100.

0%

90.0% f(x) = 0.936669081 exp( - 0.0045818474 x )

R² = 0.9319469638
80.0%

70.0%

60.0%
A%

A%
50.0% Exponential (A
%)
40.0%

30.0%

20.0%

10.0%

0.0%
0.00 20.00 40.00 60.00 80.00 100.00 120.00 140.00 160.00
Co (mg/L)
 70.00

f(x) = - 0.0039207111x^2 + 1.0200931884x - 0.9304807086

60.00 R² = 0.997888805
q (mg/g)

50.00

40.00
q
Polynomial (q)
30.00

20.00

10.00

0.00
0.00 20.00 40.00 60.00 80.00 100.00 120.00 140.00 160.00
Co (mg/L)
 0.06

0.05
k (min-1)

f(x) = - 6.81249461814651E-05x + 0.0442417575

0.04 R² = 0.3719274885

k
0.03 Linear (k)

0.02

0.01

0
0.00 20.00 40.00 60.00 80.00 100.00 120.00 140.00 160.00
Co (mg/L)
 80.00

70.00
f(x) = 0.0039207111x^2 - 0.0200931884x + 0.9304807086
Ce (mg/L)

R² = 0.9980825119
60.00

50.00

Ce
40.00 Polynomial (Ce)

30.00

20.00

10.00

0.00
0.00 20.00 40.00 60.00Co80.00
(mg/L)
100.00 120.00 140.00 160.00
A4 A3 A2 A1 methylene blue 1st-3rd αραιωση 5:100 20
0.2941 -1.1677 1.6979 2.9839 4th-6th αραιωση 100:100 1
Untreated Wheat Straw H2O: Ρέμα Πικροδάφνης

1 lt methylene blue αχυρο (g) 1.00

προσρόφηση σε θ=23C V (L) 1.00
ημερομηνια 4/16/2015
αραιώσεις 1000:1000 500:1000 200:1000 90:1000 50:1000
t (min) abs 1 abs 2 abs 3 abs 1 abs 2 abs 3 abs1 abs3 abs1 abs 2 abs3 abs1 abs 2 abs3
0 1.755 1.984 1.795 0.973 0.967 0.955 0.387 0.391 0.384 2.491 2.471 1.815 1.899
5 1.777 2.048 1.774 0.968 0.964 0.962 0.360 0.364 0.392 2.457 2.480 1.766 1.818
10 1.798 1.958 1.826 0.967 0.955 0.976 0.395 0.389 0.389 2.510 2.484 1.724 1.777
15 1.743 1.871 1.866 0.989 0.975 0.961 0.381 0.379 0.378 2.502 2.483 1.706 1.765
20 1.757 1.902 1.899 0.954 0.963 0.972 0.390 0.388 0.383 2.486 2.472 1.694 1.738
25 1.759 1.996 1.877 0.943 0.939 0.946 0.396 0.390 0.388 2.487 2.464 1.681 1.719
30 1.785 1.996 1.835 0.954 0.948 0.953 0.375 0.377 0.396 2.471 2.455 1.669 1.707
35 1.787 1.940 1.880 0.983 0.964 0.972 0.386 0.383 0.377 2.459 2.450 1.662 1.678
40 1.774 1.927 1.835 0.964 0.966 0.975 0.391 0.387 0.380 2.456 2.426 1.648 1.676
45 1.735 2.003 1.777 0.942 0.946 0.945 0.372 0.371 0.366 2.456 2.444 1.646 1.679
50 1.744 1.995 1.863 0.943 0.939 0.935 0.375 0.376 0.372 2.452 2.438 1.632 1.663
55 1.760 1.960 1.883 0.930 0.943 0.936 0.380 0.378 0.376 2.446 2.438 1.612 1.647
60 1.739 2.055 1.798 0.918 0.921 0.944 0.377 0.372 0.366 2.428 2.395 1.611 1.635
65 1.723 1.991 1.826 0.932 0.939 1.020 0.387 0.387 0.386 2.430 2.432 1.606 1.629
70 1.730 1.983 1.791 0.946 0.936 0.935 0.367 0.370 0.365 2.418 2.381 1.594 1.608
75 1.709 1.933 1.794 0.926 0.918 0.920 0.365 0.365 0.375 2.408 2.400 1.582 1.609
80 1.728 1.911 1.865 0.939 0.928 0.935 0.378 0.380 0.390 2.404 2.396 1.574 1.601
85 1.769 1.943 1.772 0.912 0.915 0.912 0.377 0.379 0.372 2.404 2.389 1.571 1.598
90 1.721 1.949 1.894 0.918 0.917 0.925 0.374 0.372 0.420 2.409 2.397 1.561 1.595
95 1.735 1.984 1.836 0.944 0.930 0.938 0.366 0.361 0.383 2.384 2.382 1.557 1.581

