PART A PHYSICS A

1. Match List - I (Event) with List - II (Order 1. -I(U) -II ( U

of the time interval for happening of the U U)
event) and select the correct option from U
the options given below the lists.
List - I List - II - I - II
Rotation period
(a) (i) 10 5 s (a) (i) 105 s
of earth

Revolution U
(b) (ii) 10 7 s (b) (ii) 107 s
period of earth

Period of a light U
(c) (iii) 10 215 s (c) (iii) 10215 s
wave

Period of a U
(d) (iv) 10 23 s (d) (iv) 1023 s
sound wave

(1) (a)-(i), (b)-(ii), (c)-(iii), (d)-(iv) (1) (a)-(i), (b)-(ii), (c)-(iii), (d)-(iv)
(2) (a)-(ii), (b)-(i), (c)-(iv), (d)-(iii) (2) (a)-(ii), (b)-(i), (c)-(iv), (d)-(iii)
(3) (a)-(i), (b)-(ii), (c)-(iv), (d)-(iii) (3) (a)-(i), (b)-(ii), (c)-(iv), (d)-(iii)
(4) (a)-(ii), (b)-(i), (c)-(iii), (d)-(iv) (4) (a)-(ii), (b)-(i), (c)-(iii), (d)-(iv)

English : 1 Set : 10 Hindi : 1 Set : 10

 th
1 1
2. A bullet looses of its velocity passing 2.
n
U U n
through one plank. The number of such U U S
planks that are required to stop the bullet U
can be :
n2 n2
(1) (1)
2n21 2n21

2n 2 2n 2
(2) (2)
n21 n21
(3) Infinite (3)
(4) n (4) n
3. A heavy box is to be dragged along a rough 3. UU U U
horizontal floor. To do so, person A pushes U , A
it at an angle 308 from the horizontal and 308 U U
requires a minimum force FA, while person FA B
B pulls the box at an angle 608 from the 608 U U
horizontal and needs minimum force FB. FB
F
If the coefficient of friction between the box 3 A
, F :
5 B
F
3 A
and the floor is , the ratio F is :
5 B

(1) 3 (1) 3
5 5
(2) (2)
3 3

3 3
(3) (3)
2 2

2 2
(4) (4)
3 3
English : 2 Set : 10 Hindi : 2 Set : 10
4. Consider a cylinder of mass M resting on 4. UU U S
a rough horizontal rug that is pulled out M U U
from under it with acceleration a U a
perpendicular to the axis of the cylinder. P U F ?
What is Ffriction at point P ? It is assumed
that the cylinder does not slip.

(1) Mg (1) Mg
(2) Ma (2) Ma
Ma Ma
(3) (3)
2 2
Ma Ma
(4) (4)
3 3

English : 3 Set : 10 Hindi : 3 Set : 10

5. 5.

A particle is released on a vertical smooth U h X

semicircular track from point X so that OX U U OX U
makes angle u from the vertical (see figure). u
The normal reaction of the track on the U Y
particle vanishes at point Y where OY U # OY f
makes angle f with the horizontal. Then :
(1) sin f5cos u (1) sin f5cos u
1 1
(2) sin f5 cos u (2) sin f5 cos u
2 2
2 2
(3) sin f5 cos u (3) sin f5 cos u
3 3
3 3
(4) sin f5 cos u (4) sin f5 cos u
4 4

English : 4 Set : 10 Hindi : 4 Set : 10

6. A ball of mass 160 g is thrown up at an 6. 608 U 10 ms21
angle of 608 to the horizontal at a speed of 160 g U U
10 ms21. The angular momentum of the U ,
ball at the highest point of the trajectory ,
with respect to the point from which the (g510 ms22)
ball is thrown is nearly (g510 ms22)
(1) 1.73 kg m2/s (1) 1.73 kg m2/s
(2) 3.0 kg m2/s (2) 3.0 kg m2/s
(3) 3.46 kg m2/s (3) 3.46 kg m2/s
(4) 6.0 kg m2/s (4) 6.0 kg m2/s

7. The gravitational field in a region is 7. L U

r r
given by g 5 5N/kg i 1 12 N/kg j . The g 5 5N/kg i 1 12 N/kg j 2 kg
change in the gravitational potential (7 m,23 m)
energy of a particle of mass 2 kg when it is L S U :
taken from the origin to a point
(7 m,23 m) is :
(1) 71 J (1) 71 J

(2) 13 58 J (2) 13 58 J
(3) 271 J (3) 271 J
(4) 1J (4) 1J

English : 5 Set : 10 Hindi : 5 Set : 10

8. The velocity of water in a river is 8. 18 km/hr
18 km/hr near the surface. If the river is 5 m U , U
5 m deep , find the shearing stress between L
the horizontal layers of water. The 51022
co-efficient of viscosity of water510 22
poise.
(1) 1021 N/m2 (1) 1021 N/m2
(2) 1022 N/m2 (2) 1022 N/m2
(3) 1023 N/m2 (3) 1023 N/m2
(4) 1024 N/m2 (4) 1024 N/m2

9. 9.

