Lm quen vi THPT QG 2016 mn Ho - 04

Cu 1. in phn dung dch hn hp CuSO4 v KCl n khi thy bt kh u xut hin hai
in cc tr th ngt dng in. Thy anot c 448 ml kh ( ktc) thot ra v dung dch sau
in phn c th ha tan ti a 0,8 gam MgO. Khi lng dung dch sau in phn gim (coi
nh H2O bay hi khng ng k):
A. 2,25 gam
B. 2,57 gam
C. 2,79 gam
D. 2,95 gam

Cu 2. Pht biu khng ng l

A. Trong dung dch, H2NCH2COOH cn tn ti dng ion lng cc H3N+CH2COO-
B. Amino axit l hp cht hu c tp chc,phn t cha ng thi nhm amino v nhm
cacboxyl.
C. Amino axit l nhng cht rn, kt tinh, tan tt trong nc v c v ngt.
D. Hp cht H2NCH2COOH3NCH3 l este ca glyxin (Gly).

Cu 3. Ha tan hon ton 20 gam hn hp X gm MgO, CuO v Fe2O3 phi dng va ht

350 ml dung dch HCl 2M. Mt khc nu ly 0,4 mol hn hp X t nng trong ng s
(khng c khng kh) ri thi 1 lung H2 d i qua phn ng xy ra hon ton th thu
c m gam cht rn v 7,2 gam nc. Gi tr ca m l
A. 24,8 gam
B. 25,6 gam
C. 32 gam
D. 28,4 gam

Cu 4. S ng phn amin bc 1, mch thng c cng thc phn t C5H13N l

A. 1
B. 2
C. 3
D. 4

Cu 5. Nhng vt bng nhm hng ngy tip xc vi H2O d nhit cao cng khng
phn ng vi H2O v b mt ca vt c lp mng:
A. Al2O3 rt mng bn chc khng cho H2O v kh thm qua.
B. Al(OH)3 khng tan trong nc ngn cn khng cho Al tip xc vi H2O v kh.
C. Hn hp Al2O3 v Al(OH)3 bo v Al.
D. Al tinh th b th ng vi kh v H2O.

Cu 6. in phn nng chy m kg Al2O3 vi anot bng than ch thu c 358,4 m3 (ktc)
hn hp kh X gm CO, CO2 v O2 d trong th tch O2 nhiu gp i th tch CO. Cho
hn hp kh X vo mt bnh kn ri bt tia la in t chy hon ton hn hp th thy
th tch kh trong bnh gim i 44,8 m3 (th tch kh o cng nhit v p sut). Gi tr
ca m l
A. 952.
B. 544.
C. 816.
D. 986.

Cu 7. Phn ng no di y vit khng ng?

A. Cl2 + Ca(OH)2 CaOCl2 + H2O
o
t C

B. 2KClO3 2KCl + 3O2

o
t C

C. Cl2 + 2KOH KCl + KClO + H2O

D. 3Cl2 + 6KOH long
5KCl + KClO3 + 3H2O

Cu 8. Trn 3 dung dch H2SO4 0,1M; HCl 0,2M; HNO3 0,3M vi th tch bng nhau c
dung dch X. Cho 300 ml dung dch X tc dng vi V lt dung dch Y cha NaOH 0,2M v
Ba(OH)2 0,1M c dung dch Z c pH = 1. Gi tr ca V l
A. 0,06
B. 0,08
C. 0,30
D. 0,36

Cu 9. C 100 ml dung dch X gm: NH4+, K+, CO32, SO42. Chia dung dch X lm 2 phn
bng nhau:
Phn 1 cho tc dng vi dung dch Ba(OH)2 d thu c 6,72 lt (ktc) kh NH3 v 43 gam
kt ta.
Phn 2 tc dng vi lng d dung dch HCl th thu c 2,24 lt (ktc) kh CO2.
C cn dung dch X thu c m gam mui khan. Gi tr ca m l
A. 24,9.
B. 44,4.
C. 49,8.
D. 34,2.

Cu 10. C 4 dung dch ring bit l HCl, CuCl2, FeCl3, HCl c ln CuCl2. Nhng vo mi
dung dch mt thanh st nguyn cht. S trng hp xut hin n mn in ho l
A. 3.
B. 2.
C. 5.
D. 1.