t (min) ABS Φ1 ABS Φ2 ABS Φ3 ABS Φ4 ABS Φ5 ABS Φ6

0 1.845 0.965 0.387 2.481 1.857 0.801
5 1.866 0.965 0.372 2.469 1.792 0.750
10 1.861 0.966 0.391 2.497 1.751 0.730
15 1.827 0.975 0.379 2.493 1.736 0.760
20 1.853 0.963 0.387 2.479 1.738 0.766
25 1.877 0.943 0.391 2.476 1.700 0.755
30 1.872 0.952 0.383 2.463 1.688 0.737
35 1.869 0.973 0.382 2.455 1.670 0.743
40 1.845 0.968 0.386 2.441 1.662 0.726
 45 1.838 0.944 0.370 2.450 1.663 0.737
50 1.867 0.939 0.374 2.445 1.648 0.726
55 1.868 0.936 0.378 2.442 1.630 0.728
60 1.864 0.928 0.372 2.412 1.623 0.725
65 1.847 0.964 0.387 2.431 1.618 0.705
70 1.835 0.939 0.367 2.400 1.601 0.693
75 1.812 0.921 0.368 2.404 1.596 0.691
80 1.835 0.934 0.383 2.400 1.588 0.688
85 1.828 0.913 0.376 2.397 1.585 0.680
90 1.855 0.920 0.389 2.403 1.578 0.680
95 1.852 0.937 0.370 2.383 1.569 0.687

t (min) C1 C2 C3 C4 C5 C6
0 147.15 73.33 26.99 11.16 7.42 3.00
5 149.21 73.30 25.81 11.07 7.11 2.79
10 148.67 73.41 27.27 11.29 6.92 2.71
15 145.46 74.14 26.37 11.26 6.86 2.83
20 147.91 73.16 26.96 11.15 6.87 2.86
25 150.26 71.51 27.29 11.12 6.70 2.81
30 149.75 72.24 26.63 11.03 6.65 2.74 αραιώσεις 1000 500 200 90 50 20
35 149.46 73.97 26.58 10.96 6.57 2.76 1000 1000 1000 1000 1000 1000
40 147.22 73.60 26.88 10.86 6.53 2.69 Co 156.0 78.0 31.2 14.0 7.8 3.1
45 146.56 71.65 25.63 10.93 6.53 2.74
50 149.30 71.22 25.99 10.89 6.47 2.70
55 149.33 71.00 26.27 10.87 6.39 2.70
60 148.98 70.30 25.78 10.64 6.36 2.69
65 147.34 73.22 26.93 10.78 6.34 2.61
70 146.21 71.22 25.45 10.55 6.27 2.56
75 144.10 69.78 25.53 10.59 6.25 2.55
80 146.21 70.82 26.63 10.56 6.21 2.54
85 145.59 69.11 26.12 10.53 6.20 2.51
90 148.10 69.67 27.09 10.58 6.17 2.51
95 147.81 71.08 25.66 10.43 6.13 2.54

