2.

WORKING SCHEME

A. VOLTAIC CELL

START

- PUT 150 mL ZnSO4 1 M SOLUTION INTO A BEAKER AND DIP A PIECE OF

ZINC METAL INTO THE SOLUTION
- PUT 50 mL CuSO4 1M SOLUTION INTO A BEAKER AND DIP A PIECE OF
COPPER METAL INTO THE SOLUTION
- MAKE A SALT BRIDGE BY ENTERING THE KNO3 1 M SOLUTION INTO U
TUBE UNTIL FULL
- CLOSE THE MOUTH OF THE U TUBE WITH COTTON
- CONNECT SOLUTION 1 AND SOLUTION 2 WITH THE SALT BRIDGE
- CONNECT THE TWO Zn AND Cu ELECTRODES THROUGH THE
VOLTMETER BY USING CABLES AND ALLIGATOR CLAMPS
- LEAVE IT FOR A MOMENT AND RECORD THE POTENTIAL DIFFERENCE
THAT OCCURS

POTENTIAL
DIFFERENCE =
1,063 VOLT
1. ELECTROLYSIS CELL

START

- ASSEMBLING THE ELECTROLYSIS DEVICES

- PUT THE CuSO4 SOLUTION INTO A U TUBE UP TO 1,5 cm FROM THE
MOUTH TUBE
- DIP BOTH CARBON ELECTRODES INTO EACH U TUBE LEG
- CONNECT THE ELECTRODES WITH A DIRECTS CURRENT JOURCE OF 9
V FOR ABOUT 10 MINUTES
- RECORD THE CHANGES THAT OCCURS AT EACH ELECTRODE
CALCULATION

1. GIVEN :
63,5
e= = 31,75
2
w Cu = 0,248 gram
t1 = 15 MINUTES ; t2 = 30 MINUTES
I1 = 1,21 A ; I2 = 1,20 A
F = 96500
ASK : PERCENT YIELD ?
ANSWER :
- 15 MINUTES
𝑒.𝐼.𝑡
w=
𝐹
31,75 .1,21 .1800
= 96500
= 0,3583 gram
𝑤 𝐶𝑢
% YIELD = 𝑤 𝑇𝐸𝑂𝑅𝐼𝑇𝐼𝑆 x 100%
0,0018 𝑔
= 0,3583 𝑔 x 100%
= 0,5023 %
- 30 MINUTES
𝑒.𝐼.𝑡
w= 𝐹
31,75 .1,20 .1800
= 96500
= 0,6996 gram
𝑤 𝐶𝑢
% YIELD = 𝑤 𝑇𝐸𝑂𝑅𝐼𝑇𝐼𝑆 x 100%
0,0081 𝑔
= 0,6996 𝑔 x 100%
= 1,1578 %

𝑅𝑇 [𝐶𝑢]
2. ESEL = E0SEL - 𝑛𝐹 In [𝑍𝑛]
ESEL = 1,1 V – 0,01284 . In 1/1
ESEL = 1,1 V – 0
ESEL = 1,1 V (THEORYTICAL)
- TEORITICAL RESULT
𝑅𝑇 [𝐶𝑢]
ESEL = E0SEL – 𝑛𝐹 In [𝑍𝑛]
ESEL = E0SEL – 0,01284 . In 1
ESEL = 1,1 V – 0
ESEL = 1,1 V

- EXPERIMENTAL RESULT
ESEL = 1,063 V
𝑅𝑇 [𝐶𝑢]
ESEL = E0SEL – 𝑛𝐹 In [𝑍𝑛]
ESEL = E0SEL – 0,01284 . In 1
ESEL = 1,063 V – 0
ESEL = 1,063 V

DIAGRAM POURBAIX Zn
𝑅𝑇
ESEL = E0SEL – 2,303 𝑛𝐹 log [H+]
- pH 0
ESEL = -0,76 – 0,029 . 0
= -0,76
- pH 1
ESEL = -0,76 – 0,029 . 1
= -0,789
- pH 3
ESEL = -0,76 – 0,029 . 3
= -0,1847
- pH 5
ESEL = -0,76 – 0,029 . 5
- = -0,905

POURBAIX DIAGRAM
OF Zn
-0.74
-0.76 0 2 4 6
-0.78
-0.8
-0.82
E
-0.84 Series1
-0.86
-0.88
-0.9
-0.92
pH
 DIAGRAM POURBAIX Cu
𝑅𝑇
ESEL = E0SEL – 2,303 𝑛𝐹 log [H+]
- pH 0
ESEL = 0,34 – 0,029 . 0
= 0,34 V
- pH 1
ESEL = 0,34 – 0,029 . 1
= 0,31 V
- pH 3
ESEL = 0,34 – 0,029 . 3
= 0,253 V
- pH 5
ESEL = 0,34 – 0,029 . 5
= 0,195 V

POURBAIX DIAGRAM
OF Cu
-0.75
0 2 4 6
-0.8

E -0.85
Series1
-0.9

-0.95
pH