JEE (Main)-2022 : Phase-1 (25-06-2022)-Evening

CHEMISTRY

SECTION - A 3. Solute A associates in water. When 0.7 g of solute

Multiple Choice Questions: This section contains 20 A is dissolved in 42.0 gof water, it depresses the
multiple choice questions. Each question has 4 choices freezing point by 0.2°C. The percentage
(1), (2), (3) and (4), out of which ONLY ONE is correct. association of solute A in water is :
Choose the correct answer : [Given : Molar mass of A = 93 g mol–1. Molal
1. The minimum energy that must be possessed by depression constant of water is 1.86 K kg mol–1.]
photons in order to produce the photoelectric effect (A) 50%
with platinum metal is
(B) 60%
[Given The threshold frequency of platinum is 1.3 ×
1015 s–1 and h = 6.6 × 10–34 Js.] (C) 70%
(A) 3.21 × 10–14 J (B) 6.24 × 10–16 J (D) 80%
(C) 8.58 × 10–19 J (D) 9.76 × 10–20 J
Answer (D)
Answer (C)
Sol.: Since, Tf = ikfm
Sol.: The minimum energy possessed by photons will be
equal to the work function of the metal. 0.7 1000
m= 
Hence, 93 42
w0 = h0 0.7  1000
0.2 = i  1.86 
= 6.6 × 10–34 × 1.3 × 1015 93  42
= 8.58 × 10–19 J
i = 0.6
2. At 25°C and 1 atm pressure, the enthalpy of
i − 1 0.6 − 1
combustion of benzene (I) and acetylene (g) are = = = 0.8
1 1
–3268 kJ mol–1 and –1300 kJ mol–1, respectively. −1 −1
n 2
The change in enthalpy for the reaction
3C2H2(g) → C6H6(I), is Hence, percentage association of solute A is 80%.
(A) +324 kJ mol–1 (B) +632 kJ mol–1 4. The Ksp for bismuth sulphide (Bi2S3) is 1.08 ×
(C) –632 kJ mol –1
(D) –732 kJ mol –1 10–73. The solubility of Bi2S3 in mol L–1 at 298 K is
Answer (C) (A) 1.0 × 10–15
15
Sol.: I. C6H6 ( ) + O (g) → 6CO2 (g) + 3H2O(g) (B) 2.7 × 10–12
2 2
H1 = –3268 kJ/mol (C) 3.2 × 10–10

5 (D) 4.2 × 10–8

II. C2H2 (g) + O2 (g) → 2CO2 (g) + H2O(g)
2
Answer (A)
H2 = –1300 kJ/mol
Sol.: Bi2S3 2Bi3+ + 3S2−
III. 3C2H2 (g) → C6H6 ( ) H3
2s 3s
Applying Hess’s law of constant heat summation
Ksp = (2s)2(3s)3 = 108s5
H3 = 3 × H2 – H1
= 3 × (–1300) – (–3268) 108s5 = 108 × 10–75

= –632 kJ/mol s = 1.0 × 10–15 mol/L

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 JEE (Main)-2022 : Phase-1 (25-06-2022)-Evening
5. Match List I with List II. (1) Both Statement-I and Statement-II are true.
List I List II (2) Both Statement-I and Statement-II are false.

A Zymase I Stomach (3) Statement-I is true but Statement II is false.

B Diastase II Yeast (4) Statement-I is false but Statement-II is true

C Urease III Malt Answer (A)

D Pepsin IV Soyabean Sol. Copper is refined using an electrolytic method.