t (min) T(oC) 1 T(oC) 2 T(oC) 3 T(oC) 4 T(oC) 5 T(oC) 6

0 23.0 23.0 23.0 23.0 23.0 23.0
5 23.0 23.0 23.0 23.0 23.0 23.0
10 23.0 23.0 23.0 23.0 23.0 23.0
15 23.0 23.0 23.0 23.0 23.0 23.0
 20 23.0 23.0 23.0 23.0 23.0 23.0
25 23.0 23.0 23.0 23.0 23.0 23.0
30 23.0 23.0 23.0 23.0 23.0 23.0
35 23.0 23.0 23.0 23.0 23.0 23.0
40 23.0 23.0 23.0 23.0 23.0 23.0
45 23.0 23.0 23.0 23.0 23.0 23.0
50 23.0 23.0 23.0 23.0 23.0 23.0
55 23.0 23.0 23.0 23.0 23.0 23.0
60 23.0 23.0 23.0 23.0 23.0 23.0
65 23.0 23.0 23.0 23.0 23.0 23.0
70 23.0 23.0 23.0 23.0 23.0 23.0
75 23.0 23.0 23.0 23.0 23.0 23.0
80 23.0 23.0 23.0 23.0 23.0 23.0
85 23.0 23.0 23.0 23.0 23.0 23.0
90 23.0 23.0 23.0 23.0 23.0 23.0
95 23.0 23.0 23.0 23.0 23.0 23.0
μ.ο. 23 23 23 66 66 23

t (min) pH 1 pH 2 pH 3 pH 4 pH 5 pH 6
0 8.00 8.00 8.00 8.00 8.00 8.00
5 8.00 8.00 8.00 8.00 8.00 8.00
10 8.00 8.00 8.00 8.00 8.00 8.00
15 8.00 8.00 8.00 8.00 8.00 8.00
20 8.00 8.00 8.00 8.00 8.00 8.00
25 8.00 8.00 8.00 8.00 8.00 8.00
30 8.00 8.00 8.00 8.00 8.00 8.00
35 8.00 8.00 8.00 8.00 8.00 8.00
40 8.00 8.00 8.00 8.00 8.00 8.00
45 8.00 8.00 8.00 8.00 8.00 8.00
50 8.00 8.00 8.00 8.00 8.00 8.00
55 8.00 8.00 8.00 8.00 8.00 8.00
60 8.00 8.00 8.00 8.00 8.00 8.00
65 8.00 8.00 8.00 8.00 8.00 8.00
70 8.00 8.00 8.00 8.00 8.00 8.00
75 8.00 8.00 8.00 8.00 8.00 8.00
80 8.00 8.00 8.00 8.00 8.00 8.00
85 8.00 8.00 8.00 8.00 8.00 8.00
90 8.00 8.00 8.00 8.00 8.00 8.00
95 8.00 8.00 8.00 8.00 8.00 8.00
μ.ο. 8 8 8 8 8 8
20:1000
abs1 abs 2 abs3
0.810 0.791
0.773 0.726
0.753 0.707
0.763 0.756
0.770 0.762
0.752 0.757
0.737 0.737
0.744 0.741
0.725 0.726
0.742 0.731
0.733 0.719
0.724 0.731
0.730 0.719
0.7 0.709
0.697 0.689
0.693 0.688
0.686 0.690
0.684 0.675
0.688 0.671
0.683 0.690
 C=156 C=78 C=31 C=14 C=7,8 C=3,1 C=156 C=78 C=31 C=14 C=7,8 C=3,1 C=156 C=78 C=31 C=14
t (min) mg/L mg/L mg/L mg/l mg/l mg/l mg/L mg/L mg/L mg/l mg/l mg/l mg/L mg/L mg/L mg/l
