100.

0%

90.0% f(x) = 0.936669081 exp( - 0.0045818474 x )

R² = 0.9319469638
80.0%

70.0%

60.0%
A%

A%
50.0% Exponential (A
%)
40.0%

30.0%

20.0%

10.0%

0.0%
0.00 20.00 40.00 60.00 80.00 100.00 120.00 140.00 160.00
Co (mg/L)
 70.00

f(x) = - 0.0039207111x^2 + 1.0200931884x - 0.9304807086

60.00 R² = 0.997888805
q (mg/g)

50.00

40.00
q
Polynomial (q)
30.00

20.00

10.00

0.00
0.00 20.00 40.00 60.00 80.00 100.00 120.00 140.00 160.00
Co (mg/L)
 0.06

0.05
k (min-1)

f(x) = - 6.81249461814651E-05x + 0.0442417575

0.04 R² = 0.3719274885

k
0.03 Linear (k)

0.02

0.01

0
0.00 20.00 40.00 60.00 80.00 100.00 120.00 140.00 160.00
Co (mg/L)
 80.00

70.00
f(x) = 0.0039207111x^2 - 0.0200931884x + 0.9304807086
Ce (mg/L)

R² = 0.9980825119
60.00

50.00

Ce
40.00 Polynomial (Ce)

30.00

20.00

10.00

0.00
0.00 20.00 40.00 60.00Co80.00
(mg/L)
100.00 120.00 140.00 160.00
A4 A3 A2 A1 methylene blue 1st-3rd αραιωση 5:100 20
0.2941 -1.1677 1.6979 2.9839 4th-6th αραιωση 100:100 1
Untreated Wheat Straw H2O: Substitute Seawater

1 lt methylene blue αχυρο (g) 1.00

προσρόφηση σε θ=23C V (L) 1.00
ημερομηνια 4/16/2015
αραιώσεις 1000:1000 500:1000 200:1000 90:1000 50:1000
t (min) abs 1 abs 2 abs 3 abs 1 abs 2 abs 3 abs1 abs2 abs3 abs1 abs 2 abs3 abs1 abs 2 abs3
0 1.802 1.813 1.783 1.028 1.081 1.114 0.375 0.404 0.413 2.340 2.329 1.579 1.582
5 1.736 1.740 1.709 0.989 1.046 1.050 0.354 0.358 0.383 2.286 2.301 1.555 1.564
10 1.823 1.812 1.809 0.977 0.989 1.024 0.374 0.371 0.376 2.265 2.277 1.561 1.560
15 1.698 1.697 1.687 1.008 1.075 1.011 0.375 0.378 0.391 2.278 2.249 1.580 1.564
20 1.761 1.748 1.765 0.977 0.989 1.024 0.386 0.378 0.395 2.281 2.240 1.546 1.548
25 1.720 1.720 1.713 1.008 1.075 0.999 0.364 0.369 0.378 2.249 2.250 1.550 1.554
30 1.796 1.824 1.819 0.957 0.971 1.009 0.384 0.382 0.413 2.256 2.249 1.547 1.546
35 1.749 1.752 1.776 0.947 1.037 0.989 0.397 0.397 0.405 2.254 2.237 1.545 1.538
40 1.837 1.821 1.812 0.985 0.944 1.005 0.369 0.369 0.381 2.248 2.244 1.536 1.533
45 1.745 1.746 1.745 0.965 1.048 1.054 0.371 0.381 0.454 2.251 2.229 1.530 1.529
50 1.756 1.681 1.680 0.958 1.044 1.050 0.376 0.380 0.388 2.236 2.222 1.529 1.517
55 1.737 1.747 1.780 0.967 1.048 1.044 0.371 0.367 0.375 2.250 2.226 1.514 1.512
60 1.815 1.802 1.790 0.947 1.028 1.030 0.412 0.405 0.416 2.215 2.181 1.523 1.515
65 1.746 1.750 1.756 0.975 0.989 1.075 0.364 0.365 0.376 2.219 2.198 1.513 1.527
70 1.800 1.802 1.785 0.958 1.013 1.009 0.359 0.359 0.363 2.209 2.223 1.495 1.492
75 1.609 1.663 1.710 0.917 0.996 0.989 0.372 0.379 0.412 2.204 2.210 1.502 1.501
80 1.588 1.574 1.600 0.938 0.954 0.980 0.377 0.385 0.405 2.226 2.202 1.484 1.465
85 1.757 1.747 1.68 0.926 0.983 0.991 0.349 0.349 0.358 2.189 2.212 1.477 1.483
90 1.565 1.553 1.625 0.991 0.986 0.911 0.363 0.359 0.368 2.206 2.187 1.481 1.478
95 1.712 1.703 1.732 0.999 0.932 0.932 0.378 0.383 0.392 2.211 2.211 1.484 1.491

