80.

0%

70.0%
f(x) = 0.6874147609 exp( - 0.0149894374 x )
60.0% R² = 0.9460088001

50.0%
A%

A%
40.0% Exponential (A
%)

30.0%

20.0%

10.0%

0.0%
0.00 20.00 40.00 60.00 80.00 100.00 120.00 140.00
Co (mg/L)
 16.00
f(x) = - 0.0014840518x^2 + 0.2795760798x + 3.0932819498
R² = 0.8042091233
14.00

12.00
q (mg/g)

10.00

q
8.00 Polynomial (q)

6.00

4.00

2.00

0.00
0.00 20.00 40.00 60.00 80.00 100.00 120.00 140.00
Co (mg/L)
 0.0500

0.0450

0.0400 f(x) = - 0.0002616276x + 0.0417374538

k (min-1)

R² = 0.9166410323
0.0350

0.0300
k
0.0250 Linear (k)

0.0200

0.0150

0.0100

0.0050

0.0000
0.00 20.00 40.00 60.00 80.00 100.00 120.00 140.00
Co (mg/L)
 120.00

f(x) = 0.0014840518x^2 + 0.7204239202x - 3.0932819498

R² = 0.9969788659
100.00
Ce (mg/L)

80.00

60.00 Ce
Polynomial (Ce)

40.00

20.00

0.00
0.00 20.00 40.00 Co (mg/L)
60.00 80.00 100.00 120.00 140.00
 A4 A3 A2 A1 methylene blue 1st-3rd αραιωση 5:100 20
0.2941 -1.1677 1.6979 2.9839 4th-6th αραιωση 100:100 1
Pretreated Wheat Straw Diethylene glycol 160˚C 20 min H2O: Βρύσης

1 lt methylene blue αχυρο (g) 1.00

προσρόφηση σε θ=23C V (L) 1.00
ημερομηνια 12/7/2015
αραιώσεις 1000:1000 500:1000 200:1000 90:1000 50:1000
t (min) abs 1 abs 2 abs 3 abs 1 abs 2 abs 3 abs1 abs2 abs3 abs1 abs 2 abs3 abs1 abs 2 abs3
0 1.761 1.777 1.816 0.955 0.959 0.935 0.488 0.485 0.489 2.831 2.844 1.888 1.902
5 1.703 1.708 1.692 0.880 0.870 0.871 0.445 0.445 0.443 2.406 2.399 1.476 1.455
10 1.608 1.594 1.594 0.841 0.853 0.851 0.449 0.446 0.445 2.187 2.199 1.321 1.365
15 1.582 1.585 1.554 0.865 0.860 0.858 0.419 0.436 0.425 2.155 2.161 1.262 1.259
20 1.565 1.567 1.583 0.843 0.840 0.837 0.402 0.400 0.403 1.969 1.966 1.166 1.156
25 1.615 1.607 1.587 0.822 0.828 0.815 0.398 0.393 0.391 1.910 1.895 1.102 1.123
30 1.637 1.629 1.635 0.831 0.833 0.823 0.379 0.378 0.379 1.829 1.843 1.008 1.007
35 1.618 1.624 1.630 0.828 0.822 0.805 0.392 0.387 0.395 1.756 1.769 1.004 1.000
40 1.510 1.506 1.506 0.820 0.82 0.825 0.382 0.377 0.386 1.719 1.706 0.962 0.972
45 1.587 1.577 1.570 0.811 0.799 0.810 0.381 0.399 0.398 1.671 1.674 0.924 0.919
50 1.588 1.589 1.569 0.821 0.811 0.825 0.357 0.351 0.378 1.627 1.629 0.877 0.882
55 1.511 1.457 1.490 0.800 0.794 0.782 0.355 0.348 0.348 1.619 1.610 0.855 0.836
60 1.521 1.511 1.506 0.806 0.797 0.790 0.350 0.343 0.347 1.533 1.547 0.802 0.790
65 1.524 1.542 1.521 0.820 0.809 0.798 0.332 0.332 0.324 1.482 1.483 0.765 0.780
70 1.592 1.583 1.557 0.801 0.796 0.785 0.339 0.334 0.367 1.463 1.468 0.776 0.778
75 1.566 1.563 1.541 0.790 0.788 0.824 0.341 0.348 0.334 1.437 1.456 0.737 0.730
80 1.541 1.548 1.520 0.786 0.778 0.785 0.330 0.325 0.338 1.422 1.437 0.722 0.717
85 1.562 1.566 1.529 0.786 0.785 0.791 0.333 0.314 0.316 1.393 1.401 0.721 0.733
90 1.567 1.563 1.535 0.772 0.766 0.745 0.326 0.319 0.329 1.388 1.383 0.676 0.673
95 1.541 1.538 1.489 0.779 0.772 0.761 0.314 0.318 0.314 1.386 1.385 0.690 0.689