Cu 11. Trong nc t nhin, hiro ch yu tn ti 2 ng v 1H v 2H. Bit nguyn t khi

trung bnh ca hiro trong nc nguyn cht bng 1,008. Thnh phn % v khi lng ca
ng v 2H c trong 1,000 gam nc nguyn cht l (cho: O = 16)
A. 0,178%
B. 17,762%
C. 0,089%
D. 11,012%

Cu 12. Cho cc cht sau CO, CO2, SO2, NO, NO2, Cl2, SiO2, Cl2O. Ln lt dn chng qua
dung dch Ba(OH)2 trong iu kin thch hp th c bao nhiu cht xy ra phn ng v c
bao nhiu phn ng oxi ho kh ?
A. 4 phn ng v 2 phn ng oxi ha kh
B. 6 phn ng v 2 phn ng oxi ha kh
C. 6 phn ng v 3 phn ng oxi ha kh
D. 5 phn ng v 2 phn ng oxi ho kh

Cu 13. Cho cc pht biu sau:

(1) Phenol, axit axetic, CO2 u phn ng c vi NaOH.
(2) Phenol, ancol etylic khng phn ng vi NaHCO3.
(3) CO2 v axit axetic phn ng c vi dd natri phenolat v dd natri etylat.
(4) Phenol, ancol etylic v CO2 khng phn ng vi dd natri axetat.
(5) HCl phn ng vi dd natri axetat, natri etylat.
S pht biu ng l
A. 2
B. 3
C. 4
D. 5

Cu 14. tch Ag ra khi hn hp Ag, Pb, Fe m khng lm thay i khi lng Ag ta c

th dng mt dung dch cha mt cht tan l
A. HNO3
B. H2SO4
C. FeCl3
D. Fe(NO3)3

Cu 15. Cho m gam hn hp X gm HCOOCH=CH2; CH3COOH; OHC-CH2-CHO phn

ng vi lng d Cu(OH)2 trong NaOH un nng, thu c ti a 36 gam kt ta gch.
Mt khc, nu cho m gam X tc dng vi Na d thu c 0,28 lt kh H2. Gi tr ca m l
A. 10,5.
B. 15,0.
C. 15,9.
D. 19,5.

Cu 16. Hp cht hu c X c cng thc n gin nht l: CH2O. X c phn ng trng bc

v ho tan c Cu(OH)2 cho dung dch mu xanh lam. X l cht no cho di y ?
A. Tinh bt
B. Xenluloz
C. Saccaroz
D. Glucoz

Cu 17. Hp cht hu c X tc dng c vi dung dch NaOH v dung dch nc brom

nhng khng tc dng vi dung dch NaHCO3. X khng phi l cht no di y ?
A. triolein.
B. amoni fomat.
C. phenol
D. phenylamoni clorua.

Cu 18. Trong cc pht biu sau:

(1) Theo chiu tng dn in tch ht nhn, cc kim loi kim th (t Be n Ba) c nhit
nng chy gim dn.
(2) Kim loi Cs c dng ch to t bo quang in.
(3) Kim loi Mg c kiu mng tinh th lp phng tm din.
(4) Cc kim loi Na, Ba, Be u tc dng vi nc nhit thng.
(5) Kim loi Mg tc dng vi hi nc nhit cao.
S pht biu ng l
A. 1
B. 2
C. 3
D. 4

Cu 19. Pht biu no sau y l khng ng ?

A. Trng hp stiren thu c poli(phenol-fomanehit).
B. T visco l t bn tng hp (nhn to).
C. Thy tinh hu c c to thnh t phn ng trng hp metyl metacrylat.
D. Trng hp buta-1,3-ien vi acrilonitrin c xc tc Na c cao su buna-N.

Cu 20. Nung 40,8 gam rn gm (C, Fe, FeO, Fe2O3, Fe3O4 trong cc oxit st v Fe c
mol bng nhau) ti phn ng hon ton thu c hn hp rn (FexOy, Fe) v 0,15 mol kh.
Ha tan cht rn mi cn ti a a mol HNO3 (sn phm kh ch c NO). Gi tr ca a l
A. 1,3
B. 2,6
C. 1,8
D. 1,9

Cu 21. Khi cho cht bo X phn ng vi dung dch brom th 1 mol X phn ng ti a vi 4
mol Br2. t chy hon ton a mol X thu c b mol H2O v V lt CO2 (ktc). Biu thc
lin h gia V vi a, b l
A. V = 22,4(b + 4a).
B. V = 22,4 (b + 5a).
C. V = 22,4(b + 6a).
D. V = 22,4(b + 7a)
Cu 22. Cho 27,6 gam hp cht thm X c cng thc C7H6O3 tc dng vi 800 ml dung
dch NaOH 1M thu c dung dch Y. trung ha ton b Y cn 100 ml dung dch H2SO4
1M thu c dung dch Z. Khi lng cht rn khan thu c khi c cn dung dch Z l
A. 44,4 gam.
B. 52,4 gam.
C. 58,6 gam.
D. 56,8 gam.