In the diagram shown, the difference in , UU U

the two tubes of the manometer is 5 cm, 5 cm A B S U
the cross section of the tube at A and B is 6 mm2 10 mm2
6 mm2 and 10 mm2 respectively. The rate U (g510 ms22)
at which water flows through the tube is
(g510 ms22)
(1) 7.5 cc/s (1) 7.5 cc/s
(2) 8.0 cc/s (2) 8.0 cc/s
(3) 10.0 cc/s (3) 10.0 cc/s
(4) 12.5 cc/s (4) 12.5 cc/s

English : 6 Set : 10 Hindi : 6 Set : 10

10. A large number of liquid drops each of 10. r
radius r coalesce to from a single drop of U R
radius R. The energy released in the , U
process is converted into kinetic energy of (
the big drop so formed. The speed of the cU T, r)
big drop is (given surface tension of liquid
T, density r)

T1 1 T1 1
(1) 2 (1) 2
rr R rr R

2T 1 1 2T 1 1
(2) 2 (2) 2
r r R r r R

4T 1 1 4T 1 1
(3) 2 (3) 2
r r R r r R

6T 1 1 6T 1 1
(4) 2 (4) 2
r r R r r R

English : 7 Set : 10 Hindi : 7 Set : 10

11. A black coloured solid sphere of radius R 11. , , U M
and mass M is inside a cavity with vacuum R U U U
inside. The walls of the cavity are U T0 U
maintained at temperature T0. The initial U 3T0
temperature of the sphere is 3T0. If the cU c
specific heat of the material of the sphere T aT3 U U U ,
varies as aT 3 per unit mass with the a SU , 2T0
temperature T of the sphere, where a is a UU (s SU U
constant, then the time taken for the sphere SU )
to cool down to temperature 2T0 will be
(s is Stefan Boltzmann constant)

Ma 3 Ma 3
(1) 2
ln (1) 2
ln
4 pR  4 pR 

Ma 16 Ma 16
(2) 2
ln (2) 2
ln
4 pR  4 pR 

Ma 16 Ma 16
(3) 2
ln (3) 2
ln
16 pR  16 pR 

Ma 3 Ma 3
(4) ln (4) ln
16 pR 2  16 pR 2 
12. A gas is compressed from a volume of 12. 100 N/m2 SU U
2 m3 to a volume of 1 m3 at a constant 2 m3 1 m3 U U
pressure of 100 N/m2. Then it is heated at SU U 150 J
constant volume by supplying 150 J of USL U
energy. As a result, the internal energy of
the gas : U
(1) Increases by 250 J (1) 250 J
(2) Decreases by 250 J (2) 250 J U
(3) Increases by 50 J (3) 50 J
(4) Decreases by 50 J (4) 50 J U

English : 8 Set : 10 Hindi : 8 Set : 10

13. A gas molecule of mass M at the surface 13. cU U M
of the Earth has kinetic energy equivalent 08C
to 08C. If it were to go up straight without U UU U U ,
colliding with any other molecules, how ?(
high it would rise ? Assume that the height ) (kB U
attained is much less than radius of the SU )
earth. (kB is Boltzmann constant)
(1) 0 (1) 0

273 k B 273 k B
(2) 2 Mg (2) 2 Mg

546 k B 546 k B
(3) 3 Mg (3) 3 Mg

819 k B 819 k B
(4) 2 Mg (4) 2 Mg

14. A body is in simple harmonic motion with 14. S U (T50.5 s)

time period half second (T50.5 s) and UUU (A51 cm) U U
amplitude one cm (A51 cm). Find the U U S
average velocity in the interval in which it S ,
moves from equilibrium position to half of U
its amplitude.
(1) 4 cm/s (1) 4 cm/s
(2) 6 cm/s (2) 6 cm/s
(3) 12 cm/s (3) 12 cm/s
(4) 16 cm/s (4) 16 cm/s

English : 9 Set : 10 Hindi : 9 Set : 10

15. The total length of a sonometer wire 15. S U U
between fixed ends is 110 cm. Two bridges 110 cm
are placed to divide the length of wire in 6 : 3 : 2 U U
ratio 6 : 3 : 2. The tension in the wire is U 400 N U ,
400 N and the mass per unit length is 0.01 kg/m cU
0.01 kg/m. What is the minimum common , U ,
frequency with which three parts can
vibrate ?
(1) 1100 Hz (1) 1100 Hz
(2) 1000 Hz (2) 1000 Hz
(3) 166 Hz (3) 166 Hz
(4) 100 Hz (4) 100 Hz

16. The electric field in a region of space is 16. l

given by, E 5 Eo i 1 2 Eo j where E 5 Eo i 1 2 Eo j E 0 5100 N/C
E05100 N/C. The flux of this field through Y-Z U 0.02 m cU
a circular surface of radius 0.02 m parallel U U l
to the Y-Z plane is nearly :
(1) 0.125 Nm2/C (1) 0.125 Nm2/C
(2) 0.02 Nm2/C (2) 0.02 Nm2/C
(3) 0.005 Nm2/C (3) 0.005 Nm2/C
(4) 3.14 Nm2/C (4) 3.14 Nm2/C

English : 10 Set : 10 Hindi : 10 Set : 10

17. The gap between the plates of a parallel 17. U U U U
plate capacitor of area A and distance A U U U d U
between plates d, is filled with a dielectric S Ul U
whose permittivity varies linearly from 1 l U U 1 U U U 2
at one plate to 2 at the other. The U M U U
capacitance of capacitor is : U
(1) 0(112)A/d (1) 0(112)A/d

(2) 0(211)A/2d (2) 0(211)A/2d

(3) 0A/[d ln(2/1)] (3) 0A/[d ln(2/1)]

(4) 0(221)A/[d ln(2/1)] (4) 0(221)A/[d ln(2/1)]

18. 18.

Four bulbs B1, B2, B3 and B4 of 100 W each 100 W U B1, B2, B3 B4
are connected to 220 V main as shown in 220 V
the figure. The reading in an ideal ammeter U
will be :
(1) 0.45 A (1) 0.45 A
(2) 0.90 A (2) 0.90 A
(3) 1.35 A (3) 1.35 A
(4) 1.80 A (4) 1.80 A

English : 11 Set : 10 Hindi : 11 Set : 10

19. 19.

