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Advanced Concept For Waste-Fired Power Plants PDF
Advanced Concept For Waste-Fired Power Plants PDF
THREE CONCEPTS 36
CONCEPTS OVERVIEW................................................................................................................36
FEATURES OVERVIEW.................................................................................................................37
Value – a solution that makes sense............................................................................38
Optimized – for absolute performance.......................................................................39
Environmental – for supreme eco-efficient performance.................................40
ON THE HORIZON 44
THE FOCUS OF OUR R&D ACTIVITIES.......................................................................................44
Electrical efficiency..............................................................................................................................44
Bottom ash.............................................................................................................................................. 45
Next generation sintering process...................................................................................................45
Ferrox® - stabilization...........................................................................................................................45
Asian Waste
Characteristics
The nature of Asian waste is wet
and with a high content of organic
matter. It is characterized by having
a relatively low heating value that
changes with seasonal precipita-
tion. The waste is a moist, wet fuel,
especially during the rainy seasons.
In developing societies the heating
value of the waste will typically
increase as a consequence of the
increasing standard of living. The use
of packaging materials including
paper, plastics and other combustible
Urbanization with its challenges is a global problem.
substances, increases.
waste hierarchy shall enforce us to reduce the tion of energy is increasing steeply in Asia as seen
amount of waste, separate the waste at the below[4], and the need for new energy resources
source for recycling and composting, landfill- is urgent.
ing, or possibly thermal treatment. These op-
tions are all part of the solution to the grow-
ing waste problem and together they form an
integrated waste management concept with
reliable environmentally friendly sound solu-
tions.
reuse
landfill and optional gas recovery
Available processes
Thermal treatment of waste can be made
in the absence of air (pyrolysis), by limited
addition landfill waste
of air (gasification) or at an am-
ple supply of air (incineration). In the latter
case the waste is simply combusted like any
thermal
other fuel, and the thermal treatment plantbiological
treatment treatment
becomes a Waste Fired Power Plant (WFPP).
landfill waste Consequently, in the remaining part of this
publication wecombustion
shall use the term ’wasteanaerobic dig
combustion’.
thermal biological
treatment treatment
pyrolysis compost
Pyrolysis and partly gasification require an
external heat source, while – when com-
combustion anaerobic digestion
gasification
busted – the energy content of the waste is
pyrolysis composting
normally sufficient to sustain the combustion
without addition of other fuels.
gasification
Two main processes are applied for the ther-
mal treatment of waste: Fluidized bed com-
The available methods of waste treatment bustion and grate combustion.
Investment
cost
6 21’ Century Advanced Concept for Waste-Fired Power Plants
Investment O&M Technology
Fluidized bed combustion (as well as most of Denmark, Copenhagen and the cities of
pyrolysis and gasification processes) re- Hangzhou, China and Seoul, Korea. Did you know that...
quires that the waste be shredded to a small ... 230 million tons of municipal solid
particle size before being introduced in the It can bee seen from the table that the val- waste or garbage is generated each
combustion (pyrolysis/gasification) cham- ues differ substantially, mainly in accordance year in the United States of America.
ber. Grate combustion; on the other hand, with the organic content. This means that on average each per-
son generates about 800 kg of waste
can accept bigger items and only oversized
per year.
materials has to be crushed. For that rea-
son grate combustion is often referred to as ... each person in the United King-
mass burning. dom, throws away seven times their
body weight (about 500kg) in waste
Mass burn combustion is by far the preferred every year, on average.
option, and the only one which has shown
its reliability during prolonged 24 hour a day
Heat input (excl. aux. fuel) 11,5 MJ/kg
operation. In other words mass burn combus- [MW] 12,5 MJ/kg
tion is the only proven technology available 10,4 MJ/kg
26 G
But the waste does also contain incombusti-
C
bles. These leave the process as bottom ash, 24
but at a much-reduced rate both by volume Medium
22
and by weight. Most often, the bottom ash
is utilized as a synthetic gravel-like material, 20
but under certain conditions it may be taken H 5,2 MJ/kg
18
to a landfill.
16 I
Low
Waste as a fuel 14
B
The diverse nature of MSW demands that
12 3,3 MJ/kg
the Waste Fired Power Plant (WFPP) must be
J
carefully designed to handle and to operate 10
efficiently over a wide range of waste input A
8
conditions. K
6
The energy recovery from MSW is a function
4
of the heating value of a given material com-
position. The energy content in the various 2
Waste through put
waste components ranges from inert to 20 [t/h]
table is a comparison between the capital Typical waste characteristics in four cities
yearly figures
flyash
8.000 t to deposits
slag
40.000 tconstruction materials
scrap
5.000 t reuse
100 % 4 % to deposits
yearly figures
Output to network
• district heating
flue gas
flue gas • district cooling
Energy generation & co-generation waste boiler
cleaning
condensation • de-salination
The WFPP can create various forms of energy & heat pumps • process steam
24 t/h • power grid
by means of thermal treatment: 192.000 t/a
A WFPP reduces the dioxin accumulated Household waste and other waste gener-
in our leftovers ated by modern society reflect production
Objectives of combustion
The prime objective of a waste combustion
plant is to burn the waste in an environ-
mentally safe manner. This means that the
burnout of the flue gas and bottom ash shall
be maximized and the formation of air, water
and soil polluting substances shall be pre-
vented as far as possible.
