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Industrial Wastewater Engineering Solutions

API
Oil water Separators
Selecting the right API oil water
separator for the application is key to
the successful outcome of the entire
treatment system performance.

The API separator design is based


on the American Petroleum Institute Skimmer Types Sludge scrapers, sludge screw
(API) Monographs on Refinery Three types of skimmers can be augers hopper bottoms and inverted
Environmental Control, Design and provided, fixed weir oil skimming pyramid bottoms can be provided
Operation of Oil-Water Separators. baffle integrated with an oil reservoir, depending on the style of sludge
adjustable rotating slotted pipe removal required or desired for a
skimmer and the drum skimmer. particular application.
The flow capacities of the design are
based on an influent of fresh water The drum skimmer design is a motor Chain & Flight Skimmers
and No. 2 fuel oil at 40°F operating driven stainless steel drum spanning Three styles of flight skimmers are
temperature. The API guide has the tank width partially submerged in offered to remove solids and oils
established optimum depth to width the water. As the drum rotates oil depending on the required design to
ratios with controlled velocities attaches to the drum and is removed fit the application.
allowing oil droplets of 150 microns via a blade riding on the drum face.
diameter or larger to separate from Type 1: surface drag skimmer located
the water phase as predicted by Solids Removal at the tank top to move floating oils to
Stokes Law. The rectangular shape of Solids are typically present in varying the oil skimmer.
the API separator along with an amounts in waste water. The API
efficient diffusion baffle and weirs design is excellent for handling solids Type 2: sludge scraper located at
creates a consistent laminar flow without upset. If the solids loading is tank bottom to move settled sludge
throughout the separation chamber light, a flat bottom design may be from the effluent end toward a sludge
cross section. This allows optimum sufficient. However, when heavier collecting v-hopper at the influent
use of the working volume. solids loads are expected hopper end.
bottoms should be used to allow easy
solids removal and prevent solids Type 3: types 1 & 2 are combined
Operation accumulation from reducing the into a single system that skims the
Flow Diffusion effective volume of the separation surface and scrapes the bottom to
API separator uses a special chamber. perform both oil movement and
diffusion baffle to diffuse the flow
sludge movement.
prior to the separation chamber.
As each application is different and
solids occur in a wide range of sizes, Chain & flight construction can be
Oil Skimming
different concentrations and densities provided as hardened
Oil skimming utilizes the specific
ultimate solids settling performance is carbon/stainless chain, sprockets &
gravity differential between lighter oil
quite variable and each application shafts or polymeric chain &
and heavier water. The oil floats on
must be reviewed for proper API sprockets. Each material has differing
the surface and in so doing displaces
design. life expectancies, stretch modulus
the water. Since oil has a lower
and liquid compatibilities. The flight
specific gravity than water the level of
Refinery sludge can be highly viscous construction of preference is a
the oil upstream of the oil baffle rises
with high concentrations of solids and fiberglass channel design where
above the water level set by the water
oils mixed together. These strength vs. length and liquid
weir plate.
characteristics need to be considered compatibilities are usually excellent.
during system design for sludge
As the oil continues to accumulate
removal as well as cleanout during Wearing components such as flight
the level rises until it spills into the oil
maintenance. shoes, guide strips and other
skimmer reservoir and automatically
components are typically UHMWPE
exits the separator via gravity flow.
Inlet screens can be provided as or XLPE.
required or desired.
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discharge oil concentration of 10
PPM or less with an oil droplet size of
API Features 20 or 30-micron oil droplet.
Some typical API features as dictated
by the API 421 are:
What is the Difference Coalescing Oil Water Separators
- Depth-to-width ratio 0.3-0.5 Between Separator are passive, physical, oil water
- Length-to-width ratio of 5:1 separator systems designed for
- Horizontal velocity no
Types? removal of oils, fuels, hydraulic fluids,
greater than 3 feet per LNAPL and DNAPL products from
second Separator Types water. Environmental's designed
- Removal of oil droplets 150 API421 outlines two types of performance can be described by a
micron & larger separator: 1. API gravity differential combination of Stoke's Law and
- Influent diffuser or reaction separator and 2. API coalescing current coalescing plate theory,
jet design separator. wherein; the oil droplet rise rate and
other parameters dictate the surface
Covers Gravity Separation vs. Coalescing area required for gravity & coalescing
Multi-sectional covers are provided to Plate Separators separation.
contain vapors. Each section is Two basic types of oil water separator