t (min) ABS Φ1 ABS Φ2 ABS Φ3 ABS Φ4 ABS Φ5 ABS Φ6

0 1.799 1.074 0.397 2.335 1.581 0.799
5 1.728 1.028 0.365 2.294 1.560 0.832
10 1.815 0.997 0.374 2.271 1.561 0.751
15 1.694 1.031 0.381 2.264 1.572 0.729
20 1.758 0.997 0.386 2.261 1.548 0.707
25 1.718 1.027 0.370 2.250 1.552 0.725
30 1.813 0.979 0.393 2.253 1.547 0.702
35 1.759 0.991 0.400 2.246 1.542 0.698
40 1.823 0.978 0.373 2.246 1.535 1.187
 45 1.745 1.022 0.402 2.240 1.530 0.705
50 1.706 1.017 0.381 2.229 1.523 0.688
55 1.755 1.020 0.371 2.238 1.513 0.683
60 1.802 1.002 0.411 2.198 1.519 0.817
65 1.751 1.013 0.368 2.209 1.520 0.653
70 1.796 0.993 0.360 2.216 1.494 0.659
75 1.661 0.967 0.388 2.207 1.502 0.648
80 1.587 0.957 0.389 2.214 1.475 0.647
85 1.728 0.967 0.352 2.201 1.480 0.703
90 1.581 0.963 0.363 2.197 1.480 0.636
95 1.716 0.954 0.384 2.211 1.488 0.630

t (min) C1 C2 C3 C4 C5 C6
0 142.93 82.19 27.75 10.10 6.18 2.99
5 136.49 78.46 25.28 9.82 6.09 3.13
10 144.35 75.89 25.94 9.68 6.10 2.80
15 133.45 78.70 26.52 9.63 6.15 2.71
20 139.16 75.89 26.91 9.61 6.05 2.62
25 135.55 78.38 25.68 9.54 6.06 2.69
30 144.19 74.46 27.42 9.56 6.04 2.60 αραιώσεις 1000 500 200 90 50 20
35 139.25 75.43 27.93 9.52 6.02 2.58 1000 1000 1000 1000 1000 1000
40 145.15 74.38 25.89 9.52 5.99 4.56 Co 156.0 78.0 31.2 14.0 7.8 3.1
45 138.02 77.97 28.11 9.48 5.97 2.61
50 134.48 77.57 26.52 9.42 5.94 2.54
55 138.86 77.76 25.73 9.47 5.90 2.52
60 143.21 76.30 28.81 9.23 5.92 3.06
65 138.50 77.22 25.53 9.29 5.93 2.40
70 142.59 75.62 24.92 9.34 5.82 2.42
75 130.53 73.52 27.01 9.28 5.85 2.38
80 124.23 72.70 27.11 9.32 5.74 2.38
85 136.46 73.46 24.29 9.24 5.76 2.60
90 123.69 73.14 25.15 9.22 5.76 2.33
95 135.37 72.46 26.75 9.30 5.79 2.31