Cu 23. Thy phn 445,05 gam peptit Val-Gly-Gly-Val-Gly thu c hn hp X gm 127,5

gam Gly; 163,8 gam Val; 39,6 gam Gly-Gly; 87 gam Val-Gly; 23,1 gam Gly-Val-Gly v m
gam mt pentapeptit X1. Gi tr ca m l
A. 77,400.
B. 4,050.
C. 58,050.
D. 22,059.

Cu 24. Th tch H2 (ktc) thu c khi cho 150 ml ancol etylic 82o tc dng vi Na d l
(bit khi lng ring ca C2H5OH bng 0,8 g/ml)
A. 40,76 lt
B. 47,92 lt
C. 23,96 lt
D. 16,8 lt

Cu 25. Trong cc cht sau: Na (1); C2H5OH (2); Cu(OH)2 (3); H2 (4); dung dch
AgNO3/NH3 (5); O2 (6); dung dch NaOH (7); Na2CO3 (8); (CH3CO)2O (9). S cht c phn
ng vi glucoz l
A. 5.
B. 7.
C. 4.
D. 6.

Cu 26. Hn hp A gm C3H4 v H2. Cho A i qua ng ng bt Ni nung nng thu c

hn hp B ch gm 3 hirocacbon c t khi so vi H2 l 21,5. T khi ca A so vi H2 l
A. 10,4
B. 9,2
C. 7,2
D. 8,6

Cu 27. un m gam hn hp X gm saccaroz v glucoz (khi lng saccaroz gp 2 ln

khi lng glucoz) vi dung dch H2SO4 long, khi phn ng kt thc em trung ha, sau
thc hin phn ng trng bc thu c 64,8 gam Ag. Gi tr ca m l
A. 56,095.
B. 90,615.
C. 52,169.
D. 49,015.

Cu 28. Cho 0,01 mol aminoaxit X tc dng va ht vi 80 ml dung dch HCl 0,125M. Ly
ton b sn phm cho tc dng vi dung dch NaOH 1M th th tch dung dch NaOH cn
dng l 30 ml. C cn dung dch sau phn ng thu c 2,495 gam cht rn. Tn gi ca X
l
A. axit glutamic
B. lysin
C. tyrosin
D. valin

Cu 29. Trng hp no sau y c coi l mi trng cha b nhim ?

A. Nc trong rung la c cha khong 1% thuc tr su v phn bn ha hc.
B. Nc thi t cc bnh vin, trm x, khu v sinh cha cc khun gy bnh.
C. Khng kh cha 78% N2, 21% O2, 1% CO2, H2O, H2.
D. Trong t cha cc c t nh asen, st, ch,... qu mc cho php.

Cu 30. Hn hp X gm Al, Fe2O3, Fe3O4, CuO trong oxi chim 25,39% khi lng hn
hp. Cho m gam hn hp X tc dng vi 8,96 lt CO (ktc) sau 1 thi gian thu c cht rn
Y v hn hp kh Z c t khi so vi hiro l 19. Cho cht rn Y tc dng vi dung dch
HNO3 long d thu c dung dch T v 7,168 lt NO (ktc, sn phm kh duy nht). C
cn dung dch T thu c 3,456m gam mui khan. Gi tr m gn gi tr no nht sau y ?
A. 35,2
B. 38,4
C. 40,0
D. 41,1

Cu 31. Cu hnh electron trng thi c bn ca nguyn t nguyn t X c tng s

electron trong cc phn lp s l 7. X khng phi nguyn t no di y ?
A. K (Z = 19)
B. Cr (Z = 24)
C. Sc (Z = 21)
D. Cu (Z = 29)

Cu 32. Hn hp X gm propan-1-ol v 2-hiroxietanal. Cho mt lng X phn ng va

vi Na, thu c 0,448 lt kh H2 (ktc) v m gam cht rn Y. Gi tr ca m l
A. 3,28
B. 2,40
C. 2,36
D. 3,32

Cu 33. Cho l Zn vo dung dch HCl, c kh thot ra. Thm vi git dung dch CuSO4 vo
th
A. Phn ng ngng li.
B. Tc thot kh khng i.
C. Tc thot kh gim.
D. Tc thot kh tng.

