The pair of given compounds exhibits ____ isomerism.

A) Structural
B) Geometrical alcohol
C) Optical phenol
D) Functional
-
Ans. (D)

(I) and (II) both have same molecular formula

but different functional groups.
Identity Z in the sequence of reactions
HBr/H2 O2 C2 H5 ONa
CH3CH2CH = CH2 Y Z
AMK

A) CH3-(CH2)3-O-CH2CH3
✓ c- c- c-
B) (CH3)2CH2-O-CH2CH3
C) CH3(CH2)4-O-CH3
g
D) CH3CH2-CH(CH3)-O-CH2CH3 Br

O C
C- C -
C -
C -
-

2115
Ans. (A)
 The rate constant K1 and k2 for two different
reactions are 1016.e-2000/T and 1015. e-1000/T,
respectively. The temperature at which K1 = K2 is:

1016 e- #=,j5
'
e- It
A) 1000 K
2000
B) K
e- 10001T
2.303
C) 2000 K 10 =

1000
D) K
iii. 2.303
¥1T
¥ 0001T
10 =
e'
log lˢ
2- 303
to =
Ans. (D)
 Which of the following orders correctly depicts the decreasing order of
stability of carbanion?
-

% -
m
) (2 -
m
)
Ans. (B)
A gaseous hydrocarbon gives upon combustion 0.72 g of
water and 3.08 g of CO2. The empirical formula of the
hydrocarbon is
→ Koz YHZO
Getty + Oz +

✓ A) C7H8 =
B) C2H4 A- 0007 3.8
C) C3H4 0.08
Ty °;÷
y
=

D) C6H5
0.07 0^04

2=7
-8
y
-
Ans. (A)
 A colloidal system having solid substance as a
dispersed phase and a liquid as a dispersion medium is
-

=
classified as:

A) Solid sol
B) Gel
C) Emulsion
D) Sol
Ans. (D)
The magnetic moment is associated with its spin angular
momentum and orbital angular momentum. Spin only
magnetic moment value of Cr3+ ion is
= hint Bm

A) 2.87 BM or 3d5 4s
'

#-)
→

✓B) 3.87 BM
Crt }
C) 3.47 BM → 3d3
D) 3.57 BM 155
Ans. (B)
 -

-
c) Buna s is the example of chain growth co-polymer
Find empirical formula of the compound containing a metal,
M = 68% (atomic mass = 34) and remaining 32% oxygen.

✓A) MO
m o
B) M2O
68% 32%
C) MO2
D) M2O3 68

7
gm %gm_
M 202
② ②
MO
✓
Myoy Ms 08
Ans. (A)
Element % mass No. of mole

M 68% 68/34 = 2

O 32% 32/16 = 2

Empirical formula = MO
The major product of the following reaction is
- -

aHgk
A) CH2 = CHCH = CHCH2CH3
B) CH2 = CHCH2CH = CHCH3
✓C) CH3CH = CH – CH = CHCH3
D) CH3CH = C = CHCH2CH3
Ans. (C)
 A certain metal when irradiated by light (v = 3.2 × 1016Hz)
-

emits photoelectrons with twice of K.E. as did photoelectrons

-

when the same metal is irradiated by light (v = 2.0 × 1016 Hz). .

The V0 of the metal is Ei Qt KE =

hit + KEZ
hdo 1- KE , hllz = .

A) 1.2 × 1014 H Z HIA =

KE , hit , hito KEZ : hitz hito

✓B) 8 × 1015 HZ
-

= -

C) 1.2 × 1016 HZ 2 ✗
KEY = keep
hit
D) 4 × 1012 HZ &×( hitz - hit) =
h↳ -

Uh Ho
262 - ZUO = -

Vo =
2T£ ↳ -

= 0 -8 ✗ 10lb
Ans. (B)
 Which one of the following statement is incorrect about
-

enzyme catalysts?