A square frame of side 10 cm and a long 10 cm U U U 1 A

straight wire carrying current 1 A are in U $ U
the plane of the paper. Starting from close U , U SU
to the wire, the frame moves towards the 10 ms21 U ( ) U
right with a constant speed of 10 ms21 (see x510 cm U
figure). The e.m.f induced at the time the U l
left arm of the frame is at x510 cm from
the wire is :
(1) 2 mV (1) 2 mV
(2) 1 mV (2) 1 mV
(3) 0.75 mV (3) 0.75 mV
(4) 0.5 mV (4) 0.5 mV

English : 12 Set : 10 Hindi : 12 Set : 10

20. An example of a perfect diamagnet is a 20. U
superconductor. This implies that when a B
superconductor is put in a magnetic field U ,
of intensity B, the magnetic field Bs inside U Bs U
the superconductor will be such that :
(1) Bs52B (1) Bs52B
(2) Bs50 (2) Bs50
(3) Bs5B (3) Bs5B
(4) Bs<B but Bs 0 (4) Bs<B U Bs 0

English : 13 Set : 10 Hindi : 13 Set : 10

21. 21.

Figure shows a circular area of radius R R

where a uniform magnetic field B is going B $
into the plane of paper and increasing in U SU U U h U
magnitude at a constant rate. In that case, S , M ,
which of the following graphs, drawn - U l E(r) U
schematically, correctly shows the ?
variation of the induced electric field
E(r) ?

(1) (1)

(2) (2)

English : 14 Set : 10 Hindi : 14 Set : 10

 (3) (3)

(4) (4)

22. If denote microwaves, X rays, infrared, 22. l SU U, X

gamma rays, ultra-violet, radio waves and U, U, U, U, UU U
visible parts of the electromagnetic U M, X, I, G, U, R U V
spectrum by M, X, I, G, U, R and V, the , U UU
following is the arrangement in ascending
order of wavelength :
(1) R, M, I, V, U, X and G (1) R, M, I, V, U, X U G
(2) M, R, V, X, U, G and I (2) M, R, V, X, U, G U I
(3) G, X, U, V, I, M and R (3) G, X, U, V, I, M U R
(4) I, M, R, U, V, X and G (4) I, M, R, U, V, X U G

English : 15 Set : 10 Hindi : 15 Set : 10

23. A ray of light is incident from a denser to
a rarer medium. The critical angle for total 23. U U
internal reflection is uiC and the Brewsters U U
angle of incidence is u iB , such that uiC U SUU uiB
sinu iC /sinu iB 5h51.28. The relative U sinuiC/sinuiB5h51.28
refractive index of the two media is :
(1) 0.2
(2) 0.4 (1) 0.2
(3) 0.8 (2) 0.4
(4) 0.9 (3) 0.8
(4) 0.9
24. The diameter of the objective lens of
microscope makes an angle b at the focus 24.
of the microscope. Further, the medium U b ; S
between the object and the lens is an oil of n
refractive index n. Then the resolving
power of the microscope.
(1) Increases with decreasing value of n
(2) Increases with decreasing value of b (1) n U
(3) Increases with increasing value of (2) b U
n sin 2b (3) n sin 2b
(4) Increases with increasing value of
1
1 (4)
n sin 2b

n sin 2b

English : 16 Set : 10 Hindi : 16 Set : 10

25. In a Youngs double slit experiment, the 25. mU , M SU
distance between the two identical slits is U SU 6.1
6.1 times larger than the slit width. Then SU U
the number of intensity maxima observed U
within the central maximum of the single
slit diffraction pattern is :
(1) 3 (1) 3
(2) 6 (2) 6
(3) 12 (3) 12
(4) 24 (4) 24

English : 17 Set : 10 Hindi : 17 Set : 10

26. Match List - I (Experiment performed) 26. -I ( ) -II (h
with List - II (Phenomena discovered/ /h )
associated) and select the correct option
from the options given below the lists :
List - I List - II - I - II
Davisson
Wave nature of U U U U U
(a) and Germer (i) (a) (i)
electrons U
Experiment

Millikans oil
Charge of an U
(b) drop (ii) (b) (ii)
electron U
experiment

Rutherford Quantisation of SU
(c) (iii) (c) UUU (iii)
experiment energy levels U
Franck -
Existence of - U
(d) Hertz (iv) (d) (iv)
nucleus S
experiment

(1) (a)-(i), (b)-(ii), (c)-(iii), (d)-(iv) (1) (a)-(i), (b)-(ii), (c)-(iii), (d)-(iv)
(2) (a)-(i), (b)-(ii), (c)-(iv), (d)-(iii) (2) (a)-(i), (b)-(ii), (c)-(iv), (d)-(iii)
(3) (a)-(iii), (b)-(iv), (c)-(i), (d)-(ii) (3) (a)-(iii), (b)-(iv), (c)-(i), (d)-(ii)
(4) (a)-(iv), (b)-(iii), (c)-(ii), (d)-(i) (4) (a)-(iv), (b)-(iii), (c)-(ii), (d)-(i)

English : 18 Set : 10 Hindi : 18 Set : 10

27. A piece of wood from a recently cut tree 27. U U
shows 20 decays per minute. A wooden U 20 U
piece of same size placed in a museum U (
(obtained from a tree cut many years back) U U ) U 2
shows 2 decays per minute. If half life of ; C14 5730 ,
C14 is 5730 years, then age of the wooden U
piece placed in the museum is
approximately :
(1) 10439 years (1) 10439
(2) 13094 years (2) 13094
(3) 19039 years (3) 19039
(4) 39049 years (4) 39049

28. 28.