t (min) ABS Φ1 ABS Φ2 ABS Φ3 ABS Φ4 ABS Φ5 ABS Φ6

0 1.785 0.950 0.487 2.838 1.895 0.779
5 1.701 0.874 0.444 2.403 1.466 0.567
10 1.599 0.848 0.447 2.193 1.343 0.504
15 1.574 0.861 0.427 2.158 1.261 0.431
20 1.572 0.840 0.402 1.968 1.156 0.407
25 1.603 0.822 0.394 1.903 1.113 0.370
30 1.634 0.829 0.379 1.836 1.008 0.366
35 1.624 0.818 0.391 1.763 1.002 0.339
40 1.507 0.822 0.382 1.713 0.967 0.327
 45 1.578 0.807 0.393 1.673 0.922 0.306
50 1.582 0.819 0.362 1.628 0.880 0.300
55 1.486 0.792 0.350 1.615 0.846 0.278
60 1.513 0.798 0.347 1.540 0.796 0.283
65 1.529 0.809 0.329 1.483 0.773 0.261
70 1.577 0.794 0.347 1.466 0.777 0.270
75 1.557 0.801 0.341 1.447 0.734 0.259
80 1.536 0.783 0.331 1.430 0.720 0.242
85 1.552 0.787 0.321 1.397 0.727 0.247
90 1.555 0.761 0.325 1.386 0.675 0.251
95 1.523 0.771 0.315 1.386 0.690 0.252

t (min) C1 C2 C3 C4 C5 C6
0 141.58 72.08 34.78 14.53 7.60 2.91
5 134.07 65.91 31.40 10.57 5.70 2.05
10 125.19 63.85 31.58 9.20 5.20 1.80
15 123.07 64.88 30.03 8.99 4.86 1.52
20 122.90 63.18 28.09 7.96 4.44 1.42
25 125.56 61.69 27.50 7.63 4.26 1.28
30 128.20 62.28 26.32 7.32 3.84 1.27 αραιώσεις 1000 500 200 90 50 20
35 127.36 61.42 27.29 6.98 3.82 1.16 1000 1000 1000 1000 1000 1000
40 117.49 61.69 26.55 6.75 3.67 1.12 Co 156.0 78.0 31.2 14.0 7.8 3.1
45 123.44 60.47 27.40 6.58 3.49 1.04
50 123.78 61.47 25.05 6.39 3.32 1.02
55 115.72 59.28 24.16 6.33 3.18 0.94
60 117.94 59.74 23.88 6.01 2.98 0.96
65 119.30 60.66 22.57 5.77 2.88 0.87
70 123.38 59.44 23.88 5.70 2.90 0.91
75 121.63 59.98 23.45 5.62 2.73 0.87
80 119.92 58.55 22.70 5.55 2.67 0.81
85 121.27 58.90 21.95 5.42 2.70 0.82
90 121.49 56.76 22.22 5.37 2.49 0.84
95 118.77 57.55 21.52 5.37 2.55 0.84