attached to the tank and to exist today in varying types of design, Gravity Separators also referred to
neighboring covers via gasket and but all are derived from these two as API oil water separators are also
bolts. types of design. passive, physical separation devices
where the tank is basically an empty,
Hatches can be provided for The first and oldest type is gravity or baffled design that provides sufficient
inspections without having to remove conventional separation, simple retention time to allow oils to
bolts and heavy cover sections. separation via gravity (density separate. This type of oil water
differential between two immiscible separator is very common and lower
Nitrogen blanketing and GAC liquids leads to one of them rising in performance than a coalescing
vapor/vent scrubbers can be provided above the other). This design, when design.
to remove VOCs from vapor space designed properly (or even
content. improperly) provides a certain tank Separation Process: The water/oil
length, width and depth that provides mixture enters the separator and is
API Performance a wide, quiet spot in the pipeline to spreadout horizontally, distributed
While the API421 guide typically give oils time to rise. This design through an energy and turbulence-
provides for an effluent discharge (also known as an API separator) diffusing device. The mixture enters
performance of 100 mg/L, 150 micron generally provides a discharge oil the Flopak coalescing media where
oil droplets it is possible with a concentration of +/-100 PPM based laminar and sinusoidal flow is
properly designed API to provide on a 150-micron droplet size. The API established and the oils impinge on
performance in the 50 mg/L and type design relies on a large water the media surface. As oils
larger range. volume shaped as dictated by the accumulate they coalesce into larger
These performance figures are API–421 criteria to maximize droplets, rising upward through the
typically independent of the influent separation. pack corrugations until they reach the
concentrations and are calculated as top of the pack, where they detach
if in an ideal environment, which is The API design has its origin in the and rise to the water's surface. At the
not accurate to real-world experience. refineries of the world where the same time solids encounter the
Actual performance is highly excess volumes are advantageous media and slide down the
dependent on the type of waste for reducing a wide variety of oil & corrugations, falling into the v-hopper
entering the separator and the solids types and characteristics. under the Flopak media.
conditions within the separator.
The coalescing design is known by Stoke's Law: This equation relates
System Considerations many names i.e. parallel plate the terminal settling or rise velocity of
The API separator is not a complete interceptor, corrugated plate a smooth, rigid sphere in a viscous
system in and of itself. A full interceptor, slant rib coalescer so on fluid of known density and viscosity to
treatment system also consists of and so forth. However, the concept, the diameter of the sphere when
peripheral components such as operation and design are generally subjected to a known force field
sludge pumps, oil pumps, feed the same. The coalescing concept is (gravity). The equation is:
pumps, walkways, alarms and other based on having a large surface area
components needed to complete the in contact with the wastestream
application. (coalescing plates). The more surface
area provided, the more enhanced
Tank Construction the separation process will typically
The API design can be provided as a be. By using the coalescing media,
factory assembled, A36 coated the size of the tank is reduced and a
carbon steel design for above or higher performance is attained than
below grade or concrete for below by gravity separation. Pan America's
ground installations. Flopak coalescing design provides a
Industrial Wastewater Engineering Solutions
V = (2gr²)(d1-d2)/9µ of accumulating solids. Plates are to into contact with the water molecule.
where be angled at 60° from the horizontal. The chemical being the bridge
V = velocity of rise (cm sec-¹), between the water and oil holds it in a
g = acceleration of gravity (cm sec-²), Flopak Coalescing Media Design stable, permanent or semi-permanent
r = "equivalent" radius of particle Pan America's Flopak coalescing state.
(cm), media provides a laminar flow path
dl = density of particle (g cm -³), that creates a quiescent zone to Dissolved: The oils are dissolved
d2 = density of medium (g cm-³), and facilitate the impact with and into solution with the water due to
µ = viscosity of medium (dyne sec attachment of oils to the media their innate characteristics, nature
cm-²). surface by reducing waste stream and external influences.
turbulence and velocity. This control
Coalescence: Gravity separation of the waste stream creates a more Crude Oils
utilizes the difference in specific ideal environment for oil removal. Crude oil is classified by its
gravity between the oil and water. Oil By virtue of our Flopak media design, characteristics.
separates from a fluid at a rate solids will also collide with the media
explained by Stoke's Law. The and settle to the separator bottom to
