1

TEST-I
CHEMISTRY
PART-I
SECTION–I
Single Correct Choice Type
1. (C) H2SO4 + 2NaOH → Na2SO4 + 2H2O
(n = 2)
H2C2O4 + 2NaOH → Na2C2O4 + 2H2O
(n = 2)
Let number of millimoles of H2SO4 be a, and
Let number of millimoles of H2C2O4 be b.
Milliequivalents of acids = Milliequivalents of base

(a + b ) × 2 = 3 × 0.1 × 1000
…(i)
10
In another experiment, KMnO4 reacts with H2C2O4 only.
+7 ( +2 )
→ Mn 2+
K MnO 4 
n=5
(+3 ) (+4 )
C 2 O 24− 
→ C O2
n=2
Milliequivalents of H 2C 2O 4 = Milliequivalents of KMnO 4
1000
b × 2 = 4 × 0·02 × 5 × …(ii)
100
Solving (i) and (ii) we get
b = 2, a = 13
wt. of H 2SO 4 = 13 × 10 −3 × 98 = 1·274 g
1·274
wt. % of H 2 SO 4 = × 100 = 40%
3·185
x (x + y )
2. (A) HF(aq ) + H 2 O (ℓ ) F–(aq) + H3O+(aq) K a (HF) =
C1
C1– x x x
y (x + y )
HCOOH (aq ) + H 2 O (ℓ ) HCOO −(aq ) + H3O + (aq ) K a (HCOOH ) =
C2
C2– y y y

Note: 'α' is very less for both the acids due to being weak
x << C1 , y << C 2
x = αC 1 , y = α C 2

♥ Brilliant Tutorials Pvt. Ltd. IIT/B.MAT2/CPM/P(I)/Solns

 2

K a (HF)C1
[H O ]
3
+
total =x+y
x
=
y K a (HCOOH )C 2
=
6·6 × 10 −4 × 0·1
2 × 10 −4 × 0·2
⇒ x : y = 3.3 : 2

3. (C) Total surface area of carbon = 88 ×100m 2 = 88 ×10 6 cm 2

Surface area of NH 3 molecule = πr 2 =

22
7
( )
× 10 −8
2
=
22
7
×10 −16 cm 2

88 × 10 6 × 7
No. of molecules adsorbed = = 28 × 10 22
22 × 10 −16
( )
Vol. of N A 6 × 10 23 molecules at STP = 22·4 L
22·4
Vol. of 28 × 10 23 molecules at STP = × 28 × 10 22 = 10.45 L
6 × 1023

O O

4. (B) +

5. (C) III step is the slowest step because there is a ring expansion which involves the
breaking and formation of C – C bond.

6. (A) H 2SO 4 + 2 NaOH 

→ Na 2SO 4 + 2H 2O ...(i)
HNO3 + NaOH  → NaNO3 + H 2 O ...(ii)
no. of millimoles of NaOH = 20 × 0.1 = 2 millimoles
no. of millimoles of SO 24 − = 0.001 × 1000 = 1 millimole
Above data matched with eq. (i) Hence, formula of the complex is
[Cr(NH 3 )5 (NO3 )]SO 4
7. (C)
O OMgBr
Ph
PhMgBr Ph PhMgBr Ph
H3O+
O O OMgBr OMgBr
18 18 18
OH
⊕ Ph Ph
−H + H+ Ph
Ph Ph
O Ph
18 OH OH
(B) 18
18

♥ Brilliant Tutorials Pvt. Ltd. IIT/B.MAT2/CPM/P(I)/Solns

 3

8. (B) In solid form XeF6 exist as XeF5+ F − because XeF6 (pentagonal bipyramidal) is
unstable due to different types of Xe–F bond length.
For cationic part XeF5+
N 8 + 5 −1
= =6
2 2
Number of bond pair = 5.
Number of lone pair = 1.
Hybridization state is sp3d2.
F
F F
Xe ⊕
F F
..
SECTION–II
Multiple Correct Choice Type
9. (A, C, D)
⇒ Shape of orbital is decided by azimuthal quantum number, ℓ . The value of ℓ = 0
for s-orbital. Therefore, s-orbital is spherical. Angular momentum depends only
upon the value of ℓ and not on value of n.
⇒ Electrons in the same shell of a Bohr atom have same velocity.
Z
v n = × 2·18 × 10 8 cms −1
n
10. (B, D) The solution is non-ideal showing –ve deviation due to extra H-bonding.
CH3 Cl
C=O H – C Cl
CH3 δ+ δ– δ+ δ– Cl
11. (B, C, D)
•
•••OMe O OMe OMe
C
AlCl3 ZnHg/HCl
+ O COOH COOH
C
O O=C CH2
(A) (B)
O
C
+
⇒ O AlCl3
C
O

