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0%
70.0%
50.0%
A%
A%
40.0% Exponential (A
%)
30.0%
20.0%
10.0%
0.0%
0.00 20.00 40.00 60.00 80.00 100.00 120.00 140.00 160.00
Co (mg/L)
25.00
15.00
q
Polynomial (q)
10.00
5.00
0.00
0.00 20.00 40.00 60.00 80.00 100.00 120.00 140.00 160.00
Co (mg/L)
0.0450
0.0300
0.0250 k
Linear (k)
0.0200
0.0150
0.0100
0.0050
0.0000
0.00 20.00 40.00 60.00 80.00 100.00 120.00 140.00 160.00
Co (mg/L)
140.00
100.00
80.00
Ce
Polynomial (Ce)
60.00
40.00
20.00
0.00
0.00 20.00 40.00 60.00Co (mg/L)
80.00 100.00120.00140.00160.00
A4 A3 A2 A1 methylene blue 1st αραιωση 5:100 20
0.2941 -1.1677 1.6979 2.9839 2nd-3rd αραιωση 10:100 10
Pretreated Wheat Straw Diethylene glycol 160˚C 40 min H2O: Βρύσης4th-6th αραιωση 100:100 1
t (min) C1 C2 C3 C4 C5 C6
0 149.27 75.26 29.90 14.53 7.78 2.06
5 150.13 72.47 26.50 10.67 5.83 1.07
10 147.47 70.46 23.39 9.09 5.09 0.86
15 147.28 70.00 23.30 8.43 4.68 0.69
20 143.36 66.92 23.38 7.81 4.29 0.61
25 145.12 66.14 23.15 7.54 4.16 0.55
30 147.34 66.21 22.73 7.32 3.87 0.51 αραιώσεις 1000 500 200 90 50 20
35 142.44 65.98 22.26 6.90 3.69 0.47 1000 1000 1000 1000 1000 1000
40 144.69 66.59 20.89 6.71 3.54 0.45 Co 156.0 78.0 31.2 14.0 7.8 3.1
45 145.12 65.73 20.35 6.32 3.26 0.45
50 145.18 66.81 19.99 6.07 3.20 0.43
55 143.73 65.40 19.67 5.89 3.08 0.43
60 144.44 64.80 19.42 5.77 2.87 0.40
65 143.24 65.11 18.96 5.54 2.76 0.41
70 143.36 64.82 18.44 5.43 2.65 0.39
75 130.65 64.59 18.15 5.21 2.50 0.37
80 140.40 64.46 17.98 5.16 2.57 0.37
85 142.47 63.61 17.97 5.01 2.57 0.41
90 138.23 62.23 17.81 4.96 2.43 0.40
95 140.28 61.59 17.63 4.89 2.38 0.41
t (min) pH 1 pH 2 pH 3 pH 4 pH 5 pH 6
0 8.00 8.00 8.00 8.00 8.00 8.00
5 8.00 8.00 8.00 8.00 8.00 8.00
10 8.00 8.00 8.00 8.00 8.00 8.00
15 8.00 8.00 8.00 8.00 8.00 8.00
20 8.00 8.00 8.00 8.00 8.00 8.00
25 8.00 8.00 8.00 8.00 8.00 8.00
30 8.00 8.00 8.00 8.00 8.00 8.00
35 8.00 8.00 8.00 8.00 8.00 8.00
40 8.00 8.00 8.00 8.00 8.00 8.00
45 8.00 8.00 8.00 8.00 8.00 8.00
50 8.00 8.00 8.00 8.00 8.00 8.00
55 8.00 8.00 8.00 8.00 8.00 8.00
60 8.00 8.00 8.00 8.00 8.00 8.00
65 8.00 8.00 8.00 8.00 8.00 8.00
70 8.00 8.00 8.00 8.00 8.00 8.00
75 8.00 8.00 8.00 8.00 8.00 8.00
80 8.00 8.00 8.00 8.00 8.00 8.00
85 8.00 8.00 8.00 8.00 8.00 8.00
90 8.00 8.00 8.00 8.00 8.00 8.00
95 8.00 8.00 8.00 8.00 8.00 8.00
μ.ο. 8 8 8 8 8 8
20:1000
abs1 abs 2 abs3
0.570 0.567
0.312 0.314
0.254 0.257
0.210 0.211
0.189 0.186
0.171 0.167
0.153 0.163
0.147 0.148
0.136 0.143
0.140 0.141
0.136 0.133
0.133 0.138
0.125 0.125
0.13 0.130
0.121 0.126