t (min) T(oC) 1 T(oC) 2 T(oC) 3 T(oC) 4 T(oC) 5 T(oC) 6

0 23.0 23.0 23.0 23.0 23.0 23.0
5 23.0 23.0 23.0 23.0 23.0 23.0
10 23.0 23.0 23.0 23.0 23.0 23.0
15 23.0 23.0 23.0 23.0 23.0 23.0
 20 23.0 23.0 23.0 23.0 23.0 23.0
25 23.0 23.0 23.0 23.0 23.0 23.0
30 23.0 23.0 23.0 23.0 23.0 23.0
35 23.0 23.0 23.0 23.0 23.0 23.0
40 23.0 23.0 23.0 23.0 23.0 23.0
45 23.0 23.0 23.0 23.0 23.0 23.0
50 23.0 23.0 23.0 23.0 23.0 23.0
55 23.0 23.0 23.0 23.0 23.0 23.0
60 23.0 23.0 23.0 23.0 23.0 23.0
65 23.0 23.0 23.0 23.0 23.0 23.0
70 23.0 23.0 23.0 23.0 23.0 23.0
75 23.0 23.0 23.0 23.0 23.0 23.0
80 23.0 23.0 23.0 23.0 23.0 23.0
85 23.0 23.0 23.0 23.0 23.0 23.0
90 23.0 23.0 23.0 23.0 23.0 23.0
95 23.0 23.0 23.0 23.0 23.0 23.0
μ.ο. 23 23 23 66 66 23

t (min) pH 1 pH 2 pH 3 pH 4 pH 5 pH 6
0 8.00 8.00 8.00 8.00 8.00 8.00
5 8.00 8.00 8.00 8.00 8.00 8.00
10 8.00 8.00 8.00 8.00 8.00 8.00
15 8.00 8.00 8.00 8.00 8.00 8.00
20 8.00 8.00 8.00 8.00 8.00 8.00
25 8.00 8.00 8.00 8.00 8.00 8.00
30 8.00 8.00 8.00 8.00 8.00 8.00
35 8.00 8.00 8.00 8.00 8.00 8.00
40 8.00 8.00 8.00 8.00 8.00 8.00
45 8.00 8.00 8.00 8.00 8.00 8.00
50 8.00 8.00 8.00 8.00 8.00 8.00
55 8.00 8.00 8.00 8.00 8.00 8.00
60 8.00 8.00 8.00 8.00 8.00 8.00
65 8.00 8.00 8.00 8.00 8.00 8.00
70 8.00 8.00 8.00 8.00 8.00 8.00
75 8.00 8.00 8.00 8.00 8.00 8.00
80 8.00 8.00 8.00 8.00 8.00 8.00
85 8.00 8.00 8.00 8.00 8.00 8.00
90 8.00 8.00 8.00 8.00 8.00 8.00
95 8.00 8.00 8.00 8.00 8.00 8.00
μ.ο. 8 8 8 8 8 8
20:1000
abs1 abs 2 abs3
0.794 0.764
0.571 0.562
0.503 0.505
0.434 0.428
0.406 0.407
0.368 0.371
0.361 0.371
0.335 0.342
0.329 0.325
0.303 0.309
0.296 0.303
0.277 0.278
0.289 0.277
0.257 0.264
0.265 0.275
0.250 0.268
0.236 0.248
0.243 0.250
0.249 0.252
0.253 0.250
 C=156 C=78 C=31 C=14 C=7,8 C=3,1 C=156 C=78 C=31 C=14 C=7,8 C=3,1 C=156 C=78 C=31 C=14
t (min) mg/L mg/L mg/L mg/l mg/l mg/l mg/L mg/L mg/L mg/l mg/l mg/l mg/L mg/L mg/L mg/l