♥ Brilliant Tutorials Pvt. Ltd. IIT/B.MAT2/CPM/P(I)/Solns

 4
12. (A, C, D)
CH2NH2 +
CH2–N≡N
HONO
Cl–
273–278K

–N2,–Cl–
⊕
OH CH2 CH2
H2O ⊕

–H+ –H+
(c) (d)
⊕
H2O –H

CH2OH

(a)
13. (A, B, C)
(A) Cl 2 O 6 has paired electrons. In liquid or in aqueous solution, Cl − Cl bond
breaks giving one unpaired electron.
O O O
O = Cl – Cl = O O = Cl•

O O O

(B) In solid state, PBr5 exist as [PBr4 ]+ Br − .

(C) Due to high lattice energy these per chlorates are slightly soluble in water.
(D) In two dimensional sheet silicates, each tetrahedron shares three of its oxygen
atoms with the neighbouring tetrahedral units.

SECTION–III
Paragraph Type
Paragraph for Question Nos. 14 to 16
14. (C) Increase in H+ promotes dehydration step. It proceeds most effective at pH ≈ 3.5.
⊕
When pH is decreased most of the reagent NH2–Z gets converted into N H 2 − Z and
the first step slows down, that becomes rate determining step.

Ph Ph NH2
15. (C) C=N C=N
Me and (Geometrical)
NH2 Me

Me Me
Ph C = N–NH2 Ph CH – N=NH (Tautomerism)

16. (D)

♥ Brilliant Tutorials Pvt. Ltd. IIT/B.MAT2/CPM/P(I)/Solns

 5
Paragraph for Question Nos. 17 to 18

17. (C)
18. (B) 6CaO + P4O10 → 2Ca3(PO4)2
Mole of CaO = 6 × mole of P4O10
852
=6× = 6 × 3 = 18.
284
SECTION−IV
Integer Type
19. Three asymmetric carbon atoms are present in the given compound.
23 = 8.
Ans. 8
PVm Vm
20. Z= =
RT Vm perfect
Given, Vm = Vm perfect – 0·12 Vm perfect
= 0·88 Vm perfect
Vm
Z= = 0·88
Vm perfect

= 88 × 10−2
Ans. 2
21. Ist cell
At anode, → Cr 3+ + 3e − ,
Cr  , E º = +0·74 V
3+ − 2+
At cathode 3Cr + 3e 
→ 3Cr , E º = −0.40 V
3+ n =3 2+
Cr + 2Cr →
 3Cr , º
E cell = 0.34V
∆G º = − nF E cell
º
= −3 × 96500 × 0.34 = −98430 J
IInd cell
At anode → 3Cr 2 + + 6e − , E º = 0·91 V
3Cr 
2Cr 3+ + 6e − 
→ 2 Cr, E º = −0·74 V
At cathode =6
Cr + 2Cr 3+ n → 3Cr 2+ E cell
º
= 0·17 V
∆G º = −6 × 96500 × 0·17 = −98430 J
IIIrd cell
At anode Cr → Cr 2+ + 2e − , E º = 0·91 V
At cathode 2Cr3+ + 2e– → 2Cr2+, E° = –0.40 V
n =2
Cr + 2Cr3+ →
 3Cr2+ E° = 0.51 V
∆G° = –nFE° = –2 × 96500 × 0.51 = –98430 J.
Ans. 3

♥ Brilliant Tutorials Pvt. Ltd. IIT/B.MAT2/CPM/P(I)/Solns

 6
EA
22. ln k A = ln A −
RT
E
ln k B = ln B − B
RT
k E − E B 10·46 × 1000
So, ln B = A = = 3.37
kA RT 373 × 8·314
kB 3.37
or log = = 1.4633
k A 2.303
kB
= 29
kA
100 1 10
60 k A = ln ⇒ kA = ln
70 60 7
29 10
k B = 29 k A = ln
60 7
100
k B t = ln
30
 10 
ln 
60 (1 − 0.4771) 60 0.5229
t=   ; t=
3
= × = 7 min.
29 10 29 (1 − 0.845) 29 0.155
ln
60 7
Ans. 7
10 × 2 × 3600
23. Total charge passed through the electrolyte = F = 0.746 F
96500
If n is the oxidation state of metal in the salt, then
Equivalents of metal deposited = 0.25 × n = total charge passed in F.
∴ 0.25 × n = 0.746
⇒ n ~− 3
Ans. 3

24. Given compound exists in polar form in which both inner five membered ring as well as
outer peripheral part will have Huckel’s number of electrons.

Outer peripheral part has 14 π-electrons in close loop. Hence, n = 3.