Cu 34. Nh t t n d dung dch NaOH long vo mi dung dch sau: Fe2(SO4)3, ZnSO4,
Ca(HCO3)2, AlCl3, Cu(NO3)2, Ba(HS)2. Sau khi cc phn ng xy ra hon ton, s trng
hp thu c kt ta l
A. 4.
B. 6.
C. 3.
D. 5.

Cu 35. Cho hn hp kim loi gm x mol Na v y mol Ba vo nc d c V lt H2 (o

iu kin tiu chun) v dung dch X. Khi cho CO2 hp th t t n d vo dung dch X, kt
qu th nghim c biu din trn th sau:

T l x : y l
A. 2 : 1
B. 1 : 3
C. 1 : 1
D. 1 : 2.

Cu 36. t chy hon ton 0,1 mol mt peptit X (X c to thnh t cc amino axit ch
cha 1 nhm -NH2 v 1 nhm -COOH) cn 58,8 lt O2 (ktc) thu c 2,2 mol CO2 v 1,85
mol H2O. Nu cho 0,1 mol X thu phn hon ton trong 500ml dung dch NaOH 2M thu
c m gam cht rn. S lin kt peptit trong X v gi tr m ln lt l
A. 8 v 92,9 gam.
B. 8 v 96,9 gam.
C. 9 v 92,9 gam.
D. 9 v 96,9 gam.

Cu 37. Cho hnh v m t th nghim iu ch kh Cl2 t MnO2 v dung dch HCl:

Kh Cl2 i ra thng ln hi nc v hiro clorua. thu c kh Cl2 kh th bnh (1) v
bnh (2) ln lt ng
A. Dung dch NaOH v dung dch H2SO4 c.
B. Dung dch H2SO4 c v dung dch NaCl.
C. Dung dch H2SO4 c v dung dch AgNO3
D. Dung dch NaCl v dung dch H2SO4 c.

Cu 38. C cc dung dch sau: Phenylamoni clorua, axit aminoaxetic, ancol benzylic, metyl
axetat, anilin, valin, etylamin, natri axetat, metylamin, alanin, axit glutamic, natri phenolat,
lysin. S cht c kh nng lm i mu qu tm l
A. 5.
B. 6.
C. 8.
D. 7.

Cu 39. Mnh no sau y khng ng ?

A. Kh nng oxi ho ca cc halogen gim t flo n iot.
B. Trong cc hp cht, cc halogen u c th c s oxi ho: -1, +1, +3, +5, +7.
C. Halogen l nhng cht oxi ho mnh.
D. Cc halogen c nhiu im ging nhau v tnh cht ho hc.

Cu 40. Cho 9,55 gam hn hp gm Mg, Al v Zn tc dng va vi 870 ml dung dch

HNO3 1M, thu c dung dch cha m gam mui v 0,06 mol hn hp kh X gm N2 v
N2O, t khi ca X so vi H2 bng 20,667. Gi tr ca m gn nht vi
A. 55,0
B. 54,5
C. 55,5
D. 54,0

Cu 41. Hp cht khng ha tan c Cu(OH)2 l

A. propan-1,3-iol.
B. propan-1,2-iol.
C. glixerol.
D. etylen glicol.

Cu 42. Mt hp cht hu c X mch h cha (C, H, O) c khi lng phn t l 60u. X tc

dng vi Na gii phng H2. S cht tho mn X l
A. 4.
B. 5.
C. 2.
D. 3.

Cu 43. Ha tan hon ton m gam hn hp gm Ba v Al2O3 vo nc thu c dung dch

X v 0,2 mol H2. Sc kh CO2 ti d vo X, xut hin 11,7 gam kt ta. Gi tr ca m l
A. 37,60.
B. 21,35.
C. 42,70.
D. 35,05.