Note: Grate
All limit values refer to liquid to solid ratio (L/S) When introduced onto the grate, the waste is
I
TDS is total dissolved solids first dried, then partly pyrolised under forma-
II
DOC is dissolved organic carbon tion of combustible as well as incombustible
gases. The combustible gases burn above the Post combustion chamber
grate. The remaining waste is subsequently Modern standards require that the flue gas
burned out on the grate to a TOC content of be exposed to a temperature of min. 850°C
less than 3% before it falls into the – normally for a time of min. 2 seconds after the last sec-
wet – bottom ash system. The system may also ondary air injection. The furnace must there-
be designed in accordance with the required fore have a post combustion or afterburning
leaching properties of the bottom ash. chamber of a certain height above the grate.
The final burnout of the flue gas takes place in
Primary combustion air is supplied from un- that chamber, and secondary combustion air
derneath through small openings in the grate. is added in the required amount and in a way
The air supply is determined by two consider- that secures maximum turbulence. Flue gas cleaning
ations: Firstly, enough air must be supplied to
During combustion when fuels are
cool the grate (air-cooled grate), and second- It is in the post combustion chamber that the burned a certain number of gas
ly, enough air must be supplied to sustain the auxiliary burner(s) are located (if installed) and components remains beside the ash.
(primary) combustion. Normally, the former that the injection of ammonia (NH3) or urea These are after the heat is extracted
quantity is the larger. Thus, by partly cooling ((NH2)2CO) for NO x reduction according to the called flue gases and are cleaned in
the grate by water (water-cooled grate), it is SNCR process is made. a flue gas cleaning (FGC) system.
possible to adjust the primary air supply to
Flue gases include: carbon dioxide
exactly the flow needed for the primary com- Flow design and flue gas (CO2), carbon monoxide (CO), nitro-
bustion process, only. Numerous samples of re-circulation (FGR) gen oxides (NO x ),nitrogen (N 2),
grate siftings shows a very good burnout and sulphur (S), sulphur dioxide (SO2),
in the same order as the main ash flow. The total air supply to the combustion process water vapour, soot, hydro carbons and
is the sum of the primary and secondary air. heavy metals etc.
The small openings in the grate carpet allow, To secure complete burnout it is necessary to
Tremendous advancements have been
on the other hand, smaller particles of the operate at a certain surplus of air. The excess
done in the field of FGC and emission
waste to fall through the grate as grate sift- air passes all the way through the boiler and
monitoring. Many emissions can now
ings. The siftings are collected, and normally the flue gas treatment system to the chimney be measured continuously for online
they are mixed into the bottom ash, but they and – depending on the flue gas temperature monitoring of compliance with regula-
may be removed separately and possibly re- in the chimney – it represents a loss of energy tions.
turned to the feeding hopper. and hence a loss of thermal efficiency.
The excess air ratio can be reduced on the In or after the FGT system it is possible to re-
primary side by using a water-cooled grate cover additional heat in economizers or by
and on the secondary side by re-circulating condensing part of the water vapor content
a part of the treated flue gas (FGR). of the flue gas.
It is also of importance whether the entire An induced draft fan creates the necessary
gas flow through the furnace is counter flow, under pressure through the whole waste to
centre flow or parallel flow as explained lat- energy plant and a series of emission moni-
er on in the present publication. tors checks that the flue gas complies with
the relevant emission limit values before it is
Thus, the air supply and the volumetric mix- discharged through the chimney. The moni-
ing of primary flue gases with secondary air toring results are sent to the CMS system.
is a delicate design feature. Computerized
Fluid Dynamic (CFD) modeling is an impor- On the commercial side
tant tool in this design operation. A new era requires new initiatives. The market
opens and liberalization sets new rules and
Boiler design demands economically optimal operation of
Boilers for Waste Fired Power Plants are the complex plants in the waste sector.
normally water tube boilers and most often
they have four passes: 3 vertical radiation The increasing liberalization of the waste and
passes and a convection pass. The first of energy sectors is already affecting the waste
the radiation passes is integrated in the fur- management companies. The shift from mo-
Renewable energy nace as the post combustion chamber. The nopoly to free competition will be easiest for
Renewable energy (RE) captures en- convection pass, in which the evaporators, the companies that have prepared themselves
ergy from existing flows of energy, from
superheaters and economizers are located, – new business models and new technology
on-going natural processes, such as
may be vertical or horizontal. will be decisive competitive parameters.
sunshine, wind, flowing water, bio-
logical processes, and geothermal heat
flows. The most common definition is When designing a boiler for waste firing it is The operation is facing new challenges, when
that renewable energy is from an en- important to take the special risk of corro- competition increases and becomes more in-
ergy resource that is replaced rapidly sion into account. This risk is mainly due to fluential in the coming years.
by a natural process such as power the release of clorine from the waste during
generated from biomass, the sun or
the combustion combined with condens- Due to the high investment costs of estab-
from the wind.
ing components of the metals Zn and Pb. In lishing thermal waste treatment plants, new
Biomass is a Renewable Source of practice this limits the steam parameters to operation models are becoming more popu-
Energy (RES) and re-grow in nature, a maximum of around 400°C and 50 bar. lar and include financing models such as BOO
such as wood, crops, or other plants and BOOT.