Ans. 3

♥ Brilliant Tutorials Pvt. Ltd. IIT/B.MAT2/CPM/P(I)/Solns

 7

Cl Cl Cl
25. I I
Cl Cl Cl
Ans. 8

26. The corner atom C is shared by 6 unit cells. Hence, its effective contribution per unit cell is
1/6th.
Ans. 6

8RT
27. Vav =
πM
VHe M Ar 40
= = = 3.16
VAr M He 4
VHe = 3 VAr (approx)
Ans. 3

28. ∆G° = –nFE°

Cell reaction is
LiC6 + CoO2 → LiCoO2 + 6C
n = 1, F = 96500 C
E° = 3.70 V
∆G° = –1 × 96500 × 3.70 = 357050 = 3.57 × 105.
Ans. 5

♥ Brilliant Tutorials Pvt. Ltd. IIT/B.MAT2/CPM/P(I)/Solns

 8
PHYSICS
PART – II
SECTION – I
Single Correct Choice Type
29. 10t = 2T. Here T is tension in the string.
⇒ T = 5t
Block A will lose contact when F = 10 t
T ≥ mAg
5t ≥ mAg
⇒ t ≥ 2 sec
While block B will lose contact, when T T
T ≥ mB g
⇒ 5t ≥ m B g A B
or t ≥ 4 sec
For block A, at any time t ≥ 2 s
dv
5t −10 = a =
dt
v 4
⇒ ∫ 0
dv = ∫ (5t − 10)dt
2

v = 10 m/s
∴ (C)

( P0 + P0 − ρgh) ρgh
30. Pavg = = P0 −
2 2
F1 = (Pavg)hl
F2 = P0hl
F3 = Sl (surface tension is S)
l = length of aquarium inside the plane of paper
F1 + F3 = F2 P0 – ρgh
F2
 ρgh 
 P0 − hl + Sl = P0hl F1 h
 2  P0
F.B.D. of aquarium F3
ρgh 2
P0 h − + S = P0 h
2
2S
h= = 2 mm
ρg
∴ (B)

♥ Brilliant Tutorials Pvt. Ltd. IIT/B.MAT2/CPM/P(I)/Solns

 9
dN A dN B
31. = −λ1 N A , = 2 λ1N A − λ 2 N B ,
dt dt
dN B
N B = maximum ⇒ =0
dt
⇒ 2λ 1 N A = λ 2 N Bmax
2λ1
⇒ N Bmax = NA
λ2
2λ
⇒ N Bmax = 1 N 0e −λ1t = 2.
λ2
∴ (A)

32. As half the length of candle always remains submerged in water therefore density of
material of the candle is half the density of water. If it burns at the rate of 4 mm h–1, the
candle will come up at the rate of 2 mm h–1 from the water, then the top of the candle fall at
the rate of 2 mm h–1.
∴ (B)

1 2 −λ 2l dr λ 3
33. mv = ∫ + mgl ⇒ v = ln + 2 gl = 2.8 gl
2 2πε 0 3l r πε 0 m 2
∴ (A)

34. For multiple reflection 2θ ≥ 90°, θ ≥ 45°, θmin = 45° θ

θ
∴ (B)
θ

35. Maximum heat is released when block reaches the point A. v 02 = 2µgl , v0 = 2µgl
∴ (B)
36. The magnetic induction of the solenoid is directed along its R B
axis. Therefore, the Lorentz force acting on the electron at any O
instant of time will lie in the plane perpendicular to the A C
solenoid axis. Since the electron velocity at the initial moment v v'
is directed at right angles to the solenoid axis, the electron r ϕ
trajectory will lie in the plane perpendicular to the solenoid
axis. The Lorentz force can be found from the formula O1
F = evB .
The trajectory of the electron in the solenoid is an arc of the circle whose radius can be deter
mined from the relation evB = mv 2 / r , whence
mv
r=
eB

♥ Brilliant Tutorials Pvt. Ltd. IIT/B.MAT2/CPM/P(I)/Solns

 10
The trajectory of the electron is shown in figure, where O1 is the centre of curvature of the
arc AC described by the electron, v' is the velocity at which the electron leaves the
solenoid. The segments OA and OC are tangents to the electron trajectory at points A and
C. The angle between v and v' is obviously ϕ = ∠AO1C since ∠OAO1 = ∠OCO1 = 90 0
In order to find ϕ, let us consider the right triangle OAO1 ; side OA = R and side AO1 = r.
Therefore, tan(ϕ / 2) = R / r = eBR /( mv).
 eBR 
Therefore, ϕ = 2 tan −1  
 mv 
Obviously, the magnitude of the velocity remains unchanged over the entire trajectory since
the Lorentz force is perpendicular to the velocity at any instant. Therefore, the transit time
of electron in the solenoid can be determined from the relation
rϕ mϕ 2m  eBR 
t= = = tan −1  .
v eB eB  mv 
∴ (B)
SECTION – II
Multiple Correct Choice Type
37. In a frame moving with a velocity of 3 m/s along the z–axis, the displacement of the
particle from the equilibrium position is given by
 3 
∆r =  2iˆ − ˆj  cos 2ωt .