A) Enzymes are mostly protein in nature

B) Enzymes action is specific
C) Enzymes are denatured by ultraviolet rays and
at high temperature

mst
D) Enzymes are least reactive at optimum
temperature
Ans. (D)
 tf
What are the possible values of n, l and m1 for an atomic
orbital 4f?
A) n = 4, I = 0, m1 = -2, -1, 0, +1, +2 '
-
E
- B) n = 4, I = 3, m1 = -3, -2, -1, 0, +1+ +2, +3
C) n = 4, I = 2, m1 = -2, -1, 0, +1, +2, +3
D) n = 4, I = 0, m1 = -1, 0, +1
Ans. (B)
 CHZN #
z

'
on

-412N C
☒
Ans. (C)
 The first, second and third ionization enthalpies of an element
are 737, 1450 and 7731 kJ mol-1 respectively. What will be the
formulae of its oxide and chloride? 811307970€
A) M2O, MCI

ʳT;÷;÷
B) MO, MCI2
,
C) M2O3, MCI3
D) MO2, MCI4 =

MO MC / 2
Ans. (B)

The element belongs to group 2 and so it forms MO and

MCl2.
 0
In which of the following arrangements, the order is not
according to the property indicated against it?
A) AI3+ < Mg2+ < Na+ < F- : Ionic size
→
✗ B) B < C < N < O : First ionization enthalpy
C) I < Br < F < CI : Electron gain enthalpy with negative sign
D) Li < Na < K < Rb : Metallic radius
Ans. (B)
 Which of the following is correct regarding bond angles?
✗ (i) SO2 < H2O (ii) H2S < SO2
(iii) SO2 < H2S (iv) SbH3 < NO+2
A) ii and iv
E.
-
B) i, ii and iv
C) i and iii
D) None of these

"
y
o h
SPZ
104°
I /
7/1/60 ( 120°)
?⃝?⃝
?⃝
Ans. (A)
¥
"
Which compound exhibits maximum dipole moment among
the following?
A)
↑ ↑

↑
v
Ans. (B)

x
 Which of the following pairs have different hybridization and
same shape?
I
(i) NO −
3 and CO2− ✗
3
"
f-
÷ 0=c=0

(ii)SO2 and NH2− µ oh o

/

Spa
_
-

(iii)XeF2 and CO2 spz

(iv)H2 O and NH3 ✗
✗ A) i and iv
bent
✗ B) ii and iv N

+C) ii and iii § "o ✓

D) None of these
:O

h th ✓ ↑ -
n

ti
?⃝?⃝?⃝
Ans. (C)
Intermolecular hydrogen bonding is present in
(i)O-nitrophenol Cintra)
-

(ii)ROH
(iii)HF
(iv)H2O
A) (i) only
- B) (ii), (iii) & (iv) only
C) (iii) and (iv) only
D) All of these
Ans. (B)
 2571
-
e-
( Be 15 14 e-
-

(3)
Bond order of N2+ , N2− and N2 will be
A) 2.5, 2.5 and 3 respectively
-
B) 2, 2.5 and 3 respectively
C) 3, 2.5 and 3 respectively
D) 2.5, 2.5 and 2.5 respectively
Ans. (A)
 Study the following graph and mark the incorrect -

statement following it.

is
0b¥

A) At zero volume all lines meet at -273.15 0C. This temperature is

-
known as absolute zero
B) Each line of the volume vs temperature at constant pressure of graph
✗ is called isotherm
C) All gases obey Charles’ law at very low pressure and high temperature
D) Pressure remaining constant, volume of a gas is directly proportional
to its absolute temperature
Ans. (B)
0.5 moles of gas A and x moles of gas B exert a pressure of 200 -
- -

=
-

Pa in a container of volume 10 m3 at 1000 K. Given R is the gas

_

constant in JK-1 mol-1, X is

.

2𝑅 Pr = n RT

§
A) 4+𝑅
B)
C)
2𝑅
4−𝑅
4−𝑅
2%0×10 =
(0.5+2) R ✗

2𝑅
✓

%
D)
4+𝑅 0.51-a
=
2𝑅

✗ =

Ip Iz
-
=
¥
Ans. (C)
 0
An inorganic compound ‘y’ on heating gives a green
coloration & evolves O2 gas. Then, y is-

A) (NH4)2Cr2O7 +3
B) K2Cr2O7 →
C)
D)
CrO2CI2
Both A & C
;÷ .
Ans. (B)
☆
{ %④-%◦
Given C(graphite) + O2(g) → CO2(g); ∆𝑟 𝐻 0 = -393.5 kJ mol-1
1
H2(g) + 𝑂 → H2O(I); ∆𝑟 H0 = -285.8 kJ mol-1
2 2(𝑔)
CO2(g) + 2H2O(I) → CH4(g) + 2O2(g); ∆rH0 = +890.3 kJ mol-1 -1900

Based on the above thermochemical equations, the value of ∆rH0 at 298

K for the reaction, C(graphite) + 2H2(g) → CH4(g) will be

A)
¢B)
-74.8 kJ mol-1 ① 1- 2 ✗ ② + ③
-144.0 kJ mol-1
C) +74.8 kJ mol-1
D) + 144.0 kJ mol-1
Ans. (A)
 Ent
The correct order of magnetic moments (spin only values
in B.M.) among is