0.115 0.120
0.113 0.119
0.130 0.130
0.128 0.124
0.130 0.125
C=156 C=78 C=31 C=14 C=7,8 C=3,1 C=156 C=78 C=31 C=14 C=7,8 C=3,1 C=156 C=78 C=31 C=14
t (min) mg/L mg/L mg/L mg/l mg/l mg/l mg/L mg/L mg/L mg/l mg/l mg/l mg/L mg/L mg/L mg/l
0 149.3 75.3 29.9 14.5 7.8 2.1 149.9 72.6 30.0 13.1 7.6 1.0 0.003932 -0.03662 0.002388 -0.10608
5 150.1 72.5 26.5 10.7 5.8 1.1 149.0 71.6 28.0 11.6 6.6 0.9 -0.00181 0.001795 0.115651 0.187271
10 147.5 70.5 23.4 9.1 5.1 0.9 148.1 70.6 26.3 10.3 5.8 0.8 0.015963 0.029498 0.219496 0.307874
15 147.3 70.0 23.3 8.4 4.7 0.7 147.3 69.7 24.9 9.3 5.2 0.7 0.017222 0.035762 0.222633 0.358093
20 143.4 66.9 23.4 7.8 4.3 0.6 146.5 69.0 23.7 8.5 4.6 0.6 0.043369 0.078261 0.219944 0.40554
25 145.1 66.1 23.1 7.5 4.2 0.5 145.8 68.2 22.7 7.8 4.2 0.6 0.03161 0.088957 0.227562 0.426195
30 147.3 66.2 22.7 7.3 3.9 0.5 145.0 67.6 21.8 7.3 3.8 0.5 0.016803 0.087951 0.241443 0.442829
35 142.4 66.0 22.3 6.9 3.7 0.5 144.3 67.0 21.1 6.8 3.6 0.5 0.049515 0.091168 0.257098 0.47428
40 144.7 66.6 20.9 6.7 3.5 0.4 143.7 66.4 20.5 6.4 3.3 0.5 0.034508 0.082709 0.303048 0.48887
45 145.1 65.7 20.4 6.3 3.3 0.4 143.0 65.9 20.0 6.1 3.1 0.5 0.03161 0.094579 0.320838 0.518829
50 145.2 66.8 20.0 6.1 3.2 0.4 142.4 65.4 19.6 5.9 3.0 0.4 0.031195 0.079678 0.332827 0.538076
55 143.7 65.4 19.7 5.9 3.1 0.4 141.8 65.0 19.2 5.7 2.9 0.4 0.040903 0.099184 0.343471 0.551809
60 144.4 64.8 19.4 5.8 2.9 0.4 141.3 64.6 18.9 5.5 2.8 0.4 0.036162 0.107362 0.351887 0.560685
65 143.2 65.1 19.0 5.5 2.8 0.4 140.7 64.2 18.7 5.4 2.7 0.4 0.044191 0.103178 0.367369 0.577835
70 143.4 64.8 18.4 5.4 2.6 0.4 140.2 63.9 18.4 5.3 2.6 0.4 0.043369 0.107163 0.384583 0.58628
75 130.7 64.6 18.2 5.2 2.5 0.4 139.7 63.6 18.3 5.2 2.6 0.4 0.12818 0.110345 0.394275 0.60309
80 140.4 64.5 18.0 5.2 2.6 0.4 139.2 63.3 18.1 5.1 2.5 0.4 0.063136 0.112132 0.399997 0.606814
85 142.5 63.6 18.0 5.0 2.6 0.4 138.8 63.1 18.0 5.1 2.5 0.4 0.049311 0.123806 0.400437 0.618428
90 138.2 62.2 17.8 5.0 2.4 0.4 138.3 62.9 17.9 5.0 2.5 0.4 0.077621 0.142848 0.405713 0.621984
95 140.3 61.6 17.6 4.9 2.4 0.4 137.9 62.6 17.8 5.0 2.4 0.4 0.063945 0.151623 0.411864 0.627854
Ce 128.0 60.4 17.3 4.8 2.3 0.4 14% 20% 42% 67% 70% 83%
Co 149.9 72.6 30.0 13.1 7.6 1.0
k 0.0083 0.0177 0.0340 0.0406 0.0417 0.0394
sum 167.0075 27.03749 16.62373 6.057775 1.724678 1.226325
n-p 18 18 18 18 18 18
s 3.046013 1.225595 0.96101 0.580123 0.309541 0.261016
Co Ce k q A%
149.86 128.04 0.0083 21.82 14.6%
72.60 60.36 0.0177 12.24 16.9%
29.97 17.27 0.0340 12.70 42.4%
13.13 4.79 0.0406 8.34 63.5%