 2 
∴ (B, C, D)

38. As rod is in equilibrium, net force = 0, net torque = 0

Taking torque about hinge 2, N1 N2
L L
N1 × L =Mg × +F×
2 4
Mg F
∴ N1 = + = 11 N
2 4 Mg F
After breaking of hinge 2, rod is not in Before breaking of hinge 2
equilibrium,
⇒ Mg – N = Ma … (1)
N
and τ = I α
 L  ML
2
a
⇒ Mg   = .
2 3 ( L / 2)
 ML2  L 
∵ I = , a = α   Mg
 3  2  After breaking of hinge 2
3
⇒ a= g … (2)
4
From (1) and (2)

♥ Brilliant Tutorials Pvt. Ltd. IIT/B.MAT2/CPM/P(I)/Solns

 11
Mg
N= = 5N
4
By conservation of energy
L 1 1  ML2  2
Mg   = Iω2 =  ω
2 2 2  3 
3g
∴ ω=
L
∴ Acceleration of the end point = ω2L = 3g.
∴ (A, B, D)

39. Centre of mass should be at the same height in both cases.

∴ (A, D)

40. y = 2 A sin (kx − ωt )

 ∂K 
  = 2µA 2 ω2 sin 2 ωt
 ∂x  antinodes
 ∂U 
  = 2µA 2 ω2 cos 2 ωt
 ∂x  nodes
 ∂K   ∂U 
  +  = 2µA 2 ω2 = constant
 ∂x  antinodes  ∂x  nodes
For a point midway between a node and an adjacent antinode
∂K
= µA 2 ω2 sin 2 ωt
∂x
∂U
= µA 2 ω 2 cos 2 ωt
∂x
∂K ∂U
+ = µA 2 ω 2 = constant
∂x ∂x
Let y = A sin (kx − ωt ) + 2 A sin kx cos ωt
∂K 1  ∂y 
2

= µ  = µ[− 2 Aω sin kx sin ωt − Aω cos(kx − ωt )]

1 2

∂x 2  ∂t  2
∂U 1  ∂y 
2

= T   = V 2µ[2 Ak cos kx cos ωt + Ak cos(kx − ωt )]

1 2

∂x 2  ∂x  2
∴ (A, B, C, D)
dN B
41. = λ1 N A − λ 2 N B
dt
dN B 3N 0 3N 0
at, t = t0, = 0 , NB = ⇒ 2 N 0 λ1e −λ1t0 − λ 0 =0
dt 2 2
1 4 λ1
t 0 = ln
λ1 3 λ 2
∴ (A, C)
♥ Brilliant Tutorials Pvt. Ltd. IIT/B.MAT2/CPM/P(I)/Solns
 12
SECTION − III
Paragraph Type
Paragraph for Question Nos. 42 to 44
42. X L = 18 ×10−3 × 500 = 9Ω
1
XC = = 16 Ω
125 × 10 −6 × 500
 500 
i1 =   sin (500t − 37 º )
 15 
 500 
i2 =   sin (500t + 53º )
 20 
So phase difference = 90º.
∴ (C)

43. If S 1 is opened
(12 + 9 jˆ ) × (12 − 16 jˆ ) 288 − 84 j
Z = +8 = + 8 = 12 + 8 = 20 Ω
(12 + 9 j ) + (12 − 16 j )
ˆ ˆ 24 − 7 j
∴ (A)

44. If S 1 and S 2 both are opened

Z = 20 2 Ω
250 2
i rms = = 12.5 A
20 2
2
 25  625
Power =   × 20 = × 20 = 3.125 KW .
 2  4
∴ (B)
Paragraph for Question Nos. 45 & 46
1 π
45. cos θ = ; θ =
2 3
emf induced across the rod, between ends P and Q is
3R 3
v0 µ 0 i0
EPQ= ∫R 3
2
2 2π x
dx A
2 P Q
vµi i0 θ R/2
= 0 0 0 ln (3)
4π
The current loop can be redrawn as
v
EPAQ = EPBQ = 0 µ0i0 ln (3)
2π B
[∵ velocity of loop is v0)