(biomass). Plants (biomass) use Corrosion protection
photosynthesis to store solar energy in HCl is highly corrosive at high (> 450°C) as Modern waste fired power plants are built to
the form of chemical energy. Waste – a
well as at low (<110°C) temperatures. To pre- last 30 years and to make money for the com-
byproduct of industrialization – in-
vent corrosive attacks on the furnace boiler munity or their owner. In order to finance the
cludes biomass.
system the heating surfaces in the radiant plants in ways that make them affordable to
Waste fired power plants can part is protected by a resistant refractory the operator, the community, county or re-
produce clean, renewable energy material and/or welded high-alloy materials. gion requires a solid and sustainable founda-
through the combustion of munici- In the radiant passes the flue gas is cooled tion with optimum life-cycle cost.
pal solid waste with the most modern slowly to a temperature of less than 700°C
pollution control equipment for clean-
before it – in the convections pass – is fur- Availability
ing emissions. Commitments to fulfill
ther cooled by the heating surface bundles As basis of a sound business model, predict-
the obligations under the Kyoto pro-
tocol will lead to an increase in the use there. ability is one of the most important issues. If
of renewable sources of energy. The the revenue is not predictable then the return
EU has already proposed to generate To prevent low temperature corrosion the of investment becomes unpredictable and
22.5% of its electricity from renewable feed water should be preheated to minimum thus the whole fundament of the business is
energy sources by 2010. Energy from 125°C before being introduced in the boiler. questionable or at least very risky.
waste is now considered a source of
renewable energy under existing law
in many countries.
Flue gas treatment (FGT) To ensure your operation the availability is
In the boiler the flue gas is cooled to 150- maybe the one most important parameter of
200°C depending on the subsequent FGT your whole plant. Availability can be charac-
Regional/national Regional/national
ance, reliability and effectiveness.
Exploitation
Revenue and cost streams
Investment
Interests
in WFPP operation
support
Every hour counts and this is where the profit
Cost-benefit
is made. scheme re-
duction
Heat sale
Exploitation
Cost-benefit considerations Revenue and cost streams
Investment
Interests
inGate
WFPP operation
fee
reusePower sale
support
Proven solutions and technology form the for waste waste fired
streams Steam sale
basis for a sound and financial viable project Cost-benefit power plant
scheme Emission credits
with the highest return on investment for the recycling & composting
By products
(iron, non-ferrous metals)
community. A business model involves many Heat sale
Gate fee
revenue and cost flows and numerous param- energy recovery
Power sale
for waste waste fired
eters shall be considered for a true cost-ben- streams (thermal treatment)
Steam sale
power plant
Personnel
Operation
Maintenance
Consumables
Wastewater
Bottom ash
Flyash
Public relations
efit scheme. Emission credits
By products
landfill and optional gas
(iron, recovery
non-ferrous metals)
Personnel
Operation
Maintenance
Consumables
Wastewater
Bottom ash
Flyash
Public relations
time of the plant, the implementation costs The main cost and revenue
plant flows in a WFPP
operation administrative
Manning manager manager personel
will balance out. The cost of operation and three shifts day shift day shift day shift
maintenance will affect the project in its full
lifetime the next 30 years. The secondary crane operator
side-effects from a non-performance opera- 24 hours
plant operation administrative
tion are loss of income, penalties, pollution Manning manager manager personel 14
waste fired
three shifts day shift day shift day shift full time
and breach of contracts. power plant positions
plant operator landfill waste
crane
24 operator
hours
For an optimum return-on-investment, lifecy- 24 hours
cle costs shall be assessed. 14
waste fired
mechanical
thermal
full time biological
power plant electrical treatment
positions treatment
Operation vs. personnel costs maintenance maintenance
day shift day shift
plant operator
Operating the plant require real people. With 24 hours
a plant designed for low personnel costs a combustion anaerobic digestion
limited number of persons is necessary.