Anodes are of impure copper and pure copper
Choose the correct answer from the options given
strips are taken as cathode
below
Impurities from the blister copper deposit as anode
(A) A-II, B-III, C-I, D-IV
mud which contains antimony, selenium, tellurium,
(B) A-II, B-III, C-IV, D-I
silver, gold and platinum.
(C) A-III, B-II, C-IV, D-I
Hence both statements are true
(D) A-III, B-II, C-I, D-IV
8. Given below are two statements one is labelled as
Answer (B)
Assertion A and the other is labelled as Reason R:
Sol.:
Assertion A: The amphoteric nature of water is
Enzyme Source
explained by using Lewis acid/base concept
Zymase → Yeast
Reason R: Water acts as an acid with NH3 and as
Diastase → Malt a base with H2S.
Urease → Soyabean In the light of the above statements choose the
correct answer from the options given below:
Pepsin → Stomach
(1) Both A and R are true and R is the correct
Hence, A-II, B-III, C-IV, D-I
explanation of A.
6. The correct order of electron gain enthalpies of Cl,
F, Te and Po is (2) Both A and R are true but R is NOT the correct
explanation of A.
(1) F < Cl < Te < Po
(2) Po < Te < F < Cl (3) A is true but R is false.
(3) Te < Po < Cl < F (4) A is false but R is true.
(4) Cl < F < Te < Po Answer (D)
Answer (B) Sol. The amphoteric nature of water is explained by
Sol. Te → –190 kJ mol–1 using Bronsted-Lowry acid base concept
Po → –174 kJ mol–1 H2O + NH3 OH– + NH4+
F → –333 kJ mol–1
(acid)

Cl → –349 kJ mol–1 H2O + H2S H3 O+ + HS –

(base)
Hence, correct order is Cl > F > Te > Po
Hence, A is false but R is true
7. Given below are two statements.
Statement-I: During electrolytic refining, blister 9. The correct order of reduction potentials of the
copper deposits precious metals. following pairs is

Statement-II: In the process of obtaining pure (A) Cl2/Cl– (B) I2/I–

copper by electrolysis method, copper blister is (C) Ag+/Ag (D) Na+/Na
used to make the anode. (E) Li+/ Li
In the light of the above statements, choose the
Choose the correct answer from the options given
correct answer from the options given below.
below:
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 JEE (Main)-2022 : Phase-1 (25-06-2022)-Evening
(1) A > C > B > D > E Sol. Valence shell Unpaired
(2) A > B > C > D > E Configuration electrons

(3) A > C > B > E > D V2+

→ 3
3d 4s 0
n=3
Ni2+ → 3d84s0 n=2
(4) A > B > C > E > D
Cr2+ → 3d44s0 n=4
Answer (A)
Fe 2+
→ 6
3d 4s 0
n=4
Sol. Standard Reduction Potential 2+
Since Ni has least number of unpaired electrons.
(A) Cl2/Cl 1.36 V Hence Ni2+ will have lowest spin only magnetic
(B) I2/I– 0.54 V moment Value.
12. Given below are two statements: one is labelled
(C) Ag+/Ag 0.80 V
as Assertion A and the other is labelled as
(D) Na+/Na –2.71 V Reason R.
(E) Li+/ Li –3.05 V Assertion A: Polluted water may have a value of
Hence, correct order is A > C > B > D > E BOD of the order of 17 ppm.
Reason R: BOD is a measure of oxygen required
10. The number of bridged oxygen atoms present in
to oxidise both the bio-degradable and non-
compound B formed from the following reactions is
biodegradable organic material in water.
Pb(NO3 )2 ⎯⎯⎯
673 K
→ A + PbO + O2 In the light of the above statements, choose the
A ⎯⎯⎯⎯
Dimerise
→B most appropriate answer from the options given
below.
(1) 0
(A) Both A and R are correct and R is the correct
(2) 1 explanation of A.
(3) 2 (B) Both A and R are correct but R is NOT the
(4) 3 correct explanation of A.
(C) A is correct but R is not correct.
Answer (A)
(D) A is not correct but R is correct.
Sol. 2Pb(NO3 )2 ⎯⎯⎯→ 4NO2 + 2PbO + O2
673 K
Answer (C)
A
Sol. Highly polluted water could have a BOD value of 17
NO2 ⎯⎯⎯⎯
Dimerise
→ N2 O4 ppm or more.
A B
The amount of oxygen required by bacteria to break
down the organic matter present in a certain volume
of a sample of water is called Biochemical Oxygen
demand (BOD).
Hence A is correct but R is not correct.
13. Given below are two statements: one is labelled
Hence no bridged oxygen atom is present in N2O4.
as Assertion A and the other is labelled as
11. The metal ion (in gaseous state) with lowest spin- Reason R.
only magnetic moment value is Assertion A: A mixture contains benzoic acid and
2+ naphthalene. The pure benzoic acid can be
(A) V
(B) Ni2+ separated out by the use of benzene.
Reason R: Benzoic acid is soluble in hot water.
(C) Cr2+
In the light of the above statements, choose the
(D) Fe2+ most appropriate answer from the options given
Answer (B) below.