Given : A and B are input terminals. A B U

Logic 1 5 > 5 V 1 5 > 5 V
Logic 0 5 < 1 V 0 5 < 1 V
Which logic gate operation, the following U - U
circuit does ? U U ?
(1) AND Gate (1) AND U
(2) OR Gate (2) OR U
(3) XOR Gate (3) XOR U
(4) NOR Gate (4) NOR U

English : 19 Set : 10 Hindi : 19 Set : 10

29. Long range radio transmission is possible 29. U UU SU
when the radiowaves are reflected from UU U U
the ionosphere. For this to happen the UU U U
frequency of the radiowaves must be in the
range :
(1) 80 - 150 MHz (1) 80 - 150 MHz
(2) 8 - 25 MHz (2) 8 - 25 MHz
(3) 1 - 3 MHz (3) 1 - 3 MHz
(4) 150 - 500 kHz (4) 150 - 500 kHz

English : 20 Set : 10 Hindi : 20 Set : 10

30. 30.

In an experiment for determining the U S U

gravitational acceleration g of a place with L U g ,
the help of a simple pendulum, the U UU
measured time period square is plotted
against the string length of the pendulum
in the figure.
What is the value of g at the place ? S U g
(1) 9.81 m/s2 (1) 9.81 m/s2
(2) 9.87 m/s2 (2) 9.87 m/s2
(3) 9.91 m/s2 (3) 9.91 m/s2
(4) 10.0 m/s2 (4) 10.0 m/s2

English : 21 Set : 10 Hindi : 21 Set : 10

 PART B CHEMISTRY B U
31. Ionization energy of gaseous Na atoms is 31. U U
495.5 kJmol 21 . The lowest possible 495.5 kJ 21 U U
frequency of light that ionizes a sodium U
atom is (h56.626310234 Js, (frequency) ? (h56.626310234 Js,
NA56.02231023 mol21) NA56.02231023 21)
(1) 7.503104 s21 (1) 7.503104 s21
(2) 4.7631014 s21 (2) 4.7631014 s21
(3) 3.1531015 s21 (3) 3.1531015 s21
(4) 1.2431015 s21 (4) 1.2431015 s21

32. Choose the correct statement with respect 32. c

to the vapour pressure of a liquid among
the following :
(1) Increases linearly with increasing (1) U U
temperature
(2) Increases non-linearly with (2) U U
increasing temperature
(3) Decreases linearly with increasing (3) U U
temperature U
(4) Decreases non-linearly with (4) U U
increasing temperature U

English : 22 Set : 10 Hindi : 22 Set : 10

33. Which one of the following molecules is 33. ?
paramagnetic ?
(1) N2 (1) N2
(2) NO (2) NO
(3) CO (3) CO
(4) O3 (4) O3
34. Zirconium phosphate [Zr 3 (PO 4 ) 4 ] 34. U $S$U [Zr3(PO4)4] U
dissociates into three zirconium cations of 14 U U U
charge 14 and four phosphate anions of U 23 U $S$U
charge 23. If molar solubility of zirconium U $S$U U
phosphate is denoted by S and its solubility S U Ksp
product by Ksp then which of the following -
relationship between S and K sp is S U Ksp ?
correct ?
(1) S5{Ksp/(6912)1/7} (1) S5{Ksp/(6912)1/7}
(2) S5{Ksp/144}1/7 (2) S5{Ksp/144}1/7
(3) S5(Ksp/6912)1/7 (3) S5(Ksp/6912)1/7
(4) S5{Ksp/6912}7 (4) S5{Ksp/6912}7

English : 23 Set : 10 Hindi : 23 Set : 10

35. For the decomposition of the compound, 35. NH2COONH4(s) 2NH3(g)1CO2(g)
represented as
NH2COONH4(s) 2NH3(g)1CO2(g)
the Kp52.931025 atm3. Kp52.931025 atm3
If the reaction is started with 1 mol of the 1
compound, the total pressure at U S
equilibrium would be :
(1) 1.9431022 atm (1) 1.9431022 atm
(2) 5.8231022 atm (2) 5.8231022 atm
(3) 7.6631022 atm (3) 7.6631022 atm
(4) 38.831022 atm (4) 38.831022 atm

36. For the reaction, 36.

3A12B C1D, 3A12B C1D
the differential rate law can be written U
as :

1 d [A ] d [C ] 1 d [A ] d [C]
5 k [A ] [ B ] 5 k [A ] [ B ]
n m n m
(1) 5 (1) 5
3 dt dt 3 dt dt

d [A ] d [C ] d [A ] d [C ]
5 k [A ] [ B ] 5 k [A ] [ B ]
n m n m
(2) 2 5 (2) 2 5
dt dt dt dt

1 d [A ] d [C ] 1 d [A ] d [C]
5 k [A ] [ B ] 5 k [A ] [ B ]
n m n m
(3) 1 52 (3) 1 52
3 dt dt 3 dt dt

1 d [A ] d [C ] 1 d [A ] d [C]
5 k [A ] [ B ] 5 k [A ] [ B ]
n m n m
(4) 2 5 (4) 2 5
3 dt dt 3 dt dt

English : 24 Set : 10 Hindi : 24 Set : 10

37. Sulphur dioxide and oxygen were allowed 37. U U $U UU U
to diffuse through a porous partition. U U U
20 dm3 of SO2 diffuses through the porous 20 dm3 SO2 U 60 U
partition in 60 seconds. The volume of O2 S U O2
in dm3 which diffuses under the similar dm3 30 U ($U
condition in 30 seconds will be (atomic U 532 )
mass of sulphur532 u) :
(1) 7.09 (1) 7.09
(2) 14.1 (2) 14.1
(3) 10.0 (3) 10.0
(4) 28.2 (4) 28.2

38. The observed osmotic pressure for a 38. 258 C U Fe(NH4)2(SO4)2 0.10 M
0.10 M solution of Fe(NH4)2(SO4)2 at 258C U (UU) 10.8 atm
is 10.8 atm. The expected and U U U
experimental (observed) values of Vant () U
Hoff factor (i) will be respectively :
(R50.082 L atm k2mol21) (R50.082 L atm k221)
(1) 5 and 4.42 (1) 5 U 4.42
(2) 4 and 4.00 (2) 4 U 4.00
(3) 5 and 3.42 (3) 5 U 3.42
(4) 3 and 5.42 (4) 3 U 5.42