mechanical electrical
maintenance maintenance pyrolysis composting
day shift day shift
The operators normally work in three shifts
with the administrative and maintenance per-
gasification
sonnel work during the day only. With holi- A plant optimized for low operation costs, requires a
days, illnesses, etc. a total of 8 operators are minimum of persons to operate it
required. Plant management, administration
and daily maintenance are handled by 6 per-
sons. The 2 administrative people also handle
waste registration, etc. In total a minimum of
14 persons can manage the plant. This does
Investment
not include manpower for residue handling, cost
plant cleaning, etc. • High efficiency
• Proven technology O&M Technology
For main revision of the plant, extra help will • Availability and reliability cost
be required from outside entrepreneurs. The • Few people to manage Best
contractor can supply assistance for inspec- & operate evaluated
tion, revision and optimization. In practise • Technical and environmental price
the number of persons employed is normally performance
Availability Efficiency
somewhat higher. • Low risk
• Capital costs
Decisive parameters for Performance
the selection of technology The parameters related to the overall
In Europe the selection of the right thermal performance and commercial viability are
treatment solution is in most cases based extracted from each proposal and compared
upon a selection model where certain pa- against each other. The technical aspects are Evaluating a waste treatment solution
rameters are decisive and prevailing for the often indirectly evaluated thorough other in- require all of the above criteria to be con-
evaluation. dicators. sidered
Sludge co-combustion VoluMix™ Ferrox® Low excess air Boiler preheating Operator training
Vølund Control & Vertical & horizontal FGR – In operation Strategic sparepart
flue gas recirculation Co-generation
Monitoring System superheater/eco cleaning system program
Operation &
Six’ Waste Thermal Environmental Performance & Availability
Maintenance
elements flexibility design focus efficiency engineering
engineering
Platform technology
Boiler VølundSystems™
technology
Combustion
technology BS Technology™ VølundSystems™
VALUE
> CONCEPT
Value VølundSystems Technology
proven & rock-solid See overview page 36
lowest operating and maintenance cost See details page 38
efficient
BAT
Packaged & delivered only as pre - engineered modules
in the range of 2-5-10-15-20-25-30-35-40 t/h
OPTIMIZED
> CONCEPT
Optimized BS Technology
highest efficiency See overview page 36
advanced combustion technology See details page 39
minimum loss of ignition
customized to meet your needs
BAT
Packaged as pre - engineered modules
in the range of 2-5-10-15-20-25 t/h
ENVIRONMENTAL
> CONCEPT
Environmental Rotary Kiln Grate Technology
meets the stringents environmental requirements
See overview page 36
long residence time at high temperature See details page 40
an effective way to destroy contaminants
sintering of bottom ash
minimum leaching
BAT
Packaged & delivered only as pre - engineered modules
in the range of 5-10 t/h
Extracting energy from waste is a demanding modern requirements with the objective to
task as explained earlier in this publication. develop and improve the systems to meet
The result of our strong focus at research and future challenges to waste treatment. All
development is innovation turned into ma- modules are confirming to EU standards.
ture and well-functioning products. This can
however only be done when combined with The features and benefits of the technologies
applied experience and knowledge. embedded in our modules are listed below.
The overview is followed by a detailed descrip-
We have developed the technologies and tion of selected modules and components on
plant components to make them conform to the following pages.
Vølund Control System Our basic state of the art User-friendly, well designed,
control system provided on complete and easily
all plants operated
ACC – Automatic Adjustment to non- Optimized production,
Combustion Control predictable waste streams uniform combustion
CFD optimization Advanced guidelines for Uniform temperature & flow
furnace & boiler design field, extremely low CO
emission and corrosion
Integrated 3D visual modelling of the For smooth EPC integration
plant design plant using PDMS and sub-assembly
Ferrox® Stabilization and Environmentally safe
immobilization of heavy disposal of residues
metals in various residues
Sintering process Stabilization and High quality
immobilization of bottom ash bottom ash, low leaching
residues
WasteBoostTM Increased steam temperature High electrical efficiency
Sealing
The correct design of the feed hopper pre-
Feed hopper vents waste clogging and ensures a continu-
Level
ous waste transport to the water-cooled chute.
indicator
Two powerful hydraulic gates are placed be-
tween chute and hopper. These gates can be
Safety gates Water closed in the event of a fire in the chute, and
cooled they will close automatically in the event of
chute
power failure.
Support
Sealing The water-cooled feed chute is made of heavy
Hydraulic
feeder steel plates. The smooth sides have a negative
mechanism inclination to ensure a free waste transport
through the chute to the feed platform. The
Feeder
chute cooling system makes it fire-resistant.
among the most reliable and optimal solu- The patented water-cooled DynaGrate® has
tions on today’s market. been through approx. 32,000 hours of proto-
type operation and approx. 32,000 hours of
We offer updated spare parts for all our grates commercial operation (up to year 2006).
and plant optimization for achievement of the
best possible combustion with minimal envi- The watercooled DynaGrate® is distinguished
ronmental impact. by its suitability for high calorific fuel and offers
full integration with the air-cooled DynaGrate®,
providing complete freedom within the grate
D ynagrate® area, whether air-cooled, water-cooled, or both.
