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MACROSCOPIC ELECTROSTATICS
we obtain
(E(r))= -V ds/ c[ 1
r-slV v
dV
j
qjkb(rj - s - r)
t)S,
+ (V, r - s l dV
j
pjS(rj - s - r)] (4.5)
where we define as
N ( s ) : the number of molecules per unit volume at s ,
(qmol(S)): average charge per molecule at s ,
p ( s ) : macroscopic charge density at s ,
P(s): polarisation vector (= dipole m o m e n t per unit volume) at s ,
(Pmol(s)): average dipole m o m e n t per molecule at s.
We then have (with s replaced by r)
where in the step from the first line to the second we used the replacement
1
V2---+ -47r6(r - r),
Ir - rl