English : 25 Set : 10 Hindi : 25 Set : 10

39. The total number of octahedral void(s) per 39. U () U S
atom present in a cubic close packed U cU U
structure is :
(1) 2 (1) 2
(2) 4 (2) 4
(3) 1 (3) 1
(4) 3 (4) 3

40. For an ideal solution of two components 40. U A U B

A and B, which of the following is true ? ?
(1) DHmixing < 0 (zero) (1) DH < 0 (zero)
(2) DHmixing > 0 (zero) (2) DH > 0 (zero)
(3) A2B interaction is stronger than (3) A2A U B2B U S U
A2A and B2B interactions A2B USU
(4) A2A, B2B and A2B interactions (4) A2A, B2B U A2B USU
are identical
41. Consider the reaction : 41.
41 21
41
H 2 SO 3(aq)1Sn (aq)1H 2 O (l ) Sn (aq)
21
1HSO24(aq)13H1(aq) H 2 SO 3()1Sn()1H 2 O(l ) Sn()1HSO24()13H1
()

Which of the following statements is - ?

correct ?
(1) Sn41 is the oxidizing agent because (1) Sn41 U
it undergoes oxidation
(2) Sn41is the reducing agent because (2) Sn41
it undergoes oxidation
(3) H2SO3 is the reducing agent because (3) H2SO3
it undergoes oxidation
(4) H2SO3 is the reducing agent because (4) H2SO3
it undergoes reduction

English : 26 Set : 10 Hindi : 26 Set : 10

42. Which one of the following has largest 42. ?
ionic radius ?
(1) Li1 (1) Li1
22 22
(2) O2 (2) O2
(3) B31 (3) B31
(4) F2 (4) F2

43. An octahedral complex with molecular 43. U M.5 NH3.Cl.SO4 cU

composition M.5NH 3 .Cl.SO 4 has two U A U B A
isomers, A and B. The solution of A gives AgNO3 $
a white precipitate with AgNO3 solution U B BaCl2 $
and the solution of B gives white U mU -
precipitate with BaCl2 solution. The type U
of isomerism exhibited by the complex is :
(1) Linkage isomerism (1) () -
(2) Ionisation isomerism (2) -
(3) Coordinate isomerism (3) -
(4) Geometrical isomerism (4) -

44. How many electrons are involved in the 44. - U

following redox reaction ? ?
Cr2O7221Fe211 C 2 O 242 Cr2O7221Fe211 C 2 O 242

Cr311Fe311CO2 (Unbalanced) Cr311Fe311CO2 ()

(1) 3 (1) 3
(2) 4 (2) 4
(3) 6 (3) 6
(4) 5 (4) 5

English : 27 Set : 10 Hindi : 27 Set : 10

45. Amongst LiCl, RbCl, BeCl2 and MgCl2 the 45. LiCl, RbCl, BeCl2 U MgCl2
compounds with the greatest and the least U U
ionic character, respectively are : U
(1) LiCl and RbCl (1) LiCl U RbCl
(2) RbCl and BeCl2 (2) RbCl U BeCl2
(3) MgCl2 and BeCl2 (3) MgCl2 U BeCl2
(4) RbCl and MgCl2 (4) RbCl U MgCl2

46. Nickel(Z528) combines with a 46. (Z528) U

uninegative monodentate ligand to form U U [NiL4]22,
a diamagnetic complex [NiL 4 ] 22 . The U U U U
hybridisation involved and the number of U U
unpaired electrons present in the complex
are respectively :
(1) sp3, two (1) sp3,
(2) dsp2, zero (2) dsp2,
(3) dsp2, one (3) dsp2,
(4) sp3, zero (4) sp3,

47. Which of these statements is not true ? 47. - ?

(1) NO1 is not isoelectronic with O2 (1) NO1 O2 U
(2) B is always covalent in its (2) U
compounds
(3) In aqueous solution, the Tl1 ion is (3) , Tl (III) Tl1
much more stable than Tl (III) S
(4) LiAlH4 is a versatile reducing agent (4) LiAlH4
in organic synthesis.

English : 28 Set : 10 Hindi : 28 Set : 10

48. Example of a three-dimensional silicate 48. - U U
is :
(1) Zeolites (1) $U
(2) Ultramarines (2) UU
(3) Feldspars (3) USU
(4) Beryls (4) U
49. Amongst the following, identify the 49. 16 S U
species with an atom in 16 oxidation S$
state :
(1) [MnO4]2 (1) [MnO4]2
(2) [Cr(CN)6]32 (2) [Cr(CN)6]32
(3) Cr2O 3 (3) Cr2O3
(4) CrO2Cl2 (4) CrO2Cl2

50. Which one of the following ores is known 50. U S

as Malachite :
(1) Cu 2O (1) Cu 2O
(2) Cu 2S (2) Cu2S
(3) CuFeS2 (3) CuFeS2
(4) Cu(OH)2.CuCO3 (4) Cu(OH)2.CuCO3

51. The major product formed when 1, 1, 12 51. 1, 1, 12 UU U

trichloro - propane is treated with aqueous UU
potassium hydroxide is :
(1) Propyne (1)
(2) 1 - Propanol (2) 1 -
(3) 2 - Propanol (3) 2 -
(4) Propionic acid (4) U

English : 29 Set : 10 Hindi : 29 Set : 10

52. Which one of the following is an example 52. ?
of thermosetting polymers ?
(1) Neoprene (1)
(2) Buna -N (2) - N
(3) Nylon 6, 6 (3) 6, 6
(4) Bakelite (4) U

