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VERSION – A1
2
Ans : ma 2 5. Relative permittivity and permeability of a ……
3
* None of the given answers matches with our 8. A wave traveling along the x-axis is …..
answer.
Ans : α = 25.00 π, β = π
4. A thin spherical shell of radius R has ……..
2π 2π
Sol: α= = = 25 π
Ans : E (r) λ 0.08
2π
β=ω= =π
T
r
O R
⇒ α = 25.00 π, β = π
L/2
14. A body is at rest at x = 0. At t = 0 …….
n
x1 − x2 O
Ans :
L n
x
∫
0
x.K dx
L n+1
Sol: xcm = =
t L n n+2
x
∫ K L dx
O
1
Sol: x1 − x2 = at 2 − ut 0
2
xcmM
x1 − x2
L
L/2
n
t
O
5 × 1− 2 × 2
Sol: Eeff = ⇒ Ι = 0.03 A P2 to P1
2 +1
Ans :
A B
2GM
Sol: vesc =
r
v2 10
= = 10
v1 1 / 10
⇒ v2 = 110 km/s
Sol: Surface tension is lowered.
21. An insulated container of gas has two……
27. Two coaxial solenoids are made ……
T1T2 (P1V1 + P2 V2 )
Ans :
P1V1T2 + P2 V2T1 Ans : 2.4 π × 10− H
4
35
Sol: 3+ × 0.5 + 0.03
50
= 3.38 mm
O u (cm)
23. A horizontal overhead powerline is ……
∫ Edr
+ 2– –
Sol: ∆V = 2. Ans: NO , C2 , CN , N2
a
+
ρΙ ρΙ Sol : Total no. of electrons in NO = 14 (7+8–1),
= −
πa π(a + b )
2– –
C2 = 14 (6+6+2), CN = 14 (6+7+1) and
N2 = 14 (7+7).
33. If a strong diffraction peak is observed when
electrons are incident at an angle `i’ − 39. Four species are…….
i. ii. iii. iv.
Ans: 2d cos i = n λdB …… the correct sequence of their acid strength?
36. The ionization enthalpy of hydrogen ……. 42. ……. CH3MgX with CH3C ≡ C–H …….
5 –1
Ans: 9.84 x 10 J mol Ans: CH4
47. …… the industrial preparation of hydrogen from Sol : The incorrect statement is “Ozone layer
water gas …….. does not permit Ι.R radiation from the sun
to reach the earth”. Actualy ozone layer
Ans: CO is oxidized to CO2 with steam in the prevents u.v. radiation from the sun to
presence of a catalyst followed by reach the earth.
absorption of CO2 in alkali.
53. The coordination number and the oxidation state
Sol : From water gas (CO + H2), CO is oxidized of the element ……..
to CO2 with steam and which is then
absorbed in alkali. Ans: 6 and 3
48. …… substituted silane the one ……… to cross Sol : en and C2O24− are bidendate ligands.
linked silicone ……..
∴Coordination number of E is 6 and
oxidation state of E is 3 (en is neutral and
Ans: RSiCl3
NO2− )
Sol : Among the substituted silanes, RSiCl3 on
hydrolysis give rise to cross linked silicone 54. ……. Octahedral complexes of Co ….
polymers.
3-
Ans: [Co(CN)6]
Sol: :
Sol : The strongest ligand is CN and hence ∆0
-
OH OH OH
3- SO 3H
will be the highest for [Co(CN)6] .
Conc.H 2SO4
55. Larger number of oxidation states are exhibited +
…..
Ans: lesser energy difference between 5f and
OH SO 3H
6d than between 4f and 5d orbitals.
Sol : The energy difference between 5f and 6d O2N NO2
(actinoids) is less than between 4f and 5d Conc.HNO3
Ans: CH3Cl
Ans: CH3CHO
(i ) O
Sol : Primary alkyl halides undergo SN2 reaction
Sol : CH3−CH=CH−CH3 3
→ 2CH3CHO. with inversion of configuration.
(ii) H2O / Zn
Ans: *2,4,6-trinitrophenol.
62. The absolute configuration of ………
68. The equilibrium constant KP1 and KP2 for ……
Ans: R, R
Ans: 1 : 36
Sol : The absolute configuration of both the
Sol : X 2Y, Equilibrium constant = K p1
carbons are ‘R’.
Z P + Q, Equilibrium constant = K p 2
63. α -D-(+)-glucose and β -D-(+)-glucose are When the degree of dissociation is the
same for the two reactions, then
Ans: anomers K p1 = 4p1 and K p 2 = p2.
