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ABSTRACT
A new soil chemical stabilizer with improved soil characteristics is presented in this paper.
Styrene Butadiene Rubber (SBR) polymer has been effectively used as an inexpensive, eco-
friendly, reliable, and easily applied material for soil stabilization and the obtained response
performance has been evaluated. The herein described method is an improvement on the
traditional stabilizing agents previously used as it provides a cost effective pathway with a
simple technical strategy. In particular, this research emphasizes improving the engineering
properties of virgin soil by mixing it with varying percentages of liquid chemical stabilizer.
The evaluation of the effectiveness and the performance of SBR as a soil stabilizer was
performed in a series of laboratory tests on geotechnical soil properties such as consistency
limits, compaction, direct shear, and permeability. The obtained results revealed that the
addition of SBR (2.5% SBR) to the virgin soil resulted in a 17.8% increase in soil strength and
a 71.9% decrease in the liquid lim 13.5% decrease in the plasticity index.
KEYWORDS: SBR, Chemical stabilization, Geotechnical properties, direct shear test,
consistency limits
INTRODUCTION
Soil is widely used in various earthwork construction projects due to its being cheap and
available. Recently, a decrease in desert soil type has led to dependence on the un-desert soils, that
of low strength (California Bearing Ratio, CBR < 3) [1], low bearing capacity (B.C. < 98 kN/m2)
[2], high consolidation compressibility (Cc > 0.35) [3], high plasticity, and low density, making
them unsatisfactory for established construction requirements. Therefore, it is imperative to utilize
developing technology to improve the soil quality and its engineering performance. Out of the
different soil improvement techniques to be applied is the chemical stabilization of its components.
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Vol.
V 18 [2013], Bund.. D 736
Until
U now, the research com mmunity has dedicated
d seriious attentionn to investigatting the use oof a
varietty of chemiccal additives to solve soiil problems and thereby improving iits geotechniccal
propeerties. In geneeral, chemicaal stabilizers can be classiified into threee main categgories; powdder,
liquidd and emulsiffied additives. Powder cheemicals like liime [4] , cem ment [5], and ash (fly ash [6]
and RHA
R [7]) or their
t mixturess [8] have beeen widely appplied; whereeas, liquid cheemicals such as
epoxy y resin polym mer [9], sodiumm hydroxide, polyvinyl al cohol (PVA), bitumen em mulsion, aquappol
resin [10] have shown improv ved performaance regardinng soil strenngth and other geotechniccal
propeerties. There are
a a group off factors affeccting the perfformance of lliquid additives, whereby tthe
rheolo ogy as the maajor parameteer to be taken n into consideeration, as prresented in Taable 1 [11]. F For
particculate suspenssions, the parrticle size of the suspensioon is a contrrolling factor determining its
penetrrability, althoough the rheo ological propperties are equually importaant [12]. Thuus, the selectiion
criteriion of the liquuid additive chemical
c is governed
g by thhe characterisstics that deteermine the finnal
perforrmance of th he modified soil, with em mulsified liqquids being oone of the nnewly explorred
materrials.
Sttyrene Butad diene Rubberr (SBR) is an n example oof a liquid addditive, whicch is a randoom
copolymer, deriveed from styrrene and buttadiene monoomers. Theree are two cllasses of SB BR;
emulssion SBR (E--SBR) and so olution SBR (S-SBR) [13 ]. Solution (S SBR) is one of the polym mer
group
ps that have immense potential
p appllications in different inddustries [14]. SBR can be
considdered as an in
nexpensive ch hemical, whicch is widely aavailable, nonn-toxic, and reeadily solublee in
waterr. Furthermore, it can be applied
a as a local
l soil stabbilizer in connstruction sitee work with no
speciffic instrumenttations being required. Sch
heme 1 illustrrates the Styreene-butadienee scheme.
and enhance the hydrophilicity of clays. This action causes undesired plasticity when the quantity
of the water molecules and the mobility of cat-ions and anions in clay-water systems increase [18].
To reduce the plasticity of clays, the stabilizer may act as a coated surround on clay particles to
prevent ion exchange between the water and clay molecules. Hence, the water molecules will
become free to drain out of the soil body under a small load.
According to the published facts, there is no reported data for the use of SBR in the soil
improvement field; making this report the first and the only study dealing with this scenario. The
selection of SBR as a soil stabilizer is due to economic, technical and environmental aspects.
Therefore, the current research work emphasizes improving the weak soil properties for
construction purposes. The evaluation of the as-modified soil was performed via different
mechanical and engineering properties.
EXPERIMENTAL PROGRAM
MATERIALS
SBR
Next Base Technology (NBT II) is the commercial name for the chemical additives that were
used in this research, whose a scientific name is SBR “Soluble Styrene Butadiene Rubber” and
was provided by the Next Base Technology Company in Malaysia.