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 JEE (Main)-2022 : Phase-1 (25-06-2022)-Evening
(A) Both A and R are true and R is the correct Answer (A)
explanation of A.
Sol.
(B) Both A and R are true but R is NOT the correct
explanation of A.
(C) A is true but R is false.
(D) A is false but R is true.
Answer (D)
Sol. Since, both benzoic acid and naphthalene will
dissolve in benzene. Hence assertion is wrong. 16. In the given reaction
Benzoic acid is almost insoluble in cold water but OH
soluble in hot water. Hence Reason is true
(i) 2 Mg, THF C
14. During halogen test, sodium fusion extract is boiled 2A
(ii) Methyl benzoate
+
with concentrated HNO3 to (iii) H2O/H

(A) remove unreacted sodium

(B) decompose cyanide or sulphide of sodium
‘A’ can be
(C) extract halogen from organic compound
(A) Benzyl bromide
(D) maintain the pH of extract.
(B) Bromo benzene
Answer (B)
(C) Cyclohexyl bromide
Sol. During test for halogen, if nitrogen or sulphur is also
(D) Methyl bromide
present in the compound, then sodium fusion
Answer (B)
extract is first boiled with concentrated nitric acid to
Sol.
decompose cyanide or sulphide of sodium formed
S+
during Lassaigne's test. Br MgBr
S–
15. Amongst the following, the major product of the
2Mg, THF
given chemical reaction is 2 2

'A' O
C – O – CH3

(A) O–

(B)

+
H2O/H

(C) OH

(D)

Hence 'A' is bromobenzene.

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 JEE (Main)-2022 : Phase-1 (25-06-2022)-Evening
17. Which of the following conditions or reaction (B)
sequence will NOT give acetophenone as the major O OH
product?
O
O
(C)
O H
(A) (a) C6H5 H + CH 3MgBr

(b) Na2Cr2O7, H+
(D)
O O O
(B) (a) H3C H + C 6H5MgBr Answer (D)

(b) PCC, DCM Sol.

O
H+ OH

(C) C6H5 OC2H5 + 2CH 3MgBr 

O O
O

O
(D) C6H5 Cl + CH 3MgBr + CdCl 2 O

Answer (C) 19. Which of the following ketone will NOT give
Sol. C will not give acetophenone enamine on treatment with secondary amines?
[where t-Bu is –C(CH3)3]

O O
(A) C (B)

C2H5 C2H5 C2H5 CH3

O
O
(C) (D)
C
t-Bu t-Bu

Answer (C)

Sol. In order to form enamine from the reaction of

carbonyl compound with 2º amine, the carbonyl
18. The major product formed in the following reaction, compound must have -hydrogen.
is
O
+
H
OH + In C No -hydrogen is present.

O t-Bu t-Bu
Along with this, due to steric crowding by t-Bu
(A)
O group, it is difficult for 2º amine to attack on this
O compound.

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 JEE (Main)-2022 : Phase-1 (25-06-2022)-Evening
20. An antiseptic Dettol is a mixture of two compounds 30 P
= 2
‘A’ and ‘B’ where A has 6 electrons and B has 2 300 318
electrons. What is ‘B’?
P2  32 atm
(A) Bithionol
(B) Terpineol 3. Amongst BeF2, BF3, H2O, NH3, CCl4 and HCl, the
number of molecules with non-zero net dipole
(C) Chloroxylenol
moment is ______.
(D) Chloramphenicol
Answer (3)
Answer (B)
Sol. Dettol is a mixture of chloroxylenol and terpineol. Sol. F – Be – F =0

Chloroxylenol has 6 electrons and terpineol has 2

electrons. =0

Hence B is terpineol.
SECTION - B ≠0
Numerical Value Type Questions: This section
contains 10 questions. In Section B, attempt any five
questions out of 10. The answer to each question is a ≠0
NUMERICAL VALUE. For each question, enter the
correct numerical value (in decimal notation,
truncated/rounded-off to the second decimal place; e.g.
06.25, 07.00, –00.33, –00.30, 30.27, –27.30) using the =0
mouse and the on-screen virtual numeric keypad in the
place designated to enter the answer.
1. A protein 'A' contains 0.30% of glycine (molecular H – Cl ≠0
weight 75). The minimum molar mass of the protein 4. At 345 K, the half life for the decomposition of a
'A' is _______ × 103 g mol–1 [nearest integer] sample of a gaseous compound initially at 55.5 kPa
Answer (25) was 340 s. When the pressure was 27.8 kPa, the
Sol. 0.3% glycine means half life was found to be 170 s. The order of the
100 g protein 'A' contains 0.3 g glycine. reaction is ________. [integer answer]

