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  • Ammanoium Chloride and Ammonium Bisulfide Calculation

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    The document provides calculations related to the desublimation of ammonium bi-sulfide and ammonium chloride in a reactor. It gives feed rates and compositions for sulfur, nitrogen, hydrogen, and quench flows. The outputs from the reactor are total flow rate and quantities of hydrogen sulfide, ammonia, hydrogen chloride formed. It also provides mole fractions, partial pressures, equilibrium constants, and deposition temperatures.

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    The document provides calculations related to the desublimation of ammonium bi-sulfide and ammonium chloride in a reactor. It gives feed rates and compositions for sulfur, nitrogen, hydrogen, and quench flows. The outputs from the reactor are total flow rate and quantities of hydrogen sulfide, ammonia, hydrogen chloride formed. It also provides mole fractions, partial pressures, equilibrium constants, and deposition temperatures.

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    13 views2 pages

    Ammanoium Chloride and Ammonium Bisulfide Calculation

    Uploaded by

    rocap76046
    The document provides calculations related to the desublimation of ammonium bi-sulfide and ammonium chloride in a reactor. It gives feed rates and compositions for sulfur, nitrogen, hydrogen, and quench flows. The outputs from the reactor are total flow rate and quantities of hydrogen sulfide, ammonia, hydrogen chloride formed. It also provides mole fractions, partial pressures, equilibrium constants, and deposition temperatures.

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    © All Rights Reserved
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    of 2

    Ammonium Bi-Sulphide and Ammonium Chloride Desublimation Calculation

    Feed Sulphur = 0.3 wt% Feed Nitrogen


    De-Sulphurisation in the Unit = 99% De-Nitrification in the Unit
    Feed Specific Gravity = 0.8
    Feed Flow Rate (Combined) = 139977 Kg/hr 1206.7 Kmol/hr Avg Mol wt (Feed)
    Flow Rate H2 = 7036 Kg/hr 3518.0 Kmol/hr Avg Mol wt (H2)
    Quench Flow rate = 14732 Kg/hr 128.1 Kmol/hr Avg Mol wt (Quench)

    Total Reactor Out = 161745 Kg/hr 4852.8 Kmol/hr

    Quantity of Sulphur = 420 Kgs/hr Quantity of Ammonia formed


    = 13 Kmol/hr

    Mole fraction of H2S = 0.265527 Mole fraction of NH3


    Reactor Pressure = 1.8 bar Reactor Pressure
    26 psia

    Partial pressure of H2S = 6.80 psia Partial pressure of NH3

    Kp = 64.855 psia2

    Deposition Temperature = 85.0 deg C


    = 0.005 wt% Feed Chloride = 0.00003 wt%
    = 25% De-Sulphurisation in the Unit = 100%

    116
    2
    115

    = 7 Kgs/hr Quantity of HCl formed = 0.0420 Kgs/hr


    = 0 Kmol/hr = 0.0011 Kmol/hr

    = 0.3727 Mole fraction of Hcl = 0.0000002


    = 1.8 bar Reactor Pressure = 22.0 bar
    25.6 psia 312.9 psia

    = 9.5 psia Partial pressure of HCl = 0.00007 psia

    Kp = 6.89E-04 psia2

    Deposition Temperature = 120 - 125 deg C

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