♥ Brilliant Tutorials Pvt. Ltd. IIT/B.MAT2/CPM/P(I)/Solns

 13
Rπ EPAQ R1
R2 = λR(2π – 2θ) = 4λ
3
Rπ i1 EPQ
R1 = λR2θ = 2λ
3
i2 EPBQ
E − E PQ EPBQ − EPQ
i = i1 + i2 = PAQ +
R1 R2 R2
v0µ 0i0 ln 3  1 1  3 9v0µ 0i0 ln 3
=  +  =
4π  2 4  λRπ 16λRπ 2
∴ (C)

9µ 02i02 v0 (ln 3)
3 R 3/2 2
46. F= ∫ i Bdx = 32 Rλπ3
R 3
2

∴ (D)
SECTION − IV
Integer Type

q q Rdθ
47. dq = .Rdθ = .dθ dθ
2πR 2π
θ
dq qdθω
di = =
T 2π 2 π
qω
di = .dθ
4π 2
µ di ( R sin θ) 2
dB = 0
2R3
µ 0 sin 2 θ  qω 
π
∫ dB = ∫   dθ
0 2 R  4π 2 
µ 0 qω
B=
16πR
φ = Bπa2
µ qω
φ = πa 2 . 0
16πR
µ q ωa 2
φ= 0
16 R
dφ µ qa 2
|ε| = = 0 α= 8 V
dt 16 R
8
I = = 8A
1
Ans.: 8

♥ Brilliant Tutorials Pvt. Ltd. IIT/B.MAT2/CPM/P(I)/Solns

 14
48. Thermal resistance of the rod,
l
R=
kA
When heat is transferred from first vessel to second, temperature of first vessel decreases
while that of second vessel increases. Due to the both reasons, difference between
temperature of vessels decreases.
Let at an instant t, the temperature difference between two vessels be θ.
q KAθ
Rate of heat flowing, H = =
R l
KAθ
Amount of heat, dQ = Hdt = dt …(i)
l
Since gases are contained in two vessels, the processes gases are undergoing are isochoric
processes.
Hence, decrease in temperature of gas in first vessel,
dQ dQ dQ
∆θ1 = = =
nCV 5R 5R
2×
2
Increase in temperature of gas in second vessel is
dQ dQ
∆θ 2 = =
3R 6 R
4×
2
∴ Decrease in temperature difference (–dθ) = ∆θ1 + ∆θ2
dQ 11
− dθ = ×
R 30
KAθ × 11
or, − dθ = dt
30 Rl
25 dθ KA × 11 t
−∫
30lR ∫0
or = dt
50 θ

KA × 11
or, ln2 = t
30lR
0.693 × 30 × 242 × 10 −2 × 8.3 × 7
or t= = 3 seconds.
693 × 7 × 22 × 8.3 × 10 − 4 × 11
Ans.: 3

49. Copper expands more than steel, so increase in temperature will lead to elastic compression
of the copper. Let F be the force with which the copper plate is controlled.
Fl
Net expansion of copper, x = lα c ∆θ −
YC A
Fl
Net expansion of steel, x = lα s ∆θ +
YS 2 A

♥ Brilliant Tutorials Pvt. Ltd. IIT/B.MAT2/CPM/P(I)/Solns

 15
2(α c − α s ) A∆θYsYc
On solving, F =
Yc + 2Ys
3
= 112 × 10 N = 112 kN = 56 n kN
∴ n=2
Ans.: 2

50. C1C2 = b – R
In ∆C1 PC2 , ⊗B
b–R= R +a
2 2 v0
p
a
b2 − a 2 C1 R
i.e. R =
2b
C2
mv02
Also, ev0 B =
R
mv0
R=
eBmin
mv0 b2 − a2
∴ =
eBmin 2b
⇒ Bmin = 3T
Ans.: 3

51. At a point at depth y from free water surface, pressure is P = yρg. Due to this pressure, water
molecules are compressed. Hence, an elastic deformation energy (strain energy) is stored in
P2
water molecules. That strain energy per unit volume is given by .
2B
Now consider a thin layer of water of thickness dy at depth y from free water surface
Volume of this layer = A dy
∴ Strain energy stored in water molecules of this layer,
P2 ρ2 g 2 A 2
dU = A dy = y dy
2B 2B
∴ Total strain energy stored in water of the vessel,
ρ2 g 2 A h 2
U = ∫ dU =
2 B ∫0
y dy

ρ2 g 2 Ah3
or U= = 5 × 10–7 J
6B
Ans.: 5

♥ Brilliant Tutorials Pvt. Ltd. IIT/B.MAT2/CPM/P(I)/Solns

 16
52. Let the angle of projection of the particle be θ.
y 30

θ 10
x
O 40
The path of the particle has to pass through the point where x = 40, y = 10
Using the equation of the path of the projectile in the form
x2 g
y = x tan α − (1 + tan 2 α)
2v 2
x2
gives, y = x tan θ − (1 + tan 2 θ)
180
The point (40, 10) lies on this path, hence
80
10 = 40 tan θ − (1 + tan 2 θ)
9
⇒ 8 tan θ − 36 tan θ + 17 = 0 … (1)
2