Since, molar mass of glycine is 75 Answer (0)

100 1
75 g glycine will be present in  75 g protein Sol. t 1 
0.3 2 [P0 ]n−1
Minimum molar mass of protein A is 25 × 103 g/mol
( t1 2 )1 P0 n2−1
2. A rigid nitrogen tank stored inside a laboratory has =
a pressure of 30 atm at 06:00 am when the ( t1 2 )2 P0 1n−1
temperature is 27°C. At 03:00 pm, when the n −1
340  27.8 
temperature is 45°C, the pressure in the tank will be = 
170  55.5 
_______ atm. [nearest integer]
n−1
Answer (32)  1
2= 
Sol. Since 2
PT 2 = (2)1 – n

P1 P2  P1 is pressure at 6 am  1–n=1
Hence, =  
T1 T2  P2 is pressure at 3 pm  n=0

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 JEE (Main)-2022 : Phase-1 (25-06-2022)-Evening
5. A solution of Fe2(SO4)3 is electrolyzed for 'x' min [Co(NH3)6]Cl3 → Inner-orbital complex
with a current of 1.5 A to deposit 0.3482 g of Fe.
Since CN– is a strong field ligand than NH3. Hence
The value of x is _______. [nearest integer]
K3[Fe(CN)6] is the inner-orbital complex that
Given : 1 F = 96500 C mol–1 absorbs light at shortest wavelength.
Atomic mass of Fe = 56 g mol–1
Fe(III) → valence shell configuration 3d5
Answer (20)
Since CN– will do pairing, so unpaired electron = 1
Sol. Fe3+ + 3e– → Fe
0.3482  = 1(1 + 2) = 3 BM 2 BM
Moles of Fe deposited = = 6.2  10−3
56
8. The Novolac polymer has mass of 963 g. The
For 1 mole Fe, charge required is 3 F
number of monomer units present in it are
For 6.2 × 10–3 mole Fe, charge required is
Answer (9)
3 × 6.2 × 10–3 F
Since, charge required = 18.6 × 10–3 × 96500 C Sol. Novolac is

= 1794.9 C
And,
1.5 × t = 1794.9
1794.9
t= min Molar mass of monomer is 107 g/mol
1.5  60
963
t  20 min n= =9
107
6. Consider the following reactions:
Number of monomer units present in it are 9.
PCl3 + H2O → A + HCl
9. How many of the given compounds will give a
A + H2O → B + HCl positive Biuret test_________? Glycine,
The number of ionisable protons present in the Glycylalanine, Tripeptide, Biuret.
product B is Answer (2)
Answer (2)
Sol. Since dipeptides and free amino acids do not give
Sol. PCl3 + H2O ⎯⎯→ P(OH)Cl2 + HCl biuret test. Hence glycine and glycylalanine do not
A give this test.

P(OH)Cl2 + H2O ⎯⎯→ P(OH)2 Cl + HCl 10. The neutralization occurs when 10 mL of 0.1M acid
A B ‘A’ is allowed to react with 30 mL of 0.05 M base
M(OH)2. The basicity of the acid ‘A’ is_________.
Hydrogen attached with oxygen are ionisable.
Hence number of ionisable protons present in [M is a metal]
compound B are 2. Answer (3)
7. Amongst FeCl3.3H2O, K3[Fe(CN)6)] and
Sol. Milieq of acid A = Milieq of base M(OH)2
[Co(NH3)6]Cl3, the spin-only magnetic moment
value of the inner-orbital complex that absorbs light (M  V  n − Factor)A = (M  V  n − Factor)M(OH)2
at shortest wavelength is_______B.M. [nearest
[n-Factor of M(OH)2 = 2]
integer]
Answer (2) 0.1 × 10 × n-Factor = 0.05 × 30 × 2

Sol. [Fe(H2O)3Cl3] → Outer-orbital complex (n-Factor)A = 3

K3[Fe(CN)6] → Inner-orbital complex Hence basicity of acid A is 3.

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