DynaGrate® is the result of 40 years of devel-
opment. The proven air-cooled DynaGrate®, is DynaGrate® is capable of handling all sorts of
ideal for combustion of refuse with very high unsorted waste and has the possibility of bio-
combustion efficiency for greater energy re- mass co-firing. DynaGrate®
covery while limiting environmental pollu- has a very strong aggetation of the fuel
tion. How the grate works bed, because of the unique move-
The grate resembles a staircase. The indi- ment of the grate bars. This result in
vidual steps – the grate bars – are alternately extremely good burn-out of the waste.
placed horizontally and vertically. These The water-cooled version of the Dy-
grate bars are mounted on shafts and, as naGrate® is outstanding because the
the grate bars of one axle interferes with cooling system is integrated in the
the bars of the adjoining axle, a continuous shaft which is also support for the grate
grate carpet is formed. When the axles turn bars. Thereby there are no moveable
parts under the grate and the risk of un-
60 degrees in opposite directions during the
controlled stops are minimized.
movement of the grate, the steps are chang-
ing from vertical to horizontal and from hori-
DynaGrate® ready for shipment zontal to vertical.
The changing of the steps from horizontal physical contact exists between the individu-
to vertical and vice versa produces a waving al bars during the grate movement.
longitudinal movement. This produces opti-
mum turnover and distribution which ensures A grate consists of modules which can be com-
the drying, conveying, and combustion of the bined to grates of various lengths and widths.
waste bed. The largest width of one grate line is 4.8 me-
ters. Larger grate widths can be achieved by
The driving mechanism, which is situated out- placing several lines side-by-side. There are
side the furnace, provides a constant 2 mm no limits to the number of sections which can
gap between successive grate bars in all axle be combined or to the grate length. The grate
positions. It is through this 2 mm gap that the is placed at a 25 degree inclination from the
combustion air is added between the succes- horizontal axis.
sive bars.
The individual sections can be operated in-
The grate movement ensures that the air gaps dependently of one another at a velocity
are always clean and free from particles. No adapted to the energy release. Each grate
section is equipped with a complete driving
mechanism, including double-acting hydrau-
lic cylinders. The driving mechanism also en-
sures that the gap between two subsequent
grate bars remains constant during the grate
movement.
Water-cooled DynaGrate®
Process advantages Mechanical advantages
Grate surface cooling is independent of com- Cooling water is led to and from the grate
bustion; air can thus be added and adjusted for through the shaft ends and to the middle
optimal combustion sections of the shafts through pipe connec-
tions
Excellent primary air distribution, minimizing Fans may be smaller
excess air and giving reduced quantities of
combustion gases
Minimal corrosion due to low grate surface No grate bar damage due to temporary cool-
temperature ing system failure
Constant high flow of cooling water through Separate cooling system for each grate section
the grate bars, avoiding local boiling provides protection against total cooling water
failure
Low differential temperature over the grate Water cooling provides adequate grate dura-
results in low thermal stress bility for combustion of high calorific refuse
which causes high thermal stresses in the
grate.
Lowest in Europe
The majority of the WFPPs in Denmark
shall be neutral and must not create a
profit.
• Handling of unsorted waste The grate sections are integrated into one
unit, and all sections are operated and con-
• Low total organic carbon in ash content trolled individually. This means that each sec-
tion has its own grate drive and control sys-
• Possibility of biomass co-firing tem for combustion air.
The grate movement is like a “walking floor” The individual components used in the grate
and is unique in its simplicity and low mechani- design are specially developed for highly var-
cal wear. The combustion air is blown in and up iable loads and high temperatures. The result
through many small gaps, ensuring perfect air is high reliability with minimal downtime.
distribution. This results in combustion of the
waste with minimal power consumption for air The water-cooled grate version is fully com-
injection and grate movement. Inspection and patible with the air-cooled version, i.e. with
maintenance during the planned yearly stop- the same modular design, lengths, widths,
pages are also very simple because all servic- declination, vertical grate transition, etc. The
ing of grate bars, grate blocks, grate girders air-cooled grate blocks on the grate girder are
and rollers takes place in the furnace above the replaced by water-filled blocks, and water-
grate with hand tools only, and there is no need cooled long blocks in the full length of each
to work below the grate. grate girder.
The grate is divided into a feeding section A grate solution can have partly or fully water-
with pusher, a combustion grate and a burn- cooled sections. For example, the combustion
out grate. Our grate has four sections, two of grate sections can be water-cooled while the
which form the combustion grate at an angle burn-out grate sections is air-cooled. The wa-
of 15º whereas two sections form the burn- ter-cooled grate has relatively few inlet holes
out grate at an angle of 7.5º to the horizontal for combustion air, which is injected at high
plane. A one metre high vertical grate transi- speed. This largely prevents burned-out ash
tion between the combustion grate and the and molten metals such as aluminium from fall-
burn-out grate ensures that waste lumps are ing through the grate down into the primary air
broken up and burned. hoppers underneath the grate.
Low pressure loss across the grate Minimizing fan energy consumption
Corrosion attacks in a waste-fired boiler can in The corrosion rate can be reduced by using
principle be divided into two main types. high-alloy tubes and/or by protecting the
• Low-temperature corrosion tubes with refractory lining or welded high-
• High-temperature corrosion alloy materials such as Inconel®. The choice
between refractory lining and Inconel® de-
Low-temperature corrosion appears in the pends on:
boiler and on other surfaces where the tem- • The plant size
perature is under approx. 135°C. It is caused • Regulatory requirements on the reten-
by condensation of the acidic sulphurous and tion time of the flue gasses
chlorine-containing gases. This type of corro- • Variation in heating values
sion is temperature-dependent. New plants • Which type of heating surface and
are being designedin order to avoid low-tem- design is chosen
perature corrosion.