Cu 44. Cho 16,5 gam cht X c CTPT l C2H10O3N2 vo 200 gam dung dch NaOH 8%.
Sau khi cc phn ng xy ra hon ton thu c dung dch Y v hn hp kh Z. Tng nng
% cc cht c trong Y gn nht vi gi tr no sau y ?
A. 7,6%
B. 7,3%
C. 9,5%
D. 9,2%

Cu 45. Cho cc phn ng:

(1) Zn + HCl
(2) MnO2 + HCl (c)
(3) Fe + H2SO4 (long)
(4) Fe2O3 + HNO3
(5) C + H2SO4 (c)
(6) FeO + HCl
S phn ng trong axit ng vai tr cht oxi ha l
A. 3
B. 5
C. 4
D. 2

2 NH3 (k) ; H < 0.
Cu 46. Cho cn bng ha hc sau: N2 (k) + 3 H2 (k)

Pht biu no sau y ng ?
A. Thm mt t bt Fe (cht xc tc) vo bnh phn ng, cn bng chuyn dch theo chiu
thun.
B. Gim th tch bnh cha, cn bng chuyn dch sang chiu thun.
C. Tng nhit , cn bng chuyn dch sang chiu thun.
D. Thm mt t HCl vo bnh phn ng, cn bng khng chuyn dch.

Cu 47. Cho hn hp X gm Fe2O3 v ZnO, Cu tc dng vi dung dch HCl (d) thu c
dung dch Y v phn khng tan Z. Cho Y tc dng vi dung dch NaOH (long, d) thu
c kt ta gm:
A. Fe(OH)2 v Cu(OH)2
B. Fe(OH)2; Cu(OH)2 v Zn(OH)2
C. Fe(OH)3
D. Fe(OH)3 v Zn(OH)2

Cu 48. Chn phng n ng trong s cc phng n sau:

A. Oxi ha ancol no, n chc thu c anehit.
B. Mt mol anehit n chc phn ng trng gng to ra ti a hai mol Ag.
C. un cc ancol thuc dy ng ng ca ancol etylic vi H2SO4 c 170oC u thu c
anken.
D. Phenol tc dng c vi dd NaOH nhng khng tc dng vi dd NaHCO3.

Cu 49. Cho cht axetilen (C2H2) v benzen (C6H6). Chn nhn xt ng trong cc nhn xt
sau:
A. Hai cht ging nhau v cng thc phn t v khc nhau v cng thc n gin nht.
B. Hai cht khc nhau v cng thc phn t v ging nhau v cng thc n gin nht.
C. Hai cht khc nhau v cng thc phn t v khc nhau v cng thc n gin nht.
D. Hai cht c cng cng thc phn t v cng cng thc n gin nht.

Cu 50. Khi cn ng v, Napoleon III (1808 - 1873) ny ra mt thch k qui l cn

phi c mt chic vng min lm bng kim loi cn qu hn c vng vi ngc. Vi s gip
ca cc nh ha hc Php lc , nguyn t ny c tm ra. l nguyn t no sau
y ?
A. Al
B. Cu
C. Ag
D. Au
P N & LI GII CHI TIT

Cu 1: D
V dung dch sau in phn ha tan c MgO nn c H2SO4, do nc b in phn
anot

Chn D

Cu 2: D
Ta thy, A, B, C u ng.
D sai do H2NCH2COOH3NCH3 l mui ch khng phi este.
=> p n D

Cu 3: B

Cu 4: C
Cc ng phn amin bc 1, mch thng c cng thc phn t C5H13N l:

=> Chn p n C
Cu 5: A
Do c mng oxit Al2O3 mng, bn nn cc vt lm bng nhm d c tip xc vi nc
nhit cao cng khng b n mn.

Chn A

Cu 6: A
Th tch kh gim chnh l th tch O2 phn ng (do th tch O2 nhiu hn CO nn CO phn
ng ht)

S mol nguyn t Oxi c trong Al2O3 l nO = 4 + 2.8 + 4.2 = 28

=> p n A

Cu 7: D
D sai v thiu nhit , nu nhit thng th n s ra phn ng C

Chn D

Cu 8: B
bi c ngha l trn 100 ml mi dung dch trn vo nhau...
Ta c nH+ = 0,1.(0,1.2 + 0,2 + 0,3) = 0,07
nOH- = 0,4V
pH =1 -> H+ d
nH 0,1(0,3 V )
du

=> 0,07 0,4V = 0,1(0,3 + V) V = 0,08

=> p n B

LI GII KHC:
bi khng ni g thm, ta coi th tch dung dch sau phn ng khng i.
Ta c:3 dung dch H2SO4 0.1M; HCl 0.2 M; HNO3 0.3M vi th tch bng nhau c dung
dch A. (gm 300ml)
Gi th tch dung dch B l: V(lt)

