LAMPIRAN C

HASIL ANTARA
C.1. Kalibrasi Termometer

Tabel C.1. Data Kalibrasi Termometer

Percobaan Literatur
Termometer
Tb (˚C) Td (˚C) Tb (˚C) Td (˚C)
Alkohol 150 ˚C 0 98 0 98.5
Raksa 250 ˚C 0 98 0 98.5
Alkohol 360 ˚C 0 98 0 98.5
Raksa 110 ˚C 0 98 0 98.5

120

100

80
TLiteratur

60

40

20
y = 1.0051x
0 R² = 1
0 20 40 60 80 100
TPercobaan

Gambar C.1. Kalibrasi Termometer Alkohol 150°C

120

100

80
TLiteratur

60

40

20
y = 1.0051x
R² = 1
0
0 20 40 60 80 100

TPercobaan

Gambar C.2. Kalibrasi Termometer Raksa 250°C

 120

100

80

TLiteratur 60

40

20
y = 1.0051x
0 R² = 1
0 20 40 60 80 100
TPercobaan

Gambar C.3. Kalibrasi Termometer Alkohol 360°C

120

100

80
TLiteratur

60

40

20
y = 1.0051x
R² = 1
0
0 20 40 60 80 100
TPercobaan

Gambar C.4. Kalibrasi Termometer Raksa 110°C

C.2. Kalibrasi Piknometer Dan Penentuan Densitas Metanol

C.2.1. Kalibrasi Piknometer

Tabel C.2. Data Kalibrasi Piknometer

Massa Piknometer Kosong (gram) 11,7750

Massa Piknometer + Aquadest (gram) 17,1468
Massa Piknometer + Metanol (gram) 15,9632
Massa Aquadest (gram) 5,3718
Massa Metanol (gram) 4,1882
 C.2.2. Penentuan Densitas Metanol

Tabel C.3. Data Penentuan Densitas Metanol

Densitas Aquadest (g/mL) 0,9965

Volume Piknometer Sebenarnya (mL) 0,0054
Densitas Metanol (g/mL) 0,7769

C.3. Kalibrasi Refraktometer

Tabel C.4. Data Kalibrasi Refraktometer

Indeks Bias
Zat
1 2 3 Rata-Rata Literatur
Aquadest 1,334 1,334 1,334 1,334 1,331

Benzene 1,495 1,496 1,497 1,496 1,490

Tabel C.5. Indeks Bias Metanol Teknis

Indeks Bias
Zat
1 2 3 Rata-Rata

Metanol Teknis 1,327 1,327 1,327 1,327

Kalibrasi Refraktometer
1.5
1.48
1.46
1.44
ηLiteratur

1.42
1.4
1.38
1.36
y = 0.9761x + 0.0293
1.34
R² = 1
1.32
1.32 1.34 1.36 1.38 1.4 1.42 1.44 1.46 1.48 1.5
ηPercobaan

Gambar C.5. Kalibrasi Refraktometer

C.4 Kalibrasi Pompa

Tabel C.6 Data Kalibrasi Pompa

Volume (mL) Volume Rata - Rata Laju Alir

Skala pompa Waktu (s)
1 2 3 (mL) (m3/s)
10 85 90 80 85 2.8333
20 120 130 110 120 4
30 150 160 140 150 5
40 190 200 220 203.3333 6.7778
50 200 220 210 210 7
30
60 240 250 230 240 8
70 260 270 250 260 8.6667
80 280 280 270 276.6667 9.2222
90 300 290 300 296.6667 9.8889
100 310 320 330 320 10.6667

12

10

8
Q (m3/s)

2
y = 0.0845x + 2.5556
R² = 0.9748
0
10 20 30 40 50 60 70 80 90 100
% Bukaan Pompa

Gambar C.6 Kurva Kalibrasi Pompa

 C.5. Hubungan Indeks Bias Campuran Terhadap Fraksi Mol Metanol

C.5.1. Penentuan Mol Aquadest

Tabel C.7 Data Pengamatan Mol Aquadest

Komposisi Massa Massa

Massa Mr Mol
Botol Volume Volume Botol Botol +
Aquadest Aquadest Aquadest
ke- Aquadest Metanol Kosong Aquadest
(gram) (gram/mol) (mol)
(ml) (ml) (gram) (gram)
1 5,0 0,0 9.4034 14.1959 4.7925 0.2663
2 4,5 0,5 9.6195 13.8802 4.2607 0.2367
3 4,0 1,0 9.6297 13.3199 3.6902 0.2051
4 3,5 1,5 9.5054 12.6601 3.1547 0.1753
5 3,0 2,0 9.1342 11.8179 2.6837 0.1491
6 2,5 2,5 9.614 11.8654 2.2514 18 0.1251
7 2,0 3,0 9.659 11.3451 1.6861 0.0937
8 1,5 3,5 9.4999 10.7057 1.2058 0.0669
9 1,0 4,0 9.3913 10.1205 0.7292 0.0405
10 0,5 4,5 10.5812 11.1296 0.5484 0.0305
11 0,0 5,0 9.5062 9.5062 0 0

