. C. Fe3O4. D. Fe(OH)3.
Cu 49. Dung dch no sau y lm qu tm chuyn mu xanh ?
A. Glyxin. B. Etylamin. C. Anilin. D. Phenylamoni clorua.
Cu 50. Hi ngh ln th 21 Cng c khung ca Lin hp quc v bin i kh hu (gi
tt l COP21) ti Paris (Php) c nh gi l "c hi cui cng cc nh lnh o tm ra
mt gii php hu hiu nhm ngn chn thm ha nng ln ton cu".
Ho cht l nguyn nhn chnh gy nn hin tng nng ln ton cu l
A. CO2 B. NO2 C. CO D. NO

LI GII CHI TIT

Cu 1: B
Hp cht C6H5CH2OH l ancol loi A, D
Hp cht hu c m phn t c cha nhm -NH2 lin kt trc tip vi nguyn t cacbon ca
vng benzen l anlin (C6H5NH2) loi C

p n B.

Cu 2: C
Trong mt chu k, theo chiu tng ca in tch ht nhn th nng lng ion ha, m in
tng dn ng thi bn knh gim dn lm cho kh nng nhng electron gim nn tnh kim
loi gim, kh nng nhn electron tng nn tnh phi kim tng p n A, B sai.

Trong mt chu k, i t tri sang phi, ha tr cao nht ca cc nguyn t i vi oxi tng ln
lt t 1 n 7 p n C ng.

Trong mt chu k,, ha tr vi hiro ca cc phi kim gim t 4 n 1 p n D sai.

Cu 3: A
Do c mng oxit Al2O3 mng, bn nn cc vt lm bng nhm d c tip xc vi nc
nhit cao cng khng

b n mn.

Chn A

Cu 4: D
(1)Sai do nhit nng chy ca cc kim loi kim th khng sp xp mt cch c quy lut
do mng tinh th mi kim loi khc nhau
(2)ng do Cs l kim loi kim mnh nn c dng ch to t bo quang in
(3) Sai do Mg c mng tinh th dng lc phng
(4) Sai do Be khng tc dng vi nc nhit thng
(5) ng do Mg tc dng vi hi nc nhit cao.
=> Chn p n D

Cu 5: A
"to kt ta vi dung dch BaCl2": A, C => (loi c B v D)
"phn ng vi NaOH to ra kh c mi khai": A, C
"phn ng vi dung dch HCl to ra kh lm c nc vi trong v lm mt mu dung dch
thuc tm": A (CO2 khng lm mt mu thuc tm)
=> p n A

Cu 6: B
X gm cc cht hu c mch , c CTPT l C3H4O2

Trong X gm: HCOOCH=CH2 v CH2=CHCOOH

nX = 0,2

HCOOCH=CH2 td vi AgNO3 to 4 mol Ag.

Cu 7: C
Lin kt ho hc trong hp cht hu c thng l lin kt cng ho tr, rt t khi c lin kt
ion Chn C.

Cu 8: C

C th to mui Fe2+ hoc Fe3+ hoc c 2

Vy ch c p n C l tha mn

Cu 9: C
Do s mol FeO v Fe2O3 bng nhau nn ta quy i hn hp v Fe3O4.
Ta c:

Khi lng mui khan thu c khi c cn dung dch:

p n C

Cu 10: C
Nhn xt: tc phn ng tng khi tng din tch tip xc gia 2 cht phn ng (p n A);

tng nhit (p n B); tng nng cc cht( D, cng nh tng kh nng tip xc gia
cc cht).

ch cn C l khng lm thay i tc phn ng (tng V trong TH ny khng c ngha).

Tm li chn p n C.

Cu 11: B
Phng php sunfat khng c dng iu ch HI v HBr do HI v HBr u l cc cht
c tnh kh mnh c kh nng tng tc lun vi H2SO4 c nng hnh thnh I2 hoc Br2

2NaBr + 2H2SO4 c Br2 + NaHSO4 + SO2 + 2H2O

o
t

2NaI + 2H2SO4 c I2 + NaHSO4 + SO2 + 2H2O

o
t

Loi A, C, D

p n B.

Cu 12: A
Gi s electron nhng ca cht X l a

Theo nh lut bo ton electron a.nX =2nSO2 a. 0,01 = 2. 0,005 a = 1

Vy X ch nhng 1 electron, cc cht tha mn gm Fe3O4, FeCO3, Fe(NO3)2

V khi tc dng vi H2SO4 ch sinh ra kh SO2 loi FeCO3( sinh thm CO2), loi Fe(NO3)2
( sinh thm NO)

Vy ch c Fe3O4 tha mn. p n A.

Cu 13: B
Gi s mol ca propen ( CH2=CH-CH3) v vinylaxetilen ( CH2=CH-CCH) ln lt l x , y

Khi tc dng vi AgNO3 trong NH3 thu c kt ta CH2=CH-CCAg : y mol y = 15,9 :

159 = 0,1 mol

Khi tc dng vi Br2 nBr2 = 0,35 = x + 3y x = 0,05 mol

a = 0,1 + 0,05 = 0,15 mol

p n B.