Cu 9: C

Nh vy, trong A c 0,2 mol K+, 0,6 mol NH4+, 0,2 mol CO3 2-, 0,2 mol SO4 2-.
Khi c cn th thu c lng mui khan l m = 0,2.39 + 0,6.18 + 0,2.60 + 0,2.96 = 49,8
=> p n C

Cu 10: B
Trng hp n mn in ho

CuCl2, Fe + CuCl2 FeCl2 + Cu,Fe Cu (1)

HCl + CuCl2 (2) tng t nh trn

--> Vy ch c 2 TH--> B

Cu 11: A

% H 99, 2%
1

S dng ng cho ta tnh c phn trm s nguyn t 1 H v 2 H : 2

% H 0,8%

Thnh phn % v khi lng ca 2
H trong H2O l:
 2.0, 008.2
0,178%
16 2.1, 008
=> p n A

Cu 12: B

Cu 13: D
1. ng

2. ng, Phenol v C2H5OH c tnh axit yu hn NaHCO3 nn khng c phn ng

3. ng, do cc axit H2CO3 v CH3COOH mnh hn C6H5OH v C2H5OH nn c th

y c mui ca cc cht ny khi dung dch

4. ng, phenol, C2H5OH v H2CO3 u c tnh axit yu hn CH3COOH nn phn ng

khng xy ra

5. ng, HCl c tnh axit mnh hn nn c phn ng.

Vy, c 5 cu u ng

=> p n D

Cu 14: D
Ta loi ngay p n A v B v 2 axit ny u tc dng vi c 3 kim loi.
p n C, c Pb v Fe tc dng vi FeCl3 v Ag khng tc dng.
Nhng trong phn ng Pb 2 FeCl3 2 FeCl2 PbCl2
Do , cht rn sau phn ng c Ag v PbCl2 nn khng th tch Ag ra c.
p n D ng v FeCl3 tc dng vi Pb v Fe, cht rn ch cn li Ag v khng lm thay i
khi lng Ag trong hn hp.
=> p n D

Cu 15: A
Ch c Ch3COOH tc dng vi Na. => nCH3COOH = 0,025
Ta thy HCOOCH=CH2 khi cho vo NaOH th s phn ng v thnh HCOONa v CH3CHO
u c kh nng tc dng vi Cu(OH)2.
Ni tm li, c HCOOCH=CH2 v OHC-CH2-CHO u phn ng vi Cu(OH)2 to ra Cu2O
theo t l 1:2
36
nX 0,125
2.144
Do c HCOOCH=CH2 v OHC-CH2-CHO u c chung cng thc phn t nn:
=> m = 0,025.60 + 0,125.72 = 10,5
=> p n A

Cu 16: D
Nhn thy xenluloz v tinh bt khng c kh nng ha tan c Cu(OH)2 cho dung dch
mu xanh lam loi A, B

Trong cu to ca ssaccaroz khng cn nhm CHO nn khng c kh nng tham gia phn
ng trng bc loi C

p n D.

Cu 17: D
phenylamoni clorua c tc dng vi NaOH nhng khng tc dng vi nc brom

Chn D

Cu 18: B
(1) Sai v trong nhm kim loi kim th nhit nng chy khng tun theo quy lut

(2) ng

(3) sai v Mg c kiu mng tinh th lc phng

(4) sai v Be khng tan trong nc mi nhit

(5) ng

Chn B

Cu 19: A
A sai do trng hp stiren thu c polistiren (nha PS).
=> p n A
Cu 20: D
Kh thot ra l CO2 => nC = 0,15
t s mol ca cc oxit v Fe u l x mol.

Quy i hn hp v C, Fe v O2.
Ta thy, c 0,15 mol C, 0,525 mol Fe v 0,3 mol O2.
Xt ton b qu trnh:
Cht nhng e, Fe ln Fe3+, v C ln C+4
CHt nhn e, O2 + 4e 2O2- v N+5 + 3e n+2
3nFe 4nC 4nO2
nNO 0,325
3
a nHNO 3 3nFe nNO 1,9

=> p n D

Cu 21: C

Cu 22: C

Chn C

Cu 23: C
X1 cng chnh l peptapeptit X ban u || tm lng X thy phn l ok.!