0 141.6 72.1 34.8 14.5 7.6 2.9 128.5 67.6 35.9 13.0 7.4 2.4 -0.10177 -0.06556 0.032152 -0.11782
5 134.1 65.9 31.4 10.6 5.7 2.1 127.7 66.6 33.9 11.5 6.5 2.1 -0.04329 0.025652 0.126075 0.186214
10 125.2 63.9 31.6 9.2 5.2 1.8 126.9 65.6 32.1 10.3 5.8 1.9 0.025766 0.056073 0.121003 0.292293
15 123.1 64.9 30.0 9.0 4.9 1.5 126.1 64.7 30.6 9.3 5.2 1.6 0.042308 0.040862 0.164381 0.308198
20 122.9 63.2 28.1 8.0 4.4 1.4 125.4 63.9 29.3 8.5 4.7 1.5 0.043627 0.066081 0.218273 0.387651
25 125.6 61.7 27.5 7.6 4.3 1.3 124.8 63.2 28.1 7.9 4.3 1.4 0.022887 0.088097 0.234721 0.412475
30 128.2 62.3 26.3 7.3 3.8 1.3 124.1 62.5 27.2 7.4 4.0 1.2 0.002407 0.07929 0.267501 0.436917
35 127.4 61.4 27.3 7.0 3.8 1.2 123.5 61.9 26.3 7.0 3.7 1.2 0.008883 0.092099 0.240434 0.462974
40 117.5 61.7 26.6 6.8 3.7 1.1 123.0 61.4 25.6 6.7 3.5 1.1 0.085701 0.088097 0.2611 0.480211
45 123.4 60.5 27.4 6.6 3.5 1.0 122.4 60.9 25.0 6.4 3.3 1.0 0.039449 0.106108 0.237578 0.493756
50 123.8 61.5 25.0 6.4 3.3 1.0 121.9 60.4 24.4 6.2 3.1 1.0 0.036807 0.091299 0.302945 0.508602
55 115.7 59.3 24.2 6.3 3.2 0.9 121.5 60.0 24.0 6.0 3.0 0.9 0.099525 0.123717 0.327635 0.513064
60 117.9 59.7 23.9 6.0 3.0 1.0 121.0 59.6 23.6 5.9 2.9 0.9 0.082236 0.116914 0.335373 0.537385
65 119.3 60.7 22.6 5.8 2.9 0.9 120.6 59.3 23.2 5.7 2.8 0.9 0.0716 0.103307 0.371812 0.555864
70 123.4 59.4 23.9 5.7 2.9 0.9 120.2 58.9 22.9 5.6 2.8 0.9 0.039889 0.121316 0.335373 0.561288
75 121.6 60.0 23.5 5.6 2.7 0.9 119.8 58.7 22.7 5.6 2.7 0.9 0.053494 0.113312 0.347312 0.567331
80 119.9 58.5 22.7 5.6 2.7 0.8 119.5 58.4 22.5 5.5 2.7 0.8 0.066813 0.13452 0.368319 0.572723
85 121.3 58.9 21.9 5.4 2.7 0.8 119.1 58.1 22.3 5.5 2.6 0.8 0.056338 0.129319 0.389244 0.582995
90 121.5 56.8 22.2 5.4 2.5 0.8 118.8 57.9 22.1 5.4 2.6 0.8 0.054588 0.160921 0.381581 0.586619
95 118.8 57.5 21.5 5.4 2.5 0.8 118.5 57.7 22.0 5.4 2.6 0.8 0.075729 0.149322 0.401064 0.586619