K p1 4p1
Sol : α-D(+)glucose and β-D(+)glucose are =
Kp2 p2
anomers.
1 4p1 p1 1
i.e., = ; =
⊕ 9 p2 p2 36
64. The electrophile, E attacks …….
H 1
69. For a reaction A → 2B, rate of ………
2
Ans: + E
d[ A ] 1 d[B]
Ans: − =
dt 4 dt
Sol : −NO2 group is a deactivating group.
Hence the intermediate formed from Sol : For the give reaction,
benzene will have lower energy than that d[ A ] 1 [d[B]
2X − =
formed from nitro benzene. dt 2 dt
d[ A ] 1 d[B]
or − =
65. Standard entropy of X2, Y2 and XY3 ……. dt 4 dt
0
Ans: 750K 70. At 80 C, the vapour pressure of pure liquid ‘A’ is
520 mm Hg and that of ……..
∆H
Sol : T =
∆S Ans: 50 mol percent
∆S = −40 J
−30000 Sol : poA .x A + pB
o
.xB = 760
∴T=
− 40
520XA + 1000(1 − XA) = 760
= 750K 240 1
xA = =
480 2
66. For the following three reactions a, b and c, ….. Mole percent = 50
PART C − MATHEMATICS
Ans : K3 = K1 K2.
71. Let f : N → Y be a function defined as ……….
Sol : The first two reactions are added to get the
third reaction, hence K3 = K1 × K2. y − 3
Ans: g(y) =
4
67. Bakelite is obtained from phenol …..
Sol: y = 4x + 3
Ans: HCHO y −3
x=
4
Sol : Bakelite is a polymer of phenol and y − 3
formaldehyde. g(y) =
4
⇒ A− = A ⇒ A− will have all enteries as
1 T 1
integers
72. Let R be the real line. Consider the following…..
Ans: T is an equivalence relation on R but S is 76. Let a, b, c be any real numbers. Suppose…….
not
Ans: 1
Sol: S = {(x, y): y = x + 1 0 < x < 2
(x, x) → x = x + 1 → not reflexive Sol: x − cy − bz = 0
(x, y) ≠ (y, x) → not symmetric −cx + y − az = 0
−bx − ay + z = 0
1 Given that x, y, z not all zero.
73. The conjugate of a complex number is …….
i −1 ⇒ The given homogeneous system has
−1 non-trivial solutions.
Ans:
i +1 1 −c −b
⇒ −c 1 −a = 0
Sol:
1 −b −a 1
i −1
⇒ 1(1 − a ) + c(−c − ab) −b(ac + b) = 0
2
1 ⇒ −a − b − c − 2abc + 1 = 0
2 2 2
Conjugate number =
− i −1 2 2 2
⇒ a + b + c + 2abc = 1
−1
=
(1 + i) 77. How many different words can be formed by ……
6 8
74. The quadratic equations x − 6x + a = 0 and ……
2
Ans: 7. C4. C4
α, γ be the roots of x − cx + 6 = 0
2
*−*−*−*−*−*−*−*
⇒α+β=6 α+γ=c In the eight places in between (marked as *)
8
and we can arrange the 4s’s in C4.wsays
αβ = a αγ = 6 7!
∴ Total number of words = × 8C 4
β 4 3 4!2!
and = ⇒ γ = β 6 8
γ 3 4 = 7. C4. C4
3
∴ α β = 6 ⇒ αβ = 8 ⇒ a = 8 78. The first two terms of a geometric progression….
4
∴ The first equation is x − 6x + 8 = 0
2
Ans : − 12
⇒ 2 and 4 are the roots.
3 Sol: a + ar = 12
If β = 2, then γ = ⇒ Not possible, since 2 3
2 ar + ar = 48
2
r (a + ar) = 48
roots are integers 2
r =4
If β = 4 ⇒ γ = 3 ⇒ possible r=±2
∴ The common root is 2 r = − 2, since terms are alternately positive
and negative
75. Let A be a square matrix all of whose entries…… 12
a= = − 12
1+ r
Ans: If det A = ±1, then A− exists and all its
1
(x − 1) sin
entries are integers 1
if x ≠ 1
79. Let f(x) = x −1 ……..
Sol: If det A ≠ ± 1, then det A may be zero ⇒ A −1 0 if x = 1
does not exist.