A) [Fe(CN)6]4- > [MnCI4]2- > [CoCI4]2-

-

B) [MnCI4]2- > [Fe(CN)6]4- > [CoCI4]2-

-

C) [MnCI4]2- > [CoCI4]2- > [Fe(CN)6]4-

t '
-

D) [Fe(CN)6]4- > [CoCI4]2- > [MnCI4]2-

• ÷
Ans. (C)
Which of them is correct order for solvolysis rate in aqueous
acetone? (via SNI)
-

p >a > R
+
s >
+

It
Ans. (D)
 For a reaction, 2K(g) + L(g) → 2M(g); ∆U0 = -10.5 kJ and ∆S0 = -44.1 J K-1. Calculate
- -

∆G0 for the reaction and predict whether the reaction will be spontaneous or non-
-

spontaneous?
A) ∆G = + 0.16 kJ, non-spontaneous AG = AH TAS
-

B) ∆G = -0.16 kJ, spontaneous

C) ∆G = + 26.12 kJ, non-spontaneous =
-712.98 -
298×(-44-1)
D) ∆G = -26.12 kJ, spontaneous

AH = but
Ang
RT
_
=
-10-5 + C- 1) ✗ 8.314 ✗ 298

= -12 .
98 KJ /MY
Ans. (A)
Identify X, Y in following sequence

CH
3-
CH NHZ
¥
¢
K - N -
C
'
' "
n
Ans. (A)
1 mole of NO and 1 mole of O3 are taken in a 10 L vessel and heated. At
equilibrium, 50% of NO (by mass) reacts with O3 according to the equation:
NO(g) + O3(g) ⇌ NO2(g) + O2(g)
What will be the equilibrium constant for this reaction?
✓ A) 1
NO 1- 03
¥ Noz +02
B) 2
C) 3 I 1 0 0
D) 4

¥ ÷ ÷

ka=E%3-= '
Ans. (A)
 The concentration of Ag+ in a saturated solution of Ag2CrO4 at 20 0C is
1.5 × 10-4 mol L-1. The solubility product of Ag2CrO4 at 20 0C is
"
A) 1.687 × 10-12
*B) 1.75 10-10
C) 3.0 × 10-8
Agzcroy ¥ 2Ag++ Croy

D) 4.5 × 10-10 2s s
- w

/ '
5×10-4 0.75×10-4

Ksp (2)
-_( s )

=
(-5×10-4)<(075×10-4)
Ans. (A)
Ans. (A)

H2 is not a green house gas

Which will make basic buffer?
-

A) 100 mL of 0.1 M HCI + 100 mL of 0.1 M NaOH

B) 50 mL of 0.1 M NaOH + 25 mL of 0.1 M CH3COOH
C) 100 mL of 0.1 M CH3COOH + 100 mL of 0.1 M NaOH
D) 100 mL of 0.1 M HCI + 200 mL of 0.1 M NH4OH
-
Ans. (D)
Consider the following reaction: 0
1- I
HCHO + 2[Ag(NH3)2] + 3OH → 2Ag + HCOO- + 4NH3 + 2H2O
+ -

Which of the following statements regarding oxidation and reduction is correct?

+A) HCHO is oxidized to HCOO- and [Ag(NH3)2]+ is reduced to Ag

B) HCHO is reduced to HCOO- and [Ag(NH3)2]+ is oxidized to Ag
C) [Ag(NH3)2]+ is reduced to Ag while OH- is oxidized to HCOO-
D) [Ag(NH3)2]+ is oxidized to Nh3 while HCHO is reduced to H2O
Ans. (A)
Identify the reaction which does not liberate hydrogen.
Bz He 1- LIAIHY → Li Hy
A) Reaction of lithium hydride with B2H6
B) Electrolysis of acidified water using Pt electrodes
te
C) Reaction of zinc with aqueous alkali
D) Allowing a solution of sodium in liquid ammonia to
stand ce
Ans. (A)
Sulphates of Be and Mg are readily soluble in water but sulphates of Ca, Sr and Ba
- -

are insoluble. This is due to the fact

tA) The greater hydration enthalpies of Be 2+ and mg2+ overcome the lattice

enthalpy
B) High lattice enthalpy of Be2+ and Mg2+ makes them soluble in water
C) Solubility decreases from BeSO4 to BaSO4 due to increase in ionic size
D) BeSO4 and MgSO4 are ionic in nature while other sulphates are covalent
Ans. (A)
 BZH ° NAI
NaBH4 + I2 → X + Y + Z Bztlt
𝟒𝟓𝟎 𝑲
BF3 + NaH X+P Balls 1- N9F
-
BF3 + LiAIH4 → X + Q + R t.ir/-A1r-3
X, Y, Z, P, Q and R in the reactions are