Ce 113.4 55.6 21.1 5.3 2.4 0.8 20% 23% 39% 64% 68% 73%
Co 128.5 67.6 35.9 13.0 7.4 2.4
k 0.0114 0.0184 0.0297 0.0429 0.0388 0.0425
sum 366.4295 34.40922 21.03927 5.195644 1.434167 0.283977
n-p 18 18 18 18 18 18
s 4.511895 1.382615 1.081133 0.537259 0.282269 0.125605

Co Ce k q A%
128.50 113.40 0.0114 15.10 11.8%
67.65 55.63 0.0184 12.02 17.8%
35.93 21.09 0.0297 14.84 41.3%
12.99 5.26 0.0429 7.73 59.5%
7.38 2.44 0.0388 4.94 66.9%
2.42 0.79 0.0425 1.63 67.3%
C=7,8 C=3,1 C=156 C=78 C=31 C=14 C=7,8 C=3,1
mg/l mg/l mg/L mg/L mg/L mg/l mg/l mg/l D1 D2 D3 D4 D5 D6
-0.03009 -0.20458 0 0 0 0.432358 0.672361 1.042112 171.0368 19.66957 1.3347 2.343833 0.04926 0.244439
0.227132 0.150383 0.006505 0.015616 0.057043 0.499359 0.714616 1.017914 40.95226 0.460963 6.152779 0.859511 0.647568 0.002679
0.295289 0.253255 0.01265 0.029859 0.106207 0.554548 0.748775 0.989338 2.84082 3.144597 0.282635 1.212445 0.348473 0.002343
0.340742 0.371821 0.018455 0.042851 0.148582 0.600006 0.77639 0.982493 9.395465 0.018097 0.32226 0.112851 0.112144 0.017226
0.398099 0.411134 0.023939 0.054701 0.185105 0.63745 0.798714 0.981948 6.400668 0.592588 1.42036 0.34127 0.073654 0.003793
0.421957 0.469964 0.029119 0.06551 0.216584 0.668293 0.816762 0.99053 0.641341 2.334579 0.424725 0.075067 0.002171 0.004991
0.479591 0.475493 0.034013 0.075369 0.243716 0.693697 0.831351 0.999004 16.49601 0.070378 0.730424 0.00656 0.020049 0.000557
0.482613 0.518696 0.038636 0.084361 0.2671 0.714623 0.843146 0.996324 14.61764 0.274007 0.918127 5.75E-05 0.011671 3.84E-05
0.50185 0.536632 0.043002 0.092564 0.287255 0.731859 0.852681 0.964538 30.10761 0.091314 0.883249 0.010175 0.036141 0.001101
0.526879 0.569174 0.047128 0.100045 0.304627 0.746057 0.860389 0.983677 0.973639 0.168215 5.804259 0.037294 0.036094 0.00013
0.549997 0.579189 0.051024 0.106869 0.3196 0.757751 0.86662 0.98477 3.338034 1.109445 0.358121 0.046942 0.029385 0.001099
0.568719 0.612873 0.054705 0.113094 0.332504 0.767384 0.871658 0.958818 33.1716 0.516411 0.030613 0.111118 0.025121 0.000123
0.595975 0.604483 0.058183 0.118771 0.343627 0.775318 0.87573 0.965972 9.554284 0.015788 0.087953 0.025041 0.003667 0.001538
0.60891 0.638666 0.061468 0.12395 0.353213 0.781854 0.879022 0.970373 1.695425 1.950108 0.446589 0.001014 0.002507 0.000365
0.606433 0.624278 0.064571 0.128673 0.361476 0.787237 0.881684 0.983494 10.05994 0.247719 0.879699 0.002823 0.019123 0.001246
0.630359 0.640931 0.067502 0.132982 0.368598 0.791671 0.883835 0.977865 3.240334 1.770491 0.584961 0.002367 0.000377 0.000119
0.638052 0.666488 0.070271 0.136912 0.374736 0.795324 0.885575 0.972354 0.197566 0.026167 0.053165 0.00147 0.000103 0.001445
0.633932 0.659745 0.072887 0.140496 0.380026 0.798332 0.886981 0.976688 4.52266 0.5717 0.109698 0.002203 0.00634 0.000129
0.662743 0.653738 0.075358 0.143766 0.384586 0.80081 0.888117 0.977412 7.123767 1.346758 0.011658 0.00304 0.010138 0.000134
0.65452 0.652234 0.077693 0.146748 0.388516 0.802851 0.889036 0.968664 0.063675 0.030329 0.203295 0.000564 0.000182 0.000483

366.4295 34.40922 21.03927 5.195644 1.434167 0.283977

 160.0

140.0
C (mg/L)

120.0 C=156 mg/L

C=78 mg/L
100.0 C=31 mg/L
C=14 mg/l
80.0 C=7,8 mg/l
C=3,1 mg/l
60.0 C=156 mg/L
C=78 mg/L
40.0 C=31 mg/L
C=14 mg/l