If refractory lining is chosen as protection,
High-temperature corrosion (HT-corrosion) is the choice between the different lining types
more complex and only appears on the heat- will be based on requirements regarding the
ing surfaces in steam boilers in particular on: resultanting heat conduction, the residual
• Evaporator heating surfaces porosity and the smoothness of the lining sur-
• Superheater tubes face. Inconel® cladding is done robotic
The total NO x reduction with ammonia or Temperature window for the NO reduction by ammonia
urea depends on three classical reaction Temperature window for the NO reduction by ammonia
mechanisms and thereby also on the follow-
200
ing design and operational parameters:
• Temperature 1 80
Reation time
• Turbulence 1 60
NO mole fraction [ppm]
• Time 1 sec
1 40
5 sec
Another important factor is the waste com- 1 20
position including: the calorific value and the 1 00
amount of nitrogen bound in the waste.
80
With our integrated SNCR system it is possi- 60
ble to achieve 70 – 80% NO x removal with a
40
slip of ammonia (un-reacted ammonia) with-
in the range of 5 – 10 mg/Nm3. 20
0
Why not Selective Catalytic Reduction? 600 7 00 800 900 1 000 1 100 1200
Unless specific circumstances prevail, Vølund T emperature [°C]
recommends that NO x be reduced by SNCR.
The investment in SCR (Selective Catalytic
Reduction) is high, and the system is com-
plex. Maintenance is expensive and consum-
ables in addition to ammonia are natural gas
(or low sulphur oil) and power due to a high
pressure drop in the catalyst. At the same
time the service life of the catalyst is only 4 –
5 years. On the other hand the SCR removes
dioxins from the flue gas.
2,0 CO 10,00
Excess Air
The Vølund boiler design with staged com-
1,0 5,00
bustion, centre/- or parallel flow furnace, FGR,
0,0 0,00
etc., allows us to operate with a very low ex-
0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24
cess air ratio, which results in O2 levels of 4-5%
Time [h] wet with low CO emission and no CO corro-
Oxygen & Carbon Monoxide sion!
IR
V
C C D c ame ra ( R G B )
Combustion G A C Acoustic gas temperature
Control A Tf measurement
G IR Tf Temperature measurement
Tf Tp Temperature, primary air
F P Pressure drop over fuel bed
AC G Gas components ( O2 , H2O , CO etc . )
S IM
F Flame position and colour
2
H C ame ra
3 M Mass flow sensor
S Grate speed
1
3 S e c . air
P rim. air
V Crane weight
V
A Fue l leve l measurement
M F
H H2O -content, humidity measurement
P T
T Tempe rature measurements
Tp S
in cooling circuit
Secondary air
S IM Simulator = combustion + process
Primary air mode l
Waste combustion is one of the most complex • Increased lifetime of boiler & refractory
combustion processes. The process in a burning through a more constant thermal
refuse bed includes: exposure of the plant components
• Drying • Reduction of excess air
• Ignition • Reduced emissions
• Pyrolysis • Optimal quality of ashes through
• Gasification systematically controlled burnout
• Gas-phase combustion • Increased thermal effiency
• Solid-phase combustion • Increased availability
96
quantity.
94
92
The main objectives of our ACC system are to
90
maintain a uniform flue gas temperature pro-
88
file – thus reducing the size and number of high
86
temperature regions and to control the primary
0 4 8 12 16 20 24 28 32 36 40 44 48
combustion air distribution and ratio of primary Time [h]
to secondary combustion air flow. Furthermore, Optimized steam flow with ACC
the system controls and adjusts the position of
the main combustion zone to meet variations in Values [%] O2 content in fluegas with ACC O2 content in fluegas without ACC
100,0
the waste heating value. The system sensors are 95,0
90,0
IR cameras and the signals are digitized and ana- 85,0
80,0
lyzed in a neural network-based control system 75,0
70,0
with feed forward signal to the Vølund Control 65,0
System[20]. 60,0
55,0
50,0
45,0
The benefits of using the ACC system are: 40,0
35,0
• Increased annual waste throughput 30,0
25,0
• Improved steam production with more 20,0
15,0
constant production rate 10,0
5,0
• Reduced stress on the turbine, less 0,0
7 8
5 6
maintenance and stops 2 3 4 O2 content
1
• Reduction in the use of auxilary fuels Optimized O2 content with ACC
(observations)
Cleaning during operation the radiant part during operation. The system
Slagging is one of the most critical operating cleans the surfaces with jet spays through
problems related to the combustion of waste special rotating nozzles on hoses lowered
fuels. through the top of the boiler. The process and
the system is fully automatic.
