Dimensioning and design

of nitrogen removal technologies

Dipl.-Ing. S. Rettig
TU Berlin, Department of Urban water management
Gustav-Meyer-Allee 25, D - 13355 Berlin

Phone: +49 / (0) 30 / 314 72356; Fax: +49 / (0) 30 / 314 72248
e-mail: stefan.rettig@tu-berlin.de
 Introduction

 Biological wastewater treatment: Fixed film (trickling filter, rotating disk

filter) or suspended biomass (activated sludge system)
 Predominantly the activated sludge system is practiced
 Municipal and industrial wastewater treatment
 Basic of the activated sludge system:
 Combination of aeration tank
+ subsequent sedimentation (clarifier)
+ return of the separated biomass (return sludge)
 Carrier of biological treatment - activated sludge -
 Invention of the activated sludge system 1914 (Ardern, Lockett)

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 Basis of dimensioning
basic possibilities

1. Evaluation of available data (normal case)

2. Additional specific investigations (series of
measurements), if data is insufficient
3. Mathematical determination with known (exceptional
case)
 Consideration of future development
(mostly with the help of characteristic values)
 Demography (population development)
 Residential areas
 Industry
 Tourism

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 Cumulative frequency / Undercut frequency

Inflow rate
100

90
[%]

80
frequency[%]

70
COD-load, inflow
Summenhäufigkeit

60

50
Undercut [%]
40
Cumulative

30

20

10

0
0 100 200 300 400 500 600
3
Qo in m /d

Departement of urban water management Bd,COD[1000 kg/d] COD-load 4

 Dimensioning Flows and Loads

 The following values are required from the influent to the biological
reactor:
 lowest and highest wastewater temperature
 organic load (Bd,BOD Bd,COD), load of suspended solids (Bd,SS) and of
phosphorus (Bd,P) for the determination of the sludge production and
thus the calculation of the volume of the aeration tank
 organic load and nitrogen load for the design of the aeration facility
for (as a rule) the highest relevant temperature
–Loading condition: BOD/N; highest saisonal peak
 maximum inflow rate with dry weather QDW,h (m³/h) for the design of
the anaerobic mixing tank and the internal recirculation flow rate
 dimensioning inflow rate QWW,h (m³/h) for the design of the
secondary settling tanks

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 Biological Standard Processes
Activated sludge processes

Elimination of: COD, BOD5, NH4-N, NO3-N, P

anoxic zone aerobic zone
denitrification COD-elimination
Influent & nitrification
(primary-treated)

Effluent

Aeration

Recirclation sludge Clarifier

Return sludge

Excess sludge

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 Inhabitant-specific loads

g/(Inhabitant·d)

German standard (ATV-DVWK A 131)

During biological wastewater treatment process for each kg BOD5 about 0,04-0,05 kg
Nitrogen and about 0,01 kg Phosphorus are needed for the development of biomass
and discharged in the waste sludge.
*) The share returned in the sludge liquor has to be concerned. Thus the loads in the
influent of the biological treatment stage can increase up to 20 %.
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 Dimensioning
of the activated sludge process I

1. Determination of the relevant flows and loads

2. Selection of the treatment process
=> Nitrification/Denitrification

Activated sludge tank (Part 1)

 Set up of a Nitrogen-balance
 Selection of the treatment process
Nitrification/Denitrification; P-Elimination; Selector
 Selection of the return sludge ratio;
intermitting DN  time
 Determination of the denitrification capacity
 Determination of the required sludge age
 Calculation of the sludge production

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 Nitrogen balance

anoxic zone aerobic zone

Influent denitrification COD-elimination
(primary-treated)
& nitrification

Effluent
aeration
Recirculation sludge Clarifier

Co,TKN Return sludge

N in influent: Excess sludge

Co,N = Co,org.N + Co,NH 4-N

+ Co,NO
3-N
+ Co,NO
2-N
N in effluent:
Ce,N = Ce,org.N + Ce,NH 4-N
+ Ce,NO
3-N
+ Ce,NO
2-N
N in sludge:
CNWS = 0,04 - 0,05 · Co,BOD 5
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 German effluent regulations for municipal
sewage; monitoring values