Cu 14: B

V l aminoaxit no, mch h nn: m 3 = 2.(n 1) + 2 2 m = 2n + 1

Chn B

Cu 15: D
Gi s mol ca X l a mol nNaOH = 5a mol v nH2O = b mol

Bo ton khi lng ta c 7,46 + 5a. 40 = 11,1 + 18a a = 0,02

Khi thy phn X bng dung dch HCl nHCl = 5a = 0,1 mol, nH2O = 4a = 0,08 mol

Bo ton khi lng m = 7,46 + 0,1. 36,5 + 0,08. 18 = 12,55 gam. p n D.

Cu 16: C
Ch nung mui Y n khi lng khng i.

Mui Y cha cht rn Z

m= 0,1. 153 + 0,2. 56 + 0,15. 106 = 42,4 gam

p n C.

Cu 17: C
V s mol axit acrylic ( C3H4O2) bng s mol axit propanoic (C3H6O2) nn quy i hn hp X
thnh axit aipic : C6H10O4 ( C6H10O4 = C3H4O2+ C3H6O2): x mol v ancol etylic : y mol

Ta c pt 10,33 = 146x + 46y (1)

Dn sn phm chy 0,35 mol Ca(OH)2 thu c kt ta CaCO3: 0,27 mol , dun nng nc lc
li thu c kt ta hnh thnh ng thi hai sn phm CaCO3: 0,27 mol v Ca(HCO3)2

Bo ton nguyn t Ca nCa(HCO3)2 = 0,35 - 0,27 = 0,08 mol

Bo ton nguyn t C nCO2 = nCaCO3 + 2nCa(HCO3)2 = 0,27 + 2. 0,08 = 0,43 mol

6x + 2y = 0,43 (2)

Gii h cha pt (1) v (2) x= 0,055 v y = 0,05

Khi cho X tc dng vi KOH th ch c axit aipic tham gia phn ng sinh ra mui: KOOC-
[CH2]4-COOK v nc

Thy nKOH = 0,12 > 2nC6H10O4 = 0,11 KOH cn d : 0,01 mol

mcht rn = mKOOC-[CH2]4-COOK + mKOH d = 0,055.222+ 0,01. 56= 12,77 gam.

p n C.

Cu 18: A
Khi Cl nh trc tip vo nhm vinyl -CH=CH2 hoc benzyl -C6H5 th phn ng th xy trong
iu kin t0 cao, p cao v NaOH c

Cl-CH=CH-COO-CH=CH2 + NaOH long Cl-CH=CH-COONa (Y) + CH3CHO (Z) +

H2O

Y khng cha nhm CHO nn khng tham gia phn ng trng bc.

HCOO - CH2CHO + NaOH HCOONa (Y ) + HO-CH2CHO (Z). Y, Z u tham gia

phn ng trng bc loi B

HCOO-CH2Cl + NaOH HCOONa (Y) + HCHO (Z) + NaCl + H2O Y, Z u tham gia
phn ng trng bc loi C
Cl2CH-COO-CH=CH2 + 3NaOH HOC-COONa (Y) + CH3CHO(Z) + 2NaCl + H2O
Y, Z u tham gia phn ng trng bc loi D.

p n A.

Cu 19: A
tch ring Ag t hn hp Ag, Cu, Fe m khng thay i khi lng Ag th mui cn dng
tha mn: khng phn ng vi Ag v phn ng vi Cu, Fe khng to Ag hay kim loi no
khc

Vy p n A l tha mn

+ B loi v cn d Cu trong hn hp

+ C loi v to Ag nn lng Ag thay i

+ D loi v cn d Cu, Fe trong hn hp

Cu 20: C

Cu 21: A
Nung Y vi CaO/NaOH thu ng parafin n gin nht tc CH4, X c 4 Oxi nn X l
CH3COO- hoc -OOC-CH2-COO-

+ X -OOC-CH2-COO-. thu c 2 nc v 1 mol cht Z, X l HOOC-CH2-COO-C6H5 -

> Z l C6H5ONa -> T l phenol -> Loi

+ X: CH3COO- th Y l CH3COONa. thu c 2 nc v 1 mol Z, ph hp vi bt

bo ha xa X, ta c th suy ra trong X c vng benzen nh vi nhm COO-. CT ph hp
ca X: CH3COO-C6H4-COOH hoc CH3COO-C6H3(OH)-CHO nhng v T k c phn ng
trng gng nn X l CH3COO-C6H4-COOH. Z l NaO-C6H4-COONa, T l HO-C6H4-
COOH tha mn

a sai t l 1:3
b sai v Y tnh bazo

c sai C7H4O3Na2

d ng

-> A

Cu 22: A

Z gm

Coi

Suy ra H tnh theo S. Khi

Cu 23: C
Y gm 2 kim loi l Ag v Cu

Nn trong X khng c mui

Cu 24: A
Kh k mu ha nu trong kk l NO. V t khi ca 2 kh l 24,4 nn c 1 kh l H2

V to kh H2 nn NO3- phn ng ht
Cu 25: C
A loi v X tc dung vi NaOH va cho 1 cht tan Na2CO3