t (min) T(oC) 1 T(oC) 2 T(oC) 3 T(oC) 4 T(oC) 5 T(oC) 6

0 23.0 23.0 23.0 23.0 23.0 23.0
5 23.0 23.0 23.0 23.0 23.0 23.0
10 23.0 23.0 23.0 23.0 23.0 23.0
15 23.0 23.0 23.0 23.0 23.0 23.0
 20 23.0 23.0 23.0 23.0 23.0 23.0
25 23.0 23.0 23.0 23.0 23.0 23.0
30 23.0 23.0 23.0 23.0 23.0 23.0
35 23.0 23.0 23.0 23.0 23.0 23.0
40 23.0 23.0 23.0 23.0 23.0 23.0
45 23.0 23.0 23.0 23.0 23.0 23.0
50 23.0 23.0 23.0 23.0 23.0 23.0
55 23.0 23.0 23.0 23.0 23.0 23.0
60 23.0 23.0 23.0 23.0 23.0 23.0
65 23.0 23.0 23.0 23.0 23.0 23.0
70 23.0 23.0 23.0 23.0 23.0 23.0
75 23.0 23.0 23.0 23.0 23.0 23.0
80 23.0 23.0 23.0 23.0 23.0 23.0
85 23.0 23.0 23.0 23.0 23.0 23.0
90 23.0 23.0 23.0 23.0 23.0 23.0
95 23.0 23.0 23.0 23.0 23.0 23.0
μ.ο. 23 23 23 66 66 23

t (min) pH 1 pH 2 pH 3 pH 4 pH 5 pH 6
0 8.00 8.00 8.00 8.00 8.00 8.00
5 8.00 8.00 8.00 8.00 8.00 8.00
10 8.00 8.00 8.00 8.00 8.00 8.00
15 8.00 8.00 8.00 8.00 8.00 8.00
20 8.00 8.00 8.00 8.00 8.00 8.00
25 8.00 8.00 8.00 8.00 8.00 8.00
30 8.00 8.00 8.00 8.00 8.00 8.00
35 8.00 8.00 8.00 8.00 8.00 8.00
40 8.00 8.00 8.00 8.00 8.00 8.00
45 8.00 8.00 8.00 8.00 8.00 8.00
50 8.00 8.00 8.00 8.00 8.00 8.00
55 8.00 8.00 8.00 8.00 8.00 8.00
60 8.00 8.00 8.00 8.00 8.00 8.00
65 8.00 8.00 8.00 8.00 8.00 8.00
70 8.00 8.00 8.00 8.00 8.00 8.00
75 8.00 8.00 8.00 8.00 8.00 8.00
80 8.00 8.00 8.00 8.00 8.00 8.00
85 8.00 8.00 8.00 8.00 8.00 8.00
90 8.00 8.00 8.00 8.00 8.00 8.00
95 8.00 8.00 8.00 8.00 8.00 8.00
μ.ο. 8 8 8 8 8 8
20:1000
abs1 abs 2 abs3
0.779 0.818
0.807 0.857
0.737 0.764
0.724 0.734
0.696 0.718
0.715 0.735
0.693 0.711
0.689 0.706
0.683 1.690
0.692 0.718
0.682 0.694
0.674 0.691
0.662 0.971
0.653 0.653
0.652 0.665
0.642 0.654
0.643 0.651
0.705 0.701
0.633 0.638
0.635 0.625
 C=156 C=78 C=31 C=14 C=7,8 C=3,1 C=156 C=78 C=31 C=14 C=7,8 C=3,1 C=156 C=78 C=31 C=14
t (min) mg/L mg/L mg/L mg/l mg/l mg/l mg/L mg/L mg/L mg/l mg/l mg/l mg/L mg/L mg/L mg/l