Lng ny cho 1,7 Gly + 1,4 mol Val + 0,3 mol Gly-Gly + 0,5 mol Val-Gly + 0,1 mol Gly-
Val-Gly.

|| Gly = 3,0 mol || c 1,0 mol X (cha 3Gly v 2Ala) thy phn khi lng =
387,0 gam.

|| m = 445,05 Ans = 58,05 gam. Chn C

Cu 24: A

=> p n A

Cu 25: D
Glucoz phn ng c vi cc cht :

Na (1); Cu(OH)2(3) ; H2(4) ; dd AgNO3/NH3 (5); O2(6) ; (CH3CO)2O (9)

Cu 26: D
Gi s mol ca C3H4 ; H2 : x; y

Gi s x + y = 1

40x + 2y = 43x => x = 0,4 ; y = 0,6

0, 4.40 0, 6.2
d A/ H 2 8, 6 D
1.2

Cu 27: C
Thy phn saccarozo thu c 1 glucozo v 1 fructozo.

KHi lng ca glucozo v saccarozo ln lt l m/3 v 2m/3

m m
S mol 2 cht trn ln lt l nglucozo , nsaccarozo
540 513
Phn ng vi AgNO3: 2nglucozo 4nsaccarozo nAg m 52,169

=> p n C

Cu 28: A

Cu 29: C
khng kh cha 78% N2, 21%O2, 1% CO2, H2O v H2 cha c coi l b nhim.

Chn C.

Cu 30: B
Bi tp ny cng chia lm 2 phn:

1: x l CO nhn 1.Otrong oxit CO2 (ci ny kh n gin v quen thuc).

(gii ng cho or my tnh bm nhanh ra CO = 0,15 mol; CO2 = 0,25 mol).

2: nhn c v ri v c cht kh khn, nhng thc cht n l dng BT hn hp kim loi v

oxit phn ng vi axit HNO3 quen thuc, khng quan trng t hay nhiu kim loi, l kim loi
g. Ty vo cch nhn nhn cng nh cch gii quyt nhng bi n gin m cc bn c th
c phng n gii quyt khc nhau cho bi ton ny.

Cch 1: hn hp Y gm {0,7461m gam kim loi + 0,2539m 0,2516 gam O)

tc dng vi HNO3 3,456m gam mui + 0,32 mol NO.

Bo ton e c: ne cho = ne kim loi = 2nO + 3.nNO. Tht ch thm rng:

kim loi mt ne th to ion Mn+, trong mui c dng M(NO3)n nn ne cho = ne kim loi = n = nNO3.

Vy c:

Cch 2: c:
Vy khi lng mui:

Gii phng trnh ta cng c kt qu tng t: m 38,4 gam. Vy chn B.

Cu 31: C
Cu hnh electron trng thi c bn ca nguyn t nguyn t X c tng s electron trong
cc phn lp s l 7

X c cu hnh electron: 1s22s22p63s23p64s1 hoc 1s22s22p63s23p63d54s1 hoc

1s22s22p63s23p63d104s1

Tng ng X c s hiu nguyn t l 19 hoc 24 hoc 29.

X khng th l Sc Chn C.

Cu 32: A
Gi s mol ca propan-1-ol : HO-CH2-CH2-CH3 v 2-hiroxietanal: CH2(OH)-CHO ln lt
l x, y mol

HO-CH2-CH2-CH3 + Na NaO-CH2-CH2-CH3 + 0,5H2

CH2(OH)-CHO + Na CH2(ONa) -CHO + 0,5H2

C 0,5x + 0,5y = nH2 = 0,02 mol x + y = 0,04 mol

Bo ton khi lng mcht rn = x . 60 + y. 60 + 0,04. 23- 0,02. 2 = 60.( x+ y)+ 0,04. 23 -
0,02. 2 = 3,28 gam

p n A.

Cu 33: D
Khi thm vi git CuSO4 xy ra phn ng: Zn+ Cu2+ Zn2+ + Cu

Khi hnh thnh n mn in ha, tc n mn in ha nhanh hn n mn ha hc

tc thot kh tng
p n D.

Cu 34: C
6 NaOH + Fe2(SO4)3 2Fe(OH)3 + 3Na2SO4

4NaOH d + ZnSO4 Na2[Zn(OH)4] + Na2SO4

2NaOH d + Ca(HCO3)2 CaCO3 + Na2CO3 + 2H2O

4NaOH d + AlCl3 Na[Al(OH)4] + 3NaCl

2NaOH + Cu(NO3)2 Cu(OH)2 + 2NaNO3

2NaOH + Ba(HS)2 BaS + Na2S + 2H2O

Vy s trng hp thu c kt ta l 3. p n C.