0 147.2 73.3 27.0 11.2 7.4 3.0 148.6 74.3 26.7 11.4 7.3 3.0 0.009624 0.012784 -0.00994 0.022033
5 149.2 73.3 25.8 11.1 7.1 2.8 148.5 73.9 26.7 11.3 7.2 2.9 -0.0042 0.013148 0.034051 0.030533
10 148.7 73.4 27.3 11.3 6.9 2.7 148.3 73.6 26.6 11.2 7.0 2.9 -0.00057 0.011692 -0.02049 0.010998
15 145.5 74.1 26.4 11.3 6.9 2.8 148.2 73.3 26.6 11.2 6.9 2.8 0.020987 0.001864 0.013041 0.014119
20 147.9 73.2 27.0 11.1 6.9 2.9 148.1 73.0 26.5 11.1 6.8 2.8 0.004539 0.014968 -0.00898 0.0234
25 150.3 71.5 27.3 11.1 6.7 2.8 148.0 72.7 26.5 11.0 6.7 2.8 -0.01128 0.037179 -0.02145 0.025786
30 149.7 72.2 26.6 11.0 6.6 2.7 147.9 72.4 26.4 11.0 6.7 2.7 -0.00784 0.027347 0.003474 0.03424
35 149.5 74.0 26.6 11.0 6.6 2.8 147.8 72.1 26.4 10.9 6.6 2.7 -0.00591 0.004048 0.005389 0.03993
40 147.2 73.6 26.9 10.9 6.5 2.7 147.7 71.9 26.3 10.9 6.5 2.7 0.009201 0.009144 -0.0061 0.04887
45 146.6 71.6 25.6 10.9 6.5 2.7 147.5 71.7 26.3 10.8 6.5 2.7 0.013634 0.035358 0.040725 0.042923
50 149.3 71.2 26.0 10.9 6.5 2.7 147.4 71.5 26.2 10.8 6.4 2.6 -0.00484 0.041186 0.027372 0.046233
55 149.3 71.0 26.3 10.9 6.4 2.7 147.3 71.3 26.2 10.7 6.4 2.6 -0.00505 0.044099 0.016865 0.048212
60 149.0 70.3 25.8 10.6 6.4 2.7 147.2 71.1 26.1 10.7 6.3 2.6 -0.0027 0.05357 0.035005 0.068001
65 147.3 73.2 26.9 10.8 6.3 2.6 147.1 70.9 26.1 10.7 6.3 2.6 0.008355 0.01424 -0.00802 0.055416
70 146.2 71.2 25.5 10.6 6.3 2.6 147.0 70.7 26.1 10.6 6.3 2.6 0.01595 0.041186 0.047394 0.075629
75 144.1 69.8 25.5 10.6 6.2 2.6 146.9 70.5 26.0 10.6 6.2 2.6 0.030169 0.060492 0.044537 0.072779
80 146.2 70.8 26.6 10.6 6.2 2.5 146.8 70.4 26.0 10.6 6.2 2.6 0.01595 0.046503 0.003474 0.075313
85 145.6 69.1 26.1 10.5 6.2 2.5 146.8 70.2 26.0 10.6 6.2 2.5 0.020149 0.0696 0.022597 0.077522
90 148.1 69.7 27.1 10.6 6.2 2.5 146.7 70.1 25.9 10.5 6.2 2.5 0.003264 0.061949 -0.01377 0.073413
95 147.8 71.1 25.7 10.4 6.1 2.5 146.6 70.0 25.9 10.5 6.2 2.5 0.005176 0.043007 0.039772 0.085975