0 142.9 82.2 27.8 10.1 6.2 3.0 144.6 79.7 26.8 9.9 6.2 3.1 0.011217 -0.03078 -0.03376 -0.02468
5 136.5 78.5 25.3 9.8 6.1 3.1 143.4 79.1 26.8 9.8 6.2 3.0 0.055734 0.015942 0.058596 0.003037
10 144.3 75.9 25.9 9.7 6.1 2.8 142.2 78.6 26.7 9.7 6.2 3.0 0.00141 0.048128 0.033937 0.017814
15 133.5 78.7 26.5 9.6 6.1 2.7 141.2 78.1 26.6 9.7 6.1 2.9 0.076787 0.012894 0.012064 0.022674
20 139.2 75.9 26.9 9.6 6.0 2.6 140.2 77.6 26.5 9.6 6.1 2.8 0.037303 0.048128 -0.00223 0.024609
25 135.6 78.4 25.7 9.5 6.1 2.7 139.2 77.1 26.5 9.6 6.0 2.8 0.062264 0.016958 0.04343 0.03166
30 144.2 74.5 27.4 9.6 6.0 2.6 138.3 76.7 26.4 9.6 6.0 2.7 0.00248 0.066094 -0.02132 0.029744
35 139.2 75.4 27.9 9.5 6.0 2.6 137.4 76.3 26.3 9.5 6.0 2.7 0.036678 0.05389 -0.04046 0.034208
40 145.2 74.4 25.9 9.5 6.0 4.6 136.6 75.9 26.3 9.5 6.0 2.6 -0.00417 0.067111 0.035836 0.03389
45 138.0 78.0 28.1 9.5 6.0 2.6 135.8 75.6 26.2 9.4 5.9 2.6 0.045201 0.022039 -0.04716 0.037696
50 134.5 77.6 26.5 9.4 5.9 2.5 135.1 75.3 26.1 9.4 5.9 2.5 0.069664 0.02712 0.012064 0.044623
55 138.9 77.8 25.7 9.5 5.9 2.5 134.4 75.0 26.1 9.4 5.9 2.5 0.039386 0.024749 0.041532 0.038961
60 143.2 76.3 28.8 9.2 5.9 3.1 133.7 74.7 26.0 9.4 5.9 2.5 0.009304 0.043045 -0.07307 0.063797
65 138.5 77.2 25.5 9.3 5.9 2.4 133.1 74.5 25.9 9.3 5.9 2.5 0.041881 0.031524 0.04912 0.057359
70 142.6 75.6 24.9 9.3 5.8 2.4 132.5 74.2 25.9 9.3 5.8 2.4 0.013552 0.051518 0.071843 0.052725
75 130.5 73.5 27.0 9.3 5.9 2.4 131.9 74.0 25.8 9.3 5.8 2.4 0.096968 0.077961 -0.00605 0.058282
80 124.2 72.7 27.1 9.3 5.7 2.4 131.4 73.8 25.8 9.3 5.8 2.4 0.14059 0.088136 -0.00986 0.053964
85 136.5 73.5 24.3 9.2 5.8 2.6 130.8 73.6 25.7 9.3 5.8 2.4 0.05594 0.07864 0.095445 0.06227
90 123.7 73.1 25.1 9.2 5.8 2.3 130.3 73.4 25.7 9.2 5.8 2.4 0.144313 0.082709 0.063329 0.064712
95 135.4 72.5 26.8 9.3 5.8 2.3 129.9 73.3 25.6 9.2 5.8 2.4 0.063534 0.091188 0.003491 0.055818