This is a quadratic equation in tan θ with two positive roots. Therefore there are two values
of θ less than 90°, giving two possible angles of projection.
tan α + tan β
Now we are asked to calculate tan(α + β) which is equal to
1 − tan α tan β
where tan α and tan β are the roots of equation (1).
36 9
Hence tan α + tan β = = (sum of roots)
8 2
17
and tan α tan β = (product of roots)
8
9/2
Therefore tan(α + β) = = −4
1 − (17 / 8)
⇒ tan[−(α + β)] = − tan(α + β) = – (–4) = 4
Ans.: 4

53. For any plane parallel to X-Y plane, z = constant.

Hence, V = ax 2 + ay 2 + constant
For equipotential surface,
V =constant say V0
Hence V0 – constant = ax 2 + ay 2 = k (k = constant)
Which is the equation of a circle.
Substituting a = 1.25 × 103 V/m2,
V = 6250 V and z = 2 m in the given equation we get

♥ Brilliant Tutorials Pvt. Ltd. IIT/B.MAT2/CPM/P(I)/Solns

 17
6250 = (1.25 × 103) (x2 + y2 + 2 × 2)
or x 2 + y2 = 1
This is the equation of circle of radius 1 m.
Ans.: 1

54. The above arrangement can be redrawn as

O n =1
3 3
n= n=2 n=2 n=
40cm 2 2

9 cm 10 cm 10 cm 9 cm
 2  1
Shift = 181 −  + 201 −  = 16 cm
 3  2
Separation between object and image = 40 + 19 + 19 + 16 = 94 cm
∴ n=6
Ans.: 6

4
55. λα =
3R( Z − 1) 2
hc hc
Cut off wavelength λ1 = and λ2 =
eV1 eV2
Using given equation −
λ2 − λα = η( λ1 − λα)
hc  η 1  4(η − 1)
⇒  −  =
e V1 V2  3R( Z − 1) 2
By putting all the values, η=3
Ans.: 3

56. When rod is displaced to the right, the spring remains undeformed
l ml 2
∴ mg θ = − α
2 3
3g
α=− θ
2l
2l
T1 = 2π
3g

♥ Brilliant Tutorials Pvt. Ltd. IIT/B.MAT2/CPM/P(I)/Solns

 18
When rod is displaced to the left,

kx θ

mg kx
l l
mg θ + kxl − kx = − Iα
2 2
l l ml 2
mg θ + kx = − α
2 2 3
l l2 ml 2
mg θ + k θ = − α
2 4 3

(2mg + kl )θ = − 4ml α
3
3(kl + 2mg )
α=− θ
4ml
4ml
T2 = 2π
3(kl + 2mg )
∴ time period of oscillations is
T1 + T2 4ml 2l
T= =π +π
2 3(kl + 2mg ) 3g

=π
8
3 × 80
+π
2
30
=
π
30
1+ 2 ( )
∴ n=2
Ans.:2

♥ Brilliant Tutorials Pvt. Ltd. IIT/B.MAT2/CPM/P(I)/Solns

 19
MATHEMATICS
PART – III
SECTION - I
Single Correct Choice Type

z −z z P
57. (C) Clearly P  will lie on imaginary axis –z
 2 
z−z z−z π
P ′  ⇒ arg   is −
 2   2  2
∴ (C) is the correct answer
z −z
P′
4000
58. (B) = 10 ⇒ a1 a 4001 = 400
a1 a 4001
a1 + a4001 = 50
(a1 – a4001)2 = (a1 + a4001)2 – 4a1 a4001
⇒ |a1 – a4001| = 30

π
59. (C) sin–1 (sinθ) > – sin–1(sinθ)
2
π
sin–1 (sinθ) >
4
1
⇒ sinθ >
2
π 3π
⇒ <θ<
4 4

60. (B) F ' ( x) = 0

⇒ F(x) = c
x2 – 2x + 3 ≥ c ∀ x
⇒ c≤2
5
25
A = ∫ x.c dx ⇒ c
0
2
⇒ greatest area = 25

61. (A) A and B are ( 5 , 1) and (− 5 , − 1) .

Let C be (2 sec θ, 2 tan θ)
O(0, 0) is the mid point of AB
1
Slope of OC = sin θ and slope of AB =
5
Since OC ⊥ AB
So, sin θ = − 5 which is impossible.

