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38 nm 55 nm
1 (nm)
2 (nm)
characteristics of HZO-TFTs fabricated at
low temperature
0
film thickness : 88 nm 1 0 1 0
J.C. Dong, F.L. Zhao, S.D. Zhang, L.F. Liu, X. Zhang and film thickness : 55 nm 88 nm 165 nm
Y. Wang
4 (nm)
2 (nm)
The channel process to further improve the performance of bottom gate
0
film thickness : 38 nm 0 1 0
hafnium-doped zinc oxide (HZO) thin-film transistors (TFTs) is opti- 1
1 1
mised. The effects of channel thickness on the electrical performances (mm) (mm)
of HZO TFTs is studied. The results show that the extracted saturation 30 32 34 36 38 40 42 44
mobility increases first and then decreases with the increase of HZO 2q, deg
a b
film thickness, reaching maximum when the channel thickness is
optimum. The dependence of the optimum thickness on channel
length is studied and it is found that optimum thickness increases Fig. 2 XRD and AFM results of HZO films with different thickness
with the increase of channel length. a XRD images for different thicknesses of HZO film
b AFM images for different thicknesses of HZO film
Introduction: For many years, silicon-based TFTs have been the key 10–3
components of the electronic flat-panel-display industry. However,
10–4
with the development of high-resolution, high-frame-rate and high-size
AMLCD and the emerging market of AMOLED, the performance of 10–5
silicon-based TFTs are not enough to satisfy the demand of industry 10–6
[1]. Oxide semiconductor TFTs are promising candidates for better per- 10–7
ID, A
formance than silicon-based TFTs and potential application for W/L = 100 mm/10 mm
10–8
AMOLEDs and high-end AMLCDs. Oxide semiconductor materials 38 nm
10–9 55 nm
have quite high electron mobility to drive the high-end AMLCDs and
88 nm
AMOLEDs. In addition, most oxide semiconductor TFTs are transpar- 10–10
165 nm
ent devices in the visible light region. Oxide semiconductor TFTs can 10–11
be used to realise transparent displays.
10–12
Oxide semiconductor TFTs have been the mainstream of the industry,
especially ZnO-based TFTs. ZnO TFTs have high performance and high 10–13
–5 0 5 10 15 20
light transmittance for a wide bandgap of 3.4 eV. However, ZnO film is VG, V
polycrystalline and hence the off-state current is high and the uniformity
is poor. Doped ZnO can solve these problems. Hafnium doped ZnO Fig. 3 Transfer characteristics of HZO TFTs with different channel thick-
TFTs have many advantages: Hf has high oxygen bonding ability and nesses: 38, 55, 88 and 165 nm with W/L = 100 μm/10 μm for VD = 5 V
it is easy to improve stability of HZO TFTs; Hf will supress the colum-
nar growth and change the material’s crystal structure [2]; Hf is environ-
10–3
mentally friendly but In and Ga in IGZO film are toxicants. Our group
10–4
has successfully fabricated high-performance HZO TFTs [3]. In this
work, we will optimise the channel process to further improve the per- 10–5
10–8
Experiments: HZO TFTs are fabricated on glass substrate as shown in 38 nm
10–9 55 nm
Fig. 1. The ITO deposited at room temperature (RT) by RF magnetron 88 nm
sputtering is as a gate and S/D electrode. The 200 nm-thick SiO2 formed 10–10 165 nm
by plasma enhanced CVD at 80°C is as the gate insulator. A lift-off 10–11
process is used to form the pattern. An HZO layer is deposited at RT 10–12
by RF magnetron sputtering. When depositing HZO, we use a ZnO:
–5 0 5 10 15 20
Hf target as the source and the Hf concentration of ZnO:Hf target is
VG, V
3%. We have four samples with different HZO thickness which are
38, 55, 88 and 165 nm. Other process conditions remain the same: the
oxygen partial pressure is 12%, the sputtering pressure is 1.2 Pa and Fig. 4 Transfer characteristics of HZO TFT with different channel thick-
nesses: 38, 55, 88 and 165 nm with W/L = 100 μm/50 μm for VD = 5 V
the sputtering power is 70 W. The highest temperature in the process
of lithography is 100°C. Hence all the process steps mentioned here
can be carried out on flexible substrate.
Results and discussion: Fig. 2a illustrates the XRD images of different
The HZO thin-film characterisation is researched by atomic force
thickness HZO films on glass substrate. A sharp peak at 2θ ≈ 34.2° is
microscopy (AFM) and X-ray diffraction (XRD). Electrical perform-
observed and the sharp peak is very close to that of ZnO film. The
ance of HZO TFTs is tested by a semiconductor parameter analyser
peak position shows that the HZO film is just as the same with ZnO
(Agilent4156C) at RT.
film and crystallised in the hexagonal structure with a preferred c-axis
orientation, which reveals that Hf took the position of Zn in ZnO with
little change to the original crystal structure. The average grain size is
ITO
calculated using the Scherer formula [4] from the XRD peak width.
ITO
HZO The grain size increases from 18 to 30 nm with the increase of film
SiO2 thickness from 38 to 165 nm, which can be explained by the van der
ITO Drift model [5]. At the initial stage of deposition, the nuclei were devel-
glass oped at random orientation. However, then there was a competitive
growth stage and the vertical growth rate was larger than others.
a b
Finally, the crystals will be vertically oriented grains for a greater
growth rate at this orientation and larger grains are obtained over the
Fig. 1 Structure of HZO TFTs deposition time [6]. The increased grain size implied that the grain
a Cross-section view boundaries as electron scattering centres could be smaller in the
b Top view picture of TFTs on glass substrate thicker film [7]. Therefore it is expected that the electron mobility
total resistance, kW
50 40 WL = 100 mm/50 mm
Figs. 3 and 4 shows the transfer characteristics of HZO TFTs with 5
40
different channel thicknesses: 38, 55, 88 and 165 nm with VD = 5 V. 4 30
30
Figs. 3 and 4 illustrate TFTs with W/L = 100/10 and W/L = 100/50 sep- 3
20
20
arately. From the transfer characteristics, we can extract electrical par- 10
2
10
ameters of HZO TFTs. The saturation mobility (μsat) can be extracted 0
1
150
Zhao, L.F. Liu, X. Zhang and Y. Wang (Institute of Microelectronics,
100 Peking University, Beijing, 100871, People’s Republic of China)
50 ✉ E-mail: handedong@pku.edu.cn
0
References
20 40 60 80 100 120 140 160 180
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