When det A = ± 1, then A is orthogonal Ans : f is differentiable at x = 0 but not at x = 1
1 sin x dx
(x − 1) sin
Sol : f(x) =
x − 1
if x ≠ 1 Sol: 2 ∫ π
sin x −
0 , if x = 1 4
1
lim (x − 1) sin
(
sin x − π + π dx )
x→ 1
x − 1
= 2 ∫ ) (
4
sin x − π
4
4
sin
1
x − 1
)1
2
((
sin x − π
4
+
1
2
cos x − π
4
)
= 2∫
sin(x − π )
= lim dx
x →1 1
4
= x + log sin (x − ) + c
x − 1 π
sin y 4
= lim =0
y →∞ y
f (1 + h ) − f (1) 83. The area of the plane region bounded by the …..
f’(1) = lim
h→0 h
4
1 Ans:
h sin 3
= lim h
h→ 0 h
Sol: x + 2y = 0 ⇒ x = −2y
2 2
1 x + 3y = 1 ⇒ x = 1 − 3y
2 2
= lim sin
h→0 h
does not exist
Ans: 1 x = 1 − 3y2 x=
1
Sol: f(x) = x + 14x + 16x + 36x − 560
7 5 3
−2y2
6 6 2
f'(x) = 7x + 70x + 48x + 30
> 0 for all x ∈ R
f(x) is monotonic increasing
−2 −1 0
f(x) = 0 has only one real solution
p
Ans: The cubic has minima at and maxima
3 Shaded portion is the required area
∫ [(1 − 3y ) − (− 2y )]dy
p 1
at − Required area = 2 2 2
3
0
Sol: f(x) = x − px + q
3 1
∫( ) y 3
1
f'(x) = 3x − p = 2 1 − y 2 dy = 2 y −
2
3
f”(x) = 6x 0 0
p 4
3x = p ⇒ x = ±
2
=
3 3
p
f(x) is minimum at x = and 1 1
3 sin x cos x
p
84. Let Ι = ∫ x
dx and J = ∫ x
dx …….
maximum at x = − 0 0
3
2
sin x dx Ans : Ι < and J < 2
82. The value of 2∫ π
is ……….. 3
sin x − 1
sin x
4 Sol : Ι = ∫ dx
Ans: x + log sin x − π( 4
) +c 0
x
1
1 Ans: −4
< ∫ x
dx
0 1− k
<2 Sol : Slope of the line = =k−1
−1
1
cos x 1+ k 7
J= ∫ x
dx Passes through
2 2
,
0
1 Perpendicular bisector is
1
< ∫ x
dx
y−
7 1 + k
= (k − 1) x −
0 2 2
<2
2y − 7 = 2x(k − 1) − (k − 1)
2
In (0, 1) ⇒ sin x < x
2x(k − 1) − 2y = k − 8
2
sin x
< x
x k2 − 8
= −4
1 −2
2
Ι< ∫ x dx = k −8=8
2
3
0 ⇒ k = ±4
85. The differential equation of the family of circles… 88. The point diametrically opposite to the point
P(1, 0) on the circle……..
Ans: (y − 2) y’ = 25 − (y − 2)
2 2 2
Sol: Put y = Vx
dy dv 90. A focus of an ellipse is at the origin. The directrix.
=V+x
dx dx
dv x + Vx 8
∴V+ x = Ans:
dx x 3
dv
V+ x =1+V a
dx Sol: − ae = 4
e
dv dx
x = 1⇒ dv = a
dx x 2a − = 4
2
∴ V = log x + C
3a
y = 4
= log x + C 2
x
8
y(1) = 1 ⇒ C = 1 a=
y 3
∴ = log x + 1
x
y = xlogx + x x −1 y − 2 z − 3
91. If the straight lines = = and ……
k 2 3
87. The perpendicular bisector of the line segment ... Ans : −5
1 1 −2 Ans: a = 3, b = 4
Sol : k 2 3 = 0
3 k 2 a + b + 8 + 5 + 10
Sol : =6
5
⇒ (4 − 3k) − (2k − 9) − 2(k − 6) = 0
2
a + b + 23 = 30
⇒ 4 − 3k − 2k + 9 − 2k + 12 = 0
2
a + b = 7 (1)
⇒ 2k + 5k − 25 = 0
2
(a − 6) + (b − 6) = 13
2 2
a + b − 12(a + b) = −59
2 2
92. The line passing through the points (5, 1, a)….
(a + b) − 2ab − 12(a + b) = −59
2
r r r 1
93. The non-zero vectors a , b and c are related.. Ans:
3
Ans: π
A 1
Sol: a = 8 b a is parallel to b Sol: P =
B 2
c = −7 b c is parallel to c 1 P (A ∩ B) P(B )
⇒ = ⇒ P(A ∩ B ) =
⇒ a and c are opposite 2 P(B) 2
∴ angle = π 2 P(A ∩ B ) 2 P(B )
= ⇒ =
r 3 P(A ) 3 2 P(A )