Cu 35: C
Lun c nOH- = nNaOH + 2nBa(OH)2 = x + 2y

Khi sc CO2 th th t xy ra phn ng nh sau :

CO2 + 2OH- CO32- + H2O

CO32- + CO2 + H2O 2HCO3-

Nhn thy lng kt ta cc i bng 0,1 mol nBa = nBaCO3 max= y = 0,1 mol

Khi s mol CO2 : 0,3 mol th khng tn ti kt ta nOH- = nCO2 = 0,3 x + 2y = 0,3 x =
0,1 mol

x : y = 0,1 : 0, 1 = 1 : 1. p n C.

Cu 36: B
cn (2,2 1,85 = 0,35 mol) H2O chuyn 0,1 mol Xn 0,45 mol X2 || n : 2 = 4,5 n =
9.

|| mipeptit = 2,2 14 + 0,45 76 = 65 gam. Thy phn X9 hay X2 u cho m gam rn nh

nhau.
|| BTKL c m = 65 + 1 40 0,45 18 = 96,9 gam. Chn p n B. .

p/s: hi s lin kt peptit nn s l 9 1 = 8.

Cu 37: D
1, Lm kh lun l bc cui cng nn loi B, C

2, Cl2 + H2O HCl + HClO

NaCl gip hp th HCl do HCl tan tt trong nc. Cl2 t tan trong nc do phng trnh trn,
c NaCl thm Cl- -> cn bng chuyn dch theo chiu nghch -> Cl2 tan t.

Thm na NaOH tc dung vi Cl2 nn loi A

Vy p n D

Cu 38: D
Cc cht lm i mu qu tm

+ Sang xanh: etylamin, natri axetat, metylamin, natri phenolat, lysin -> 5 cht

+ Sang : phenylamoni clorua, axit glutamic -> 2 cht

-> C 7 cht -> D

Cu 39: B
A ng. C th chng minh bi phn ng vi H2 to HX

+ F2 iu kin thng

+ Cl2 chiu sng hoc un nng nh

+ Br2 un nng

+ I2 y l phn ng thun nghch

B sai v Flo ch c s oxh l -1

C ng

D ng do c cng cu trc e lp ngoi cng ns2np5

Cu 40: A

Cu 41: A
Ancol a chc c 2 nhm -OH nh vi 2 C lin nhau th ha tan c Cu(OH)2

-> Hp cht k tha mn l A HOCH2-CH2-CH2OH

Cu 42: A

Cu 43: D
V sau phn ng k c cht rn d nn Al2O3 ha tan ht. CO2 ti d vo X ch c kt ta
Al(OH)3

Cu 44: C
Cu 45: A

Cu 46: B
A sai v thm xc tc k lm chuyn dch cn bng

B ng, gim th tch bnh th p sut tng (do cng thc pV=nRT) -> Cn bng chuyn dch
theo chiu lm gim p sut tc chiu thun

C sai v tng nhit , cn bng chuyn dch theo chiu thu nhit tc chiu nghch

D sai v thm HCl vo th NH3 s phn ng, lng NH3 gim, cn bng chuyn dch theo
chiu thun

p n B

Cu 47: A

Chn A

Cu 48: D
A sai v ancol phi l ancol bc 1 th mi thu c andehit

B sai v HCHO to ra 4 mol Ag

C sai v CH3OH un ch to ra ete

D ng

p n D

Cu 49: B
Axetilen c cng thc phn t : C2H2

Benzen c cng thc phn t : C6H6

Axetilen v benzen u c cng thc n gin nht l CH

p n B.

Cu 50: A
Thi c xa Al c coi l nguyn t qu him hn c vng ngc do kh khn trong vic
iu ch Al. Ngi ta iu ch nhm bng cch dng kim loi kim kh mui nhm clorua
khan ( AlCl3) hoc mui tetracloaluminat ( NaAlCl4) trng thi nng chy

AlCl3 + Na Al + 3NaCl v NaAlCl4 + 3Na Al + 4NaCl

Phng php ny cho php tch c nhm dng ht c ln khng bng u kim
bng.Thi by gi, kim loi mi ny c danh ting ngay. Nhng v ngi ta ch thu c
n vi lng rt t i nn gi ca n cao hn gi vng v tm mua c n khng phi n
gin.

p n A.