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  • Joback Method

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    The document describes the Joback method for calculating heat of formation values for chemical reactions. It provides an example reaction where cinnamaldehyde and water react to form benzaldehyde and acetaldehyde. It lists the chemical structures and functional groups for each compound. It then shows the calculation steps using the Joback method to determine the heat of reaction at 298K and 323K. The heat of reaction at 298K is determined to be -182.2 kJ/mol.

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    The document describes the Joback method for calculating heat of formation values for chemical reactions. It provides an example reaction where cinnamaldehyde and water react to form benzaldehyde and acetaldehyde. It lists the chemical structures and functional groups for each compound. It then shows the calculation steps using the Joback method to determine the heat of reaction at 298K and 323K. The heat of reaction at 298K is determined to be -182.2 kJ/mol.

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    © All Rights Reserved
    Download as XLSX, PDF, TXT or read online from Scribd
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    68 views3 pages

    Joback Method

    Uploaded by

    putrikurniawati
    The document describes the Joback method for calculating heat of formation values for chemical reactions. It provides an example reaction where cinnamaldehyde and water react to form benzaldehyde and acetaldehyde. It lists the chemical structures and functional groups for each compound. It then shows the calculation steps using the Joback method to determine the heat of reaction at 298K and 323K. The heat of reaction at 298K is determined to be -182.2 kJ/mol.

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    © All Rights Reserved
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    of 3

    JOBACK METHODE

    REAKTAN DATA (Cp)


    1. Cinnamaldehyde (C9H8O) NON RING
    =CH- = 2 NON RING =CH-
    =CH- = 5 RING -O-
    =C< = 1 RING -CH3
    O=CH- = 1 OXYGEN RING
    =CH-
    2. H2O =C<
    -O- = 1 NON RING
    OXYGEN (NON RING)
    PRODUK O=CH-
    1. Benzaldehyde (C7H6O)
    =CH- = 0 NON RING REAKTAN (Cp)
    =CH- = 5 RING Cinnamaldehyde
    =C< = 1 RING a =
    O=CH- = 1 OXYGEN b =
    c =
    2. ASETALDEHID (C2H4O) d =
    -CH3 = 1 NON RING
    O=CH- = 1 OXYGEN H2O
    a =
    b =
    c =
    d =

    delta H reaktan = -12.07 J/mol -0.012075 kJ/mol


    delta H produk = 11.96 J/mol 0.011956 kJ/mol
    delta H 298 = -182.2 kJ/mol
    delta H reaksi 323 = -182.20 kJ/mol
    DATA (DELTA H 298)
    A B C D NON RING Hform
    -8 1.05E-01 -9.63E-05 3.56E-08 =CH- 37.97
    2.55E+01 -6.32E-02 1.11E-04 -5.48E-08 -O- -132.22
    1.95E+01 -8.08E-03 1.53E-04 -9.67E-08 -CH3 -76.45
    RING
    -2.14 5.74E-02 -1.64E-06 -1.59E-08 =CH- 2.09
    -8.25 1.01E-01 -1.42E-04 6.78E-08 =C< 46.43

    YGEN (NON RING) OXYGEN (NON RING)


    3.09E+01 -3.36E-02 1.60E-04 -9.88E-08 O=CH- -162.03

    AKTAN (Cp) T= 298


    namaldehyde 323
    -4.05 Cp 298 = 142.25
    5.64E-01 Cp 323 = 153.90 PRODUK (Cp)
    -1.83E-04 Benzaldehyde
    -3.93E-08 a = 11.95
    b = 0.3544
    c = 0.0000098
    2.55E+01 Cp 298 = 10.45 d = -1.105E-007
    -6.32E-02 Cp 323 = 10.87
    1.11E-04 Asetaldehid
    -5.48E-08 a = 5.04E+01
    b = -4.17E-02
    c = 3.13E-04
    d = -1.96E-07
    REAKTAN (delta H 298) PRODUK (delta H 298)
    Cinnamaldehyde Benzaldehyde
    =CH- 75.94 =CH- 10.45
    =CH- 10.45 =C< 46.43
    =C< 46.43 O=CH- -162.03
    O=CH- -162.03 -105.15
    -29.21 -36.86
    39.08
    H2O Asetaldehid
    -O- -132.22 -CH3 -76.45
    -63.93 O=CH- -162.03
    -238.48
    -170.19

    Cp 298 = 110.89
    Cp 323 = 119.77

    Cp 298 = 55.98
    Cp 323 = 59.05

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