Ce 141.2 67.7 24.9 10.2 6.0 2.5 4% 8% 8% 8% 19% 18%

Co 148.6 74.3 26.7 11.4 7.3 3.0
k 0.0034 0.0112 0.0065 0.0153 0.0229 0.0218
sum 47.68338 19.58982 6.315338 0.224163 0.04686 0.089494
n-p 18 18 18 18 18 18
s 1.627598 1.043227 0.592328 0.111595 0.051023 0.070512

Co Ce k q A%
135.07 69.98 0.033049 65.09 48.2%
69.73 17.41 0.04212 52.31 75.0%
26.58 5.43 0.043876 21.14 79.6%
12.25 0.86 0.04912 11.40 93.0%
7.01 0.60 0.043631 6.41 91.4%
2.84 0.39 0.036387 2.45 86.4%
C=7,8 C=3,1 C=156 C=78 C=31 C=14 C=7,8 C=3,1
mg/l mg/l mg/L mg/L mg/L mg/l mg/l mg/l D1 D2 D3 D4 D5 D6
-0.01493 0.000584 0 0 0 0.359966 0.589403 0.996792 2.044695 0.901601 0.070482 0.06327 0.011902 3.07E-06
0.026561 0.069584 0.000825 0.004813 0.00211 0.372252 0.597083 1.001399 0.557025 0.383302 0.728367 0.068076 0.002896 0.0233
0.05238 0.095941 0.001636 0.009362 0.004154 0.383209 0.603969 1.000189 0.107204 0.029932 0.43346 0.001876 0.013779 0.032908
0.061597 0.056061 0.002434 0.013664 0.006132 0.392979 0.610143 0.993005 7.599501 0.768203 0.034081 0.006873 0.005356 0.000277
0.060065 0.047269 0.003218 0.017731 0.008048 0.401692 0.615678 0.998487 0.038522 0.042119 0.206934 0.002175 0.001405 0.002517
0.083185 0.062823 0.003989 0.021576 0.009902 0.409462 0.62064 1.003759 5.146044 1.343097 0.701613 0.007047 0.001828 0.001581
0.090415 0.086481 0.004748 0.025212 0.011698 0.416391 0.625089 1.002613 3.498186 0.025157 0.048282 0.002231 0.000272 1.66E-06
0.101201 0.079047 0.005494 0.028649 0.013437 0.42257 0.629077 1.00197 2.871261 3.33883 0.046245 0.001419 0.000613 0.002781
0.105972 0.10202 0.006227 0.031898 0.01512 0.42808 0.632653 0.996933 0.19523 2.856444 0.321563 0.000171 1.08E-05 9.89E-05
0.105675 0.087157 0.006948 0.03497 0.01675 0.432994 0.635859 0.995456 0.986808 0.000831 0.410363 0.010475 0.00379 0.006078
0.114587 0.101345 0.007658 0.037875 0.018329 0.437375 0.638733 1.001613 3.44821 0.060465 0.058379 0.011791 0.002159 0.003181
0.125225 0.099318 0.008355 0.040621 0.019857 0.441283 0.64131 1.001685 3.969512 0.066744 0.006392 0.016076 0.000178 0.006611
0.129051 0.103371 0.009041 0.043217 0.021337 0.444767 0.643621 1.000901 3.044221 0.59127 0.133376 0.003763 0.000633 0.007401
0.132283 0.130376 0.009715 0.045672 0.022769 0.447875 0.645692 0.997215 0.040873 5.450457 0.676757 0.013766 0.001371 0.000406
0.141946 0.145891 0.010378 0.047993 0.024156 0.450646 0.647549 0.994684 0.685258 0.255635 0.385521 0.006561 3.79E-06 0.000165
0.145157 0.149262 0.011031 0.050187 0.0255 0.453117 0.649214 0.989944 8.086519 0.585827 0.25874 0.000339 7.85E-06 0.000116
0.149819 0.152633 0.011672 0.052261 0.0268 0.45532 0.650707 0.994684 0.404011 0.182905 0.388442 0.000381 3.72E-05 9.98E-05
0.151564 0.164091 0.012303 0.054222 0.028059 0.457286 0.652045 0.993284 1.359192 1.304588 0.021298 0.00036 1.28E-05 0.001196
0.155341 0.164091 0.012923 0.056077 0.029278 0.459038 0.653245 0.998912 2.059379 0.190239 1.323117 0.002684 1.61E-05 0.000667
0.16056 0.154656 0.013533 0.05783 0.030459 0.460601 0.654321 0.998275 1.54173 1.212175 0.061925 0.004828 0.000591 0.000107

47.68338 19.58982 6.315338 0.224163 0.04686 0.089494

 160.0

140.0
C (mg/L)

120.0 C=156 mg/L

C=78 mg/L
100.0 C=31 mg/L
C=14 mg/l
80.0 C=7,8 mg/l
C=3,1 mg/l
60.0 C=156 mg/L
C=78 mg/L
40.0 C=31 mg/L
C=14 mg/l

20.0 C=7,8 mg/l

C=3,1 mg/l

0.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 160.0

150.0
C (mg/L)

140.0

130.0
C=156
mg/L

120.0

110.0

100.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 80.0
75.0
C (mg/L)

70.0
65.0
60.0
55.0
C=78
mg/L
50.0
45.0
40.0
35.0
30.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 27.5