Our solution to the slagging problem is two
fold: 1) effective boiler CFD designs with mini-
mal particle carry over and 2) advanced radi-
WasteBoost™
ant water-jet cleaning systems for cleaning of With increasing focus on power produc-
tion and favourable tariffs in many markets
there is a need for maximizing electric-
Slagging in the radiation passes ity delivery to the grid. Babcock & Wilcox
Vølund continuously works to increase the
Causes Results steam parameters and to increase power
Increase of flue gas temperatures Reduction of the operating period efficiency up to 30%.
(availability)
High temperature corrosion when Reduction of the lifetime of the WasteBoost™ is used to increase the efficiency
using special waste fuels 1’ super-heater by using an external super heater powered by
Fouling in convection heating surfaces Reduction of efficiency our updraft gasifier. The fuel can be biomass
as for examples impregnated or contaminated
Increase of spraying quantities Lost capacity and loss of production wood.
Gasifier
The operating staff gets a thorough knowl-
edge of the energy and environmental aspects
related to a WFPP facility. The operation of a
WFPP involves the handling of large amounts
of energy and significant environmental issues. WasteBoostTM - superheating of the steam parameters
Operational irregularities can have signifi- with a Vølund biomass gasifier.
MSW ü ü ü
Biomass ü ü ü
Bulky waste ü ü
Semi – hazardous ü
Waste
Industrial & c ü ü ü
Commercial ü ü ü
Heating value Low to Medium Low to High Low to High
Adaptable (to higher heating values) ü ü
Capacity size per line (t/h) 2-5-10-15-20-25-30-35-40 5-10-20-25 5-10
Staged combustion ü ü ü
VoluMix™ ü ü ü
Integrated FGR (Flue gas recirculation) ü ü
SNCR ü
AWT Features
1. Investment cost 8 88 8 88 8 88
2. O&M Cost 7 77 1 11 7 77 1 11 7 77 1 11
performance
3. Efficiency
Price vs.
4. Availability
6 66 2 22 6 66 2 22 6 66 2 22
5. Waste flexibility
6. Emissions
7. AWT modules 5 55 3 33 5 55 3 33 5 55 3 33
8.Cost-performance ratio 4 44 4 44 4 44
Babcock & Wilcox Vølund 39
ENVIRONMENTAL
- for supreme eco - efficient performance
CO, H2
H2 O C xH y CH4 , C xH y
CO, CO2
CO2,O2
Ch ... In 2005 a total of 29 modern WF-
an ar
d fo PPs are in operation in Denmark and
ga rm
sif at
Char
combusts a total of 3,3 million tons of
Ac
ica io
Raw
tiv
tio n
Py
n
Ig
o
e
ati
ro
n
bu
waste
Dr
fic
l
tio
ys
asi
rn
yi
n
s
rg n
in
o
ng
a ati
g
Ch id
zo
Cha Ash
a WFPP can produce approximate-
ly 2 MWh (75%) district heating and
Feed Discharge approximately 2/3 MWh (25%) elec-
end Primary air end
tricity.
Simplified process of the combustion process that takes place on the grate
The fate of the HCN is determined mainly by The flue gas recycling also makes it possible
the availability of oxidants, generally in the to reduce the excess air flow and control the
form of O and OH radicals. If oxygen is avail- flue gas temperature in the furnace. The re-
able, the predominant reaction product will sult is a lower flue gas loss and consequently
be NO. If oxygen is not available, as during a higher total thermal efficiency of the plant.
CFD simulation of the temperature con- staged combustion, some of the volatile ni- Moreover, the limitation of temperature peaks
tours above combustion grate and first trogen components will be converted into and a lower level of oxygen in the furnace will
pass in the boiler N2. Fuel-N in the de-volatized waste will ei- result in less NO x emission.
ther be oxidized to NO x or converted to N2
depending on the combustion conditions. Recycling of the flue gas to the combustion
zone causes both an increase of the total heat
For thermal waste treatment 5% to 50% of the capacity for the combustion gas, and conse-
nitrogen content in the waste will be converted quently a reduction of the flame temperature,
to NOx and become a part of the total contribu- and a reduction of the O2 partial pressure in
tion to the NOx emission from the plant. the combustion zone.
The physico-chemical treatment causes The process does not yield a new heavy metal
changes, not only in porosity and density, but polluted waste stream, but immobilizes the
also in the incorporation of metal ions into heavy metals in the residue. The salts are ex-
the silicate and oxide lattice of the matrix. The tracted from the residues during the process.
Sintering process is a good solution and a cost The result is a stabilized residue, which is easy
effective alternative to melting facilities with to dispose of in an environmentally safe way. Ferrox-treated APC-residues
ACC – Automatic Combustion Control system, a sys- Flue Gas Recirculation – method of decreasing
tem that optimizes the combustion process. the amount flue gas.
Combustible waste – Waste which can be com- IPPC – Integrated Pollution Prevention and Control
busted.
IPPC – Integrated Pollution Prevention and Con-
Combustion – the process of burning. trol, an EU directive.
Commercial Waste – solid waste generated by ISWA – International Solid Waste Organization
businesses and institutions. (www.iswa.org).