Ce 121.2 71.0 23.8 9.0 5.6 2.3 15% 14% 14% 11% 9% 24%
Co 144.6 79.7 26.8 9.9 6.2 3.1
k 0.0104 0.0142 0.0054 0.0152 0.0152 0.0224
sum 646.1227 59.32918 27.91925 0.110728 0.039055 4.320957
n-p 18 18 18 18 18 18
s 5.991302 1.815507 1.245419 0.078432 0.046581 0.489952

Co Ce k q A%
135.07 69.98 0.033049 65.09 48.2%
69.73 17.41 0.04212 52.31 75.0%
26.58 5.43 0.043876 21.14 79.6%
12.25 0.86 0.04912 11.40 93.0%
7.01 0.60 0.043631 6.41 91.4%
2.84 0.39 0.036387 2.45 86.4%
C=7,8 C=3,1 C=156 C=78 C=31 C=14 C=7,8 C=3,1
mg/l mg/l mg/L mg/L mg/L mg/l mg/l mg/l D1 D2 D3 D4 D5 D6
0.008683 0.046679 0 0 0 0.367163 0.497044 0.996424 2.629226 6.022601 0.821365 0.059132 0.002933 0.021438
0.022937 0.003303 0.008199 0.007516 0.00303 0.371707 0.511935 0.982232 47.21438 0.451381 2.225652 0.000922 0.009656 0.006808
0.02226 0.108792 0.015981 0.014515 0.005978 0.37592 0.525246 0.99955 4.436048 7.18278 0.563473 0.003526 0.002759 0.027347
0.014462 0.136587 0.023368 0.021033 0.008848 0.379825 0.537143 0.97552 59.62553 0.421105 0.007455 0.003081 0.001196 0.031811
0.030711 0.165004 0.030379 0.027103 0.011642 0.383444 0.547777 0.988107 1.001756 2.810304 0.138703 0.000707 0.000966 0.040469
0.02801 0.141756 0.037035 0.032756 0.014361 0.386799 0.557282 0.98015 13.2998 1.586529 0.609111 0.002666 0.000355 0.004757
0.031723 0.171458 0.043353 0.03802 0.017007 0.38991 0.565778 0.999209 34.90705 5.010147 1.059089 7.14E-05 0.000693 0.011914
0.035095 0.177265 0.049349 0.042923 0.019583 0.392793 0.573372 0.988307 3.354942 0.764611 2.598456 6.95E-06 0.001136 0.006401
0.03981 -0.45474 0.055042 0.047489 0.02209 0.395465 0.58016 1.001328 73.24837 2.447621 0.136215 0.001693 0.000939 3.782006
0.043172 0.167586 0.060445 0.051741 0.02453 0.397943 0.586227 0.98559 4.855316 5.608313 3.70499 0.001326 0.001162 0.000932
0.047538 0.18952 0.065573 0.055701 0.026905 0.400239 0.59165 0.977791 0.349713 5.192805 0.158761 2.16E-06 0.00087 1.98E-05
0.054243 0.196612 0.070442 0.059389 0.029217 0.402368 0.596498 0.987443 20.15216 7.627939 0.109328 0.006804 7.49E-05 1.25E-05
0.050222 0.023373 0.075063 0.062823 0.031467 0.404342 0.60083 0.997034 90.35269 2.486694 7.877403 0.018549 0.002828 0.32942
0.049551 0.234604 0.079449 0.066021 0.033656 0.406171 0.604703 0.986648 29.48988 7.565126 0.172369 0.00236 0.005683 0.004155
0.067278 0.227527 0.083612 0.069 0.035788 0.407867 0.608165 0.99568 102.5622 1.942902 0.93707 0.00038 0.00034 0.000428
0.061936 0.241034 0.087564 0.071774 0.037863 0.409438 0.611259 0.969086 1.847518 0.243391 1.38971 0.000211 0.000921 0.001914
0.079931 0.24232 0.091316 0.074357 0.039882 0.410895 0.614024 0.955179 50.73214 1.206898 1.783719 0.002234 0.004558 0.000932
0.076273 0.170167 0.094877 0.076763 0.041847 0.412246 0.616496 0.982166 31.67843 0.022394 2.070808 0.000281 0.000985 0.044607
0.076605 0.2571 0.098257 0.079003 0.04376 0.413498 0.618706 0.953992 44.32311 0.087312 0.276047 0.000591 0.000446 0.002275
0.071278 0.264163 0.101465 0.08109 0.045622 0.414659 0.620681 0.979745 30.06237 0.648327 1.279529 0.006185 0.000554 0.00331

646.1227 59.32918 27.91925 0.110728 0.039055 4.320957

 160.0

140.0
C (mg/L)

120.0 C=156 mg/L

C=78 mg/L
100.0 C=31 mg/L
C=14 mg/l
80.0 C=7,8 mg/l
C=3,1 mg/l
60.0 C=156 mg/L
C=78 mg/L
40.0 C=31 mg/L
C=14 mg/l

20.0 C=7,8 mg/l

C=3,1 mg/l

0.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 150.0
145.0
C (mg/L)

140.0
135.0
130.0
125.0
C=156
mg/L
120.0
115.0
110.0
105.0
100.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 90.0

80.0
C (mg/L)

70.0

60.0
C=78
mg/L

50.0

40.0

30.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 30.0

29.0
C (mg/L)

28.0

27.0

26.0
C=31
mg/L
25.0

24.0

23.0

22.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 12.0
C (mg/L)