27.0
C (mg/L)

26.5

26.0
C=31
mg/L

25.5

25.0

24.5
0 10 20 30 40 50 60 70 80 90 100
t (min)
C (mg/L) 12.0

10.0
C=14
mg/l

8.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 8.0

7.0
C (mg/L)

6.0

5.0

4.0
C=7,8
3.0 mg/l

2.0

1.0

0.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 3.1

3.0

2.9
C (mg/L)

2.8

2.7

2.6 C=3,1
mg/l
2.5

2.4

2.3

2.2
0 10 20 30 40 50 60 70 80 90 100
t (min)
 C=156 C=78 C=31 C=14 C=7,8 C=3,1
t (min) mg/L mg/L mg/L mg/l mg/l mg/l
0 1.780817 1.723154 0.713395 -0.06328 0.340002 -0.61488
5 2.077992 1.718315 -0.14434 -0.17241 0.096925 -1.09753
10 2.008076 1.737529 0.842781 0.062653 -0.09089 -1.36799
15 1.446051 1.858367 0.355554 0.02861 -0.1675 -0.98279
20 1.900646 1.693766 0.700766 -0.08005 -0.15435 -0.91469
25 2.2017 1.332414 0.853761 -0.11 -0.37392 -1.03852
30 2.143534 1.508617 0.520332 -0.224 -0.45381 -1.26231
35 2.109346 1.832749 0.489464 -0.30875 -0.58628 -1.18645
40 1.791349 1.770288 0.661903 -0.45839 -0.65099 -1.44232
45 1.675009 1.367476 -0.37504 -0.3564 -0.64682 -1.2695
50 2.08986 1.250653 0.043122 -0.41188 -0.77961 -1.43378
55 2.093786 1.186685 0.281262 -0.44658 -0.96533 -1.4086
60 2.049766 0.944982 -0.17422 -0.88215 -1.04157 -1.45961
65 1.812098 1.703659 0.687978 -0.58418 -1.11083 -1.88843
70 1.608391 1.250653 -0.67518 -1.11837 -1.35218 -2.25608
75 1.058482 0.722053 -0.53543 -1.02346 -1.44725 -2.35762
80 1.608391 1.130643 0.520332 -1.10739 -1.60368 -2.47063
85 1.474956 0.323616 0.158397 -1.1868 -1.66918 -2.99259
90 1.92856 0.668043 0.762386 -1.04382 -1.82756 -2.99259
95 1.886403 1.211155 -0.33866 -1.56688 -2.09823 -2.54511

Ce 141.2176 67.72374 24.94427 10.22609 6.01097 2.457703

Co 148.5822 74.27543 26.71969 11.4163 7.306823 3.000159
ln(Co-Ce) 1.9967 1.8797 0.5740 0.1741 0.2592 -0.6116
k 0.0034 0.0112 0.0065 0.0153 0.0229 0.0218
R -0.3416 -0.7676 -0.3896 -0.9409 -0.9931 -0.9130
R^2 0.1167 0.5892 0.1518 0.8853 0.9863 0.8335
 3
C=156 mg/L
Linear
2
ln(C-Ce)

(C=156 mg/L)
C=78 mg/L
1 Linear (C=78
mg/L)
0 C=31 mg/L
0 50 100 Linear (C=31
-1 mg/L)
C=14 mg/l
-2 Linear (C=14
mg/l)
C=7,8 mg/l
-3
Linear (C=7,8
mg/l)
-4 C=3,1 mg/l
t (min)
ln(C-Ce) 2.5

1.5

1
C=156 mg/L
0.5

0
0 10 20 30 40 50 60 70 80 90 100
t (min)
ln(C-Ce) 2

1.5

0.5
C=78 mg/L
0
0 10 20 30 40 50 60 70 80 90 100
t (min)
ln(C-Ce) 1

0.5

-0.5 C=31 mg/L

-1
0 10 20 30 40 t 50
(min)
60 70 80 90 100
 0.2
0
ln(C-Ce)

-0.2
-0.4
-0.6
-0.8
-1
-1.2 0 10 20 30 40 50 60 70 80 90 100
-1.4 C=14 mg/l
-1.6
-1.8
t (min)
 0.5
ln(C-Ce)
0