53. The correct IUPAC name of the following 53.

compound

is : IUPAC
(1) 4 - methyl - 3 - ethylhexane (1) 4 - - 3 -
(2) 3 - ethyl - 4 - methylhexane (2) 3 - - 4 -
(3) 3, 4 - ethylmethylhexane (3) 3, 4 -
(4) 4 - ethyl - 3 - methylhexane (4) 4 - - 3 -
54. Which one of the following substituents at 54. S U
para-position is most effective in
, U S U
stabilizing the phenoxide ,
S ?
ion ?
(1) 2CH3 (1) 2CH3
(2) 2OCH3 (2) 2OCH3
(3) 2COCH3 (3) 2COCH3
(4) 2CH2OH (4) 2CH2OH

English : 30 Set : 10 Hindi : 30 Set : 10

55. The final product formed when Methyl 55. NaNO2 U HCl
amine is treated with NaNO2 and HCl U U
is :
(1) Diazomethane (1) U$
(2) Methylalcohol (2)
(3) Methylcyanide (3) U
(4) Nitromethane (4) U

56. Which one of the following compounds 56. - U U

will not be soluble in sodium ?
bicarbonate ?
(1) 2, 4, 6 - Trinitrophenol (1) 2, 4, 6 - UU$
(2) Benzoic acid (2) $ U
(3) o - Nitrophenol (3) o - U$
(4) Benzene sulphonic acid (4) $ $ U

57. Williamson synthesis of ether is an example 57. U

of : U ?
(1) Nucleophilic addition (1) $
(2) Electrophilic addition (2) U$
(3) Electrophilic substitution (3) U$ S
(4) Nucleophilic substitution (4) $ S

English : 31 Set : 10 Hindi : 31 Set : 10

58. The reason for double helical structure of 58. - DNA U UU
DNA is the operation of : U U ?
(1) Electrostatic attractions (1) SUl
(2) van der Waals forces (2) UU
(3) Dipole - Dipole interactions (3) m - m USU
(4) Hydrogen bonding (4) U
59. Among the following organic acids, the 59. U U
acid present in rancid butter is : - ?
(1) Pyruvic acid (1) L U
(2) Lactic acid (2) U U
(3) Butyric acid (3) UU U
(4) Acetic acid (4) U U

English : 32 Set : 10 Hindi : 32 Set : 10

60. In a set of reactions p - nitrotoluene yielded 60.
a product E

The product E would be : p - UU E

(1) (1)

(2) (2)

(3) (3)

(4) (4)

English : 33 Set : 10 Hindi : 33 Set : 10

 PART C MATHEMATICS C
x 21 x 21
61. Let f : RR be defined by f(x)5
x 11
61. f : RR , f(x)5 x 11
mU U ,
then f is : f :
(1) both one - one and onto (1) U
(2) one - one but not onto (2) U
(3) onto but not one - one (3) U U
(4) neither one - one nor onto. (4) U U

62. For all complex numbers z of the form 62. 11ia, a e R U

11ia, a e R, if z25x1iy, then : z , z25x1iy , :
(1) y 2 24x1250 (1) y 224x1250
(2) y 2 14x2450 (2) y 214x2450
(3) y 2 24x1450 (3) y 224x1450
(4) y 2 14x1250 (4) y 214x1250

63. The equation 3x 21x15 5x23, where x 63. U 3x 21x15 5x23, x S

is real, has : , / :
(1) no solution (1)
(2) exactly one solution (2) U
(3) exactly two solutions (3) U
(4) exactly four solutions. (4) U U

English : 34 Set : 10 Hindi : 34 Set : 10

64. Let A and B be any two 333 matrices. If 64. A B 333 A
A is symmetric and B is skewsymmetric, B ,
then the matrix AB2BA is : AB2BA :
(1) skewsymmetric (1)
(2) symmetric (2)
(3) neither symmetric nor (3) U
skewsymmetric
(4) I or 2I, where I is an identity matrix. (4) I 2I , I
65. If
65.
r 2r 2 1 3r 2 2
n r 2r 2 1 3r 2 2
Dr 5 n2 1 a
2 n
1 1 Dr 5 n2 1 a
n ( n 2 1) ( n 2 1 )2 ( n 2 1 )( 3n 1 4 ) , 2
2 2 1 1
n ( n 2 1) ( n 2 1 )2 ( n 2 1 )( 3n 1 4 )
2 2
n2 1
then the value of Dr :
n2 1
r5 1
, Dr :
(1) depends only on a r5 1

(2) depends only on n (1) a U U

(3) depends both on a and n (2) n U U
(4) is independent of both a and n. (3) a n U U
(4) a n S

English : 35 Set : 10 Hindi : 35 Set : 10

66. Two women and some men participated 66. U U
in a chess tournament in which every L
participant played two games with each U L
of the other participants. If the number of U L
games that the men played between them- mU U 66
selves exceeds the number of games that , L ,
the men played with the women by 66, , U
then the number of men who participated
in the tournament lies in the interval :
(1) [8, 9] (1) [8, 9]
(2) [10, 12) (2) [10, 12)
(3) (11, 13] (3) (11, 13]
(4) (14, 17) (4) (14, 17)

67. The coefficient of x1012 in the expansion of 67. (11xn1x253)10, ( n 22 Z

(11x n 1x 253 ) 10 , (where n 22 is any ) U x1012

positive integer), is :
(1) 1 (1) 1
(2) 10C (2) 10C
4 4
(3) 4n (3) 4n
(4) 253C (4) 253C
4 4

English : 36 Set : 10 Hindi : 36 Set : 10

68. The number of terms in an A.P. is even; 68. U
the sum of the odd terms in it is 24 and 24 30
that the even terms is 30. If the last term 1
, 10 2 ,
1
exceeds the first term by 10 , then the
2 U
number of terms in the A.P. is :
(1) 4 (1) 4
(2) 8 (2) 8
(3) 12 (3) 12
(4) 16 (4) 16

