CHEMISTRY

Q 1. A square planar complex is formed by hybridization of which atomic orbital?

(A) s, px, py, dyz (B) s, px, py, dx2 - y2 (C) s, px, py, dz2 (D) s, px, py, dxy

Q 2. The pair of species having identical shapes for molecule of both species is
(A) XeF2, CO2 (B) BF3, PCl3 (C) PF3, IF5 (D) CF4, SF4

Q 3. Which of the following has regular tetrahedral structure?

(A) BF4- (B) SF4 (C) XeF4 (D) [Ni(CN)4]2-

Q 4. Which of the following is diamagnetic in nature?

(A) He2+ (B) H2 (C) H2+ (D) H2-

Q 5. Using MO theory predicts which one of the following species has the shortest bond length?
(A) O2- (B) O22- (C) O22+ (D) O2+

Q 6. The molecule having smallest bond angle is

(A) PCl3 (B) NCl3 (C) AsCl3 (D) SbCl3

Q 7. In which of the following pairs the two species are not isostructural?
(A) AlF63-, SF6 (B) CO32-, NO3- (C) PCl4+ , SiCl4 (D) PF5, BrF5

Q 8. The species in which the N atom is in a state of sp hybridization

(A) NO2 (B) NO2+ (C) NO2- (D) NO3-

Q 9. Which of the following set of ions represents a collection of isoelectronic species

(A) N3-, O2-, F-, S2- (B) Li+, Na+, Mg2+, Ca2+
(C) K+, Cl-, Co+2, Sc+3 (D) Ba+2, Sr+2, K+2, Ca+2

Q 10. Which of the following has highest value of ionic radius?

(A) O2- (B) B+3 (C) Li+ (D) F-

Q 11. The IP of Na is 5.1 eV The value of electron affinity of Na+ will be (in eV )
(A) - 2.55 (B) -5.1 (C) -10.2 (D) +2.55

Q 12. The ionic radii of N3-, O2-, F- in 𝐴̇ are

(A) 1.71, 1.40, 1.36 (B) 1.71, 1.36, 1.40
(C) 1.36, 1.40, 1.71 (D) 1.36, 1.71, 1.40

Q 13. The correct bod order of the following species are

(A) O2+ < O2- < O22+ (B) O2- < O2+ < O22+ (C) O22+ < O2+ < O2- (D) O22+ < O2- <O2+

Q 14. Maximum bond angle of nitrogen is present in which of the following

(A) NO2+ (B) NO3- (C) NO2 (D) NO2-
Q 15. Bond order of 1.5 is shown by
(A) O2+ (B) O2- (C) O22- (D) O2

Q 16. Which of the following is trigonal planar?

(A) N3 (B) NO3- (C) NO2- (D) CO2

Q 17. XeF2 is isostructural with

(A) SbCl3 (B) BaCl2 (C) TeF2 (D) ICl2-

Q 18. In which of the following central atom does not have sp3 hybridization
(A) CH4 (B) SF4 (C) BF4- (D) NH4+

Q 19. Among the following which compound will show the highest lattice energy?
(A) KF (B) NaF (C) CsF (D) RbF

Q 20. The first IP of Be and B are

(A) 8.29 and 8.29 (B) 9.32 and 9.32 (C) 8.29 and 9.32 (D) 9.32 and 8.29

Q 21. Which of the following element has maximum electron affinity?

(A) I (B) Br (C) Cl (D) F

Q 22. Among the following which one has the highest cation to anion size ratio
(A) CsI (B) CsF (C) LiF (D) NaF

Q 23. Solubility is directly dependent on

(A) Hydration energy (B) Lattice energy (C) Bond angle (D) Bond length

Q 24. Electronic geometry of XeF2 is

(A) Trigonal bipyramidal (B) Tetrahederal
(C) Linear (D) Trigonal planar
Q 25. Which one of the following has greater bond strength?
(A) 1s-1s (B) 2p-2p (C) 2s-2p (D) 2s-2s
Q 26. Which of the following has highest thermal stability?
(A) BeCO3 (B) MgCO3 (C) CaCO3 (D) BaCO3
Q 27. Which one of the following has highest solubility strength?
(A) LiF (B) NaF (C) KF (D) RbF

Q 28. On increasing polarization the charge on cation

(A) increases (B) decreases (C) remain constant (D) increases and decreases
Q 29. If the atomic number is 33, it will be placed in the periodic table in ……. group

(A) 1st (B) 3rd (C) 5th (D) 7th

Q 30. Which of the following has minimum bond length?
(A) O2+ (B) O2- (C) O22- (D) O2