-0.5

-1
0 10 20 30 40 50 60 70 80 90 100
-1.5 C=7,8 mg/l

-2

-2.5

t (min)
 0
0 10 20 30 40 50 60 70 80 90100
ln(C-Ce)
-0.5
-1
-1.5
-2
-2.5
-3
-3.5

t (min)
 C=156 C=78 C=31 C=14 C=7,8 C=3,1
t (min) mg/L mg/L mg/L mg/l mg/l mg/l
0 -0.21587 -0.15657 0.139356 -0.23742 0.080833 -0.00323
5 0.081303 -0.16141 -0.71838 -0.34654 -0.16224 -0.48588
10 0.011387 -0.14219 0.268742 -0.11148 -0.35006 -0.75634
15 -0.55064 -0.02136 -0.21849 -0.14552 -0.42667 -0.37114
20 -0.09604 -0.18596 0.126727 -0.25418 -0.41352 -0.30304
25 0.205012 -0.54731 0.279722 -0.28413 -0.63309 -0.42687
30 0.146845 -0.37111 -0.05371 -0.39813 -0.71298 -0.65066
35 0.112657 -0.04697 -0.08458 -0.48289 -0.84544 -0.57481
40 -0.20534 -0.10944 0.087863 -0.63252 -0.91015 -0.83067
45 -0.32168 -0.51225 -0.94908 -0.53053 -0.90599 -0.65785
50 0.093171 -0.62907 -0.53092 -0.58602 -1.03878 -0.82213
55 0.097097 -0.69304 -0.29278 -0.62071 -1.2245 -0.79695
60 0.053077 -0.93474 -0.74826 -1.05628 -1.30074 -0.84796
65 -0.18459 -0.17607 0.113938 -0.75831 -1.37 -1.27679
70 -0.3883 -0.62907 -1.24922 -1.2925 -1.61134 -1.64443
75 -0.93821 -1.15767 -1.10947 -1.19759 -1.70642 -1.74597
80 -0.3883 -0.74908 -0.05371 -1.28152 -1.86285 -1.85898
85 -0.52173 -1.55611 -0.41564 -1.36093 -1.92835 -2.38095
90 -0.06813 -1.21168 0.188347 -1.21795 -2.08673 -2.38095
95 -0.11029 -0.66857 -0.9127 -1.74101 -2.3574 -1.93346

Ce 141.2176 67.72374 24.94427 10.22609 6.01097 2.457703

Co 148.5822 74.27543 26.71969 11.4163 7.306823 3.000159
k 0.0034 0.0112 0.0065 0.0153 0.0229 0.0218
 0.5
ln[(C-Ce)/(Co-Ce)]
C=156 mg/L
0
0 10 20 30 40 50 60 70 80 90 100 Linear (C=156 mg/L)

C=78 mg/L
-0.5
Linear (C=78 mg/L)

C=31 mg/L
-1
Linear (C=31 mg/L)

-1.5 C=14 mg/l

Linear (C=14 mg/l)

-2 C=7,8 mg/l

Linear (C=7,8 mg/l)

-2.5
C=3,1 mg/l

Linear (C=3,1 mg/l)

-3
t (min)
0.4
C=156 mg/L
0.2 Linear (C=156 mg/L)

0
0 f(x)10
= - 0.0033563852x
20 30 40 50 60 70 80 90 100
R² = 0.329140226
-0.2

-0.4

-0.6

-0.8

-1
t (min)
 0
0 f(x)10
= - 0.0112206902x
20 30 40 50 60 70 80 90 100
R² = 0.8419388032
-0.2
C=78 mg/L
-0.4 Linear (C=78 mg/L)

-0.6

-0.8

-1

-1.2

-1.4

-1.6

-1.8
t (min)
0.4

0.2
C=31 mg/L
Linear (C=31 mg/L)
0
0 f(x) 10
= - 0.0064549688x
20 30 40 50 60 70 80 90 100
R² = 0.3992525909
-0.2

-0.4

-0.6

-0.8

-1

-1.2

-1.4
t (min)
 0
0 f(x) =10
- 0.0153012287x
20 30 40 50 60 70 80 90 100
R² = 0.96628394
-0.2

-0.4

C=14 mg/l
-0.6
Linear (C=14 mg/l)

-0.8

-1

-1.2

-1.4

-1.6

-1.8

-2
t (min)
0.5
C=7,8 mg/l
0 Linear (C=7,8 mg/l)
0 f(x) =10
- 0.0229120382x
20 30 40 50 60 70 80 90 100
R² = 0.9962717335

-0.5

-1

-1.5

-2

-2.5
t (min)
 0
0 f(x) =10
- 0.0218411232x
20 30 40 50 60 70 80 90 100
R² = 0.9489612298 C=3,1 mg/l
Linear (C=3,1 mg/l)
-0.5

-1

-1.5

-2

-2.5
t (min)
 25.0

20.0
T (oC)

T(oC) 1
15.0
T(oC) 2
T(oC) 3
T(oC) 4
T(oC) 5
10.0
T(oC) 6

5.0

0.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 9.00

8.00

7.00

6.00
pH
1
pH

5.00 pH
2
pH
4.00 3
pH
4
3.00

2.00

1.00

0.00
0 10 20 30 40 50 60 70 80 90 100
t (min)