1 3n 1 3n
69. Let f(n) 5 1
3 100
n , where [n] denotes 69. f(n)5 3 1 100 n , [n]
the greatest integer less than or equal to n. Z , n U U U U ,
56 56
Then f ( n ) is equal to : f ( n) UU
n5 1 n5 1
(1) 56 (1) 56
(2) 689 (2) 689
(3) 1287 (3) 1287
(4) 1399 (4) 1399

English : 37 Set : 10 Hindi : 37 Set : 10

70. If the function
2 1 cos x2 1
, x p
f (x ) 5 ( p 2 x )
2
2 1 cos x2 1
, x p 70. k
f (x ) 5 ( p 2 x )
2
, x5p
k , x5p

is continuous at x5p, then k equals : x5p U , k UU :

(1) 0 (1) 0
1 1
(2) (2)
2 2
(3) 2 (3) 2
1 1
(4) (4)
4 4
71. Let f: R R be a function such that 71. f: R R x e R
?f(x)? x2, for all x e R. Then, at x50, f is : ?f(x)? x2 , x50 U f :
(1) continuous but not differentiable (1) U
(2) continuous as well as differentiable (2)
(3) neither continuous nor differentiable (3) U
(4) differentiable but not continuous. (4) U

English : 38 Set : 10 Hindi : 38 Set : 10

72. If non-zero real numbers b and c are such 72. U S b c
that min f(x) > max g(x), where min f(x) > max g(x), f(x)5x212bx12c2
g(x)52x222cx1b2 (x e R) ,
f(x)5x212bx12c2 and

g(x)52x222cx1b2 (x e R) ;

c c
then
b
lies in the interval : b
U , :

1 1
(1) 0, (1) 0,
2 2

1 1 1 1
(2) 2 , 2 (2) 2 , 2

1 1
(3) 2 , 2 (3) 2 , 2

(4) ( 2 , ) (4) ( 2 , )

73. If the volume of a spherical ball is 73. U 4p /.

increasing at the rate of 4p cc/sec, then U U , 288p
the rate of increase of its radius , U (/. ) U ,
(in cm/sec), when the volume is 288p cc, :
is :
1 1
(1) (1)
6 6
1 1
(2) (2)
9 9
1 1
(3) (3)
36 36
1 1
(4) (4)
24 24
English : 39 Set : 10 Hindi : 39 Set : 10
74. If m is a non - zero number and 74. m U
x 5m21 1 2 x 4 m21 x 5m21 12 x 4 m21
d x5 f ( x )1c , d x5 f ( x )1c
( ) ( )
3 3
x 2 m 1 x m 11 x 2 m 1 x m 11

then f(x) is : , f(x) :

x 5m x 5m
(1) (1)
( ) ( )
2 2
2m x 2m 1 x m 1 1 2m x 2m 1 x m 1 1

x 4m x 4m
(2) (2)
( ) ( )
2 2
2m x 2m 1 x m 1 1 2m x 2m 1 x m 1 1

(
2 m x 5m 1 x 4m) (
2 m x 5m 1 x 4m)
(3) (3)
( x2m 1 xm 1 1) ( x2m 1 xm 1 1)
2 2

( x 5m 2 x 4 m ) ( x 5m 2 x 4 m )
(4) (4)
2 m ( x 2 m 1 x m 1 1) 2 m ( x 2 m 1 x m 1 1)
2 2

English : 40 Set : 10 Hindi : 40 Set : 10

 x
et
75. Let function F be defined as 75. F , F( x ) 5 dt , x > 0 mU
1 t

et
x
x et
F( x ) 5 1 t dt , x > 0 then the value of U , 1
t1 a
dt ,

x et
the integral 1 t 1 a dt , where a > 0 , :
a > 0, is :
(1) ea[F(x)2F(11a)] (1) ea[F(x)2F(11a)]
(2) e2a[F(x1a)2F(a)] (2) e2a[F(x1a)2F(a)]
(3) ea[F(x1a)2F(11a)] (3) ea[F(x1a)2F(11a)]
(4) e2a[F(x1a)2F(11a)] (4) e2a[F(x1a)2F(11a)]
p p
76. The area of the region above the x-axis 76. y5tan x, 0 x 2
U x5
4
p
bounded by the curve y5tan x, 0 x
2
U S U mU U , x
p
and the tangent to the curve at x5
4
is : U , :

1 1 1 1
(1) log 2 2 (1) log 2 2
2 2 2 2

1 1 1 1
(2) log 2 1 (2) log 2 1
2 2 2 2

1 1
(3) ( 1 2 log 2 ) (3) ( 1 2 log 2 )
2 2
1 1
(4) ( 1 1 log 2 ) (4) ( 1 1 log 2 )
2 2

English : 41 Set : 10 Hindi : 41 Set : 10

 dy dy
77. If 1y tan x5sin 2x and y(0)51, then 77. 1y tan x5sin 2x y(0)51
dx dx
y(p) is equal to : y(p) UU :
(1) 1 (1) 1
(2) 21 (2) 21
(3) 25 (3) 25
(4) 5 (4) 5

78. The circumcentre of a triangle lies at the 78. U U

origin and its centroid is the mid point of , (a211, a211) (2a, 22a),
the line segment joining the points a 0 UU ,
(a211, a211) and (2a, 22a), a 0. Then a U
for any a, the orthocentre of this triangle U S ,
lies on the line :
(1) y22ax50 (1) y22ax50
(2) y2(a211)x50 (2) y2(a 211)x50
(3) y1x50 (3) y1x50
(4) (a21)2x2(a11) 2y50 (4) (a21) 2x2(a11) 2y50

English : 42 Set : 10 Hindi : 42 Set : 10

79. If a line L is perpendicular to the line 79. U L, U 5x2y51 U
5x2y51, and the area of the triangle U L mU
formed by the line L and the coordinate 5 , U L U x15y50 U :
axes is 5, then the distance of line L from
the line x15y50 is :
7 7
(1) (1)
5 5