7.62 2.34 0.0417 5.28 69.4%
0.98 0.36 0.0394 0.62 63.3%
C=7,8 C=3,1 C=156 C=78 C=31 C=14 C=7,8 C=3,1
mg/l mg/l mg/L mg/L mg/L mg/l mg/l mg/l D1 D2 D3 D4 D5 D6
-0.02164 -1.10288 0 0 0 0.419794 0.871353 0.995988 0.347278 7.069531 0.005122 1.940675 0.027178 1.168682
0.235464 -0.08887 0.005948 0.014256 0.066313 0.495554 0.885926 1.001846 1.351724 0.818381 2.186127 0.857318 0.63871 0.039262
0.331414 0.127736 0.011654 0.027307 0.122246 0.557051 0.897891 0.983715 0.417034 0.025295 8.493527 1.582937 0.522275 0.005928
0.38545 0.292978 0.017126 0.039254 0.169423 0.606969 0.907714 0.98243 0.000208 0.064265 2.542748 0.803049 0.229313 0.000103
0.43643 0.375809 0.022375 0.050191 0.209215 0.64749 0.915779 0.955755 9.899022 4.152884 0.103384 0.469825 0.112343 0.000892
0.45422 0.441573 0.027409 0.060203 0.242778 0.680381 0.9224 0.967752 0.396316 4.357569 0.207921 0.076264 0.001505 0.001926
0.492483 0.480296 0.032238 0.069368 0.271087 0.70708 0.927836 0.982858 5.350308 1.819948 0.789189 0.003702 0.000411 0.001634
0.516158 0.516985 0.036869 0.077758 0.294965 0.728752 0.932299 0.949485 3.591528 0.947683 1.287746 0.010237 0.015501 0.001796
0.535592 0.544754 0.041311 0.085439 0.315105 0.746344 0.935963 0.964795 1.039297 0.039279 0.130568 0.078188 0.043035 0.001737
0.57236 0.541292 0.045572 0.092471 0.332093 0.760624 0.938972 0.967752 4.377972 0.023433 0.113764 0.035427 0.013185 0.000236
0.580356 0.562028 0.049659 0.098907 0.346421 0.772216 0.941442 0.968175 7.655901 1.948906 0.165964 0.033117 0.042486 0.000285
0.595549 0.558579 0.053578 0.1048 0.358507 0.781625 0.943469 0.958271 3.608266 0.16623 0.203038 0.041144 0.045762 3.83E-06
0.623526 0.594671 0.057338 0.110194 0.3687 0.789262 0.945134 0.963108 10.0709 0.042271 0.253863 0.062754 0.01021 0.00043
0.638169 0.57752 0.060944 0.115132 0.377298 0.795462 0.946501 0.954917 6.303479 0.753167 0.088544 0.025385 0.005026 4.21E-05
0.652532 0.599803 0.064403 0.119653 0.38455 0.800494 0.947623 0.955755 9.935444 0.822146 9.57E-07 0.024911 0.000759 4.63E-05
0.672184 0.620274 0.06772 0.123791 0.390667 0.804579 0.948544 0.869233 82.09008 0.952902 0.011693 0.000696 0.004698 0.000394
0.66316 0.625377 0.070902 0.127579 0.395826 0.807895 0.9493 0.935589 1.354555 1.257631 0.015618 0.002537 0.001915 0.000364
0.662894 0.57752 0.073954 0.131047 0.400178 0.810587 0.949921 0.949694 13.63882 0.276361 6E-05 0.00182 0.006581 0.00106
0.681462 0.591246 0.076882 0.134222 0.403849 0.812772 0.950431 0.920812 0.01227 0.392198 0.003122 0.001665 0.001002 0.000528