♥ Brilliant Tutorials Pvt. Ltd. IIT/B.MAT2/CPM/P(I)/Solns

 20
62. (D) P ( A'∩B ' ) = 0.6
⇒ P ( A ∪ B )' = 0.6
⇒ P ( A ∪ B ) = 0.4
∴ P ( A ∩ B ' or A'∩ B )
= P ( A ∩ B ' ) + P ( A'∩ B )
= P(A ∪ B) – P(A ∩ B) = 0.4 – 0.3 = 0.1

63. (D) Let there be a value of k for which x 3 − 3 x + k = 0 has two distinct roots between
0 and 1.
Let a, b be two distinct roots of x 3 − 3 x + k = 0 lying between 0 and 1 such that a < b.
Let f (a) = f (b) = 0. Since between any two roots of a polynomial f (x) there exists at least
one roots of its derivative f ′ (x). Therefore f ′ (x) = 3 x 3 − 3 has at least one root
between a and b. But f ′(x) = 0 has two roots equal to ± 1 which do not lie between a and b.
Hence f (x) = 0 has no real roots lying between 0 and 1 for any value of k.
f " ( x)
64. (A) f " ( x) = f ' ( x) ⇒ =1
f ' ( x)
On integrating,
f ' ( x ) = Ce x
Which gives f (x) = Ce x + D
But f (0) = 1 ⇒ C + D = 1
∴ f (x) = Ce x +1 − C
So, f ' ( x ) = Ce x
1
Putting it in f ' ( x) = f ( x) + ∫ f ( x) dx
0
1
2
⇒ Ce x = Ce x + 1 − C + ∫ (Ce x + 1 − C ) dx ⇒ C =
0
3−e
2e − e + 1
x
So, f ( x ) =
3−e

SECTION - II
Multiple Correct Choice Type

65. (B), (D) B

1 3
= 30°
3 h + k − 2 h − 4k − 4
2 2 P
(h, k) (1, 2)
O

⇒ x 2 + y 2 − 2 x − 4 y − 31 = 0
So locus of P is a circle of radius 6

Locus of Q is (x − 1) + ( y − 2) = 6 2
2 2
( ) 2

♥ Brilliant Tutorials Pvt. Ltd. IIT/B.MAT2/CPM/P(I)/Solns

 21
66. (A), (B), (C)
f (x ) = e 2 x
ln 3
(A) ∫ [e
x
] dx = ln 2 + 2(ln 3 − ln 2 ) = ln 9 − ln 2 = ln 4.5
0

(B) lim+ [e 2 x ] = 1; lim−[e 2 x ] = 0 ⇒ lim[e 2 x ] does not exist

x →0 x →0 x →0

(C) f −1 ( x ) = ln x , V x > 0
−4 x
(D) e 2 x < e x ; 2x < x 2 − 4x
2

⇒ x 2 − 6 x > 0 ⇒ x < 0 or x > 6 .

67. (A), (B)

b − a = c − b = d − c = λ (say)
x+a x+b x+a−c x+a x+b x+a−c x+a λ x+a−c
f ( x) = x + b x+c x −1 = λ λ − 1 + 2λ = λ 0 − 1 + 2λ
x+c x+d x−b+d λ λ 1 + 2λ λ 0 1 + 2λ

↓ ↓
R2 → R2 − R1 C 2 → C 2 − C1
R3 → R3 − R2

f ( x) = −λ (λ + 2λ2 + λ − 2λ2 ) = −2λ2

2
∫ − 2λ2 dx = −4 ⇒ 2λ2 [ x]02 = 4 ⇒ 2λ2 × 2 = 4 ⇒ λ2 = 1 ⇒ λ = ±1
0

68. (A), (C)

(α − β)2 = (16 + 20i − 4 M ) ⇒ 16 + 20i − 4M = 28
⇒ M − 4 − 5i = 7
69. (A), (B), (C), (D)

SECTION - III
Paragraph Type
Paragraph for Question Nos. 70 to 72

dy 1
70. (C) =
dx x + y
Let y + x = v
dy dv
+1 =
dx dx

♥ Brilliant Tutorials Pvt. Ltd. IIT/B.MAT2/CPM/P(I)/Solns

 22
dv 1
−1 =
dx v
dv v + 1
=
dx v
 v + 1 − 1
dv  = dx
 v +1 
v – ln (v + 1) = x + c
y + x – ln (x + y + 1) = x + c
at x = 0, y = 0
c=0
y = ln (x + y + 1)
x = ey – y – 1
dy 1
= y
dx e − 1
dy 1 1
⇒ = ln 3 =
dx ln 3 e − 1 2

