DATOS EXPERIMENTALES

Acetona Agua
Frasco
V1previo(mL) V2previo(mL) mpic+sol(g) T(C) Vpic(mL)
1 20 0 36.8686 9.868
2 19.2 1 37.0572 23.8
3 18.2 2.1 37.1930 22.4
4 17.1 2.9 37.4313 22.2
5 15 5 37.8920 26.5
6 11.9 8 38.0987 20.2
7 9.5 11.1 38.3133 26.2
8 6 14 38.5526 22.4
9 3 17 38.7640 23
10 1.9 18.1 38.8426 23.2
11 0 20 38.9242 21.8

PM(g/mol) teo(g/mL) Pureza

Acetona 58.08 0.7657377381 1
Agua 18.015 0.974047426 1
 1
2
3
4
5
6
7
8
9
10
11
 1 2
mpic(g) sol(g/mL) Vsol(mL/g)
29.3123 0.765738 1.305930151
0.784850 1.2741287815
0.798612 1.2521730303
0.822760 1.2154206183
0.869447 1.1501567654
0.890393 1.1230993353
0.912140 1.0963226308
0.936390 1.0679306949
0.957813 1.0440449866
0.965778 1.0354343515
0.974047 1.0266440558

15.3147547629

VE Xn ace Dens Tem Xnag

 0 1 0.784638 273.15 0
1.00498 0.7934 0.807383 296.95 0.2066
1.15707 0.6984 0.825797 295.55 0.3016
1.23355 0.5903 0.842508 295.35 0.4097
1.10639 0.3998 0.874098 299.65 0.6002
0.77602 0.2973 0.904105 293.35 0.7027
0.6552 0.2193 0.919968 299.35 0.7807
0.3247 0.0988 0.957313 295.55 0.9012
0.29176 0.0988 0.960497 296.15 0.9012
0.29176 0.0988 0.960497 296.35 0.9012
0 0 0.997019 294.95 1
 CL
3
V1real(mL) V2real(mL) m1(g) m2(g) xm
20.000 0.000 15.31475 0.00000 0.263684
19.200 1.000 14.70216 0.97405 0.253136
18.200 2.100 13.93643 2.04550 0.239952
17.100 2.900 13.09412 2.82474 0.225450
15.000 5.000 11.48607 4.87024 0.197763
11.900 8.000 9.11228 7.79238 0.156892
9.500 11.100 7.27451 10.81193 0.125250
6.000 14.000 4.59443 13.63666 0.079105
3.000 17.000 2.29721 16.55881 0.039553
1.900 18.100 1.45490 17.63026 0.025050
0.000 20.000 0.00000 19.48095 0.000000

Densidad Experimental y Bibliogrfica v

1.050000

1.000000

0.950000

0.900000
Densidad (g/mL)
0.850000

0.800000

0.750000

0.700000
0.000000 0.100000 0.200000 0.300000 0.400

densidad experimental

80

70

60

50

40

30

20
 60

50

40

30

20

10

0
0.000000 0.200000 0.400000 0.600

1.5

0.5

0
0.000000 0.200000 0.400000

-0.5

-1

-1.5

-2

-2.5

-3

Volumenes molares
80
70
60
50
40
30
20
10
0
0.000000 0.200000 0.400000 0.600

VOLUMEN MOLAR DE LA MEZCLA VOLUMEN MO

 CLCULOS
4 5
xm xn1 xn2 msol(g) Msol(g/mol)
0.000000 1.000000 0.000000 7.5563 58.080000
0.054069 0.823998 0.176002 7.7449 51.028484
0.113544 0.678797 0.321203 7.8807 45.210989
0.156799 0.589798 0.410202 8.1190 41.645261
0.270343 0.422474 0.577526 8.5797 34.941430
0.432550 0.266170 0.733830 8.7864 28.679118
0.600162 0.172660 0.827340 9.0010 24.932630
0.756962 0.094616 0.905384 9.2403 21.805783
0.919168 0.041256 0.958744 9.4517 19.667905
0.978643 0.024958 0.975042 9.5303 19.014934
1.081374 0.000000 1.000000 9.6119 18.015000

ntal y Bibliogrfica vs Fraccion Molar de Etanol

200000 0.300000 0.400000 0.500000 0.600000 0.700000 0.800000 0.900000 1.000000

X1

densidad experimental densidad bibliografica

400000 0.600000 0.800000 1.000000 1.200000

0.400000 0.600000 0.800000

molares

400000 0.600000 0.800000 1.000000 1.200000

LA MEZCLA VOLUMEN MOLAR DE LA ACETONA VOLUMEN MOLAR DEL AGUA

 6 7 8
Vmsol(mL/mol) Vid(mL/mol) VE(mL/mol)
75.8484231701 75.848423 0.000000
65.0168596684 65.754110 -0.737250
56.6119814865 57.426311 -0.814330
50.616509207 52.321938 -1.705428
40.1881222987 42.725339 -2.537217
32.2094983302 33.760779 -1.551281
27.3342062257 28.397646 -1.063440
23.2870645186 23.921534 -0.634470
20.534177769 20.861142 -0.326964
19.6887155288 19.926407 -0.237692
18.4949926653 18.494993 0.000000