10.0
C=14
mg/l

8.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 6.3

6.2

6.1
C (mg/L)

6.0

5.9

5.8 C=7,8
mg/l
5.7

5.6

5.5

5.4
0 10 20 30 40 50 60 70 80 90 100
t (min)
 5.0

4.5

4.0
C (mg/L)

3.5

3.0

2.5
C=3,1
2.0 mg/l

1.5

1.0

0.5

0.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 C=156 C=78 C=31 C=14 C=7,8 C=3,1
t (min) mg/L mg/L mg/L mg/l mg/l mg/l
0 3.077908 2.413577 1.374873 0.063207 -0.58143 -0.31698
5 2.726417 2.008038 0.388713 -0.23301 -0.75459 -0.14572
10 3.141156 1.585642 0.759462 -0.43614 -0.74565 -0.62827
15 2.504289 2.040146 1.002238 -0.51311 -0.64806 -0.8067
20 2.887154 1.585642 1.134027 -0.54549 -0.86341 -1.02948
25 2.662641 1.997102 0.632475 -0.67322 -0.82424 -0.8437
30 3.134449 1.238379 1.286692 -0.63686 -0.87849 -1.08782
35 2.89218 1.486825 1.419363 -0.72369 -0.93045 -1.1434
40 3.17541 1.214593 0.735311 -0.71725 -1.00792 0.833406
45 2.821413 1.940549 1.461987 -0.79721 -1.0671 -1.05241
50 2.585082 1.880599 1.002238 -0.9615 -1.14956 -1.27192
55 2.870234 1.909024 0.659184 -0.82525 -1.29112 -1.35461
60 3.090564 1.66539 1.611461 -1.6432 -1.20384 -0.22134
65 2.849578 1.825562 0.547823 -1.35943 -1.18999 -1.97415
70 3.062245 1.528705 0.112798 -1.19577 -1.64159 -1.82587
75 2.231914 0.917814 1.166454 -1.3955 -1.48288 -2.13109
80 1.102607 0.526268 1.197877 -1.23696 -2.1649 -2.16566
85 2.724468 0.89598 -0.72213 -1.56822 -1.98358 -1.07588
90 0.905756 0.753897 0.298613 -1.69096 -1.99878 -2.6836
95 2.649751 0.37102 1.083351 -1.30196 -1.7795 -3.0756

Ce 121.2163 71.01136 23.8002 9.032812 5.623285 2.261941

Co 144.5507 79.73113 26.84849 9.854888 6.236536 3.136703
ln(Co-Ce) 3.1499 2.1656 1.1146 -0.1959 -0.4890 -0.1338
k 0.0104 0.0142 0.0054 0.0152 0.0152 0.0224
R -0.5016 -0.7547 -0.2878 -0.9256 -0.9343 -0.7188
R^2 0.2516 0.5696 0.0828 0.8567 0.8729 0.5167
 4
C=156 mg/L
3 Linear
ln(C-Ce)

(C=156 mg/L)
2 C=78 mg/L
Linear (C=78
1 mg/L)
C=31 mg/L
0 Linear (C=31
0 50 100 mg/L)
-1 C=14 mg/l
Linear (C=14
-2 mg/l)
C=7,8 mg/l
-3 Linear (C=7,8
mg/l)
-4 C=3,1 mg/l
t (min)
ln(C-Ce) 3.5
3
2.5
2
1.5
1 C=156 mg/L
0.5
0
0 10 20 30 40 50 60 70 80 90 100
t (min)
ln(C-Ce) 3
2.5
2
1.5
1
0.5 C=78 mg/L
0
0 10 20 30 40 50 60 70 80 90 100
t (min)
ln(C-Ce) 2
1.5
1
0.5
0
C=31 mg/L
-0.5
-1
0 10 20 30 40 t 50
(min)
60 70 80 90 100
 0.2
0
ln(C-Ce)
-0.2
-0.4
-0.6
-0.8
-1
-1.2 0 10 20 30 40 50 60 70 80 90 100
-1.4 C=14 mg/l
-1.6
-1.8
t (min)
 0
ln(C-Ce)
-0.5

-1
0 10 20 30 40 50 60 70 80 90 100
-1.5
C=7,8 mg/l
-2

-2.5

t (min)
 1.5
1
ln(C-Ce)