20.0 C=7,8 mg/l

C=3,1 mg/l

0.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 145.0

140.0
C (mg/L)

135.0

130.0

125.0
C=156
120.0 mg/L

115.0

110.0

105.0

100.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 75.0

70.0
C (mg/L)

65.0

60.0

55.0
C=78
50.0 mg/L

45.0

40.0

35.0

30.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 40.0

35.0
C (mg/L)

30.0

25.0

20.0
C=31
mg/L
15.0

10.0

5.0

0.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 16.0

14.0
C (mg/L)

12.0

10.0

8.0
C=14
mg/l
6.0

4.0

2.0

0.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 8.0

7.0
C (mg/L)

6.0

5.0

4.0
C=7,8
3.0 mg/l

2.0

1.0

0.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 3.5

3.0
C (mg/L)

2.5

2.0

1.5 C=3,1
mg/l

1.0

0.5

0.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 C=156 C=78 C=31 C=14 C=7,8 C=3,1
t (min) mg/L mg/L mg/L mg/l mg/l mg/l
0 3.338677 2.800694 2.616384 2.225822 1.640968 0.751997
5 3.028546 2.330758 2.333241 1.669671 1.182606 0.233801
10 2.467473 2.107525 2.350762 1.369148 1.015277 0.014675
15 2.268708 2.225361 2.189965 1.315155 0.885776 -0.31712
20 2.251024 2.021664 1.945689 0.990613 0.694043 -0.45691
25 2.498363 1.801968 1.857459 0.863021 0.602025 -0.71119
30 2.69425 1.895711 1.654335 0.719161 0.336972 -0.73877
35 2.63635 1.756269 1.824902 0.5389 0.320931 -0.9854
40 1.408705 1.801968 1.697375 0.398865 0.212294 -1.10883
45 2.306012 1.577563 1.841309 0.273168 0.050599 -1.38111
50 2.339289 1.765578 1.375239 0.114409 -0.12627 -1.48238
55 0.839112 1.295264 1.121307 0.061313 -0.29668 -1.92625
60 1.512029 1.413949 1.026331 -0.29142 -0.61205 -1.79596
65 1.775412 1.615949 0.393057 -0.67909 -0.80557 -2.4846
70 2.30036 1.338778 1.026331 -0.82874 -0.76551 -2.13597
75 2.107716 1.471511 0.859434 -1.02702 -1.24266 -2.55254
80 1.874563 1.071973 0.474382 -1.24475 -1.46157 -4.1277
85 2.062294 1.185707 -0.15648 -1.86735 -1.33839 -3.42908
90 2.090484 0.126828 0.12265 -2.2309 -3.00069 -3.059
95 1.68123 0.652238 -0.843 -2.2309 -2.20358 -2.98442

Ce 113.4012 55.62587 21.09055 5.26416 2.437895 0.789879

Co 128.5049 67.6469 35.93199 12.9943 7.376112 2.416704
ln(Co-Ce) 2.7149 2.4867 2.6974 2.0451 1.5970 0.4866
k 0.0114 0.0184 0.0297 0.0429 0.0388 0.0425
R -0.5916 -0.9128 -0.9505 -0.9872 -0.9652 -0.9623
R^2 0.3500 0.8333 0.9035 0.9746 0.9316 0.9261
 4
C=156 mg/L
3 Linear
ln(C-Ce)

(C=156 mg/L)
2 C=78 mg/L
Linear (C=78
1 mg/L)
0 C=31 mg/L
0 50 100 Linear (C=31
-1 mg/L)
C=14 mg/l
-2 Linear (C=14
-3 mg/l)
C=7,8 mg/l
-4 Linear (C=7,8
mg/l)
-5 C=3,1 mg/l
t (min)
ln(C-Ce) 4
3.5
3
2.5
2
1.5
1 C=156 mg/L
0.5
0
0 10 20 30 40 50 60 70 80 90 100
t (min)
ln(C-Ce) 3
2.5
2
1.5
1
0.5 C=78 mg/L
0
0 10 20 30 40 50 60 70 80 90 100
t (min)
ln(C-Ce) 3
2.5
2
1.5
1
0.5
0 C=31 mg/L
-0.5
-1
-1.50 10 20 30 40 t 50 60 70 80 90 100
(min)
 2.5
2
ln(C-Ce)

1.5
1
0.5
0
-0.5
-1
-1.5 0 10 C=14
20 mg/l
30 40 50 60 70 80 90 100
-2
-2.5
t (min)
 2
ln(C-Ce)
1