C.5.2. Penentuan Fraksi Mol Metanol

Tabel C.8 Data Penentuan Fraksi Mol Metanol

Komposisi Massa
Massa
Botol + Massa Mr Mol
Botol Volume Volume Botol +
Aquadest + Metanol Aquadest Metanol
ke- Aquadest Metanol Aquadest
Metanol (gram) (gram/mol) (mol)
(ml) (ml) (gram)
(gram)
1 5,0 0,0 14.1959 14.1959 0 0
2 4,5 0,5 13.8802 14.2323 0.3521 0.011
3 4,0 1,0 13.3199 13.947 0.6271 0.0196
4 3,5 1,5 12.6601 13.7657 1.1056 0.03455
5 3,0 2,0 11.8179 13.2519 1.434 0.04481
6 2,5 2,5 11.8654 13.6427 1.7773 32 0.05554
7 2,0 3,0 11.3451 13.5677 2.2226 0.06946
8 1,5 3,5 10.7057 13.2513 2.5456 0.07955
9 1,0 4,0 10.1205 13.2731 3.1526 0.09852
10 0,5 4,5 11.1296 14.5542 3.4246 0.10702
11 0,0 5,0 9.5062 13.3099 3.8037 0.11887
 C.5.3. Hubungan Indeks Bias Campuran Dan Fraksi Mol Metanol

Tabel C.9. Data Indeks Bias Campuran Dan Fraksi Mol Metanol

Botol Indeks Bias

Fraksi Mol
Ke- 1 2 3 Rata - Rata Koreksi Metanol
1 1.335025 1.33502 1.33502 1.3350217 1.332415 0
2 1.33702 1.33701 1.33608 1.3367033 1.334056 0.04442
3 1.338035 1.338035 1.338035 1.338035 1.335356 0.08725
4 1.34106 1.34006 1.34006 1.3403933 1.337658 0.16467
5 1.342065 1.34206 1.34206 1.3420617 1.339286 0.2311
6 1.34307 1.34307 1.34307 1.34307 1.340271 0.3075
7 1.342065 1.34206 1.34206 1.3420617 1.339286 0.42578
8 1.34005 1.34005 1.34005 1.34005 1.337323 0.54286
9 1.33602 1.33602 1.335015 1.335685 1.333062 0.70862
10 1.33401 1.33401 1.33401 1.33401 1.331427 0.7784
11 1.329 1.329 1.329 1.329 1.326537 1

1.342

1.34

1.338

1.336

1.334
η

1.332

1.33

1.328

1.326

1.324
0 0.05 0.1 0.15 0.2 0.25 0.3 0.35 0.4 0.45 0.5 0.55 0.6 0.65 0.7 0.75 0.8 0.85 0.9 0.95 1
xM

Gambar C.7. Hubungan Indeks Bias Campuran Terhadap Fraksi Mol Metanol
C.6 Distilasi Kontinyu Refluks Parsial

Tabel C.10 Data Umpan

Volume Metanol (mL) 1024

Volume Aquadest (mL) 803
Indeks Bias Umpan 1,34022
Fraksi Umpan (Xf) 0.34

Tabel C.11. Data Perolehan Bottom

Suhu Massa Botol

Waktu Massa Botol + Massa Bottom
Suhu (°C) Koreksi Kosong
(Menit) Bottom (gram) (gram)
(°C) (gram)
10 72 72.367 9.2686 11.482 2.214