0.687288 0.586104 0.079689 0.137128 0.406944 0.814545 0.95085 0.934764 5.567091 1.107405 0.02173 0.006124 0.002784 0.000974
140.0
C (mg/L)
0.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
160.0
150.0
C (mg/L)
140.0
130.0
C=156
mg/L
120.0
110.0
100.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
80.0
75.0
C (mg/L)
70.0
65.0
60.0
55.0
C=78
mg/L
50.0
45.0
40.0
35.0
30.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
35.0
30.0
C (mg/L)
25.0
20.0
C=31
15.0 mg/L
10.0
5.0
0.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
16.0
14.0
C (mg/L)
12.0
10.0
8.0
C=14
mg/l
6.0
4.0
2.0
0.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
9.0
8.0
7.0
C (mg/L)
6.0
5.0
4.0 C=7,8
mg/l
3.0
2.0
1.0
0.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
2.5
2.0
C (mg/L)
1.5
C=3,1
1.0 mg/l
0.5
0.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
C=156 C=78 C=31 C=14 C=7,8 C=3,1
t (min) mg/L mg/L mg/L mg/l mg/l mg/l
0 3.055536 2.701244 2.535562 2.275821 1.695472 0.531453
5 3.095265 2.493955 2.222382 1.772161 1.249978 -0.34608
10 2.966802 2.31233 1.811122 1.458564 1.014937 -0.70292
15 2.957042 2.266247 1.795633 1.292062 0.853338 -1.09912
20 2.729327 1.880653 1.808924 1.104333 0.672454 -1.37843
25 2.838193 1.754631 1.770805 1.010132 0.600752 -1.67392
30 2.960305 1.767185 1.697375 0.92724 0.42654 -1.9001
35 2.667339 1.726473 1.607528 0.748815 0.30126 -2.17515
40 2.812439 1.830156 1.284665 0.653835 0.185223 -2.4491
45 2.838193 1.68141 1.125037 0.424925 -0.07976 -2.41056
50 2.841824 1.864845 1.001015 0.244295 -0.14802 -2.6673
55 2.753164 1.617175 0.876335 0.092008 -0.29216 -2.61975
60 2.797447 1.491805 0.7654 -0.02039 -0.62834 -3.28495
65 2.721263 1.557906 0.522305 -0.28158 -0.86297 -2.91407
70 2.729327 1.49505 0.157038 -0.44053 -1.16324 -3.42924
75 0.960499 1.441865 -0.12832 -0.86052 -1.8156 -4.39443
80 2.514495 1.4107 -0.34513 -0.98338 -1.46319 -4.91384
85 2.669463 1.179059 -0.36393 -1.5072 -1.45449 -2.91407
90 2.321376 0.625338 -0.62209 -1.74393 -2.38549 -3.19908
95 2.504641 0.208485 -1.0427 -2.32543 -3.0438 -3.08259
(C=156 mg/L)
2
C=78 mg/L
1 Linear (C=78
mg/L)
0 C=31 mg/L
0 50 100
-1 Linear (C=31
mg/L)
-2 C=14 mg/l
-3 Linear (C=14
mg/l)
-4 C=7,8 mg/l
-5 Linear (C=7,8
mg/l)
-6 C=3,1 mg/l
t (min)
ln(C-Ce) 3.5
3
2.5
2
1.5
1 C=156 mg/L
0.5
0
0 10 20 30 40 50 60 70 80 90 100
t (min)
ln(C-Ce) 3
2.5
2
1.5
1
0.5 C=78 mg/L
0
0 10 20 30 40 50 60 70 80 90 100
t (min)
ln(C-Ce) 3
2.5
2
1.5
1
0.5
0
-0.5 C=31 mg/L
-1
-1.50 10 20 30 40 t 50 60 70 80 90 100
(min)
3
2
ln(C-Ce)
-1
0 10 20 30 40 50 60 70 80 90 100
C=14 mg/l
-2
-3
