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Introduction
• Compounds having similar chemical properties to benzene
are called aromatics. When two substituents are attached to the benzene ring, three
• The name aromatic is used for characteristic pleasant odor. isomeric structures are possible.
Example 2
Draw the structures of the following aromatic compounds.
m-nitrotoluene ,m-dinitrobenzene, 1,3-dichloro-5-nitrobenzene,
nitrobenzene, triphenylmethane
Isomer structures
Halogenation
Alkylation or Fridel-
Craft Reaction
Sulfonation Naphthalene
• Two benzene rings are fused together.
• Colorless, crystalline compound which sublimes easily.
• Insoluble in water but soluble in organic solvents.
• Has a sharp, aromatic odor.
Hydrogenation • Used to protect clothes from moths and to dispel the bad
odors in bathrooms.
Anthracene
Halogenation • Formed by fusing three benzene rings together in a linear
geometry.
• Colorless, crystalline compound used in the production of
paints.
• It is also used in wood preservatives, insecticides, and
coating materials.
6. Occurrence and Preparation of Benzene