5 5
(2) (2)
13 13

7 7
(3) (3)
13 13

5 5
(4) (4)
7 7

80. The equation of the circle described on the 80. x21y2516 3x1y1550
chord 3x1y1550 of the circle U :
x21y2516 as diameter is :
(1) x 21y 213x1y21150 (1) x 21y 213x1y21150
(2) x 21y 213x1y1150 (2) x 2 1y 2 13x1y1150
(3) x 21y 213x1y2250 (3) x 2 1y 2 13x1y2250
(4) x 21y 213x1y22250 (4) x 21y 213x1y22250

English : 43 Set : 10 Hindi : 43 Set : 10

81. A chord is drawn through the focus of the 81. U y256x U
parabola y256x such that its distance from 5
U U ,
5 2
the vertex of this parabola is , then its
2 U :
slope can be :

5 5
(1) (1)
2 2

3 3
(2) (2)
2 2
2 2
(3) (3)
5 5

2 2
(4) (4)
3 3

x2 y2
82. The tangent at an extremity (in the first 82. U 2 5 1
4 5
quadrant) of latus rectum of the hyperbola U ( Z ) U S
x2 y2
4
2
5
5 1 ,meets x - axis and y - axis U x- y- A B
at A and B respectively. Then U , (OA)22(OB)2, O
(OA) 2 2(OB) 2 , where O is the origin, , UU :
equals : 20
(1) 2
20 9
(1) 2
9 16
(2)
16 9
(2)
9 (3) 4
(3) 4 4
(4) 2
4 3
(4) 2
3

English : 44 Set : 10 Hindi : 44 Set : 10

 x y z
83. Equation of the line of the shortest distance 83. U 5 5
1 21 1
x y z x21 y11 z
between the lines
1
5
21
5
1
and 5 5 U
0 22 1
x21 y11 z
0
5
22
5 is :
1
U U :

x y z x y z
(1) 5 5 (1) 5 5
1 21 22 1 21 22

x21 y11 z x21 y11 z

(2) 5 5 (2) 5 5
1 21 22 1 21 22

x21 y11 z x21 y11 z

(3) 5 5 (3) 5 5
1 21 1 1 21 1

x y z x y z
(4) 5 5 (4) 5 5
22 1 2 22 1 2
84. If the angle between the line 84. U 2(x11)5y5z14
2(x11)5y5z14 and the plane p
2x2y1 l z1450 6
,
p
2x2y1 l z1450 is , then the value l :
6
of l is :
135 135
(1) (1)
7 7

45 45
(2) (2)
11 11

45 45
(3) (3)
7 7

135 135
(4) (4)
11 11

English : 45 Set : 10 Hindi : 45 Set : 10

 r r r r
85. If x 5 3i 2 6 j 2 k , y 5 i 1 4 j 2 3k 85. x 5 3i 2 6 j 2 k , y 5 i 1 4 j 2 3k
r r r r r
and z 5 3i 2 4 j 2 12k ,
then the z 5 3i 2 4 j 2 12k x 3y z U
r r r
magnitude of the projection of x 3y on z U :
is :
(1) 12 (1) 12
(2) 15 (2) 15
(3) 14 (3) 14
(4) 13 (4) 13

86. Let A and E be any two events with 86. A E U

positive probabilities :
Statement - 1 : P(E/A) P(A/E)P(E) -1 : P(E/A) P(A/E)P(E)
Statement - 2 : P(A/E) P(AE). -2 : P(A/E) P(AE).
(1) Both the statements are true (1)
(2) Both the statements are false (2)
(3) Statement - 1 is true, Statement - 2 is (3) -1 , -2
false
(4) Statement - 1 is false, Statement - 2 (4) -1 , -2
is true.

English : 46 Set : 10 Hindi : 46 Set : 10

87. Let x , M and s 2 be respectively the mean, 87. n x1, x2, ..., xn
mode and variance of n observations U x , M s 2 di52xi2a,
x1, x2, ..., xn and di52xi2a, i51, 2, ..., n, i51, 2, ..., n , a
where a is any number.
Statement I : Variance of d1, d2, ..., dn is I : d1, d2, ..., dn U s2
s2.

Statement II : Mean and mode of II : d1, d2, ..., dn

d 1 , d 2 , ..., d n are 2 x 2a and 2M2a, 2 x 2a 2M2a
respectively
(1) Statement I and Statement II are (1) I II
both false
(2) Statement I and Statement II are (2) I II
both true
(3) Statement I is true and Statement II (3) I II
is false
(4) Statement I is false and Statement II (4) I II
is true

88. The function f ( x )5 sin 4x 1 cos 2 x , is a 88. f ( x )5 sin 4x 1 cos 2x

periodic function with period : :
(1) 2p (1) 2p
(2) p (2) p
p p
(3) (3)
2 2
p p
(4) (4)
4 4

English : 47 Set : 10 Hindi : 47 Set : 10

 21 43p 43p
89. The principal value of tan cot is : 89. tan21 cot :
4 4

3p 3p
(1) 2 (1) 2
4 4
3p 3p
(2) (2)
4 4
p p
(3) 2 (3) 2
4 4
p p
(4) (4)
4 4
90. The contrapositive of the statement if I 90. SS , UUU
am not feeling well, then I will go to the
doctor is :
(1) If I am feeling well, then I will not (1) SS , UUU
go to the doctor
(2) If I will go to the doctor, then I am (2) UUUU , SS
feeling well
(3) If I will not go to the doctor, then I
(3) UUUU ,
am feeling well
SS
(4) If I will go to the doctor, then I am
(4) UUUU , SS
not feeling well.

-o0o-
-o0o-

English : 48 Set : 10 Hindi : 48 Set : 10