ETS – Emissions Trading System MJ/Nm3 – Megajoule per Normal cubic meter
NO x – nitrogen oxides are GHG and contribute to t/h –tonnes per hour
acid rain and reacts to form ground level ozone
and smog. NO x are removed with SNCR and SCR. TJ – terajoule (1012 Joule) (unit)
PCC – post combustion chamber. VoluMix™ – method of mixing flue gases by air in-
jection in the combustion chamber for optimized
PDMS – Plant Design Management System. gas blending
PFI – Private Finance Initiatives. Waste – general term for normal waste. See also
MSW.
PJ – petajoule (1015 Joule) (unit)
Waste management – Methods and processes
RDF – Refused Derived Fuel. involving the collection, transport, recovery, and
disposal of waste.
RE – Renewable energy.
WasteBoost™ – method of increasing the electri-
Refuse – another term for Waste cal efficiency on WFPP by increasing the steam
parameters to the turbine.
RES – Renewable Energy Sources.
Waste–to–Energy – is a method of extraction
SCR – Selective Catalytic Reduction, method for
of energy from waste, and defined as a combus-
reduction and removal of NO x .
tion process in which the organic fraction of
solid waste is combusted and the released heat is
Sintering – the process where powder and small
utilized to generate hot water, steam, and electric
particles of metals and ceramics melts and solidify
power, leaving the inorganic fraction (ash) as a
when heat is applied. Sintering is used to achieve
residue.
a high density and low porosity material.
Water Injection – method of controlling the tem-
Slag, bottom ash – material which is not combus-
perature in a furnace and boiler.
tible, for example, glass, scrap iron, and stone–like
material. After separation of metals etc. and siev-
WFPP – Waste Fired Power Plant.
ing the result is a product that can be reused as
construction material. WTE – see Waste–to–Energy.
SNCR – Selective Non–catalytic Reduction, Zn – Zinc
method for reduction and removal of NO x .
[1] Global Waste Management Market Report 2004, [17] Federal Ministry for the Environment, Nature Conservation and
Research and Markets, Dublin, Ireland Nuclear Safety. Waste incineration – a potential danger? Bid-
ding farewell to dioxin spouting. September 2005.
[2] UNEP, Waste on the rise
http://vitalgraphics.grida.no/waste/html//file/22-23municipal [18] Muller, Kipinen, Hupa; Combustion & Flame no. 113 1998.
rise.html
[19] Madsen O.H, New technologies for waste to energy plant,
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D.L. (1999). Sheffield University, UK 29 June – 2 July 2003.
PCDD/F emissions from uncontrolled domestic waste burn-
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China.
[4] International Energy Outlook 2005 , EIA, http://www.eia.doe.
gov/oiaf/ieo/world.html [21] Rogers J.E.L., Sarofim A.F. and Howard J.B.; Effect of underfire
air rate on a burning simulated refuse bed, Proceedings 1972
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Processes, Conference paper 6th Annual Conference on
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Miljøstyrelsen; Waste Statistics 2004,
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rates and temperatures during large particle refuse derive
[7] Amagerforbrænding, fuel - Municipal solid waste devolatilization.
Waste-to-energy plant in Copenhagen, www.amfor.dk
[24] Survey and Evaluation of Physical composition of MSW, Re-
[8] Vestforbrændingen, port on Thailand State of Pollution 2004, Public Cleansing Bureau
Waste-to-energy plant in Copenhagen, www.vestfor.dk and Pollution Control De-partment.
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Zhejiang University, 3rd i-CIPEC, Oct. 21-23 2004, Hangzhou China
[10] European Integrated Pollution Prevention and Control Bureau;
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[11] Schmidt, I., Kircherer, A., and Zwahr, H, Eco-Efficiency Analy- able Urban Energy Use for Asian Cities, February 4 & 5, 2002, East
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(Image courtesy U.S. National Aeronautics and Space
[12] Themelis, N.J., 2003, An Overview of the Global Waste-to-Ener- Administration)
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July-August 2003, p. 40-47 Wikipedia, the encyclopedia http://en.wikipedia.org
100 years with Waste Incineration, J.Swithenbank, V. Nasserzadeh Sharifi, Mathematical Modelling of
Heron Kleis, Babcock & Wilcox Vølund & Søren Dalager, RAM- Waste to Energy Plants using FLIC and FLUENT codes and Incinera-
BØLL tor Bed Modelling /FLIC Mathematical Model, Y B Yang, V N Sharifi, Y R
Goh, J Swithenbank
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41th edition, The Babcock & Wilcox Company, Barberton, Ohio, U.S.A XU Xin-hua,YANG Yue-ping,WANG Da-hui, CH4 emission and recovery
2006. from Municipal Solid Waste in China, Journal of Zhejang Univeristy
2003 http://www.zju.edu.cn/jzus/2003/0303/030319.pdf
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O ur profile
Babcock & Wilcox Vølund is one of the world’s
leading suppliers of equipment and technol-
ogies designed to convert household waste
and bio-fuels into thermal energy.
Denmark