SBR Soil Stabilizer is a polymer emulsion, and is a simple example of a bonding agent, which
bonds soil particles together and also produces a waterproofing effect. SBR Soil Stabilizer is
added to the soil in the form of liquid, which is diluted in the correct amount of water. The dilution
amount is selected to achieve the target additive quantity at the desired (OMC) required for the
most efficient soil compaction.
Soil
The soil used in this study was collected from the University Science Malaysia (USM),
Engineering campus, Nibong Tebal, Penang, Malaysia. Distributed soil samples were collected
from a depth 0.3- 1.0 m from the ground surface then air dried. A mixer machine was used to
pulverize the soil and prepare it for testing. All samples utilized were oven dried and then sieved
on No.4 British sieve (4.75mm) before any test.
Figure 3: Relation between viscosity and torque percent for the SBR
where ν, t, and T are the viscosity in Cp, time in min., and the theoretical calculated torque %,
respectively.
SOIL CLASSIFICATION
Soil classification tests were performed based on combining sieving- sedimentation analysis
with wet sieving and the fine soil passing from sieve No.200, which was determined as a
percentage by the hydrometer procedure in accordance with BS 1377: part 2. [20],[21]. The soil
classification results were investigated and are presented in Table 4 and Fig. 4.
CONSISTENCY LIMITS
Dry soil that passed from sieve No.40 (425µm) was used throughout this experiment. Liquid
limit utilizing cone penetrometer device was carried out immediately, 3, 7 and 14 days,
respectively after being mixed. The results of the consistency limits are shown in Fig. 5 - 7.
Fig. 5 shows effect of SBR percentage by weight on liquid limit with curing time. Generally,
the liquid limit increases as the SBR percentage increase. After being mixed with soil directly, the
liquid limit increased more than the virgin soil at all SBR percentages, which can be attributed to
the effect of the liquid on the mixture without any mechanical or chemical effect on the soil. After
a 3- day curing time the stabilizer effect on the liquidity of the mixture was found by decreasing
the liquid limit for every SBR% -MH mixture. Nevertheless, the 2.5% had a lower liquid limit
compared with the other percentages of SBR-MH. The plastic limit increase as the SBR% also
increased with curing time, as can be seen in Fig.6. Depending on the liquid limit and plastic limit
results; the plasticity index decreased for all SBR% and with curing time but still 2.5% SBR has
less result. This result is similar to those of other research [7, 22, 23]. The consistency limits
results show the change in the position of the soil mixture 2.5% SBR from the right under A-line
at plasticity chart to left side. This change caused a change in the soil classification from MH to
ML as presented in Fig.8.
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Figure 7: Relationship between P.I. and SBR percent by weight at different curing time
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Figure 10: Effect curing time on shear resistance with different SBR percentage by
weight
= + Ф (3)
where τ and σ are the shear resistance in kPa and stress in kPa respectively, and c - Ф are the shear
strength parameters of the soil.
PERMEABILITY RESULTS
Fig.11 shows the permeability coefficient increases as the SBR percentage increases. This
result can be attributed to the behavior of the stabilizer which works as a waterproof at first action
Vol. 18 [2013], Bund. D 745
then by increaseing the SBR percentage, the SBR performed as an expansion materials in the soil
body that caused on increase in the space between particles (porosity). Therefore, the permeability
increased depending on this result about 14.7% in 2.5% SBR. These results can form to the type of
soil MH and the classification by Terzaghi and peck [25], same results are presented by[26] .
pH TEST RESULTS
Fig.12 shows the pH effect on soil specimens with curing time (1, 3, 7 and14 days). The pH of
the virgin soil was less than 7 and also SBR, which means the media of the mixture had a pH less
than 7 (acidic media). A pH of less than 7 in soil effects its strength by decreasing the percentage
of free iron oxide ( in the tropical soil used) and the iron oxide increases the strength property to
the soil by coating the iron oxide on the surface which aggregates the particles into clusters.
Generally, there is a decrease in the pH in soil with an increase in SBR percentage. However, there
is an increase in pH as curing time increases and the (7.5%, 10% and 12.5% SBR) produced the
same results, Stable in every curing time. In Fig.12 four curves appeared because three curves
fitted on it. the results in Fig.12 were similar [24] .
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CONCLUSION
Depending on all the results obtained from these experiments the following conclusion can be
made on the performance of the SBR as a stabilizer:
1. The plasticity index was reduced to 71.9% by preventing the water from attacking the clay
particles.
2. The optimum moisture content was reduced due to reduction in the ionizing and
exchanging of the water molecules on the surface of the clay platelets.
3. The shear strength increased 17.8% by increasing inter -particle bonding.
4. pH decreased by about 14% for the virgin soil.
5. After the soil has been improved, it can be used in a wide range of construction projects as
well as a filling materials because it has very low permeability in 2.5% SBR had
permeability coefficient 1*10-7 m/sec.
6. Generally the chemical stabilizer (SBR) demonstrates the ability to improve this type of
soil, while with SBR non- toxic, non- vapor and safely handling used.
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© 2013, EJGE