0.5
0
-0.50 10 20 30 40 50 60 70 80 90100
-1
-1.5
-2
-2.5
-3
-3.5

t (min)
 C=156 C=78 C=31 C=14 C=7,8 C=3,1
t (min) mg/L mg/L mg/L mg/l mg/l mg/l
0 -0.07202 0.247985 0.260295 0.259129 -0.09245 -0.18318
5 -0.42351 -0.15755 -0.72587 -0.03709 -0.26561 -0.01191
10 -0.00877 -0.57995 -0.35512 -0.24022 -0.25667 -0.49447
15 -0.64564 -0.12545 -0.11234 -0.31719 -0.15908 -0.6729
20 -0.26278 -0.57995 0.019449 -0.34957 -0.37443 -0.89567
25 -0.48729 -0.16849 -0.4821 -0.47729 -0.33526 -0.7099
30 -0.01548 -0.92721 0.172114 -0.44094 -0.38952 -0.95402
35 -0.25775 -0.67877 0.304785 -0.52776 -0.44147 -1.0096
40 0.025481 -0.951 -0.37927 -0.52132 -0.51894 0.96721
45 -0.32852 -0.22504 0.347409 -0.60129 -0.57812 -0.91861
50 -0.56485 -0.28499 -0.11234 -0.76557 -0.66058 -1.13811
55 -0.2797 -0.25657 -0.45539 -0.62933 -0.80214 -1.2208
60 -0.05937 -0.5002 0.496883 -1.44727 -0.71486 -0.08753
65 -0.30035 -0.34003 -0.56676 -1.16351 -0.70101 -1.84034
70 -0.08768 -0.63689 -1.00178 -0.99984 -1.15261 -1.69206
75 -0.91802 -1.24778 0.051876 -1.19958 -0.9939 -1.99728
80 -2.04732 -1.63932 0.083299 -1.04103 -1.67592 -2.03185
85 -0.42546 -1.26961 -1.8367 -1.37229 -1.4946 -0.94208
90 -2.24417 -1.41169 -0.81596 -1.49503 -1.5098 -2.5498
95 -0.50018 -1.79457 -0.03123 -1.10604 -1.29052 -2.94179

Ce 121.2163 71.01136 23.8002 9.032812 5.623285 2.261941

Co 144.5507 79.73113 26.84849 9.854888 6.236536 3.136703
k 0.0104 0.0142 0.0054 0.0152 0.0152 0.0224
 1.5
ln[(C-Ce)/(Co-Ce)]
1 C=156 mg/L

Linear (C=156 mg/L)

0.5
C=78 mg/L
0
0 10 20 30 40 50 60 70 80 90 100 Linear (C=78 mg/L)

-0.5 C=31 mg/L

-1 Linear (C=31 mg/L)

C=14 mg/l
-1.5
Linear (C=14 mg/l)
-2
C=7,8 mg/l

-2.5 Linear (C=7,8 mg/l)

-3 C=3,1 mg/l

Linear (C=3,1 mg/l)

-3.5
t (min)
0.5

C=156 mg/L
0
0 f(x)10
= - 0.0104246085x
20 30 40 50 60 70 80 90 100 Linear (C=156 mg/L)
R² = 0.5553355951
-0.5

-1

-1.5

-2

-2.5
t (min)
0.5

C=78 mg/L
0 Linear (C=78 mg/L)
0 f(x)10
= - 0.0142390368x
20 30 40 50 60 70 80 90 100
R² = 0.8309579384

-0.5

-1

-1.5

-2
t (min)
 1

C=31 mg/L
0.5
Linear (C=31 mg/L)

0
0 f(x) 10
= - 0.0054092078x
20 30 40 50 60 70 80 90 100
R² = 0.2511233934
-0.5

-1

-1.5

-2
t (min)
0.4

0.2

0
0 f(x) =10
- 0.0152347861x
20 30 40 50 60 70 80 90 100
R² = 0.956895372 C=14 mg/l
-0.2
Linear (C=14 mg/l)

-0.4

-0.6

-0.8

-1

-1.2

-1.4

-1.6
t (min)
 0
0 f(x) =10
- 0.0151657539x
20 30 40 50 60 70 80 90 100
R² = 0.9622906286 C=7,8 mg/l
-0.2
Linear (C=7,8 mg/l)
-0.4

-0.6

-0.8

-1

-1.2

-1.4

-1.6

-1.8
t (min)
1.5
C=3,1 mg/l
1
Linear (C=3,1 mg/l)
0.5

0
0 f(x) =10
- 0.0224470604x
20 30 40 50 60 70 80 90 100
R² = 0.7988208586
-0.5

-1

-1.5

-2

-2.5

-3

-3.5
t (min)
 25.0

20.0
T (oC)

T(oC) 1
15.0
T(oC) 2
T(oC) 3
T(oC) 4
T(oC) 5
10.0
T(oC) 6

5.0

0.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 9.00

8.00

7.00

6.00
pH
1
pH

5.00 pH
2
pH
4.00 3
pH
4
3.00

2.00

1.00

0.00
0 10 20 30 40 50 60 70 80 90 100
t (min)