X Y Z P Q R
A) Na4B4O7 NaI HI HF LiF AIF3

+B) B2H6 NaI H2 NaF LiF AIF3

C) =
B2H6 BH3 NaI B3N3H6 AI2F6 AIF3
D) BH3 B2H6 H2 B3N3H6 LiF AIF3
Ans. (B)
 Among the following compounds, the correct order of
electrophilic substitution reaction is
Im

A) P>Q>R>S
B) S>Q>P>R
a> p > r >s
→ C) Q>P>R>S
D) Q>P>S>R
Ans. (C)
t
Ans. (D) All of these
 Which of the compounds with molecular formula C5H10 yields
acetone on ozonolysis?
=

É
F- I

A) 3-Methyl-I-butene
B) Cyclopentane Hzc -

CHS-

C) 2-Methyl-I-butene
D) 2-Methyl-2-butene

E-
1-
c- a
c-

◦
I c- É
Ans. (D)
 A metal crystallises into two cubic phases, face centred (FCC)
- -
=
& body centred (BCC) whose unit cell lengths are 3.5 𝐴ሶ and 3.0
𝐴ሶ respectively. Calculate ratio of their densities:
- - -

= A) 1 : 26
B) 1 : 20 d ✗ ✗ 93€

C) 1 : 10 93 2 be
c

D) 1 : 15 Fcc

=
Ans. (A)
 Match the list I with List II and select the answer using the
codes given below the lists:

refectory cucoz .
CU ( 0h32
-
A / 203 .
21120
2h03
-

\
-
Agzs
Ans. (A)
 The freezing point depression constant for water is
-1.860Cm-1. If 5.00 g Na2SO4 is dissolved in 45.0g
H2O, the freezing point is changed by -3.820C.
Calculate the Van’t Hoff factor for Na2SO4

A) 0.381 Atf = I ✗
kf ✗ M

B) 2.05
C) 2.63 r - r
D) 3.11
Ans. (C)
Incorrect reaction among the following is/are:
WHY N°2 ↳ N2 1- 1120
∆ "
A) NH4NO3 → N2O + H2O

+④
∆
B) (NH4)2 Cr2O7 → Cr2O7 + O2
<𝟐𝟓𝟎𝑲
C) NO + NO2 N2O3
D) NO2 + H2O → HNO2 + HNO3
Ans. (B)
 - ① _
②
0 0
If EFe 2+ /Fe = x 1 V, EFe3+ /Fe2+ = x 2 V, What is
0
② ①
the EFe3+ /Fe ?
⑤
𝟐𝐱𝟏 +𝐱𝟐
③ =
② + ①
A)

E=Xz-z#
𝟒
𝟐𝐱𝟏 +𝐱𝟐
µB) 𝟑
𝟐𝐱𝟏 +𝐱𝟐
C) 𝟐
D) 2x1 + x2
Ans. (B)
 For a first order reaction the rate constant is 6.909 min-
-

1. The time taken for 75% conversion in minutes is:

-

A)
3
2
log2
k =

23,03g log An÷

2
B) log3
3
C)
2
3
3
log2
3
t=;÷→ loge 25
D) log
2 4

± boy y § log 22
= =

=
3- bg2
Ans. (C)
 ñ i
Which of the following statement is correct? no -5
§
-
-
oh

¥
✓A) S-S bond is present in H2S2O6
B) In peroxosulphuric acid (H2SO5) sulphur is in
+8 oxidation state✗
C) Copper powder along with AI2O3 and K2O is
used as a catalyst in the preparation of NH3 by
Haber’s process ✗
D) Change in enthalpy is positive for the
preparation of SO3 by catalytic oxidation of SO2
↑
Ans. (A)
Which of the following is correct reaction?

µ
-
Ans. (A)
Which of the following ions show higher spin only
magnetic moment value?

A) Ti3+ B) Mn2+
-
C) Fe2+ D) Co3+
Ans. (B)
The cell reaction for the given cell is:
Pt(H2) | pH = 2 || pH = 3 | Pt(H2)
P1 = 1 atm P2 = 1 atm

A) Spontaneous
B) Non-spontaneous
C) In equilibrium
D) Either of these
Ans. (B)