∫ (e )
1
71. (C) Area = y
− y − 1 dy
0

1 5
=e− −2=e−
2 2
72. (B)

Paragraph for Question Nos. 73 and 74

73. (A) g′(x) = x2 + x + 1
⇒ g(x) is increasing function
g(0) = 0
Now for x ≥ 0
g(x) ≥ g(0)
⇒ g(x) ≥ g(0)
⇒ g(x) > 0 ∀ x > 0





Since A, B makes obtuse angle A . B < 0
⇒ 2f(x) g(x) < 0
⇒ f(x) < 0

74. (B) lim g ( x) → + ∞

x →∞

lim f ( x ) → − ∞ or some negative number

x →∞

⇒ lim f ( x) g ( x) → − ∞
x →∞

♥ Brilliant Tutorials Pvt. Ltd. IIT/B.MAT2/CPM/P(I)/Solns

 23
SECTION – IV
Integer Type

2ac 2ac
a+ c+
a+b c+b a+c + a + c = a + 3c + 3a + c = 1 + 3c a
75. + =  + ≥4
2 a − b 2c − b 2ac 2ac 2a 2c 2a c
2a − 2c −
a+c a+c
1 1 1
+ + + ....∞
also λ λ λ.....∞ = λ2 4 8
=λ
∴ λ=4
Ans. 4

e
76. f ( e) = ⇒ fof (e) = e
e −1
2

 e
 n is odd
∴ fff ...... f (e) =  e 2 − 1
e



n times
 n is even
3
∴ ∫ fff .... f (e)de = 4 (n is even)
1
Ans. 4

77. x + 2 y = 10, where x is the number of times he takes single steps, and y is the number of
times he takes two steps

Cases Total number of ways

1. x = 0, y = 5 5! / 5!= 1
2. x = 2, y = 4 6! / 2!4!= 15
3. x = 4, y = 3 7! / 4!3!= 35
4. x = 6, y = 2 8!/ 2!6!= 28
5. x = 8, y = 1 9!/ 8!= 9
6. x = 10, y = 0 10!/10! = 1
∴ p = 89
Ans. 1
1  3
78. equation of normal is y − t 2 = − ( x − t ) it passes through  0, 
2t  2
∴ t = 0 or t = 1, − 1
hence P, Q, R are (0, 0) (1, 1) and (–1, 1)
⇒ PQR is a right triangle
∴ radius of circum circle is 1.
Ans. 1

♥ Brilliant Tutorials Pvt. Ltd. IIT/B.MAT2/CPM/P(I)/Solns

 24
−e
b x/a b/ x
e
79. I =∫ dx
a
x
x b
Put =
a y
b y
e −e  ab 
a y a
⇒ Ι=∫  − 2  dy
b
ab  y 
y
eb / x − e x / a
b
=∫ dx = − Ι
a
x
⇒ 2I = 0
⇒ I=0
Ans. 0

  h   h
f  x1 +   − f ( x) f ( x ) f 1 +  − f ( x )
f ( x + h) − f ( x)  x 
= lim   x
80. f ' ( x) = lim = lim
h→0 h h → 0 h h → 0 h
h  h 
f ( x) 1 + g    
 x  x    f ( x)   h   f ( x)
= lim = lim1 + g    =
h→0 h x h → 0  x  x
f ( x)
⇒ =x
f ' ( x)
2 2
f ( x) dx x 1 5
⇒ ∫1 f ' ( x) 1 + x 2 = ∫1 1 + x 2 dx = 2 log 2 
a = 5, b = 2
Ans. 7

( A + B) × ( A + C ) = B × A + A × C + B × C











81.
(( A + B) × ( A + C )) × ( B × C ) = [ ACB]( B − C )

Thus the given expression becomes

[ ACB ]( B − C ).( B + C ) = [ ACB ](| B |2 − | C |2 ) = 0

Ans. 0

82. Differentiate both side

f ′(x) (1 – cosx) + f(x) sinx = 0
f ′( x) sin x
∫ f ( x) dx = ∫ cos x − 1dx
x
ln |f(x)| = − 2 ln sin
2

♥ Brilliant Tutorials Pvt. Ltd. IIT/B.MAT2/CPM/P(I)/Solns

 25
c
f(x) = 2
 x
 sin 
 2
f(π) = 2 ⇒ c = 2
π
⇒ f =4
2
Ans. 4

83. y2 = ax
y=x+2
(x + 2)2 – ax = 0
x2 + x (4 – a) + 4 = 0
D≤0
a≤8
Ans. 8

84. PS = ePM ⇒ a ∈ (5, ∞) , then b = 5

Ans. 5

♥ Brilliant Tutorials Pvt. Ltd. IIT/B.MAT2/CPM/P(I)/Solns