t (min)
2
ln(C-Ce)
1
-1
0 10 20 30 40 50 60 70 80 90 100
-2 C=7,8 mg/l
-3
-4
t (min)
ln(C-Ce) 1
0
0 10 20 30 40 50 60 70 80 90100
-1
-2
-3
-4
-5
-6
t (min)
C=156 C=78 C=31 C=14 C=7,8 C=3,1
t (min) mg/L mg/L mg/L mg/l mg/l mg/l
0 -0.02738 0.196584 -0.00565 0.154419 0.03072 1.008931
5 0.012353 -0.01071 -0.31883 -0.34924 -0.41477 0.131393
10 -0.11611 -0.19233 -0.73009 -0.66284 -0.64981 -0.22544
15 -0.12587 -0.23841 -0.74558 -0.82934 -0.81141 -0.62164
20 -0.35359 -0.62401 -0.73229 -1.01707 -0.9923 -0.90095
25 -0.24472 -0.75003 -0.77041 -1.11127 -1.064 -1.19644
30 -0.12261 -0.73747 -0.84384 -1.19416 -1.23821 -1.42262
35 -0.41557 -0.77819 -0.93369 -1.37259 -1.36349 -1.69767
40 -0.27047 -0.6745 -1.25655 -1.46757 -1.47953 -1.97162
45 -0.24472 -0.82325 -1.41618 -1.69648 -1.74451 -1.93308
50 -0.24109 -0.63981 -1.5402 -1.87711 -1.81277 -2.18982
55 -0.32975 -0.88748 -1.66488 -2.02939 -1.95691 -2.14228
60 -0.28547 -1.01286 -1.77582 -2.14179 -2.29309 -2.80747
65 -0.36165 -0.94675 -2.01891 -2.40298 -2.52772 -2.43659
70 -0.35359 -1.00961 -2.38418 -2.56194 -2.82799 -2.95176
75 -2.12241 -1.06279 -2.66953 -2.98192 -3.48035 -3.91695
80 -0.56842 -1.09396 -2.88635 -3.10478 -3.12794 -4.43637
85 -0.41345 -1.3256 -2.90514 -3.62861 -3.11924 -2.43659
90 -0.76154 -1.87932 -3.16331 -3.86534 -4.05024 -2.7216
95 -0.57827 -2.29617 -3.58392 -4.44683 -4.70855 -2.60511
C=78 mg/L
0
0 10 20 30 40 50 60 70 80 90 100 Linear (C=78 mg/L)
C=31 mg/L
-1
Linear (C=31 mg/L)
-2 C=14 mg/l
-3 C=7,8 mg/l
0
0 f(x)10
= - 0.0083413768x
20 30 40 50 60 70 80 90 100
R² = 0.6179235541
-0.5
C=156 mg/L
Linear (C=156 mg/L)
-1
-1.5
-2
-2.5
t (min)
0.5
C=78 mg/L
0
0 f(x)10
= - 0.0176701924x
20 30 40 50 60 70 80 90 100 Linear (C=78 mg/L)
R² = 0.945452189
-0.5
-1
-1.5
-2
-2.5
t (min)
0
0 f(x) 10
= - 0.0340477348x
20 30 40 50 60 70 80 90 100
R² = 0.9901621895
-0.5 C=31 mg/L
Linear (C=31 mg/L)
-1
-1.5
-2
-2.5
-3
-3.5
-4
t (min)
1
0
0 f(x) = 10
- 0.0406177x
20 30 40 50 60 70 80 90 100
R² = 0.9903796338
C=14 mg/l
-1 Linear (C=14 mg/l)
-2
-3
-4
-5
t (min)
1
C=7,8 mg/l
0 Linear (C=7,8 mg/l)
0 f(x) =10
- 0.0417180162x
20 30 40 50 60 70 80 90 100
R² = 0.9863441189
-1
-2
-3
-4
-5
t (min)
2
C=3,1 mg/l
1 Linear (C=3,1 mg/l)
0
0 f(x) = 10
- 0.039445988x
20 30 40 50 60 70 80 90 100
R² = 0.9299770554
-1
-2
-3
-4
-5
t (min)
25.0
20.0
T (oC)
T(oC) 1
15.0
T(oC) 2
T(oC) 3
T(oC) 4
T(oC) 5
10.0
T(oC) 6
5.0
0.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
9.00
8.00
7.00
6.00
pH
1
pH
5.00 pH
2
pH
4.00 3
pH
4
3.00
2.00
1.00
0.00
0 10 20 30 40 50 60 70 80 90 100
t (min)