Size PE based on BOD COD BOD5 NH4-N *) Ntot anorg. tot P

*
Category inlet
60 g BOD5/(PEd) mg/l mg/l mg/l mg/l mg/l

1 < 1.000 150 40 – – –

2 1.000 bis < 5.000 110 25 – – –
3 5.000 bis < 10.000 90 20 10 – –
4 10.000 bis < 100.000 90 20 10 18 **) 2
5 > 100.000 75 15 10 13 **) 1

Abwasserverordnung
PE: population equivalent
(AbwV vom 2004)

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 Nitrogen removal procedures (DWA-A 131e, 2000)

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 Return Sludge Ratio I

 The operating conditions in aeration tank and secondary

settling tank are influenced through
 Mixed-liquor suspended solids concentration in the influent to the
secondary settling tank SSEAT
 Mixed-liquor suspended solids concentration of the return sludge
SSRS
 Return sludge ratio RS = QRS/Q.
 Suspended solids mass balance (neglecting XSS,EST)

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 Return Sludge Ratio II

Influent QWW,h

Effluent

Recirculation sludge

Return sludge

QRS = 0.75·QWW,h
max.QRS = 1.0 ·QWW,h

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 Denitrification capacity

(DWA-A 131e, 2000)

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 Important design parameter
for activated sludge system
Sludge age tSS: [d]
Average retention time of activated sludge in the activated sludge system

Amount of sludge in the aeration tank MLSSAT  VAT

tSS = =
Removed amount of sludge QES  MLSSES + Q  MLSSE

tSS = 1/(SPd·BSS) tSS = 1/µmax tSS …..10 to 12 days

MLSSAT: Total amount of solids (MLSS) (measured) [g/l or kg/m3]

MLSSES: Total amount of solids in the excess sludge

 Enough time for the growth of microorganisms

 Dimensioning sludge age in days dependent on the treatment target and the
temperature as well as the plant size (intermediate values are to be estimated)

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 Required Sludge Age (DWA-A 131e, 2000)

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 Sludge production SPd

 SPd = SPd,BOD + SPd,P

 SPd,BOD= SPC,BOD * Bd,BOD,ZB

(DWA-A 131e, 2000)

 SPd,P [kg/d] = Qd [m³/d]  (3  XP,BioP + 6,8  XP,Prec, Fe + 5,3  XP,Prec,Al)/1000

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 Dimensioning
of the Secondary Settling Tank
1. Selection of the sludge volume index
2. Selection of the sludge thickening time tTh; dependent on the biological process
selected
3. Determination of the return sludge suspend solids concentration (SSRS)
4. Selection of the return sludge ratio (RS) and estimation of the permissible
suspended solids concentration of the activated sludge in the biological reactor
(SSAT).
VAT reduces with increasing SSAT.
AST and tST rises with increasing SSAT.

5. Determination of the surface area of the scondary settling tank (AST) from the
permissible surface overflow rate qa or the sludge volume loading rate qav
6. Determination of the depth of the secondary settling tank from partial depths for
the functional zones and other sepcifications
7. Dimensioning of the sludge removal (scraper)
8. Verification of the selected thickening time by the sludge removal (scraper)
performance
9. Dimensioning of the return sludge and excess sludge pumps

Departement of urban water management Transfering: SS-content 18

 Characteristic parameters

 Mixed liquor suspended solids MLSS:

 Content of biomass
 Common values: 3 - 6 g/l
 Sludge volume SV:
 Volume of sludge after 30 min. settling of 1000 ml activated
sludge
 Measured value > 250 ml  dilution the sample (factor)
 Common values: 200 – 600 ml
 Sludge volume index SVI:
 Quotient of sludge volume and liquor suspended solids
 SVI = SV / MLSS
 Common values: 75 - 180 ml/g
(Steinke, 2009)
 Bulking sludge  SVI > 150 ml/g

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 Standard values for the sludge volume index

= MLSS
 Approximate values for the
MLSS concentration in the
biological reactor dependent on
the sludge volume index for
SSRS = 0.7·SSBS

(DWA-A 131e, 2000)

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 Settlement in horizontal flow tanks

(Austermann-Haun, 2011)
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 Permitted Thickening Time (tTh)

Type of wastewater treatment Thickening time tTh [h]

Activated sludge plants without nitrification 1.5 - 2.0

Activated sludge plants with nitrification 1.0 - 1.5

Activated sludge plants with denitrification 2.0 - (2.5)

 An exceeding of the thickening time of tE = 2.0 h requires a

very advanced denitrification in the biological reactor.