-1
0 10 20 30 40 50 60 70 80 90 100
-2 C=7,8 mg/l

-3

-4

t (min)
ln(C-Ce) 2
1
0
0 10 20 30 40 50 60 70 80 90100
-1
-2
-3
-4
-5

t (min)
 C=156 C=78 C=31 C=14 C=7,8 C=3,1
t (min) mg/L mg/L mg/L mg/l mg/l mg/l
0 0.623736 0.314037 -0.08104 0.180696 0.043964 0.265367
5 0.313605 -0.1559 -0.36418 -0.37546 -0.4144 -0.25283
10 -0.24747 -0.37913 -0.34666 -0.67598 -0.58173 -0.47196
15 -0.44623 -0.2613 -0.50746 -0.72997 -0.71123 -0.80375
20 -0.46392 -0.46499 -0.75173 -1.05451 -0.90296 -0.94354
25 -0.21658 -0.68469 -0.83996 -1.18211 -0.99498 -1.19782
30 -0.02069 -0.59095 -1.04309 -1.32597 -1.26003 -1.2254
35 -0.07859 -0.73039 -0.87252 -1.50623 -1.27607 -1.47203
40 -1.30624 -0.68469 -1.00005 -1.64626 -1.38471 -1.59546
45 -0.40893 -0.90909 -0.85611 -1.77196 -1.54641 -1.86774
50 -0.37565 -0.72108 -1.32218 -1.93072 -1.72328 -1.96901
55 -1.87583 -1.19139 -1.57612 -1.98381 -1.89368 -2.41288
60 -1.20291 -1.07271 -1.67109 -2.33655 -2.20905 -2.28259
65 -0.93953 -0.87071 -2.30437 -2.72422 -2.40258 -2.97123
70 -0.41458 -1.14788 -1.67109 -2.87386 -2.36251 -2.6226
75 -0.60722 -1.01515 -1.83799 -3.07214 -2.83966 -3.03917
80 -0.84038 -1.41468 -2.22304 -3.28988 -3.05857 -4.61433
85 -0.65265 -1.30095 -2.85391 -3.91248 -2.9354 -3.91571
90 -0.62446 -2.35983 -2.57477 -4.27603 -4.59769 -3.54563
95 -1.03371 -1.83442 -3.54042 -4.27603 -3.80058 -3.47105

Ce 113.4012 55.62587 21.09055 5.26416 2.437895 0.789879

Co 128.5049 67.6469 35.93199 12.9943 7.376112 2.416704
k 0.0114 0.0184 0.0297 0.0429 0.0388 0.0425
 1
ln[(C-Ce)/(Co-Ce)]
C=156 mg/L

0 Linear (C=156 mg/L)

0 10 20 30 40 50 60 70 80 90 100
C=78 mg/L

-1 Linear (C=78 mg/L)

C=31 mg/L

-2 Linear (C=31 mg/L)

C=14 mg/l

Linear (C=14 mg/l)

-3
C=7,8 mg/l

Linear (C=7,8 mg/l)

-4
C=3,1 mg/l

Linear (C=3,1 mg/l)

-5
t (min)
 1

0.5

0
0 f(x)10
= - 0.0113875909x
20 30 40 50 60 70 80 90 100
R² = 0.6666973405 C=156 mg/L
-0.5
Linear (C=156 mg/L)

-1

-1.5

-2

-2.5
t (min)
0.5

C=78 mg/L
0
0 f(x)10
= - 0.0183956731x
20 30 40 50 60 70 80 90 100 Linear (C=78 mg/L)
R² = 0.9488829612
-0.5

-1

-1.5

-2

-2.5
t (min)
 0
0 f(x) 10
= - 0.0297239897x
20 30 40 50 60 70 80 90 100
R² = 0.9720411655
-0.5 C=31 mg/L
Linear (C=31 mg/L)
-1

-1.5

-2

-2.5

-3

-3.5

-4
t (min)
0.5

0
0 f(x) =10
- 0.0429089032x
20 30 40 50 60 70 80 90 100
R² = 0.9930301954
-0.5

C=14 mg/l
-1
Linear (C=14 mg/l)

-1.5

-2

-2.5

-3

-3.5

-4

-4.5
t (min)
1
C=7,8 mg/l
0 Linear (C=7,8 mg/l)
0 f(x) =10
- 0.0387911221x
20 30 40 50 60 70 80 90 100
R² = 0.9806081798

-1

-2

-3

-4

-5
t (min)
1
C=3,1 mg/l
0 Linear (C=3,1 mg/l)
0 f(x) = 10
- 0.0425361786x
20 30 40 50 60 70 80 90 100
R² = 0.9789601736

-1

-2

-3

-4

-5
t (min)
 25.0

20.0
T (oC)

T(oC) 1
15.0
T(oC) 2
T(oC) 3
T(oC) 4
T(oC) 5
10.0
T(oC) 6

5.0

0.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 9.00

8.00

7.00

6.00
pH
1
pH

5.00 pH
2
pH
4.00 3
pH
4
3.00

2.00

1.00

0.00
0 10 20 30 40 50 60 70 80 90 100
t (min)