+ B loi v tc dng vi NaOH va cho 1 cht tan Na2S

+ C tha mn v 2 cht tan l Na2CO3 v K2CO3, khi tc dng vi Ca(OH)2 to kt ta nn

klg dung dch gim

+ D sai v khi tc dng vi Ca(OH)2, klg dung dch Y l 2a g (k to kt ta hay kh)

Cu 26: D
Z ha tan dung Cu(OH)2 -> a chc c 2 nhm OH lin k -> Loi B

Y k c phn ng trng bc -> Loi A, C

Vy p n l D

Cu 27: C
Axit bo: axit panmitic C15H31COOH, axit stearic C17H35COOH, axit oleic
C17H33COOH, axit linoleic C17H31COOH, ... l axit c t 12-24C, mch k phn nhnh, s
C chn, v c 1 chc COOH

Axit adipic HOOC-(CH2)4-COOH khng phi axit bo

Cu 28: D
Pt rt gn

(a) sai v

B sai v

C sai v

D ng

Vy p n l D c 1 pt tha mn

Cu 29: B
A, C, D u ng

B sai v khng hp th SO3 vo nc m dng H2SO4 c

Cu 30: A
Amilozo l 1 loi tinh bt

B, C, D ng

-> A

Cu 31: D
A, B, C tha mn, tng t th nghim bc khi ca NH3 vi HCl to NH4Cl

D sai v benzen t bay hi, mun c phn ng phi trn 2 cht li vi nhau

Cu 32: C
0,1 mol X tc dung vi 2 mol HCl -> c 2 chc amino

Cu 33: A
Th hin tnh oxh khi phn ng vi cht kh

A tha mn

B th hin tnh kh

C th hin tnh kh

D khng th hin tnh kh hay oxh

Cu 34: C
Cu 35: A
este no, n chc mch h

Dng tng gim khi lng c (68 40)a + (82 40)b = 14,72 8,42 = 6,3

Cu 36: D
nAg = 1,68

Gi hiu sut thy phn l H

1 mol glucozo, fructozo, mantozo + AgNO3/NH3 -> 2 mol Ag

1 mol glucozo, mantozo tc dng va vi 1 mol Br2

Cu 37: B
Cc cht va phn ng vi NaOH va phn ng vi HCl l

Cu 38: C

Cu 39: C
(1) ng

(2) Sai, ch c alinin mi c tnh cht ny

(3) ng

(4) Sai, ch c phenol mi c tnh cht ny

-> C

Cu 40: D
Axit

Cu 41: A

Kt thc phn ng ch c 1 mui l

Bo ton kim loi c

Cu 42: D
A sai v Y l CH3COONH4, phn ng vi HCl khng ra kh

B sai v X khng phi cht hu c

C sai v Y l Ag2C2 khng tc dng vi NaOH

D ng v Y l (NH4)2CO3

Cu 43: A
Rn Z l Cu d (do axit d nn Fe3O4 ha tan ht). Vy Y gm

A ng

B sai v Fe2O3 khng tha mn

C sai v BaCl2 khng tha mn

D sai do Cu khng tha mn

Cu 44: C
Cu 45: C
Sn xut clorua vi th phi dng Ca(OH)2 v Cl2

X l 1 bazo nn X l Ca(OH)2

Ca(OH)2 c ng dng lm nguyn liu cho sn xut vt liu xy dng, cht ty trng, st
trng (clorua vi)

p n C

Cu 46: A
A ng

B sai v to phc gia Ag+ v NH3

C sai v phn ng to kt ta Zn(OH)2

D sai v phn ng to kh CO2

Cu 47: D
T t nhin: t tm

T nhn to: t visco, t axetat

T tng hp: nilon-6,6, c capron, t enang

p n D

Cu 48: A
Fe2O3 + 3H2SO4 Fe2(SO4)3 + 3H2O

Fe3O4 + 4H2SO4 Fe2(SO4)3 + FeSO4 + 4H2O

2Fe(OH)3 + 3H2SO4 Fe2(SO4)3 + 6H2O

FeCl3 + H2SO4 : khng phn ng

p n A.
Cu 49: B
Glyxin: H2N-CH2-COOH c s nhm NH2 bng s nhm COOH khng lm i mu qu tm

Etyamin: C2H5NH2 lm qu tm chuyn thnh mu xanh

Anilin: C6H5 NH2 khng lm i mu qu

Phenylamoni clorua: C6H5NH3Cl : lm qu chuyn

p n B.

Cu 50: A
S nng ln ton cu c gy ra bi s tng hiu ng nh knh. Nguyn nhn chnh gy ra
hiu ng nh knh l kh CO2.

Kh CO2 hp th rt tt cc tia hng ngoi. Phn ln nng lng nhit thot ra khi Tri t l
dng tia hng ngoi, nn s tng qu mc CO2 lm tng nng nhit lng c hp thu v
t lm tng nhit trung bnh ca Tri t.

p n A.