20 70 70.357 9.3597 12.517 3.158

30 66 66.337 9.3506 14.651 5.300

40 70 70.357 9.1532 11.676 2.523

50 76 76.388 8.9539 12.338 3.384

60 70 70.357 9.2837 11.413 2.129

70 69 69.352 9.7165 12.889 3.173

80 76 76.388 9.5217 13.908 4.386

90 76 76.388 13.2337 16.216 2.982

100 70 70.357 13.4369 18.386 4.949

110 79 79.403 11.7547 14.887 3.132

120 70 70.357 11.6260 14.024 2.398

130 70 70.357 11.6826 14.138 2.455

140 72 72.367 13.390 14.215 0.826

150 70 70.357 13.275 13.057 -0.218

42.789
Jumlah
 Tabel C.12. Data Perolehan Kolom 3

Suhu Massa Botol Massa Distilat

Waktu Massa Botol +
Suhu (°C) Koreksi Kosong Kolom 3
(Menit) Sampel (gram)
(°C) (gram) (gram)
10 55 55.281 9.453 9.542 0.089

20 52 52.265 9.473 9.823 0.350

30 59 59.301 9.350 10.600 1.249

40 50 50.255 9.287 10.710 1.423

50 54 54.275 9.135 10.919 1.784

60 48 48.245 9.604 10.318 0.714

70 56 56.286 6.332 11.380 5.048

80 53 53.270 6.487 8.341 1.854

90 56 56.286 13.432 13.672 0.240

100 57 57.291 13.314 13.533 0.219

110 60 60.306 11.738 12.776 1.037

120 57 57.291 11.847 11.973 0.126

130 60 60.306 11.824 12.124 0.300

140 52 52.265 13.313 13.832 0.519

150 56 56.286 12.198 12.924 0.725

15.677
Jumlah
 Tabel C.13. Data Perolehan Kolom 5

Suhu Massa Botol

Waktu Massa Botol + Massa Distilat
Suhu (°C) Koreksi Kosong
(Menit) Sampel (gram) Kolom 5(gram)
(°C) (gram)
10 53 53.270 9.532 10.414 0.882

20 49 49.250 9.210 9.792 0.582

30 55 55.281 10.552 10.701 0.149

40 50 50.255 9.435 9.694 0.259

50 48 48.245 9.320 9.521 0.202

60 48 48.245 9.289 10.243 0.954

70 53 53.270 9.153 9.994 0.841

80 45 45.230 9.369 9.543 0.174

90 51 51.260 9.522 9.718 0.196

100 50 50.255 13.480 17.859 4.379

110 55 55.281 13.550 14.513 0.963

120 51 51.260 11.875 12.818 0.944

130 50 50.255 13.470 13.535 0.065

140 48 48.245 13.391 14.198 0.808

150 50 50.255 13.252 13.792 0.541

11.937
Jumlah
 Tabel C.14. Data Perolehan Kolom 8

Suhu Massa Botol Massa Distilat

Waktu Massa Botol +
Suhu (°C) Koreksi Kosong Kolom 8
(Menit) Sampel (gram)
(°C) (gram) (gram)
10 51 51.260 9.461 12.058 2.596

20 43 43.219 9.588 10.694 1.106

30 55 55.281 9.619 13.563 3.944

40 49 49.250 9.723 11.587 1.863

50 45 45.230 9.490 12.461 2.972

60 45 45.230 9.661 13.937 4.277

70 49 49.250 9.873 11.216 1.343

80 42 42.214 9.114 11.107 1.993

90 46 46.235 11.755 12.322 0.567

100 40 40.204 13.228 13.916 0.688

110 49 49.250 11.839 11.923 0.084

120 43 43.219 11.888 11.891 0.003

130 42 42.214 11.749 11.860 0.111

140 43 43.219 11.941 11.983 0.041

150 42 42.214 11.875 11.880 0.005

21.593
Jumlah
 Tabel C.15. Data Perolehan Distilat

Suhu Massa Botol

Waktu Massa Botol + Massa Distilat
Suhu (°C) Koreksi Kosong
(Menit) Distilat (gram) (gram)
(°C) (gram)
10 42 42.214 9.216 11.482 2.267