1.000000

0.000000
0.000000 0.200000 0.400000 0.600000 0.800000
volumen en exceso experimental, vs calculado
-0.500000

-1.000000

-1.500000

-2.000000

-2.500000

-3.000000
 -2.000000

-2.500000

-3.000000

Volumen en exceso experimental Volumen en Exceso RK

1.200000

1.000000 1.200000

.200000
 EC R-K
x1-x2
x^4 x^3 x^2 x
0 0 0 0
0.1763152199 0.2720929895 0.4198990592 0.647996
0.0163515099 0.0457265459 0.1278730227 0.357593
0.0010403723 0.0057928405 0.0322548022 0.179596
0.0005779686 -0.0037275905 0.0240409779 -0.155052
0.0478319145 -0.1022794356 0.2187050856 -0.467659
0.1837026365 -0.2805992734 0.4286054556 -0.654680
0.4321029165 -0.5329548248 0.6573453555 -0.810768
0.7086032331 -0.7723290085 0.8417857406 -0.917489
0.81479583632168 -0.8576036106 0.9026604214 -0.950084
0.00000000000000 0 0.000000 0.000000

2.3813216076 -2.2258813674 3.6531699206 -2.7705461886

COEFICIENTES
a b
9 -2.7705461886
-2.7705461886 3.6531699206
3.6531699206 -2.2258813674

0.800000 1.000000 1.200000

ntal, vs calculado
Volumen en Exceso RK
 EC R-K
VE/(x1*x2)
y xy x^2.y
0 0 0 a -7.433800
-5.0836008313 -3.294153958 -2.134599206 b 3.288970
-3.7349141954 -1.335580577 -0.477594768 c 2.442710
-7.0490801561 -1.265988149 -0.227366686
-10.398866766 1.612360233 -0.249998926
-7.9421029126 3.71419714 -1.736978297
-7.4445200582 4.873775851 -3.190761911
-7.4065199522 6.004972135 -4.868641491
-8.2663704479 7.584302494 -6.95851277
-9.7675280292 9.279976286 -8.816760967
0 0 0

-67.0935033489 27.17386145 -28.66121502

COEFICIENTES
c R
3.6531699206 -67.09350335
-2.2258813674 27.17386145
2.3813216076 -28.66121502
VEcalc(mL/mol) Vmol(ACETONA) Vmol(agua) (VEexp-VEcalc)^2/n-3coef
0 75.8484231701 0 0
-0.6202538381 75.1434441066 14.8161514214 0.0022813662
-1.2962705401 74.7733855886 16.8013881901 0.038711137
-1.6365355878 73.4182739962 15.273014226 0.0007910359
-1.9238676896 71.0379747119 14.9460927256 0.0626995546
-1.6480798669 69.8973446538 16.8862993486 0.0015616651
-1.2199363411 68.9500914905 17.4718556446 0.004081875
-0.7276861413 68.1985654856 17.8865747179 0.0014482201
-0.3320582985 67.7594554657 18.1734034768 4.32460048571655E-006
-0.2032854737 67.6367505468 18.2585507052 0.0001972988
0 68.4146231701 18.4949926653 0

Vmol a dil infinita Vmol dil etanol

ACETONA 18.494993 94.343416
agua 75.848423 94.343416

a1 3.6726982452
a2 1.7470738413
b1 -5.4353822841
b2
desviacin Estndar
0.3343298929 -16.1453189978 Esta celda tiene un
-15.61063429 -0.261471066
-15.5508349288 -0.2604694537
-14.8271823201 -0.2483485997
-12.7370660116 -0.2133400966
-11.8738123964 -0.1988809889
-11.4192430329 -0.1912671576
-11.2309882153 -0.1881139745
-11.347177346 -0.1900600899
-11.6909910997 -0.1958188148
-12.9632448309 -0.2171284896
54.9725322797 0.9207650597
 #VALUE! -0.5221715238
-26.1471066 -1.2524146389
-26.04694537 1.6788133491
-24.83485997 2.3876506808
-21.33400966 0.7094037813
-19.88809889 0.4187214159
-19.12671576 0.1888871611
-18.81139745 0.0126861406
-19.00600899 -0.0017286315
-19.58188148 -0.1706502661
-21.71284896 18.3890876838
92.07650597 18.4539067609