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Presented By:
Lok Tow Jie (SEZ150083)
Reaction A1:

Equivalence
Volume of Temperature of
Attempts Yield
Carbazole KI KIO3 AcOH Oil Bath

1 1.0 (1.0 g) 1.3 1.5 50 mL (0.35M) 120 °C 95 %

2 1.0 (2.0 g) 1.3 1.5 50 mL (0.35M) 120 °C 95 %
Reaction A2:

Equivalence
Volume of Temperature
Attempts Base Yield
Toluene of Oil Bath
Diiodo-Cz PPh2 Cl Pd(PPh3 )4

1 1.0 (0.5 g) 2.4 0.04 KOtBu 12 mL (0.1M) 115 °C 20 %

2 1.0 (0.5 g) 2.8 0.04 K2CO3 12 mL (0.1M) 115 °C 11 %

3 1.0 (0.5 g) 3.0 0.04 KOtBu 12 mL (0.1M) 120 °C 10 %

Reaction A3:

Equivalence
Volume of Temperature of
Attempts Yield
TPA KI KIO3 AcOH Oil Bath

1 1.0 (2.0 g) 1.3 1.5 12 mL (0.68M) 120 °C 86 %

2 1.0 (3.0 g) 1.3 1.5 18 mL (0.68M) 120 °C 86 %
Reaction A4:

Equivalence
Attempts Volume of DCB Yield
Compound 2 Compound 3 K2CO3 Cu 18-Crown-6

1 3.5 (0.0817 g) 1.0 16 3 16 4 mL (0.04M) 15 %

4.5 mL DCB
2 Microwave: Same conditions but reaction time shorten to 30 mins. 53 %
+ 0.5 mL DMSO