20 42 42.214 9.699 15.262 5.563

30 42 42.214 6.198 19.290 13.091

40 40 40.204 6.424 11.237 4.813

50 40 40.204 6.442 9.166 2.724

60 42 42.214 6.424 20.785 14.361

70 40 40.204 6.198 15.088 8.890

80 42 42.214 6.467 15.407 8.940

90 42 42.214 6.434 14.358 7.924

100 42 42.214 6.487 12.465 5.978

110 42 42.214 6.078 11.532 5.455

120 42 42.214 6.112 13.473 7.361

130 42 42.214 6.332 13.174 6.842

140 42 42.214 11.683 22.122 10.439

150 42 42.214 13.390 23.255 9.865

114.511
Jumlah
 Tabel C.16 Data Perolehan Fraksi Mol Bottom
Waktu Indeks Bias Fraksi
(Menit) 1 2 3 Rata - Rata Koreksi Bottom
10 1.339040 1.339040 1.339040 1.339040 1.336337 0.12
20 1.342060 1.342060 1.342060 1.342060 1.339285 0.23
30 1.341055 1.341055 1.341055 1.341055 1.338304 0.18
40 1.342060 1.342060 1.342060 1.342060 1.339285 0.23
50 1.342060 1.342060 1.342060 1.342060 1.339285 0.23
60 1.341060 1.341060 1.341060 1.341060 1.338309 0.18
70 1.341040 1.341040 1.341040 1.341040 1.338289 0.18
80 1.342060 1.342060 1.342060 1.342060 1.339285 0.23
90 1.341055 1.341055 1.341055 1.341055 1.338304 0.18
100 1.339040 1.339040 1.339040 1.339040 1.336337 0.11
110 1.339055 1.339055 1.339055 1.339055 1.336352 0.11
120 1.341055 1.341055 1.341055 1.341055 1.338304 0.18
130 1.339040 1.339040 1.339040 1.339040 1.336337 0.12
140 1.339040 1.339040 1.339040 1.339040 1.336337 0.12
150 1.339040 1.339040 1.339040 1.339040 1.336337 0.12
Rata – Rata 0,168
 Tabel C.17 Data Perolehan Fraksi Mol Kolom 3
Waktu Indeks Bias Fraksi Mol
(Menit) 1 2 3 Rata - Rata Koreksi Kolom 3
10 1.342060 1.342060 1.342060 1.342060 1.33928 0.44
20 1.342060 1.342060 1.342060 1.342060 1.33928 0.44
30 1.342060 1.342060 1.342060 1.342060 1.33928 0.44
40 1.340050 1.340050 1.340050 1.340050 1.33732 0.54
50 1.342055 1.342055 1.342055 1.342055 1.33928 0.44
60 1.342055 1.342055 1.342055 1.342055 1.33928 0.44
70 1.342055 1.342055 1.342055 1.342055 1.33928 0.44
80 1.342055 1.342055 1.342055 1.342055 1.33928 0.44
90 1.342055 1.342055 1.342055 1.342055 1.33928 0.44
100 1.342055 1.342055 1.342055 1.342055 1.33928 0.44
110 1.342055 1.342055 1.342055 1.342055 1.33928 0.44
120 1.342055 1.342055 1.342055 1.342055 1.33928 0.44
130 1.342055 1.342055 1.342055 1.342055 1.33928 0.44
140 1.342055 1.342055 1.342055 1.342055 1.33928 0.44
150 1.342055 1.342055 1.342055 1.342055 1.33928 0.44
Rata – Rata 0.447
 Tabel C.18 Data Perolehan Fraksi Mol Kolom 5
Waktu Indeks Bias Fraksi Mol
(Menit) 1 2 3 Rata - Rata Koreksi Kolom 5
10 1.341000 1.341000 1.341000 1.341000 1.33825 0.50
20 1.340080 1.340080 1.340080 1.340080 1.337352 0.54
30 1.339040 1.339040 1.339040 1.339040 1.336337 0.57
40 1.341000 1.341000 1.341000 1.341000 1.33825 0.50
50 1.341000 1.341000 1.341000 1.341000 1.33825 0.50
60 1.339004 1.339004 1.339004 1.339004 1.336302 0.56
70 1.339004 1.339004 1.339004 1.339004 1.336302 0.56
80 1.339004 1.339004 1.339004 1.339004 1.336302 0.56
90 1.339004 1.339004 1.339004 1.339004 1.336302 0.56
100 1.339004 1.339004 1.339004 1.339004 1.336302 0.56
110 1.339004 1.339004 1.339004 1.339004 1.336302 0.56
120 1.339004 1.339004 1.339004 1.339004 1.336302 0.56
130 1.339004 1.339004 1.339004 1.339004 1.336302 0.56
140 1.339004 1.339004 1.339004 1.339004 1.336302 0.56
150 1.339004 1.339004 1.339004 1.339004 1.336302 0.56
Rata – Rata 0.547
 Tabel C.19 Data Perolehan Fraksi Mol Kolom 8
Waktu Indeks Bias Fraksi Mol
(Menit) 1 2 3 Rata - Rata Koreksi Kolom 8
10 1.338035 1.338035 1.338035 1.338035 1.33536 0.62
20 1.338040 1.338040 1.338040 1.338040 1.335361 0.62
30 1.337030 1.338030 1.338030 1.337697 1.335026 0.63
40 1.338055 1.338055 1.338055 1.338055 1.335375 0.62
50 1.338008 1.338008 1.338008 1.338008 1.33533 0.62
60 1.338030 1.338030 1.338030 1.338030 1.335351 0.62
70 1.338030 1.338030 1.338030 1.338030 1.335351 0.62
80 1.338030 1.338030 1.338030 1.338030 1.335351 0.62
90 1.338030 1.338030 1.338030 1.338030 1.335351 0.62
100 1.338030 1.338030 1.338030 1.338030 1.335351 0.62
110 1.338050 1.338050 1.338050 1.338050 1.335371 0.62
120 1.338050 1.338050 1.338050 1.338050 1.335371 0.62
130 1.338050 1.338050 1.338050 1.338050 1.335371 0.62
140 1.338030 1.338030 1.338030 1.338030 1.335351 0.62
150 1.338030 1.338030 1.338030 1.338030 1.335351 0.62
Rata – Rata 0.621
 Tabel C.20 Data Perolehan Fraksi Mol Distilat
Waktu Indeks Bias Fraksi Mol
(Menit) 1 2 3 Rata - Rata Koreksi Distilat
10 1.333000 1.333000 1.333000 1.333000 1.33044 0.84
20 1.333000 1.333000 1.333000 1.333000 1.330441 0.84
30 1.332000 1.332000 1.332000 1.332000 1.329465 0.88
40 1.332000 1.332000 1.332000 1.332000 1.329465 0.88
50 1.334005 1.334005 1.334005 1.334005 1.331422 0.79
60 1.332000 1.332000 1.332000 1.332000 1.329465 0.88
70 1.332000 1.332000 1.332000 1.332000 1.329465 0.88
80 1.332000 1.332000 1.332000 1.332000 1.329465 0.88
90 1.332000 1.332000 1.332000 1.332000 1.329465 0.88
100 1.333000 1.333000 1.333000 1.333000 1.330441 0.84
110 1.333000 1.333000 1.333000 1.333000 1.330441 0.84
120 1.333000 1.333000 1.333000 1.333000 1.330441 0.84
130 1.333000 1.333000 1.333000 1.333000 1.330441 0.84
140 1.333000 1.333000 1.333000 1.333000 1.330441 0.84
150 1.334005 1.334005 1.334005 1.334005 1.331422 0.79
Rata – Rata 0.849