some degree, depending on the Class A: Light, Volatile Oils. these
formula predicts how fast an oil oils are highly fluid, often clear,
droplet will rise or settle through solids characteristics and loading.
Due to oil typically being lighter than spread rapidly on solid or water
water based on the density and size surfaces, have a strong odor, a high
of the oil droplet size and the distance water, they (oils) will rise up the
coalescing plate. As the oil droplets evaporation rate, and are usually
the object must travel. flammable. They penetrate porous
rise up the plate they will coalesce or
come together with other droplets, surfaces such as dirt and sand, and
Our separators are built to exploit the may be persistent in such a matrix.
variables of Stokes Law. creating progressively larger droplets.
Once the droplet size is sufficient or They do not tend to adhere to
With the use of our Flopak media oil surfaces; flushing with water
only need rise a short distance before the droplet reaches the top of the
media plate the droplet pulls away generally removes them. Class A oils
encountering the oleophilic, may be highly toxic to humans, fish,
coalescing media plates inside the from the plate and rises to the water
surface. To some degree, the solids and other biota. Most refined
separation chamber as opposed to products and many of the highest
rising a great distance in gravity replicate this process in reverse
(settling). quality light crudes can be included in
separation before reaching the this class.
water’s surface. Upon impinging on
the plates the oils coalesce (gather)
into larger droplets until the droplet Oil Descriptions Class B: Non-Sticky Oils. These oils
buoyancy is sufficient to pull away have a waxy or oily feel. Class B oils
from the media and rise to the water's are less toxic and adhere more firmly
Oils and fuels can exist in a variety
surface. The design will meet to surfaces than Class A oils,
of states depending on the forces
particular design criteria as indicated although they can be removed from
exerted on them.
below: surfaces by vigorous flushing. As
temperatures rise, their tendency to
Free Oils: Oils in a natural state will
penetrate porous substrates
typically be a “free and/or dispersed”
⇒The hydraulic distribution of the increases and they can be persistent.
product, meaning it will maintain its
influent flow must assure full usage Evaporation of volatiles may lead to a
typical characteristics, (oily,
of the cross-sectional area of the Class C or D residue. Medium to
hydrophobic) and will eventually form
media to fully utilize the plate pack's heavy paraffin-based oils fall into this
surface area. into a layer separate from the water
class.
phase. The free phase oil can also be
⇒Flow control and direction must be “dispersed” or spread throughout the
Class C: Heavy, Sticky Oils. Class C
determined to prevent hydraulic short body of the water due to being broken
oils are characteristically viscous,
circuiting around, under or over the into a range of droplet sizes.
media pack. sticky or tarry, and brown or black.
Flushing with water will not readily
Dispersed Oils: Are oil droplets that
⇒A laminar flow condition must be remove this material from surfaces,
have been spread throughout the
maintained (Reynolds "Re" number but the oil does not readily penetrate
body of the water due to an oil droplet
less than 500) in order to assist porous surfaces. The density of Class
droplets to rise. Per the American smaller than the free droplet.
C oils may be near that of water and
Petroleum Institute’s (API) they often sink. Weathering or
Publication 421 of February 1990. Emulsions: oils can be changed to
evaporation of volatiles may produce
an “emulsified” state where the oil
solid or tarry Class D oil. Toxicity is
⇒Horizontal flow through velocities droplet size is drastically reduced and
in the separator must not exceed 3 low, but wildlife can be smothered or
with it, it’s electrical strength. This is
feet per minute or 15 times the rate drowned when contaminated. This
achieved by mechanical shearing
of rise of the droplets whichever is class includes residual fuel oils and
forces where the reduced oil
smaller. medium to heavy crudes.
molecule becomes a temporary
⇒The media containment chamber companion to water molecule or by a
design, plate design/angle and third, chemical component that
spacing sufficient to facilitate removal controls the oil molecule and forces it
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Class D: Non fluid Oils. Class D oils
are relatively non-toxic, do not
penetrate porous substrates, and are
usually black or dark brown in color.
When heated, Class D oils may melt
and coat surfaces making cleanup
very difficult. Residual oils, heavy
crude oils, some high paraffin oils,
and some weathered oils fall into this
class.

These classifications are dynamic in


that the characteristics can change
depending on temperature or
evaporation or other conditions. So, Custom twin APIs
one class can become another and
can also revert to its class depending
on external influences.

Reference System Photos

API before paint


Concrete API-CPI 6,000 GPM

Elevated API combined with CRT chemical treatment system and DAF

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