94. The vector a = α î + 2 ĵ + β k̂ lies in the ….
P(A ) =
4 1
⇒ P(B) =
3 3
Ans: α = 1, β = 1
98. AB is a vertical pole with B at the ground level…..
Sol: a, b, c are coplanar
α 2 β
1 1 0 =0
Ans:
7 3
2
( 3 + 1) m
0 1 1
Sol: From the figure A
α−2+β=0 h
⇒α+β−2=0 tan 60 =
x
True only α = 1, β = 1 h
⇒ 3 x=h
x+7
95. The mean of the numbers a, b, 8, 5, 10 is 6 ..... tan 45 = 45 60
h
D x B
7 m.c
⇒h=x+7 But, in both cases above tr(A) = 0
h Therefore, statement 2 is false.
⇒h= 7 +
3
7 3 102. Statement 1 : For every natural number n ≥ 2,…..
⇒h=
3 −1
=
7 3 ( 3 + 1) Ans: Statement 1 is true, Statement 2 is true;
Statement 2 is a correct explanation for
2 Statement 1
5 2
99. The value of cot cos ec −1 + tan −1 is Sol : AM > GM
3 3 1 1 1
+ + ...... + 1
n > 1
n
6 1 2
Ans:
17 n n!
1
5 2 1 n
A will be Ι if a = 0
2
(1 + x) + nx(1 + x) −
n n 1
0 1 2
When a = 0, A = = C0 + C1(1 + 1)x + C2 (2 + 1)x +
1 0 + Cn(n + 2)x
n
and |A| = −1
Statement 1 is true.
n 105. Let p be the statement “x is an irrational number”
= ∑ (r + 1) nCr xr
r =0
Ans: Statement 1 is false.
Statement 2 is true and Statement 1 follows
Statement 2 is true.
from Statement 2 by substituting x = 1 is
Statement 2.
Sol: p: x is irrational
q : y is transcendental
104. In a shop there are five types of ice-creams…..
r : x is rational if and only if y is true.
Ans: Statement 1 is false, Statement 2 is true Statement 1 – r ≡ p ∨ q
Statement 2 - r ≡ ~ (p↔~q)
Sol: Statement 1 r ≡ (p ∨ q) ∧ (~q ∨ ~ p)
The required number is the number of non ≡ (p ∨ q) ∧ ~ (p ∧ q) ≡ false
negative integral solutions of the equation
Statement 1 is false
x1 + x2 + x3 + x4 + x5 = 6
(6 + 5 − 1) 10
is C5 − 1 = C4
Statement 1 is false
But statement 2 is true,
10!
Since the number of ways = = 10 C 4
6! 4!
AREAWISE DISTRIBUTION OF QUESTIONS FOR PHYSICS
Difficulty Level
Sl. No. of
Name of the Area No. of No. of No. of Percentage
No. Questions
E M D
1 Mechanics 13 3 8 2 37.14
2 Properties of Matter 3 1 2 0 8.57
Heat & 2 0 1 1 5.71
3
Thermodynamics
4 Electricity & Magnetism 9 3 6 0 25.71
5 Optics 1 1 0 0 2.85
6 Modern Physics 5 3 2 0 14.28
Electronics & 2 0 1 1 5.71
7
Communications
Total: 35 11 20 4 100
Percentage:
Electronics
AREAWISE DISTRIBUTION OF QUESTIONS FOR CHEMISTRY
Difficulty Level
No. of
Name of the Area No. of No. of No. of Percentage
No. Questions
E M D
1 Physical Chemistry 15 5 8 2 44.1
2 Organic Chemistry 10 6 4 -- 29.4
3 Inorganic Chemistry 9 4 5 -- 26.5
26.5
44.1
Physical Chemistry
Organic Chemistry
Inorganic Chemistry
29.4
AREAWISE DISTRIBUTION OF QUESTIONS FOR MATHEMATICS
Difficulty Level
Sl. No. of
Name of the Area No. of No. of No. of Percentage
No. Questions
E M D
1 ALGEBRA 13 6 4 3 37.14
COORDINATE
2 4 2 2 - 11.42
GEOMETRY
DIFFERENTIAL
3 4 1 3 - 11.42
CALCULUS
4 TRIGONOMETRY 2 2 - 5.74
VECTORS, 3-D,
5 MATRICES & 7 4 3 - 20
DETERMINANTS
INTEGRAL
6 5 2 2 1 14.28
CALCULUS
14.28
Coordinate geometry
37.14
20 Differential calculus
Trigonometry
11.42 11.42
Vectors,3D,Matrices and
5.74 Determinants
Integral Calculus