Tabel C.21 Indeks Bias Bottom

Indeks Bias Awal 1,34022 1,34022 1,34022

Indeks Bias Akhir 1.33338 1.33338 1.33338

Tabel C.22 Data Bottom Akhir

Massa Botol Kosong (g) 28

Massa Botol + Bottom (g) 908
Massa Bottom (g) 880

C.6.1 Penentuan Jumlah Tahap

Tabel C.23 Data Penentuan Jumlah Tahap

xb 0,17
xd 0,85
xf 0,34
R 2,5556
 Tabel C.24. Data Kurva Kesetimbangan

T (˚C) P˚ Metanol P˚ Aquadest x y α

63.253 95.70 23.21 1.00 1.00 4.12
66.000 106.62 26.24 0.86 0.96 4.06
69.000 119.71 29.93 0.73 0.92 4.00
72.000 134.11 34.05 0.62 0.86 3.94
75.000 149.92 38.64 0.51 0.80 3.88
78.000 167.23 43.74 0.42 0.74 3.82
81.000 186.17 49.39 0.34 0.66 3.77
84.000 206.83 55.65 0.26 0.57 3.72
87.000 229.35 62.55 0.20 0.48 3.67
90.000 253.84 70.16 0.14 0.37 3.62
93.000 280.43 78.53 0.09 0.25 3.57
96.000 309.26 87.71 0.04 0.12 3.53
98.403 334.05 95.70 0.00 0.00 3.49

Gambar C.8. Kurva Kesetimbangan dan Perhitungan Tahap

C.6.2 Penentuan HETP

Tabel C.25 Data Penentuan HETP

Tinggi Kolom (cm) 96

Jumlah Tahap 4

HETP (cm/tahap) 24
C.6.3 Penentuan Efisiensi Tahap

Tabel C.26 Data penentuan Efisiensi Tahap

Tahap
4
Teoritis

Tahap
8
Sebenarnya

Efisiensi
50%
Tahap

C.6.4 Penentuan % Recovery

Tabel C.27 Data Penentuan % Recovery

Mol
Metanol 3,2538
Distilat
Mol
Metanol 23,9017
Umpan
%
13,6133%
Recovery