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 Suspended Solids Concentration
in the bottom sludge
 Achievable suspended
solids concentration in
the bottom sludge SSBS
 can be estimated
empirically in
dependence on the SVI
and tTh

(DWA-A 131e, 2000)

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 Surface Overflow Rate and
Sludge Volume Surface Loading Rate

 The surface overflow rate qA is calculated from the

permitted sludge volume loading rate qSV and the diluted
sludge volume DSV as:

(DWA-A 131e, 2000)

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 Dimensioning of the Secondary Settling
Tank

 QWW,h (m³/h) - Max. inflow rate

 SVI (l/kg) - Sludge volume index
Effluent
 SSEAT (kg/m³) - Suspended solids
concentration in the influent to settling tanks

QRS
Return sludge

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 Settling Tank Surface Area

 The required surface area of the secondary settling tank

results as follows:

(DWA-A 131e, 2000)

 For vertical flow secondary settling tanks the effective
surface area at the mid-point between inlet aperture and
water level is to be set
 With this the geometry of normal tank shapes is taken into
account

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 Horizontal flow circular secondary settling
tanks

Settling Tank Surface Area

(DWA-A 131e, 2000)

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 Dimensioning
of the activated sludge process II

Takeover: concentration of SS

 Activated sludge tank (Part 2)

Calculation of the volume of the biological reactor
Dimensioning of aeration (O2-demand; daily peak)
Dimensioning of circulation units; design of circulation pumps
Type of biological reactor
Checking of acid capacity and pH

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 Volume of the Biological Reactor

 Required mass of suspended solids in biological reactor:

MSS,AT = tSS,Dim · SPd [kg] Usual values of MLSS,AT: 2 - 6 g/l
 The volume of the biological reactor is obtained as follows:

 As comparative figures the BOD5 volume loading rate (BR) and

the sludge loading rate (BSS) can be calculated:
Bd = BOD5  Qo
Nitrification BR =0,35 kg BOD5/(m³·d)

Nitrification BSS= 0,10 kg BOD5/(kgSS·d)

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 Design of recirculation

Influent QWW,h

Effluent

Recirculation sludge
Return sludge

S NH 4 , N
RC  1
S NO 3, AN
with S NH 4 , N  C N ,O  S orgN ,e  X orgN , BM
therefore :
Q Q Q RZ Q
RC  RS  RZ [  ]  Q RC  Qt * RF  Q RS bzw .  RF  RS
Qt Qt Qt Qt

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 Dimensioning of aeration (O2-demand)

Oxygen consumption for C-Elimination

OUd,C [kg O2/d] = OUC,BOD,spez · Bd,BOD,I
Specific oxygen consumption OUC,BOD [kg O2/kg BOD5, valid
for CCOD,IAT/CBOD;IAT ≤ 2.2

(DWA-A 131e, 2000)

Oxygen consumption for Nitrification
OUd,N [kg O2/d] = Qd * 4,3*(SNO3,D – SNO3,IAT + SNO3,EST)/1000
Oxygen consumption for Denitrification (+)
OUd,D [kg O2/d] = Qd * 2,9 * SNO3,D / 1000
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 Dimensioning of aeration (Daily peak OUh)

f C * (OU d ,C  OU d , D )  f N * OU d , N
OU h [kgO2 / h] 
24

with fC and fN = Peak factors for load peaks (appear at

different times)

Load cases:
I fN = 1 with fC = x
Sludge age in d
II fN = x with fC =1 4 6 8 10 15 25

fC 1.3 1.25 1.2 1.2 1.15 1.1

fN for BC,BOD,I ≤ 1.200 kg/d - - - - 2.5 2.0

fN for BC,BOD,I > 6.000 kg/d 2.0 1.8 1.5 -

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 Summary

 The calculated tank volumes are highly influenced by the

correct evalution of the loads (Q, COD, BOD, N- and P-load)
 Design based on sludge age
 Design of denitrification: capacity of denitrification
 Design of secondary settling tanks based on sludge volume
load

 Simple calculation according to A 131

 Computer-based models according to A 131 or equivalent
approaches

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